Meteoric water-basalt interaction in northeastern Iceland; methods and chemical analyses
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Open-File Report↗
Geology topics
S.L. Rettig
Publications and source records attributed to S.L. Rettig.
Geochemistry of Great Salt Lake, Utah I: Hydrochemistry since 1850
The hydrochemistry of Great Salt Lake, Utah, has been defined for the historic period, 1850 through 1982, from published data combined with new observations. The water balance depends largely on river inflow, atmospheric precipitation onto the lake surface and evaporation. Input of the major solutes can best be accounted for by mixing dilute calcium-bicarbonate type river waters with NaCl-dominated hydrothermal springs. Prior to 1930, lake concentrations fluctuated inversely with lake volume in response to small climatic variations. Since then, salt precipitation and dissolution have significantly modified lake brine compositions and have led to density stratification and the formation of brine pockets of differing composition. Brine mixing has become an important component of brine evolution. We have used calculated evaporation curves with mineral precipitation and dissolution to clarify these processes. Pore fluids represent important storage for solutes. Solute profiles can be modeled by simple one-dimensional diffusion calculations. Short-term historic variations in lake composition affect shallow pore fluids in the upper 2 metres of sediment. ?? 1985.
Utah↗
Great Salt Lake, and precursors, Utah: The last 30,000 years
Sediment cores up to 6.5 m in length from the South Arm of Great Salt Lake, Utah, have been correlated. Radiocarbon ages and volcanic tephra layers indicate a record of greater than 30,000 years. A variety of approaches have been employed to collect data used in stratigraphic correlation and lake elevation interpretation; these include acoustic stratigraphy, sedimentologic analyses, mineralogy, geochemistry (major element, C, O and S isotopes, and organics), paleontology and pollen. The results indicate that prior to 32,000 year B.P. an ephemeral saline lake-playa system was present in the basin. The perennial lake, which has occupied the basin since this time, rose in a series of three major steps; the freshest water conditions and presumably highest altitude was reached at about 17,000 year B.P. The lake remained fresh for a brief period, followed by a rapid increase in salinity and sharp lowering in elevation to levels below that of the present Great Salt Lake. The lake remained at low elevations, and divided at times into a north and south Basin, until about 8,000 year B.P. Since that time, with the exception of two short rises to about 1290 m, the lake level has remained near the present elevation of 1280 m. ?? 1984 Springer-Verlag.
Contributions to Mineralogy and Petrology↗
Progress report on lithium-related geologic investigations in Bolivia
The September 1, 1981, Samoa Islands Region earthquake occurred at the extreme northern end of the Tonga arc in a region where the Pacific plate may be disjointed along a hinge fault. In the last 50 years, magnitude 7 or greater earthquakes have occurred in this region on the average of once every six years, but four 7+ events have now occurred within the last six years. The mainshock was preceded about two hours earlier by a foreshock that was used as a calibration event for the Joint Epicenter Determination relocation of the mainshock and nearby seismicity occurring within a period seven months prior to and one week after the mainshock. The foreshock, better-located events of the prior seismicity, and most aftershocks are concentrated in a group near the mainshock epicenter, but several more distant aftershocks suggest that the aftershock zone may have been as large as 125 km in length and trended about S35?E. Identification of depth phases from a full suite of broadband records gives source depths of 25-3km for the mainshock and 29.5?3 km for the foreshock using a JB earth model. Source parameters were determined for the mainshock utilizing WWSSN analog and GDSN digital data. The preferred fault plane solution based on P-wave first motion data is a south by southwesterly steeply dipping normal fault, remarkably similar to the mechanism reported by Johnson and Molnar (1972) for the nearby earthquake of April 20, 196B. A waveform inversion technique described by Sipkin (1982), when applied to long-period P waveforms, gives an 'average' point source solution for a purely deviatoric moment rate tensor at a preferred source depth of 22 km. Very similar results were obtained from long-period GDSN body-wave and mantle-wave data using a centroid-moment tensor inversion technique described in Dziewonski, and others (1981). Both techniques provide solutions very close to a double couple source with a south by southwesterly shallow-dipping normal fault mechanism. To obtain the scalar mantle wave moment, GDSN vertical and transverse records 20,000 see in length were processed as described by Buland and Taggart (1981). Averaging all the data from Rayleigh and Love waves yields an estimate of 3.8 x 10^27 dyne-cm (as compared to about 1.9 x 10^27 from body-wave moment tensor inversions) or a moment magnitude (Mr) of 7.6. For the portion of the waveform analysed (50-5B sec), the body-wave inversion performed by Sipkin gives a source time function of duration approximately 28 sec with two peaks in activity. Simultaneous analysis of short-period records, and broadband ground displacements and velocities, a method described by Harvey and Choy (1982) and Choy and Boatwright (1981) revealed a complex rupture consisting of two subevents, of about the same moment, separated in time by about 25 sec, and with durations of about 25 sec each. The two peaks in activity resolved by the body-wave moment tensor inversion correspond to the first of these subevents.
Open-File Report↗
Geochemical evolution of brines in the Salar of Uyuni, Bolivia.
Recent analyses of brines from the Salars of Uyuni and Coipasa have been compared with published data for Lakes Titicaca and Poopo to evaluate solute compositional trends in these remnants of two large Pleistocene lakes once connected by overflow from the N to the S of the Bolivian Altiplano. From Titicaca to Poopo the water shows an increase in Cl and N somewhat greater than the total solutes. Ca and SO4 increase to a lesser extent than total dissolved solids, and carbonate species are relatively constant. Between Poopo and Coipasa proportions of Ca, SO4 and CO3 continue to decrease. At Coipasa and Uyuni, the great salars frequently evaporate to halite saturation. Halite crystallization is accompanied by an increased K, Mg and SO4 in residual brines. - from Authors
Chemical Geology↗
Interstitial brines in playa sediments
Study of several closed drainages in the Great Basin has shown that the interstitial solutions of shallow, fine-grained playa deposits store a large quantity of dissolved solids and are often more concentrated than associated lakes and ponds, except in peripheral zones of stream or ground-water inflow. These interstitial fluids, when compared with local runoff, impoundments, or spring waters, commonly have a distinctive ionic composition which sometimes cannot be explained by either simple mixing of surface and subsurface inflow or by evaporative concentration. At Abert Lake, Oregon, the interstitial solute concentrations increased with depth to values as much as five times greater than the lake, except where springs indicate significant ground-water input. Where Na + , Cl, and CO 2 species constitute more than 90% of the solutes, Na + Cl − "> Na+Cl− ratios in the lake water are lower than in interstitial solutions of bottom cores and higher than in playa fluids. At the same time, Na + K + "> Na+K+ ratios are highest in the fluids of lake bottom muds and lowest in playa interstitials. In deeper playa profiles, interstitial Na + Cl − "> Na+Cl− tended to decrease with depth (5 ft. maximum). In the Abert Lake area, as in other parts of the western Great Basin, Na + Cl − "> Na+Cl− ratios are indicative of total CO 2 in solution and the effects of organic decay in surficial sediments. These ratios, coupled with data on silica and bulk density, show that higher P CO2 accompanying decay promotes silicate dissolution and hydrogen ion exchange, stripping alkalis from sediment which had preferentially adsorbed K + when entering the lake. On subsequent loss of pore fluid in the playa regime, silica initially released to solution in the lake environment is readsorbed on dissolution products.
Oregon↗
Silica in alkaline brines
Analysis of sodium carbonate-bicarbonate brines from closed basins in volcanic terranes of Oregon and Kenya reveals silica contents of up to 2700 parts per million at p H's higher than 10. These high concentrations of SiO 2 can be attributed to reaction of waters with silicates, and subsequent evaporative concentration accompanied by a rise in p H. Supersaturation with respect to amorphous silica may occur and persist for brines that are out of contact with silicate muds and undersaturated with respect to trona; correlation of SiO 2 with concentration of Na and total CO 2 support this interpretation. Addition of more-dilute waters to alkaline brines may lower the p H and cause inorganic precipitation of substantial amounts of silica.
Science↗