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Scott N. Hamlin

Publications and source records attributed to Scott N. Hamlin.

9 recordsLinked to original sources

Dissolved solids in basin-fill aquifers and streams in the southwestern United States

The U.S. Geological Survey National Water-Quality Assessment Program performed a regional study in the Southwestern United States (Southwest) to describe the status and trends of dissolved solids in basin-fill aquifers and streams and to determine the natural and human factors that affect dissolved solids. Basin-fill aquifers, which include the Rio Grande aquifer system, Basin and Range basin-fill aquifers, and California Coastal Basin aquifers, are the most extensively used ground-water supplies in the Southwest. Rivers, such as the Colorado, the Rio Grande, and their tributaries, are also important water supplies, as are several smaller river systems that drain internally within the Southwest, or drain externally to the Pacific Ocean in southern California. The study included four components that characterize (1) the spatial distribution of dissolved-solids concentrations in basin-fill aquifers, and dissolved-solids concentrations, loads, and yields in streams; (2) natural and human factors that affect dissolved-solids concentrations; (3) major sources and areas of accumulation of dissolved solids; and (4) trends in dissolved-solids concentrations over time in basin-fill aquifers and streams, and the relation of trends to natural or human factors.

Arizona, California, Colorado, Idaho, Nevada, New ↗

Hydraulic/Chemical Changes During Ground-Water Recharge by Injection

Ground-water recharge by injection of reclaimed water is a feasible method of improving ground-water quality in the shallow aquifer system in the Palo Alto Baylands along the San Francisco Bay. Ground water was initially more saline than sea water. Reclaimed water was injected at a rate of 10 gallons per minute from June 5, 1980, to July 1, 1980. At the completion of injection, water from an observation well 31 feet from the injection well was 98 percent injected water-in essence, fresh water. An abrupt rise in the water level in the injection well of about 1.5 feet during the initial injection test was the result of a 3.5 percent density difference between injected fresh water and saline ground water. The arrival of injected water at observation wells showed the same effect, allowing monitoring of chemical and hydraulic changes entirely through water-level data. The initially sodic clays in the confining layer were expected to swell as the saline ground water (sodium source) was diluted by recharge water. The sodium ion causes excessive coordination with the hydronium ion (H 3 O + ) in the clay lattice, resulting in expansion as the saline water is diluted. X-ray diffraction analysis of clay samples soaked first in native and then in injected water showed this effect. Calcium replaces sodium and limits expansion. Prior to injection the saline ground water was supersaturated with calcite. Dilution, as injection proceeded, eventually produced an undersaturation of calcite. An increase in well specific capacity indicates that calcite dissolved from the aquifer matrix, improving hydraulic conductivity.

Groundwater↗

Occurrence and distribution of volatile organic compounds and pesticides in ground water in relation to hydrogeologic characteristics and land use in the Santa Ana basin, southern California

This report presents an evaluation of the occurrence and distribution of VOCs and pesticides in the Santa Ana ground-water basins in relation to two types of explanatory factors: hydrogeologic characteristics and land use. The Santa Ana Basin is subdivided into the San Jacinto, the Inland, and the Coastal ground-water basins. Most wells sampled were deep and used for public supply. Data from regional studies were used to evaluate the occurrence and distribution of pesticides and volatile organic compounds (VOCs) in relation to hydrogeologic characteristics and land uses that could potentially explain variations between basins. Additional data from special studies (flow path and aquifer susceptibility) were used to evaluate potential factors affecting water quality for individual basins. The hydrogeologic characteristics evaluated in this report were hydrogeologic setting, ground-water age, depth to the top of the well screen (top of well perforations), and proximity to engineered recharge facilities. Urban land use, agricultural land use, and population density were characterized within a 500-meter radius of sampled wells and at the basin scale. Aquifers in the San Jacinto Basin are generally unconfined, and major land-use categories are urban (33 percent), agricultural (37 percent), and undeveloped (25 percent). Recharge is primarily from the overlying landscape, but engineered recharge is locally important in the Hemet area. VOCs and pesticides were detected more frequently in younger ground water (less than 50 years old) than in older ground water, and more frequently in shallower wells than deeper wells; the numbers of VOCs and pesticides detected also were significantly higher in the younger ground water and in the shallower wells. In the Hemet area of the San Jacinto Basin, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These patterns illustrate the importance of proximity to sources of recharge in relation to the occurrence and distribution of VOCs and pesticides in ground water. Aquifers in the Inland Basin also are generally unconfined, and the major land-use category is urban (58 percent), with lesser amounts of agricultural (13 percent) and undeveloped (28 percent) land. Recharge is from engineered facilities that utilize local runoff and imported water and from vertical infiltration. VOCs and pesticides were detected more frequently in younger ground water than in older ground water, and more frequently in shallower wells than deeper wells. The number of VOCs detected per well also was significantly higher in the younger ground water and in the shallower wells. Several solvent plumes extending between 5 and 10 kilometers illustrate the large distances that contaminants travel in basins with intensive use of ground water. Aquifers in the Coastal Basin, in contrast to the other basins, are generally confined. Land use in the basin is largely urban (80 percent), with lesser amounts of agricultural (7 percent) and undeveloped (12 percent) land. Recharge is primarily from engineered facilities that utilize water diverted from the Santa Ana River and imported water. Consequently, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These compounds were also detected more frequently in the unconfined area than in the confined area of the basin. In the confined area, the numbers of VOCs and pesticides detected per well were not significantly different in wells with shallower and deeper screens. This distribution reflects the dominance of lateral flow and insulation from overlying land use in the confined aquifers of the Coastal Basin. In the unconfined area of the Coastal Basin, the numbers of VOCs and pesticides detected per well were significantly higher in shallower wells than in deeper wells. VOC and pesticide detections were not statist

Scientific Investigations Report↗

Water quality in the Santa Ana Basin, California, 1999-2001

This report contains the major findings of a 1999-2001 assessment of water quality in the Santa Ana River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live and how that water quality compares to other areas across the Nation. The water-quality conditions in the Santa Ana River Basin summarized in this report are discussed in detail in other reports that can be accessed from http://ca.water.usgs.gov/ sana_nawqa/. Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report in addition to other reports in this series from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗

Reconnaissance of acid drainage sources and preliminary evaluation of remedial alternatives at the Copper Bluff mine, Hoopa Valley Reservation, California

Acidic drainage from the inactive Copper Bluff mine cascades down a steep embankment into the Trinity River, on the Hoopa Valley Reservation in northern California. The Copper Bluff mine produced about 100,000 tons of sulfide-bearing copper-zinc-gold-silver ore during 1957–1962. This report summarizes the results of a water-resources investigation begun by the U.S. Geological Survey in 1994 with the overall objective of gathering sufficient geochemical, hydrologic, and geologic information so that a sound remediation strategy for the Copper Bluff mine could be selected and implemented by the Hoopa Valley Tribe. This study had the following specific objectives: (1) monitor the quality and quantity of the mine discharge, (2) determine seasonal variability of metal concentrations and loads, (3) map and sample the underground mine workings to determine sources of flow and suitability of mine plugging options, and (4) analyze the likely consequences of various remediation and treatment options. Analysis of weekly water samples of adit discharge over parts of two wet seasons (January to July 1995 and October 1995 to May 1996) shows that dissolved copper (Cu) and zinc (Zn) concentrations (in samples filtered with 0.20-micrometer membranes) varied systematically in a seasonal pattern. Metal concentrations increased dramatically in response to the first increase in discharge, or first flush, early in the wet season. The value of Zn/Cu in the adit discharge exhibited systematic seasonal variations; an annual Zn/Cu cycle was observed, beginning with values between 3 and 5 during the main part of the wet season, rising to values between 6 and 10 during the period of lowest discharge late in the dry season, and then dropping dramatically to values less than 3 during the first-flush period. Values of pH were fairly constant in the range of 3.1 to 3.8 throughout the wet season and into the beginning of the dry season, but rose to values between 4.5 and 5.6 during the period of lowest discharge, from October to early December 1995. Underground reconnaissance was conducted once during dry-season conditions (September 1995) and twice during wet-season conditions (March 1995 and March 1996). The main tunnel was accessed to a distance of about 600 feet from the portal entrance. Water samples were collected at nine locations along the floor of the main tunnel and from several ore shoots to evaluate the contributions of water and dissolved constituents from different portions of the mine. Values of pH ranged from 2.5 to 6.4 at different underground locations, concentrations of copper ranged from 0.020 to 44 mg/L (milligram per liter), zinc from 6.3 to 160 mg/L, and cadmium from 0.010 to 0.47 mg/L. Discharge from the ore shoots ranged from less than 1 gallon per minute to more than 30 gallons per minute and was always a small component of the total mine flow compared with the tunnel floor drainage. During March 1996, the main flow originated in the northernmost portion of the underground workings (inaccessible) and mixed with an unknown quantity of water upwelling from flooded lower workings. High-water marks observed on the tunnel walls indicate that past blockages impounded more than 100,000 gallons of water. Sudden release of a large volume of metal-rich water could have serious effects on fish and other aquatic resources in the Trinity River. Because of the hydrogeologic setting, mine plugging is not likely to offer an effective long-term solution to the problem of acid mine drainage at the Copper Bluff mine. The underground workings are close to a state highway and underlie a 500-foot-high bluff with highly fractured rocks that seep during the wet season. Total plugging likely would result in additional uncontrolled seepage and could potentially destabilize the highway. Partial plugging to restrict flow during periods of highest discharge may provide benefits in terms of reduced risk of catastrophic release without the additional risks associated with total plugging. Passive water treatment methods such as wetlands or anoxic limestone drains are unlikely to succeed at the Copper Bluff mine because of the lack of available space. A covered conveyance for the discharge directly from the mine portal to the Trinity River is a low-cost remedial alternative that would not reduce metal loadings to the Trinity River, but would reduce pathways of metal exposure to humans and wildlife. Lime neutralization or innovative, active water treatment methods such as bioreactors represent high-cost remedial alternatives that likely would be successful if sufficient resources were available for adequate design, testing, construction, long-term maintenance, and sludge disposal.

California↗

Ground-water quality in the Santa Ana Watershed, California: Overview and data summary

Water-quality samples were collected from 207 wells in the Santa Ana Basin in the Coastal Range Province of southern California to assess the occurrence and distribution of dissolved constituents in ground water as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. These wells were sampled during eight studies from 1999 to 2001 that were designed to sample the used water resource at different scales: (1) three studies characterized water quality at a regional scale; (2) two studies focused on spatial and temporal variations in water quality along flow paths; (3) a land-use study focused on evaluation of water quality in shallow ground water; and (4) two studies assessed aquifer susceptibility to contamination. The Santa Ana Basin is divided into the Coastal Basin, the Inland Basin, and the San Jacinto Basin. The Coastal Basin includes a relatively small unconfined recharge area and a relatively large confined area where ground-water pumping is the primary source of discharge. Land use is almost entirely urban. The Inland Basin is predominantly unconfined and land use is urban and agricultural. The San Jacinto Basin is largely unconfined and land use is mostly agricultural. Water-quality data discussed in this report are compared with U.S. Environmental Protection Agency (EPA) drinking-water standards, both primary and secondary. Most exceedances of maximum contaminant levels (MCLs) occurred in the shallow, coastal monitoring wells that tap ground water not used for water supply. Water from several irrigation wells in the Inland and San Jacinto basins exceeded the 10 mg/L (milligrams per liter) MCL for nitrate. Water from some wells exceeded secondary MCLs for manganese (50 μg/L [micrograms per liter]) and iron (300 μg/L) and (or) proposed MCLs for arsenic (10 μg/L) and uranium (30 μg/L). Of the 94 production wells sampled for trace elements, 3 irrigation wells in the Coastal Basin produced water that exceeded the secondary MCL for manganese. Water from production wells sampled in all three subbasins exceeded the proposed MCL for radon (300 pCi/L [picocuries per liter]). Pesticides were detected above the laboratory reporting limit (LRL) in 50 percent of the production and monitoring wells sampled in the Santa Ana Basin. Deethylatrazine, simazine, atrazine, tebuthiuron, and prometon were the five most commonly detected pesticides in the current USGS studies. All pesticide concentrations detected in these studies were below MCLs established by the EPA. Volatile organic compounds (VOCs) were detected in 115 wells (56 percent) of the 207 wells sampled. Of the 38 VOCs detected, only 13 were detected in more than five wells. The most commonly detected VOCs, in order of detection frequency, were chloroform; trichloroethlyene, TCE; 1,1,1-trichloroethane, TCA; trichlorofluoromethane, CFC 11; 1,1,2-trichloro-1,2,2-trifluoroethane, CFC 113; tetrachloroethylene, PCE; bromodichloromethane; methyl tert-butyl ether, MTBE; 1,1-dichloroethene, 1-1-DCE; and 1,2- dichloroethene, 1,2-DCE. The only exceedances of EPA MCLs for VOCs occurred in six irrigation wells and in two deep monitoring wells sampled in the Inland Basin.

California↗

Santa Ana Basin

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Fact Sheet↗

Water-quality reconnaissance of ground water in the inhabited outer islands of Chuuk State, Federated States of Micronesia, 1984-85

A reconnaissance of ground-water quality in 24 inhabited outer islands in Chuuk State was made between January 1984 and October 1985. Most of the islands are part of low-lying coral atolls within the Western, Namonuito, Hall, and Mortlock Island Groups. A total of 648 wells were located and sampled for temperature and specific conductance. A few miscellaneous sites such as taro patches also were sampled. The nitrate concentration was determined for 308 water samples. To develop a relation between specific conductance and chloride concentration, the chloride concentration was determined for 63 water samples. In addition, 21 water samples were analyzed for major and trace constituent ion concentrations. Chloride and nitrate are the primary constituents affecting the potability of ground water in the inhabited outer islands of Chuuk State. The source of chloride in ground water is seawater, whereas nitrate is derived from plant and animal waste materials. The chloride concentrations in many well waters exceed the World Health Organization guideline for drinking water, particularly in wells near the shoreline or on small islands. In addition, the nitrate concentrations in some well waters exceeded the World Health Organization guideline for drinking water.

Chuuk State↗