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Sharon A. Watkins

Publications and source records attributed to Sharon A. Watkins.

9 recordsLinked to original sources

Arsenic in ground water: A review of current knowledge and relation to the CALFED solution area with recommendations for needed research

Ground water with arsenic concentrations greater than the U.S. Environmental Protection Agency drinking water standard exists throughout much of the CALFED solution area. These high concentrations are of con-cern from the standpoint of both existing water supply and development of conjunctive use projects. Much is known about arsenic mobility in ground water subject to different hydrologic and geochemical conditions. However, some important knowledge gaps exist that limit the ability to design water supply projects that could prevent arsenic mobilization or promote arsenic removal from ground water. A few well studied sys-tems could provide a much better understanding of methods for preventing or eliminating high arsenic problems. Within the context of the examination of a few detailed field studies, some important research needs include: 1.) Determining the significance of metal-bridging aqueous complexes involving inorgan-ic arsenic and natural organic matter, 2.) In the con-text of in situ remediation, determining whether of metal oxides. Little is known about the quantitative significance competition of inorganic arsenic with other inorganic aqueous species in natu-ral systems. Experiments should be conducted with actual aquifer materials, as the effects of aging on arsenic desorption in laboratory studies are quite sig-nificant. 3.) Devise methods to detect and quantify rates of oxidation/reduction reactions of arsenic that are carried out by microorganisms at ambient concen-trations of arsenic and under in situ conditions. The findings from detailed field studies have the potential for greatly reducing the cost of meeting the new drinking-water standard for arsenic. The research would benefit a broad constituency.

San Francisco Estuary and Watershed Science

Updated computations and estimates of streamflows tributary to Carson Valley, Douglas County, Nevada, and Alpine County, California, 1990-2002

Rapid population growth in Carson Valley has caused concern over the continued availability of water resources to sustain future growth. The U.S. Geological Survey, in cooperation with Douglas County, began a study to update estimates of water-budget components in Carson Valley for current climatic conditions. Data collected at 19 sites included 9 continuous records of tributary streamflows, 1 continuous record of outflow from the valley, and 408 measurements of 10 perennially flowing but ungaged drainages. These data were compiled and analyzed to provide updated computations and estimates of streamflows tributary to Carson Valley, 1990-2002. Mean monthly and annual flows were computed from continuous records for the period 1990-2002 for five streams, and for the period available, 1990-97, for four streams. Daily mean flow from ungaged drainages was estimated using multi-variate regressions of individual discharge measurements against measured flow at selected continuous gages. From the estimated daily mean flows, monthly and annual mean flows were calculated from 1990 to 2002. These values were used to compute estimates of mean monthly and annual flows for the ungaged perennial drainages. Using the computed and estimated mean annual flows, annual unit-area runoff was computed for the perennial drainages, which ranged from 0.30 to 2.02 feet. For the period 1990-2002, estimated inflow of perennial streams tributary to Carson Valley totaled about 25,900 acre-feet per year. Inflow computed from gaged perennial drainages totaled 10,300 acre-feet per year, and estimated inflow from ungaged perennial drainages totaled 15,600 acre-feet per year. The annual flow of perennial streams ranges from 4,210 acre-feet at Clear Creek to 450 acre-feet at Stutler Canyon Creek. Differences in unit-area runoff and in the seasonal timing of flow likely are caused by differences in geologic setting, altitude, slope, or aspect of the individual drainages. The remaining drainages are ephemeral and supply inflow to the valley floor only during spring runoff in wet years or during large precipitation events. Annual unit-area runoff for the perennial drainages was used to estimate inflow from ephemeral drainages totaling 11,700 acre-feet per year. The totaled estimate of perennial and ephemeral tributary inflows to Carson Valley is 37,600 acre-feet per year. Gaged perennial inflow is 27 percent of the total, ungaged perennial inflow is 42 percent, and ephemeral inflow is 31 percent. The estimate is from 50 to 60 percent greater than three previous estimates, one made for a larger area and similar to two other estimates made for larger areas. The combined uncertainty of the estimates totaled about 33 percent of the total inflow or about 12,000 acre-feet per year.

Scientific Investigations Report

Evaluation of U.S. Geological Survey Monitoring-well network and potential effects of changes in water use, Newlands Project, Churchill County, Nevada

Domestic wells tapping shallow ground water are an important source of potable water for rural residents of Lahontan Valley. For this reason, the public has expressed concern over the acquisition of water rights directed by Public Law 101-618. The acquisition has resulted in removal of land from irrigation, which could cause shallow domestic wells to go dry and adversely affect shallow ground-water quality. Periodic water-level measurements and water-quality sampling at a monitoring-well network developed by the U.S. Geological Survey (USGS) provided data to evaluate the potential effects of changes in water use. The USGS, in cooperation with Churchill County, analyzed these data and the monitoring-well network to determine if the network provides an adequate means to measure the response of the shallow aquifer to changes in water use, and to determine if measurable changes have taken place. To evaluate the USGS monitoring-well network, wells were characterized by their distance from active canals or ditches, and from currently (2003) or formerly irrigated land. An analysis of historical data showed that about 9,800 acres of land have been removed from irrigation, generally from the late 1990's to 2003. Twenty-five wells in the network are within about 1 mile of fields removed from irrigation. Of the 25 wells, 13 are within 300 feet of canals or ditches where seepage maintains stable water levels. The 13 wells likely are not useful for detecting changes caused by reductions in irrigation. The remaining 12 wells range from about 400 to 3,800 feet from the nearest canal and are useful for detecting continued changes from current reductions in irrigation. The evaluation showed that of the 75 wells in the network, only 8 wells are likely to be useful for detecting the effects of future (after 2003) reductions in irrigation. Water levels at most of the monitoring wells near irrigated land have declined from 1998 to 2003 because of drought conditions and below normal releases from Lahontan Reservoir. This period coincides with the period of irrigation reductions, tending to mask declines directly caused by the reductions. It is likely that seepage from the diffuse network of canals and ditches in Lahontan Valley also masks declines caused by reductions in irrigation. In addition, the limited number of monitoring wells near land removed from irrigation, yet more than 300 feet from an active canal, does not allow a valid statistical correlation between reductions in irrigation and water-level declines. Water-level declines between the last two periods of below normal releases from Lahontan Reservoir, 1992-95 and 2000-2003, ranged from 0.4 to 4.2 feet at 11 monitoring wells near land removed from irrigation. The maximum observed water declines were about 2 to 4 feet in three wells in the southern part of Lahontan Valley. The three wells are near or surrounded by more than 1,000 acres removed from irrigation, are now more than 3,600 feet from continued irrigation, and are within 300 feet of a canal with greatly decreased use. Water levels generally rose in monitoring wells near Stillwater, Nevada, even though large amounts of nearby land were removed from irrigation. This was likely caused by conditions in 2003 that were not as dry as those in the early 1990's and additional seepage from the increased use and stage of canals for delivery of water to wetland areas. Five wells have been sampled since the late 1990's and two wells have been sampled since 2000 to evaluate long-term changes in water quality. Specific conductance of water sampled from these wells was used to evaluate changes in water quality. One well shows a large decline in specific conductance that may be related to changes in water use. In three other wells that showed a decrease in specific conductance it is uncertain if the decrease was related to changes in water use because samples were not collected shortly before and after the time land was removed

Scientific Investigations Report

Arsenic in Ground-Water Resources of the United States

Arsenic is a naturally occurring element in rocks, soils, and the waters in contact with them. Recognized as a toxic element for centuries, arsenic today also is a human health concern because it can contribute to skin, bladder, and other cancers (National Research Council, 1999). Recently, the National Research Council (1999) recommended lowering the current maximum contaminant level (MCL) allowed for arsenic in drinking water of 50 ?g/L (micrograms per liter), citing risks for developing bladder and other cancers. The U.S. Environmental Protection Agency (USEPA) will propose a new, and likely lower, arsenic MCL during 2000 (U.S. Environmental Protection Agency, 2000). This fact sheet provides information on where and to what extent natural concentrations of arsenic in ground water exceed possible new standards. The U.S. Geological Survey (USGS) has collected and analyzed arsenic in potable (drinkable) water from 18,850 wells in 595 counties across the United States during the past two decades. These wells are used for irrigation, industrial purposes, and research, as well as for public and private water supply. Arsenic concentrations in samples from these wells are similar to those found in nearby public supplies (see Focazio and others, 1999). The large number of samples, broad geographic coverage, and consistency of methods produce a more accurate and detailed picture of arsenic concentrations than provided by any previous studies.

Fact Sheet

A Retrospective Analysis on the Occurrence of Arsenic in Ground-Water Resources of the United States and Limitations in Drinking-Water-Supply Characterizations

The Safe Drinking Water Act, as amended in 1996, requires the U.S. Environmental Protection Agency (USEPA) to review current drinking-water standards for arsenic, propose a maximum contaminant level for arsenic by January 1, 2000, and issue a final regulation by January, 2001. Quantification of the national occurrence of targeted ranges in arsenic concentration in ground water used for public drinking-water supplies is an important component of USEPA's regulatory process. Data from the U.S. Geological Survey (USGS) National Water Information System (NWIS) were used in a retrospective analysis of arsenic in the ground-water resources of the United States. The analysis augments other existing sources of data on the occurrence of arsenic collected in ground water at public water-supply systems.The USGS, through its District offices and national programs, has been compiling data for many years on arsenic concentrations collected from wells used for public water supply, research, agriculture, industry, and domestic water supply throughout the United States. These data have been collected for a variety of purposes ranging from simple descriptions of the occurrence of arsenic in local or regional ground-water resources to detailed studies on arsenic geochemistry associated with contamination sites. A total of 18,864 sample locations were selected from the USGS NWIS data base regardless of well type, of which 2,262 were taken from public water-supply sources. Samples with non-potable water (dissolved-solids concentration greater than 2,000 milligrams per liter and water temperature greater than 50o Celsius) were not selected for the retrospective analysis and other criteria for selection included the amount and type of ancillary data available for each sample. The 1,528 counties with sufficient data included 76 percent of all large public water-supply systems (serving more than 10,000 people) and 61 percent of all small public water-supply systems (serving more than 1,000 and less than 10,000 people) in the United States. The arsenic data were summarized for the selected counties by associating the arsenic concentrations measured in the ground-water resource with the numbers and sizes of public water-supply systems using ground water in those counties. Targeted arsenic concentrations of 1, 2, 5, 10, 20, and 50 ug/L were exceeded in the ground-water resource associated with 36, 25, 14, 8, 3, and 1 percent respectively of all public water-supply systems accounted for in the analysis.Contributions to uncertainty such as changes in sampling methods and changes in laboratory reporting appear to be less important to the national occurrence estimates than other factors such as temporal variability in arsenic concentrations at a given well, the types of wells sampled, and density and types of sampling locations. In addition, no attempt was made to quantify arsenic concentrations in relation to depth within aquifers. With these qualifications, the USGS data represent the ground-water resource in general and are not restricted to wells currently used for public drinking-water sources. In this way, the broad spatial extent, large number of water samples, and low detection limits used for the USGS data provide a unique source of information to determine where targeted concentrations of arsenic are likely to occur in the ground-water resources within much of the United States.These results indicate USGS data can be effectively used to augment national estimates of arsenic occurrence in the nation's ground-water resources if limitations are recognized. Existing estimates of the occurrence of arsenic in ground water that are used as a source of drinking water can be supplemented with the USGS arsenic concentration data when associated with the public water-supply data base. One such supplementary application is the additional insight gained by establishing relations between arsenic concentration data in the ground-water resource and small public wat

Water-Resources Investigations Report

Water-quality assessment of the Las Vegas Valley area and the Carson and Truckee River basins, Nevada and California: Nutrients, pesticides, and suspended sediment, October 1969-April 1990

The U.S. Geological Survey National Water-Quality Assessment Program (NAWQA) is designed to provide long-term, consistent information on water quality that can be used to describe local, regional, and national conditions. The full-scale NAWQA Program, initiated in 1991, includes both study-unit and national synthesis activities. Study-unit investigations provide scientific data and interpretations that will be integrated by national synthesis studies to assess the quality of the Nation's water resources. The Nevada Basin and Range (NVBR) study unit is one of 60 proposed NAWQA study units in the United States. These riverbasin-scale areas were selected to represent large proportions of the Nation's water use and population served by public supplies, and the Nation's geographic diversity. The NVBR study unit includes the Las Vegas Valley area, approximately 1,640 mi in southern Nevada, and the Carson River Basin (3,970 mi 2 ) and Truckee River Basin (3,230 mi 2 ) in northwestern Nevada and northeastern California. The areas are typical of Basin and Range physiography. Snowfall in high mountains provides streamflow and ground-water recharge in adjacent basins. Unconsolidated basin-fill deposits commonly exceed 1,000 ft in thickness and are principal aquifers in the study unit. The study-unit climate varies from humid continental in the Sierra Nevada where the Carson and Truckee Rivers originate (annual precipitation exceeds 30 in.) to desert in terminal parts of the basins, including the Carson Desert and lower altitudes in Las Vegas Valley, where annual precipitation is less than 5 in. In 1990, Nevada had the greatest population growth rate and the fourth greatest percentage of population residing in urban areas in the Nation. More than 90 percent of Nevada's population (about 1,090,000 in 1990) resided in the study unit; the Las Vegas Valley area (about 710,000) was the most populous area. In 1990, water use in the study unit was about 1,117,000 acre-ft. Water use in the Las Vegas Valley area was about 317,000 acre-ft; 91 percent was for public supplies. Las Vegas Valley was 79 percent range land, but the 5 percent urban land use has significantly affected water resources. Water use in the Carson River Basin was 538,000 acre-ft in 1990. About 95 percent of the water was used for irrigation, although only 5 percent of the land was used for irrigated agriculture. Water use in the Truckee River Basin was 262,000 acre-ft in 1990. Public supply used about 36 percent of the water, although only 3 percent of the land was urban. Nutrients, pesticides, and suspended sediments are important water-quality issues in the study unit. Urban runoff and treated sewage effluent contribute these constituents to Las Vegas Wash and the Truckee River. Urban and agricultural activities in the Carson and Truckee River Basins are also sources of these constituents.

California, Nevada

The occurrence and transport of agricultural pesticides in the Tuttle Creek lake-stream system, Kansas and Nebraska

Median monthly atrazine concentrations detected in surface-water samples from the Big Blue River basin (1977-86) exceeded the U.S. Environmental Protection Agency health-advisory level (3.0 micrograms per liter) during May through September. Herbicide loads transported from the basin in 1986, expressed in tons and in percentage of amount applied, were alachlor (1.2 tons, 0.23 percent), atrazine (19 tons, 2.2 percent), and metolachlor (2.2 tons, 2.7 percent).

Kansas, Nebraska