Geology topics
Publications and source records attributed to S. Michael Linhart.
Water resources data for Iowa for the 2004 water year consists of records of ground water levels and water quality of ground-water wells. This report volume contains water-level records for 163 ground-water observation wells; water-quality data for 147 municipal wells; and precipitation-quality data for 2 precipitation sites.
This volume of the annual hydrologic data report of Iowa is one of a series of annual reports that document hydrologic data gathered from the U.S. Geological Survey’s surface- and ground-water data-collection networks in each State, Puerto Rico, and the Trust Territories. These records of streamflow, ground-water levels, and quality of water provide the hydrologic information needed by local, State, and Federal agencies, and the public for developing and managing our Nation’s land and water resources. This report is the culmination of a concerted effort by dedicated personnel of the U.S. Geological Survey who collected, compiled, analyzed, verified, and organized the data, and who typed, edited, and assembled the report. The authors had primary responsibility for assuring that the information contained herein is accurate, complete, and adheres to U. S. Geological Survey policy and established guidelines.
Water resources data for Iowa for the 2003 water year consists of records of ground water levels and water quality of ground-water wells. This report volume contains water-level records for 166 ground-water observation wells; water-quality data for 150 municipal wells; and precipitation-quality data for 2 precipitation sites.
The goal of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is to assess the status and trends in the quality of the Nation's surface and ground water, and to better understand the natural and human factors affecting water quality. The Eastern Iowa Basins study unit encompasses an area of about 50,500 square kilometers (19,500 square miles) in eastern Iowa and southern Minnesota and is one of 59 study units in the NAWQA program. Land-use studies are an important component of the NAWQA program, and are designed to assess the concentration and distribution of water-quality constituents in recently recharged ground water associated with the most significant land use and hydrogeologic settings within a study unit. The focus of the land-use study in the Eastern Iowa Basins study unit is agricultural and urban land uses and alluvial aquifers. Agriculture is the dominant land use in the study unit. Urban areas, although not extensive, represent important potential source areas of contaminants associated with residential, commercial, and industrial activities. Alluvial aquifers are present throughout much of the study unit, and constitute a major ground-water supply that is susceptible to contamination from land-use activities. Ground-water samples were collected from monitoring wells at 31 agricultural and 30 urban sites in the Eastern Iowa Basins study unit during June-August 1997 to evaluate the effects of land use and hydrogeology on the water quality of alluvial aquifers. Calcium, magnesium, and bicarbonate were the dominant ions in most samples and were likely derived from solution of carbonate minerals (calcite and dolomite) present in alluvial detrital deposits. Tritium-based ages indicate ground water was most likely recharged after the 1950's at all but one sampling site. Agricultural and urban land-use areas have remained relatively stable in the study area since the 1950's, therefore the effects of current land use should be reflected in ground water sampled during this study. Sodium and chloride concentrations were significantly higher in samples from urban areas, where roads are more numerous and road salts may be more frequently applied, than in agricultural areas. Nitrate was detected in 94 percent of samples from agricultural areas and 77 percent of samples from urban areas. Nitrate concentrations were significantly higher in agricultural areas than in urban areas and exceeded the U.S. Environmental Protection Agency maximum contaminant level for drinking water (10 milligrams per liter as N) in 39 percent of samples from agricultural areas. Nitrate concentrations in samples from urban areas did not exceed the maximum contaminant level. Greater usage of fertilizers in agricultural areas most likely contributes to higher nitrate concentrations in samples from those areas. Pesticides were detected in 84 percent of samples from agricultural areas and 70 percent from urban areas. Atrazine and metolachlor were the most frequently detected pesticides in samples from agricultural areas; atrazine and prometon were the most frequently detected pesticides in samples from urban areas. None of the pesticide concentrations exceeded U.S. Environmental Protection Agency maximum contaminant levels or lifetime health advisories for drinking water. Pesticide degradates were detected in 94 percent of samples from agricultural areas and 53 percent from urban areas. Metolachlor ethane sulfonic acid and deethylatrazine were the most frequently detected metabolites in samples from agricultural areas; metolachlor ethane sulfonic acid and alachlor ethane sulfonic acid were the most frequently detected degradates in samples from urban areas. Total degradate concentrations were significantly higher in samples from agricultural areas than in samples from urban areas. Total pesticide concentrations (parent compounds) tended to be higher in samples from agricultural areas; however, this difference was not statistically significant. Degradates constituted the major portion of the total residue concentration in the alluvial aquifer. Volatile organic compounds were detected in 40 percent of samples from urban areas and 10 percent from agricultural areas. Methyl tert-butyl ether was the most commonly detected volatile organic compound and was present in 23 percent of samples from urban areas. Elevated concentrations (greater than 30 micrograms per liter) of methyl tert-butyl ether and BTEX compounds (benzene, toluene, ethylbenzene, and xylene) in two samples from urban areas suggest the possible presence of point-source gasoline leaks or spills. Factors other than land use may contribute to observed differences in water quality between and within agricultural and urban areas. Nitrate, atrazine, deethylatrazine, and deisopropylatrazine concentrations were significantly higher in shallow wells with sample intervals nearer the water table and in wells with thinner cumulative clay thickness above the sample intervals, suggesting that longer flow paths allow for greater residence time and increase opportunities for sorbtion, degradation, and dispersion which may contribute to decreases in nutrient and pesticide concentrations with depth. Nitrogen speciation was influenced by redox conditions. Nitrate concentrations were significantly higher in ground water with dissolved-oxygen concentrations in excess of 0.5 milligrams per liter. Ammonia concentrations were higher in ground water with dissolved-oxygen concentrations of 0.5 milligrams per liter or less, however, this relation was not statistically significant. The amount of available organic matter may limit denitrification rates. Elevated nitrate concentrations (greater than 2.0 mg/L) were significantly related to lower dissolved organic carbon concentrations in water samples from both agricultural and urban areas. A similar relation between nitrate concentrations (in water) and organic carbon concentrations (in aquifer material) also was observed but was not statistically significant.
The quality of shallow alluvial ground water that is used for domestic supplies in the Wapsipinicon, Cedar, Iowa, and Skunk River Basins (Eastern Iowa Basins) is described. Water samples from 32 domestic-supply wells were collected from June through July 1998. This study of ground-water quality in alluvial aquifers in the Eastern Iowa Basins is part of the U.S. Geological Survey's National Water-Quality Assessment Program. Calcium and bicarbonate were the dominant ions in solution, likely derived from the dissolution of carbonate minerals in the alluvial aquifer material. Concentrations of iron exceeded the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level (300 micrograms per liter) for drinking water in 53 percent of the samples, and 50 percent of the samples exceeded the Secondary Maximum Contaminant Level for manganese (50 micrograms per liter). pH and alkalinity increased and sulfate concentrations decreased with increasing well depth. Nitrite plus nitrate nitrogen was detected in 53 percent of the samples and exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 milligrams per liter for drinking water in 13 percent of the samples. Nitrite plus nitrate nitrogen concentrations were negatively correlated with well depth and positively correlated with percentage of oxygen saturation. Ammonia plus organic nitrogen concentrations were positively correlated with well depth, and ratios of nitrite plus nitrate to ammonia were positively correlated with percentage of oxygen saturation. The majority of samples, 72 percent, contained water recharged since the early 1950's. The recharge date of water was earlier in deeper wells. Nitrite plus nitrate and total pesticide concentrations were greater in more recently recharged water. Eight pesticides and eight pesticide metabolites were detected in ground-water samples. Atrazine was the most commonly detected pesticide, and metolachlor ethanesulfonic acid was the most commonly detected metabolite. No pesticide detections exceeded U.S. Environmental Protection Agency drinking-water Maximum Contaminant Levels. The effects of land use on ground-water quality also were examined. There was a positive correlation between percentage of land used for soybean production and concentrations of metolachlor, metolachlor ethanesulfonic acid, and metolachlor oxanilic acid in ground-water samples. Data from this study and from previous studies in the Eastern Iowa Basins were compared statistically by well type (domestic, municipal, and monitoring wells). Well depths were significantly greater in domestic and municipal wells than in monitoring wells. pH, calcium, sulfate, chloride, and atrazine concentrations were significantly higher in municipal-well samples than in domestic-well samples. pH and sulfate concentrations were significantly higher in municipal-well samples than in monitoring-well samples. Ammonia was significantly higher in domestic-well samples than in monitoring-well samples, chloride was significantly higher in monitoring-well samples than in domestic-well samples, and fluoride was significantly higher in domestic-well samples than in municipal-well samples.