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Geology topics

Roger L. Hothem

Publications and source records attributed to Roger L. Hothem.

At least 19 recordsLinked to original sources
USGS2016

Nest survival is influenced by parental behaviour and heterospecifics in a mixed-species colony

Studies of avian nest success often focus on examining influences of variation in environmental and seasonal factors. However, in-depth evaluations can also incorporate variation in individual incubation behaviour to further advance our understanding of avian reproductive ecology. We examined these relationships in colonially nesting Black-crowned Night-Herons Nycticorax nycticorax using intensive video-monitoring methods to quantify incubation behaviours. We modelled nest survival as a function of both extrinsic factors and incubation behaviours over a 3-year period (2010–12) on Alcatraz Island, USA. Model-averaged parameter estimates indicated that nest survival increased as a function of greater incubation constancy (% of time spent incubating eggs within a 24-h period), and average daily precipitation throughout the nesting stage. Common Ravens Corvus corax are the only known nest predator of Night-Herons on Alcatraz Island, as on many other coastal Pacific islands. We also investigated the effects of heterospecific nesting of California Gulls Larus californicus and Western Gulls Larus occidentalis in a mixed-species colony with Night-Herons, based on nesting proximity data collected over a 2-year period (2011–12). This second analysis indicated that, in addition to incubation behaviours, nesting heterospecifics are an important factor for explaining variation in Night-Heron nest survival. However, contrary to our original expectation, we found that Night-Herons experienced increased nest survival with increasing distance from gull colony boundaries. These results may apply to other areas with multiple colonial nesting species and similar predator communities and climatic patterns.

Ibis↗
USGS2015

The effects of heterospecifics and climatic conditions on incubation behavior within a mixed-species colony

Parental incubation behavior largely influences nest survival, a critical demographic process in avian population dynamics, and behaviors vary across species with different life history breeding strategies. Although research has identified nest survival advantages of mixing colonies, behavioral mechanisms that might explain these effects is largely lacking. We examined parental incubation behavior using video-monitoring techniques on Alcatraz Island, California, of black-crowned night-heron Nycticorax nycticorax (hereinafter, night-heron) in a mixed-species colony with California gulls Larus californicus and western gulls L. occidentalis . We first quantified general nesting behaviors (i.e. incubation constancy, and nest attendance), and a suite of specific nesting behaviors (i.e. inactivity, vigilance, preening, and nest maintenance) with respect to six different daily time periods. We employed linear mixed effects models to investigate environmental and temporal factors as sources of variation in incubation constancy and nest attendance using 211 nest days across three nesting seasons (2010&ndash;2012). We found incubation constancy (percent of time on the eggs) and nest attendance (percent of time at the nest) were lower for nests that were located < 3 m from one or more gull nest, which indirectly supports the predator protection hypothesis, whereby heterospecifics provide protection allowing more time for foraging and other self-maintenance activities. To our knowledge, this is the first empirical evidence of the influence of one nesting species on the incubation behavior of another. We also identified distinct differences between incubation constancy and nest attentiveness, indicating that these biparental incubating species do not share similar energetic constraints as those that are observed for uniparental species. Additionally, we found that variation in incubation behavior was a function of temperature and precipitation, where the strength of these effects was dependent on the time of day. Overall, these findings strengthen our understanding of incubation behavior and nest ecology of a colonial-nesting species.

California↗
USGS2015

Environmental assessment of water, sediment, and biota collected from the Bear Creek watershed, Colusa County, California

The Cache Creek watershed lies within California's North Coast Range, an area with abundant geologic sources of mercury (Hg) and a long history of Hg contamination (Rytuba, 2000). Bear Creek, Cache Creek, and the North Fork of Cache Creek are the major streams of the Cache Creek watershed, encompassing 2978 km 2 . The Cache Creek watershed contains soils naturally enriched in Hg as well as natural springs (both hot and cold) with varying levels of aqueous Hg (Domagalski and others, 2004, Suchanek and others, 2004, Holloway and others 2009). All three tributaries are known to be significant sources of anthropogenically derived Hg from historic mines, both Hg and gold (Au), and associated ore storage/processing sites and facilities (Slotton and others, 1995, 2004; CVRWQCB, 2003; Schwarzbach and others, 2001; Gassel and others, 2005; Suchanek and others., 2004, 2008a, 2009). Historically, two of the primary sources of mercury contamination in the upper part of Bear Creek have been the Rathburn and Petray Hg Mines. The Rathburn Hg mine was discovered and initially mined in the early 1890s. The Rathburn and the more recently developed Petray open pit mines are localized along fault zones in serpentinite that has been altered and cut by quartz and chalcedony veins. Cold saline-carbonate springs are located perepheral to the Hg deposits and effluent from the springs locally has high concentrations of Hg (Slowey and Rytuba, 2008). Several ephemeral tributaries to Bear Creek drain the mine area which is located on federal land managed by the U.S. Bureau of Land Management (USBLM). The USBLM requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in sediment, water, and biota to establish baseline information prior to remediation of the Rathburn and Petray mines. Samples sites were established in Bear Creek upstream and downstream from the mine area. This report is made in response to the USBLM request, the lead agency mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to the possible removal of Hg-contaminated mine waste from Bear Creek. This report summarizes data obtained from field sampling of water, sediment, and biota in Bear Creek, above input from the mine area and downstream from the Rathburn-Petray mine area to the confluence with Cache Creek. Our results permit a preliminary assessment of the chemical constituents that could elevate levels of monomethyl Hg (MMeHg) in Bear Creek and its uptake by biota and provide baseline information for comparison to conditions after mine remediation is completed.

California↗
USGS2015

Concentrations of metals and trace elements in aquatic biota associated with abandoned mine lands in the Whiskeytown National Recreation Area and nearby Clear Creek watershed, Shasta County, northwestern California, 2002-2003

Park management of the Whiskeytown National Recreation Area, in northwestern California, identified a critical need to determine if mercury (Hg) or other elements originating from abandoned mines within the Upper Clear Creek watershed were present at concentrations that might adversely affect aquatic biota living within the park. During 2002&ndash;03, the U.S. Geological Survey, in cooperation with the National Park Service, collected aquatic invertebrates, amphibians, and fish, and analyzed them for Hg, cadmium, zinc, copper, and other metals and trace elements. The data from the biota, in conjunction with data from concurrent community bioassessments, habitat analyses, water quality, and concentrations of metals and trace elements in water and sediment, were used to identify contamination &ldquo;hot spots.&rdquo; In 2002, we selected collection sites within the study area based on the presence of historical mines and results from sampling of bed sediment in 2001. In 2003, collection sites were selected based on sediment data as well as data on water and biota from this study in 2002. Eleven sites were sampled in both 2002 and 2003, 11 sites were sampled only in 2002, and 14 sites were sampled only in 2003. Comparisons of sites within the Upper Clear Creek watershed indicated that most of the more contaminated sites were outside of the park boundaries, especially at sites within the French Gulch, Cline Gulch, and Whiskey Creek watersheds. The site with the highest overall contamination within the park, based on both fish and invertebrate data, was WLCC, a site on Willow Creek impacted by acid mine drainage and listed as impaired under Section 303(d) of the Clean Water Act. Compared with other recently evaluated mine-impacted watersheds in northern California, invertebrates, amphibians, and fish from sites within the Upper Clear Creek watershed tended to have significantly lower concentrations of Hg than at most other sites. For other metals and trace elements, Upper Clear Creek sites were only compared with the Deer Creek watershed, Nevada County, California. Copper from both Willow Creek sites (WLCC and WLTH) in the Clear Creek watershed was the only metal with concentrations in biota that were significantly higher than biota from Deer Creek

California↗
USGS2013

Assessment of mercury and methylmercury in water, sediment, and biota in Sulphur Creek in the vicinity of the Clyde Gold Mine and the Elgin Mercury Mine, Colusa County, California

At the request of the U.S. Bureau of Land Management, we performed a study during April–July 2010 to characterize mercury (Hg), monomethyl mercury (MMeHg), and other geochemical constituents in sediment, water, and biota at the Clyde Gold Mine and the Elgin Mercury Mine, located in neighboring subwatersheds of Sulphur Creek, Colusa County, California. This study was in support of a Comprehensive Environmental Response, Compensation, and Liability Act - Removal Site Investigation. The investigation was in response to an abatement notification from the California Central Valley Regional Water Quality Control Board to evaluate the release of Hg from the Clyde and Elgin mines. Samples of water, sediment, and biota (aquatic macroinvertebrates) were collected from sites upstream and downstream from the two mine sites to evaluate the level of Hg contamination contributed by each mine to the aquatic ecosystem. Physical parameters, as well as dissolved organic carbon, total Hg (Hg T ), and MMeHg were analyzed in water and sediment. Other relevant geochemical constituents were analyzed in sediment, filtered water, and unfiltered water. Samples of aquatic macroinvertebrates from each mine were analyzed for Hg T and MMeHg. The presence of low to moderate concentrations of Hg T and MMeHg in water, sediment, and biota from the Freshwater Branch of Sulphur Creek, and the lack of significant increases in these concentrations downstream from the Clyde Mine indicated that this mine is not a significant source of Hg to the watershed during low flow conditions. Although concentrations of Hg T and MMeHg were generally higher in samples of sediment and water from the Elgin Mine compared to the Clyde Mine, concentrations in comparable biota from the two mine areas were similar. It is likely that highly saline effluent from nearby hot springs contribute more Hg to the West Fork of Sulphur Creek than the mine waste material at the Elgin Mine.

California↗
USGS2012

Concentrations of mercury and other metals in black bass (Micropterus spp.) from Whiskeytown Lake, Shasta County, California, 2005

This report presents the results of a reconnaissance study conducted by the U.S. Geological Survey (USGS) to determine mercury (Hg) and other selected metal concentrations in Black bass ( Micropterus spp. ) from Whiskeytown Lake, Shasta County, California. Total mercury concentrations were determined by cold-vapor atomic absorption spectroscopy (CVAAS) in fillets and whole bodies of each sampled fish. Selected metals scans were performed on whole bodies (less the fillets) by inductively coupled plasma&ndash;mass spectroscopy (ICP-MS) and inductively coupled plasma&ndash;optical emission spectroscopy (ICP-OES). Mercury concentrations in fillet samples ranged from 0.06 to 0.52 micrograms per gram (&mu;g/g) wet weight (ww). Total mercury (HgT) in the same fish whole-body samples ranged from 0.04 to 0.37 (&mu;g/g, ww). Mercury concentrations in 17 percent of "legal catch size" (&ge;305 millimeters in length) were above the U.S. Environmental Protection Agency water-quality criterion for the protection of human health of 0.30 &mu;g/g (ww). These data will serve as a baseline for future monitoring efforts within Whiskeytown Lake.

California↗
USGS2011

The effects of sediment and mercury mobilization in the South Yuba River and Humbug Creek confluence area, Nevada County, California: Concentrations, speciation, and environmental fate – Part 1: Field characterization

Millions of pounds of mercury (Hg) were deposited in the river and stream channels of the Sierra Nevada from placer and hard-rock mining operations in the late 1800s and early 1900s. The resulting contaminated sediments are relatively harmless when buried and isolated from the overlying aquatic environment. The entrained Hg in the sediment constitutes a potential risk to human and ecosystem health should it be reintroduced to the actively cycling portion of the aquatic system, where it can become methylated and subsequently bioaccumulated in the food web. Each year, sediment is mobilized within these fluvial systems during high stormflows, transporting hundreds of tons of Hg-laden sediment downstream. The State of California and resource-management agencies, including the Bureau of Land Management (BLM) and the U.S. Forest Service, are concerned about additional disturbances, such as from suction gold dredging activities, which have the potential to mobilize Hg associated with buried sediment layers elevated in Hg that are otherwise likely to remain buried under normal storm conditions. The BLM initiated a study looking at the feasibility of removing Hg-contaminated sediment at the confluence of the South Yuba River and Humbug Creek in the northern Sierra Nevada of California by using standard suction-dredge technology. Additionally, the California State Water Resources Control Board (SWRCB) supported a comprehensive characterization of the intended dredge site. Together, the BLM and SWRCB supported a comprehensive characterization of Hg contamination at the site and the potential effects of sediment disturbance at locations with historical hydraulic mining debris on downstream environments. The comprehensive study consisted of two primary components: field studies and laboratory experiments. The field component, described in this report, had several study elements: 1) a preliminary, smallscale, in-stream dredge test; 2) comprehensive characterization of grain size distribution, Hg speciation, and mineralogy of bed and suspended sediment; 3) a determination of the past and current sources of sediment in the study area; 4) an assessment of Hg bioaccumulation in the local invertebrate population; and 5) a comparison of potential Hg transport caused by natural storm disturbances with potential Hg mobilization caused by suction dredging as a method of Hg removal at the study site. The laboratory component of the study assessed the potential influence of the disturbance of Hg-contaminated sediment through experiments designed to simulate in-stream transport, deposition, and potential methylation of Hg, described in a companion report (see Marvin-DiPasquale and others, 2011). Results of the field studies indicate that the fine-grained fraction (silt-clay, less than 0.063 millimeters) contains the greatest concentration of Hg in contaminated sediment. Because the fine-grained fraction is the most susceptible to longrange fluvial transport, disturbance of Hg-contaminated sediment is likely to increase the concentration and load of Hg in downstream waters. The preliminary, small-scale dredge test showed an increase in the concentration of fine particles and Hg in the water column caused by the dredge activity, despite relatively low concentrations of fine particles and Hg (about 300 nanograms per gram) at the dredge site. Characterization of sediment from two test pits and other sites in the vicinity of the confluence of the South Yuba River and Humbug Creek revealed a highly variable distribution of fine- and coarse-grained sediment. The highest levels of Hg contamination (up to 11,100 ng/g) were associated with the fine-grained fraction of sediment from the bedrock contact zone of Pit 2, a horizon which also yielded grains of gold and gold-Hg amalgam. A closed-circuit tank experiment with a venturi dredge at the base of Pit 1, in a gravel bar within the South Yuba River, resulted in fine-grained suspended sediment remaining in suspension more than 40 hours following the disturbance simulation. Although the volumetric concentration of Hg declined over time as particles settled out, the concentration of Hg on the suspended particles increased over time as the suspended material became finer grained, because Hg is preferentially adsorbed on to clay-sized particles. Mineralogical and chemical analyses indicated that the buried fine-grained material with the greatest Hg contamination was derived from hydraulic mining debris, which consist primarily of Eocene gravels mined in the Malakoff Diggins, North Bloomfield, and Lake City areas within the South Yuba River watershed. Coarse material and more recently deposited sediment were derived primarily from upstream sources on the South Yuba River. The biota assessment indicated that invertebrate taxa collected from all sites on the South Yuba River in 2007, including lower Humbug Creek, had elevated concentrations of total mercury (THg) and methylmercury (MeHg) compared to a reference site on the Bear River, upstream of mining effects. Differences with the reference site were less pronounced in 2008 when a significant reduction in MeHg concentrations was observed in biota across all taxa from concentrations in 2007. It is possible that the inter-annual variation was related to the fact that suction dredging was active in the South Yuba River in 2007 but not in 2008 when a local moratorium was imposed by the BLM. There were significant variations among taxa for both THg and MeHg concentrations, with the water striders (Gerridae) having the highest concentrations of both THg and MeHg; variation among sites was not as strong as between years or among taxa. These results suggest that additional monitoring would be helpful to investigate the possible linkage between variations in MeHg bioaccumulation and levels of suction dredge activity in areas of historical gold mining. Results from the field studies indicate that disturbance of the finegrained Hg-contaminated sediment would likely lead to enhanced mobilization of Hg to downstream environments; therefore, the use of suction dredging to remove Hg at the South Yuba River and Humbug Creek confluence area would likely result in enhanced Hg transport downstream relative to natural conditions.

California↗
USGS2011

Review of samples of water, sediment, tailings, and biota at the Little Bonanza mercury mine, San Luis Obispo County, California

Background and Objectives The Little Bonanza mercury (Hg) mine, located in San Luis Obispo County, California, is a relatively small mine with, a historical total Hg production of about 1,000 flasks. The mine workings and tailings are located in the headwaters of the previously unnamed west fork of Las Tablas Creek (WF Las Tablas Creek), which flows into the Nacimiento Reservoir. Wasterock and tailings eroded from the Little Bonanza Hg Mine have contributed Hg-enriched mine wastes to the headwaters of WF Las Tablas Creek. The mine is located on Federal land managed by the U.S. Bureau of Land Management (BLM), which requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in tailings, sediment, water, and biota at and downstream from the minesite. This report is in response that request, from the lead agency which is mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Little Bonanza minesite as a means of reducing Hg transport to WF Las Tablas Creek. This report summarizes data obtained from field sampling of mine tailings, wasterock, sediment, water, and biota at the Little Bonanza Mine that was completed on April 6, 2010. Conditions during sampling were dry and no rain had occurred in the watershed for several weeks. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could produce elevated levels of monomethyl mercury (MMeHg) in WF Las Tablas Creek and in biota. History and Geology The history of the Little Bonanza Hg mine is summarized here from Yates (1943) and other references as cited. The Little Bonanza Mine, located 20 mi west of Paso Robles, was discovered in 1862. Although production was minor until 1900, from 1900 to 1906, the mine produced about 1,000 flasks of Hg. Intermittent production continued into the 1940s but was relatively limited. Underground workings, now caved and inaccessible, include about 3,000 ft of drifts, crosscuts, and raises on three levels extending 260 ft downward. The workings at the Little Bonanza Mine explore a zone of fault breccia, which trends northwest. The breccia is composed of fragments of sandstone, greenstone, serpentine, and chert in a shale matrix. The serpentine has been hydrothermally altered to silica-carbonate rock, and the Hg deposit is hosted within the zone of alteration. The veins are discontinuous and irregular, but form a steplike pattern along the fault zone. The principal mineralization occurring in the veins is irregular, consisting of disseminated zones of cinnabar. Most of the veins in the mine area contain cinnabar. Sample Sites and Methods Samples were collected to assess the concentrations of Hg and biogeochemically relevant constituents in tailings and wasterock piles at the Little Bonanza Hg mine. Tailings are present adjacent to a three-pipe retort used to process the Hg ore. The tailings occur in the upper 15 cm of the soil adjacent to the retort and slag from the retort is present on the surface. An area of disturbed soil and rock uphill from the retort was likely formed during construction of a dam that provided water for mining activities. Wasterock in these piles was sampled. The largest amount of tailings is exposed to the west of the retort in the bank of WF Las Tablas Creek. Water, sediment, and biota were sampled from WF Las Tablas Creek, which flows through the mine area. Sample-site locations are shown in figures 10 and 11 and listed in table 1. Samples were collected when streamflow was low and no precipitation had occurred.

California↗
USGS2011

Impact of mine and natural sources of mercury on water, sediment, and biota in Harley Gulch adjacent to the Abbott-Turkey Run mine, Lake County, California

Executive Summary Stable-isotope data indicate that there are three sources of water that effect the composition and Hg concentration of waters in Harley Gulch: (1) meteoric water that dominates water chemistry during the wet season; (2) thermal water effluent from the Turkey Run mine that effects the chemistry at sample site HG1; and (3) cold connate groundwater that dominates water chemistry during the dry season as it upwells and reaches the surface. The results from sampling executed for this study suggest four distinct areas in Harley Gulch: (1) the contaminated West Fork of Harley Gulch, consisting of the stream immediately downstream from the mine area and the wetlands upstream from Harley Gulch canyon (sample sites HG1-HG2, (2) the East Fork of Harley Gulch, where no mining has occurred (sample site HG3), (3) sample sites HG4-HG7, where a seasonal influx of saline groundwater alters stream chemistry, and (4) sample sites HG7-HG10, downstream in Harley Gulch towards the confluence with Cache Creek. West Fork: Mine Area and Wetlands The concentration of Hg in both storm sediment and active channel sediment was highest at sample site HG1, immediately downstream from the mine. The highest concentrations of total Hg (Hg T ) in water also occurred at site HG1, and they decreased systematically downstream from the mine. The high concentration of HgT at site HG1 reflects input of thermal-water effluent from the Turkey Run mine which comprises most of the flow at this site during the dry season. During the May 2011 low-flow sampling, Hg T concentration was very high at site HG1, but the maximum in HgT concentration occurred at sample site HG1.5 in the middle of the wetland area. The high concentration of Hg T and isotopic chemistry at this site indicates that a significant input of connate groundwater into the creek at this location contributes to the high Hg concentration in water. At site HG1, just downstream from the thermal water input from the Turkey Run mine, water sampled in June 2010 was almost entirely composed of thermal-water effluent. During the storm sampling in March 2011, which resulted in the highest flows of the winter, thermal effluent was virtually undetectable at site HG1, and the water was all meteoric. During the May 2011 sampling event, the input of connate groundwater in the middle of the wetland area at site HG1.5 was dominant. Discharge from the adit and runoff from the mine contributes to the high Hg concentration at site HG1 under both high and low-flow conditions. East Fork: Background Hg levels in waters collected from the East Fork of Harley Gulch, where no mining has occurred, were as high as 32.8 parts per trillion (pptr). These levels of Hg in water are significantly higher than regional background Hg concentrations, which range from 4-7 pptr. These anomalous Hg concentrations are partially explained by the abundance of Hg-enriched groundwater in Harley Gulch. Sites HG4-HG7 Downstream from the wetland, the aqueous concentration of HgT decreased, but remained above background levels as another input of connate groundwater occurs in the creek segment between sample sites HG4 and HG7. The input of connate groundwater in this segment of the creek is reflected in the increase in dissolved constituents characteristic of the connate groundwater, such as sulfate (SO4), chloride (Cl) and magnesium (Mg). Stable-isotope data for heavy isotopes d18O and d2D also confirm two areas of input of connate groundwater into Harley Gulch: the creek segment in the West Fork near sample site HG1.5 and the segment between sample sites HG4 and HG7. Downstream from the second area of input of connate groundwater, both HgF and Hg T concentrations decrease similarly, but the percentage of Hg in the filtered fraction increases. The decreases in HgT and HgF between sample sites HG5 and HG7 suggests that this second source of connate groundwater to Harley Gulch is distinct from the Hg-enriched source that enters the middle of the wetlands at sample site HG1.5. During low-flow conditions in June 2010, input of connate groundwater increased from sample site HG4 and reached a maximum near sample site HG7, where it dominated creek water chemistry. Waters collected from sample site HG7 during the June 2010 sampling event were the heaviest isotopically and contained high concentrations of Cl and SO4, constituents that are characteristically high in the connate groundwater. Both above and below sample site HG7, the amount of connate groundwater in the creek water decreased. Sites HG8-HG10 Sediment with high Hg concentration is present throughout the West Fork of Harley Gulch below the mine and in the upper part of the Harley Gulch main stem to just above sample site HG10. At the sample site furthest downstream, HG10, Hg concentration is at background levels, as are cobalt (Co), nickel (Ni), and tungsten (W), indicating that the sediment is not significantly contaminated with Hg from the mine.

California↗
USGS2010

Mercury assessment and monitoring protocol for the Bear Creek Watershed, Colusa County, California

This report summarizes the known information on the occurrence and distribution of mercury (Hg) in physical/chemical and biological matrices within the Bear Creek watershed. Based on these data, a matrix-specific monitoring protocol for the evaluation of the effectiveness of activities designed to remediate Hg contamination in the Bear Creek watershed is presented. The monitoring protocol documents procedures for collecting and processing water, sediment, and biota for estimation of total Hg (TotHg) and monomethyl mercury (MMeHg) in the Bear Creek watershed. The concurrent sampling of TotHg and MMeHg in biota as well as water and sediment from 10 monitoring sites is designed to assess the relative bioavailability of Hg released from Hg sources in the watershed and identify environments conducive to Hg methylation. These protocols are designed to assist landowners, land managers, water quality regulators, and scientists in determining whether specific restoration/mitigation actions lead to significant progress toward achieving water quality goals to reduce Hg in Bear and Sulphur Creeks.

California↗
USGS2009

Mercury contamination in three species of anuran amphibians from the Cache Creek watershed, California, USA

Fish and wildlife may bioaccumulate mercury (Hg) to levels that adversely affect reproduction, growth, and survival. Sources of Hg within the Cache Creek Watershed in northern California have been identified, and concentrations of Hg in invertebrates and fish have been documented. However, bioaccumulation of Hg by amphibians has not been evaluated. In this study, adult and juvenile American bullfrogs ( Lithobates catesbeianus ) and foothill yellow-legged frogs ( Rana boylii ), adult Northern Pacific treefrogs ( Pseudacris regilla ), and larval bullfrogs were collected and analyzed for total Hg. One or more species of amphibians from 40% of the 35 sites had mean Hg concentrations greater than the US Environmental Protection Agency’s tissue residue criterion for fish (0.3 μg/g). Of the bullfrog tissues analyzed, the liver had the highest concentrations of both total Hg and methyl mercury. Total Hg in carcasses of bullfrogs was highly correlated with total Hg in leg muscle, the tissue most often consumed by humans.

California↗
USGS2009

Environmental Impact of the Contact and Sonoma Mercury Mines on Water, Sediment, and Biota in Anna Belcher and Little Sulphur Creek Watersheds, Sonoma County, California

The Contact and Sonoma mercury (Hg) deposits are among the youngest Hg deposits in the Coast Range Hg mineral belt and are located in the western part of the Clear Lake volcanic field in Sonoma County, California. The mine workings and tailings are located in the headwaters of Anna Belcher Creek, which is a tributary to Little Sulphur Creek. The Contact Hg mine produced about 1,000 flasks of Hg, and the Sonoma mine produced considerably less. Waste rock and tailings eroded from the Contact and Sonoma mines have contributed Hg-enriched mine waste material to the headwaters of Anna Belcher Creek. The mines are located on federal land managed by the U.S. Bureau of Land Management (USBLM). The USBLM requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in tailings, sediment, water, and biota at the Contact and Sonoma mines and in Anna Belcher and Little Sulphur Creeks. This report is made in response to the USBLM request, the lead agency mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Contact and Sonoma mines as a means of reducing Hg transport to Anna Belcher and Little Sulphur Creeks. This report summarizes data obtained from field sampling of mine tailings, waste rock, sediment, and water at the Contact and Sonoma mines that was initiated on April 20 during a storm event, and on June 19, 2001. Further sampling of water, sediment, and biota in a pond and tributaries that drain from the mine area was completed on April 1, 2003. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could elevate levels of monomethyl Hg (MMeHg) in tributaries and biota that are impacted by historic mining.

Open-File Report↗
USGS2009

Environmental Impact of the Helen, Research, and Chicago Mercury Mines on Water, Sediment, and Biota in the Upper Dry Creek Watershed, Lake County, California

The Helen, Research, and Chicago mercury (Hg) deposits are among the youngest Hg deposits in the Coast Range Hg mineral belt and are located in the southwestern part of the Clear Lake volcanic field in Lake County, California. The mine workings and tailings are located in the headwaters of Dry Creek. The Helen Hg mine is the largest mine in the watershed having produced about 7,600 flasks of Hg. The Chicago and Research Hg mines produced only a small amount of Hg, less than 30 flasks. Waste rock and tailings have eroded from the mines, and mine drainage from the Helen and Research mines contributes Hg-enriched mine wastes to the headwaters of Dry Creek and contaminate the creek further downstream. The mines are located on federal land managed by the U.S. Bureau of Land Management (USBLM). The USBLM requested that the U.S. Geological Survey (USGS) measure and characterize Hg and geochemical constituents in tailings, sediment, water, and biota at the Helen, Research, and Chicago mines and in Dry Creek. This report is made in response to the USBLM request to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Helen, Research, and Chicago mines as a means of reducing Hg transport to Dry Creek. This report summarizes data obtained from field sampling of mine tailings, waste rock, sediment, and water at the Helen, Research, and Chicago mines on April 19, 2001, during a storm event. Further sampling of water, sediment, and biota at the Helen mine area and the upper part of Dry Creek was completed on July 15, 2003, during low-flow conditions. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could elevate levels of monomethyl Hg (MMeHg) in the water, sediment, and biota that are impacted by historic mining.

Open-File Report↗
USGS2008

Metals and trace elements in giant garter snakes (Thamnophis gigas) from the Sacramento Valley, California, USA

The giant garter snake (GGS; Thamnophis gigas ) is a federally listed threatened species endemic to wetlands of the Central Valley of California. Habitat destruction has been the main factor in the decline of GGS populations, but the effects of contaminants on this species are unknown. To contribute to the recovery of these snakes, the U.S. Geological Survey (USGS) began studies of the life history and habitat use of GGSs in 1995. During a series of investigations conducted from 1995 to the present, specimens of dead GGSs were opportunistically collected from the Colusa National Wildlife Refuge (CNWR), the Natomas Basin, and other sites in northern California. Whole snakes were stored frozen for potential future analysis. As funding became available, we analyzed tissues of 23 GGSs to determine the concentrations of total mercury (Hg) and other trace elements in livers and concentrations of Hg in brains and tail clips. Mercury concentrations (μg/g, wet weight) ranged from 0.08 to 1.64 in livers, 0.01 to 0.18 in brains, and 0.02 to 0.32 in tail clips. In livers, geometric mean concentrations (μg/g, dry weight) of arsenic (25.7) and chromium (1.02) were higher than most values from studies of other snakes. Mercury concentrations in tail clips were positively correlated with concentrations in livers and brains, with the most significant correlations occurring at the Natomas Basin and when Natomas and CNWR were combined. Results indicate the value of using tail clips as a nonlethal bioindicator of contaminant concentrations.

Archives of Environmental Contamination and Toxico↗
USGS2008

Cliff swallows Petrochelidon pyrrhonota as bioindicators of environmental mercury, Cache Creek Watershed, California

To evaluate mercury (Hg) and other element exposure in cliff swallows (Petrochelidon pyrrhonota), eggs were collected from 16 sites within the mining-impacted Cache Creek watershed, Colusa, Lake, and Yolo counties, California, USA, in 1997-1998. Nestlings were collected from seven sites in 1998. Geometric mean total Hg (THg) concentrations ranged from 0.013 to 0.208 ??g/g wet weight (ww) in cliff swallow eggs and from 0.047 to 0.347 ??g/g ww in nestlings. Mercury detected in eggs generally followed the spatial distribution of Hg in the watershed based on proximity to both anthropogenic and natural sources. Mean Hg concentrations in samples of eggs and nestlings collected from sites near Hg sources were up to five and seven times higher, respectively, than in samples from reference sites within the watershed. Concentrations of other detected elements, including aluminum, beryllium, boron, calcium, manganese, strontium, and vanadium, were more frequently elevated at sites near Hg sources. Overall, Hg concentrations in eggs from Cache Creek were lower than those reported in eggs of tree swallows (Tachycineta bicolor) from highly contaminated locations in North America. Total Hg concentrations were lower in all Cache Creek egg samples than adverse effects levels established for other species. Total Hg concentrations in bullfrogs (Rana catesbeiana) and foothill yellow-legged frogs (Rana boylii) collected from 10 of the study sites were both positively correlated with THg concentrations in cliff swallow eggs. Our data suggest that cliff swallows are reliable bioindicators of environmental Hg. ?? Springer Science+Business Media, LLC 2007.

Archives of Environmental Contamination and Toxico↗
USGS2007

Mercury at the Oat Hill Extension Mine and James Creek, Napa County, California: Tailings, sediment, water, and biota, 2003-2004

The Oat Hill Extension (OHE) Mine is one of several mercury mines located in the James Creek/Pope Creek watershed that produced mercury from the 1870's until 1944 (U.S. Bureau of Mines, 1965). The OHE Mine developed veins and mineralized fault zones hosted in sandstone that extended eastward from the Oat Hill Mine. Waste material from the Oat Hill Mine was reprocessed at the OHE Mine using gravity separation methods to obtain cinnabar concentrates that were processed in a retort. The U.S. Bureau of Land Management requested that the U.S. Geological Survey measure and characterize mercury and other chemical constituents that are potentially relevant to ecological impairment of biota in tailings, sediment, and water at the OHE Mine and in the tributaries of James Creek that drain the mine area (termed Drainage A and B ) (Figs. 1 and 2). This report summarizes such data obtained from sampling of tailings and sediments at the OHE on October 17, 2003; water, sediment, and biota from James Creek on May 20, 2004; and biota on October 29, 2004. These data are interpreted to provide a preliminary assessment of the potential ecological impact of the mine on the James Creek watershed. The mine tailings are unusual in that they have not been roasted and contain relatively high concentrations of mercury (400 to 1200 ppm) compared to unroasted waste rock at other mines. These tailings have contaminated a tributary to James Creek with mercury primarily by erosion, on the basis of higher concentration of mercury (780 ng/L) measured in unfiltered (total mercury, Hg T ) spring water flowing from the OHE to James Creek compared to 5 to 14 ng/L Hg T measured in James Creek itself. Tailing piles (presumably from past Oat Hill mine dumping) near the USBLM property boundary and upstream of the main OHE mine drainage channel ( Drainage A ; Fig. 2) also likely emit mercury, on the basis of their mercury composition (930 to 1200 ppm). The OHE spring water is likely an appreciable source of sulfate and carbonate to James Creek, because the spring water was enriched in sulfate (130 mg/L) and carbonate (430 mg/L as CaCO 3 ) compared to James Creek water (70 to 100 mg/L SO 4 2- and 110 to 170 mg/L as CaCO 3 ) at the time of sampling. Concentrations of mercury in active channel sediment from James Creek are variable and potentially high, on the basis of chemical analysis (2.5 to 17 _g/g-wet sediment) and easily visible cinnabar grains in panned concentrates. Average (geometric mean) organic mercury (presumably monomethyl mercury (MMHg); §2.3.3) concentrations in several invertebrate taxa collected from the James Creek watershed locations were higher than invertebrates taken from a Northern California location lacking a known point source of mercury. The mean proportion of MMHg to total mercury in James Creek predatory insect samples was 40 percent (1 standard deviation = 30 percent); only 40 percent of all insect samples had a MMHg/Hg T proportion greater than 0.5. The low proportions of MMHg measured in invertebrates in James Creek and the presence of cinnabar in the creek suggest that some invertebrates may have anomolously high Hg concentrations as a result of the injestion or adhesion of extremely fine-grained cinnabar particles. Interpretation of Hg T in frogs and fish as an indicator of mercury reactivity, biouptake, or trophic transfer is limited, pending MMHg measuremens, by the possibility of these whole-body samples having contained cinnabar particles at the time of analysis. To minimize this limitation, the gastrointestinal tracts and external surfaces of all amphibians, where cinnabar most likely resides, were carefully flushed to remove any visible particles. However, extremely fine-grained, invisible, adhesive cinnabar particles likely exist in the amphibians' habitats. Hg T in foothill yellow-legged frogs collected from the James Creek study area, ranging from 0.1 to 0.6 μg/g Hg, was on average twice that of an extensive database compiled from Hg T in frogs studied throughout Northern California. Average concentrations of Hg T in frogs from James Creek were similar upstream (0.18 μg/g) and downstream (0.15 μg/g) of the confluence with Tributary 1 and at the lower Corona Mine adit drainage (0.14 μg/g). Frogs may be susceptible to trophic transfer of MMHg from invertebrates, but further study is required to rule out cinnabar ‘contamination.’ Hg T concentrations in rainbow trout collected from James Creek upstream and downstream of Tributary 1 averaged 0.10 μg/g and 0.13 μg/g, respectively. Compared to invertebrates, trout Hg T was less variable, suggesting that trout were less contaminated with cinnabar. California roach had significantly higher Hg T on average than trout (0.16 vs. 0.12 μg/g), and can be considered moderately contaminated compared to the same species from other sites in Northern California, which average 0.12 μg/g Hg. While limited measurements of mercury in water, sediment, and fish exceed, in some samples, predefined ecologically protective criteria for mine-impacted California systems, they do not clearly demonstrate that the biota residing in James Creek in the vicinity of the OHE are ecologically impaired. The potential for ecological impairment is clearly evident from invertebrate methyl mercury results and may manifest in other biological ecosystem residents that have yet to be studied (e.g., piscivorous birds). Methyl mercury concentrations in flowing water and sediment from James Creek and the tributary that drains the OHE are relatively low, ranging from 0.04 to 0.08 ng/L, although these data should be cautiously interpreted (see §3.2). While the results of this investigation suggest that the OHE contributes inorganic mercury to James Creek, they do not indicate the extent to which the OHE site is ecologically impairing biota relative to other sources of mercury. Improved sampling and analytical methods are recommended for future study.

California↗
USGS2005

Mercury contamination from historical gold mining in California

Mercury contamination from historical gold mines represents a potential risk to human health and the environment. This fact sheet provides background information on the use of mercury in historical gold mining and processing operations in California, with emphasis on historical hydraulic mining areas. It also describes results of recent USGS projects that address the potential risks associated with mercury contamination. Miners used mercury (quicksilver) to recover gold throughout the western United States. Gold deposits were either hardrock (lode, gold-quartz veins) or placer (alluvial, unconsolidated gravels). Underground methods (adits and shafts) were used to mine hardrock gold deposits. Hydraulic, drift, or dredging methods were used to mine the placer gold deposits. Mercury was used to enhance gold recovery in all the various types of mining operations; historical records indicate that more mercury was used and lost at hydraulic mines than at other types of mines. On the basis of USGS studies and other recent work, a better understanding is emerging of mercury distribution, ongoing transport, transformation processes, and the extent of biological uptake in areas affected by historical gold mining. This information has been used extensively by federal, state, and local agencies responsible for resource management and public health in California.

Fact Sheet↗