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T.L. Grove

Publications and source records attributed to T.L. Grove.

5 recordsLinked to original sources

Late Holocene hydrous mafic magmatism at the Paint Pot Crater and Callahan flows, Medicine Lake Volcano, N. California and the influence of H2O in the generation of silicic magmas

This paper characterizes late Holocene basalts and basaltic andesites at Medicine Lake volcano that contain high pre-eruptive H 2 O contents inherited from a subduction related hydrous component in the mantle. The basaltic andesite of Paint Pot Crater and the compositionally zoned basaltic to andesitic lavas of the Callahan flow erupted approximately 1000 14 C years Before Present ( 14 C years B . P .). Petrologic, geochemical and isotopic evidence indicates that this late Holocene mafic magmatism was characterized by H 2 O contents of 3 to 6 wt% H 2 O and elevated abundances of large ion lithophile elements (LILE). These hydrous mafic inputs contrast with the preceding episodes of mafic magmatism (from 10,600 to ∼3000 14 C years B . P .) that was characterized by the eruption of primitive high alumina olivine tholeiite (HAOT) with low H 2 O (<0.2 wt%), lower LILE abundance and different isotopic characteristics. Thus, the mantle-derived inputs into the Medicine Lake system have not always been low H 2 O, primitive HAOT, but have alternated between HAOT and hydrous subduction related, calc-alkaline basalt. This influx of hydrous mafic magma coincides temporally and spatially with rhyolite eruption at Glass Mountain and Little Glass Mountain. The rhyolites contain quenched magmatic inclusions similar in character to the mafic lavas at Callahan and Paint Pot Crater. The influence of H 2 O on fractional crystallization of hydrous mafic magma and melting of pre-existing granite crust beneath the volcano combined to produce the rhyolite. Fractionation under hydrous conditions at upper crustal pressures leads to the early crystallization of Fe-Mg silicates and the suppression of plagioclase as an early crystallizing phase. In addition, H 2 O lowers the saturation temperature of Fe and Mg silicates, and brings the temperature of oxide crystallization closer to the liquidus. These combined effects generate SiO 2 -enrichment that leads to rhyodacitic differentiated lavas. In contrast, low H 2 O HAOT magmas at Medicine Lake differentiate to iron-rich basaltic liquids. When these Fe-enriched basalts mix with melted granitic crust, the result is an andesitic magma. Since mid-Holocene time, mafic volcanism has been dominated primarily by hydrous basaltic andesite and andesite at Medicine Lake Volcano. However, during the late Holocene, H 2 O-poor mafic magmas continued to be erupted along with hydrous mafic magmas, although in significantly smaller volumes.

California

Evidence of hydrous differentiation and crystal accumulation in the low-MgO, high-Al2O3 Lake Basalt from Medicine Lake volcano, California

The late Pleistocene Lake Basalt of Medicine Lake volcano, California is comprised of variably porphyritic basalt and basaltic andesite flows and scoria. These eruptives are similar in composition and phenocryst abundance to the low-MgO, high-Al 2 O 3 mafic magmas common in convergent margin settings. The petrogenesis of the magmas that produced the Lake Basalt has been inferred from field relations, melting experiments and subsequent major and trace element modeling. Their formation involved both hydrous differentiation and plagioclase accumulation and thus the Lake Basalt can be used to constrain the relative contributions of these processes to the production of high-Al 2 O 3 arc basalt. Phenocryst-poor lavas of the Lake Basalt formed by hydrous differentiation; their compositions and observed phenocrysts were reproduced in 1 kbar, H 2 O-saturated melting experiments. Anorthite-rich plagioclase compositions of the lavas of the Lake Basalt necessitate crystallization from melts with between 4 and 6 wt% dissolved H 2 O. Phenocryst-rich lavas of the Lake Basalt, with 18 modal% phenocrysts and greater, formed by plagioclase accumulation in magmas similar to the phenocryst-poor lavas. This interpretation is supported by the depleted incompatible element abundances and enriched Sr/Zr ratio of the more porphyritic lavas relative to the phenocryst-poor lavas. We model the formation of the Lake Basalt as a two-stage process that combines a differentiation model and a plagioclase accumulation model. Stage one involved hydrous fractionation, granitic assimilation and mixing with undifferentiated parent magma. This process generated lavas with up to 19.2 wt% A1 2 O 3 and 7 modal% phenocrysts. In stage two, plagioclase accumulated in these liquids and produced more aluminous and porphyritic lavas with up to 21.8 wt% A1 2 O 3 and 33 modal% phenocrysts.

California

Assimilation of granite by basaltic magma at Burnt Lava flow, Medicine Lake volcano, northern California: Decoupling of heat and mass transfer

At Medicine Lake volcano, California, andesite of the Holocene Burnt Lava flow has been produced by fractional crystallization of parental high alumina basalt (HAB) accompanied by assimilation of granitic crustal material. Burnt Lava contains inclusions of quenched HAB liquid, a potential parent magma of the andesite, highly melted granitic crustal xenoliths, and xenocryst assemblages which provide a record of the fractional crystallization and crustal assimilation process. Samples of granitic crustal material occur as xenoliths in other Holocene and Pleistocene lavas, and these xenoliths are used to constrain geochemical models of the assimilation process. A large amount of assimilation accompanied fractional crystallization to produce the contaminated Burnt lava andesites. Models which assume that assimilation and fractionation occurred simultaneously estimate the ratio of assimilation to fractional crystallization (R) to be >1 and best fits to all geochemical data are at an R value of 1.35 at F=0.68. Petrologic evidence, however, indicates that the assimilation process did not involve continuous addition of granitic crust as fractionation occurred. Instead, heat and mass transfer were separated in space and time. During the assimilation process, HAB magma underwent large amounts of fractional crystallization which was not accompanied by significant amounts of assimilation. This fractionation process supplied heat to melt granitic crust. The models proposed to explain the contamination process involve fractionation, replenishment by parental HAB, and mixing of evolved and parental magmas with melted granitic crust. ?? 1988 Springer-Verlag.

Contributions to Mineralogy and Petrology

The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas

At Medicine Lake Volcano, California, the compositional gap between andesite (57-62 wt.% SiO2) and rhyolite (73-74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite. Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition gap). At Mt. Mazama and Mt. St. Helens, USA and Aso Caldera and Shikotsu, Japan the amphibole-bearing assemblage was important. At Krakatau, Indonesia and Katmai, USA, an augite+orthopyroxene-bearing assemblage was important. In addition to its role in the production of a compositional gap between intermediate and rhyolitic lavas, the crystallization process increases the H2O content of the residual liquid. This rapid increase in residual liquid volatile content which results from the precipitation of a large proportion of crystalline solids may be an important factor among several that lead to explosive silicic eruptions. ?? 1986 Springer-Verlag.

Contributions to Mineralogy and Petrology