USGS ScienceSearch

Geology topics

Richard W. Hammack

Publications and source records attributed to Richard W. Hammack.

4 recordsLinked to original sources

Factors controlling Li concentration and isotopic composition in formation waters and host rocks of Marcellus Shale, Appalachian Basin

In this study, water and whole rock samples from hydraulically fractured wells in the Marcellus Shale (Middle Devonian), and water from conventional wells producing from Upper Devonian sandstones were analyzed for lithium concentrations and isotope ratios (&delta; 7 Li). The distribution of lithium concentrations in different mineral groups was determined using sequential extraction. Structurally bound Li, predominantly in clays, accounted for 75-91 wt. % of total Li, whereas exchangeable sites and carbonate cement contain negligible Li (< 3%). Up to 20% of the Li is present in the oxidizable fraction (organic matter and sulfides). The &delta; 7 Li values for whole rock shale in Greene Co., Pennsylvania, and Tioga Co., New York, ranged from -2.3 to + 4.3&permil;, similar to values reported for other shales in the literature. The &delta; 7 Li values in shale rocks with stratigraphic depth record progressive weathering of the source region; the most weathered and clay-rich strata with isotopically light Li are found closest to the top of the stratigraphic section. Diagenetic illite-smectite transition could also have partially affected the bulk Li content and isotope ratios of the Marcellus Shale. In Greene Co., southwest Pennsylvania, the Upper Devonian sandstone formation waters have &delta; 7 Li values of + 14.6 &plusmn; 1.2 (2SD, n = 25), and are distinct from Marcellus Shale formation waters which have &delta; 7 Li of + 10.0 &plusmn; 0.8 (2SD, n = 12). These two formation waters also maintain distinctive 87 Sr/ 86 Sr ratios suggesting hydrologic separation between these units. Applying temperature-dependent illitilization model to Marcellus Shale, we found that Li concentration in clay minerals increased with Li concentration in pore fluid during diagenetic illite-smectite transition. Samples from north central PA show a much smaller range in both &delta; 7 Li and 87 Sr/ 86 Sr than in southwest Pennsylvania. Spatial variations in Li and &delta; 7 Li values show that Marcellus formation waters are not homogeneous across the Appalachian Basin. Marcellus formation waters in the northeastern Pennsylvania portion of the basin show a much smaller range in both &delta; 7 Li and 87 Sr/ 86 Sr, suggesting long term, cross-formational fluid migration in this region. Assessing the impact of potential mixing of fresh water with deep formation water requires establishment of a geochemical and isotopic baseline in the shallow, fresh water aquifers, and site specific characterization of formation water, followed by long-term monitoring, particularly in regions of future shale gas development.

New York, Pennsylvania

Application of near-surface geophysics as part of a hydrologic study of a subsurface drip irrigation system along the Powder River floodplain near Arvada, Wyoming

Rapid development of coalbed natural gas (CBNG) production in the Powder River Basin (PRB) of Wyoming has occurred since 1997. National attention related to CBNG development has focused on produced water management, which is the single largest cost for on-shore domestic producers. Low-cost treatment technologies allow operators to reduce their disposal costs, provide treated water for beneficial use, and stimulate oil and gas production by small operators. Subsurface drip irrigation (SDI) systems are one potential treatment option that allows for increased CBNG production by providing a beneficial use for the produced water in farmland irrigation. Water management practices in the development of CBNG in Wyoming have been aided by integrated geophysical, geochemical, and hydrologic studies of both the disposal and utilization of water. The U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) and the U.S. Geological Survey (USGS) have utilized multi-frequency airborne, ground, and borehole electromagnetic (EM) and ground resistivity methods to characterize the near-surface hydrogeology in areas of produced water disposal. These surveys provide near-surface EM data that can be compared with results of previous surveys to monitor changes in soils and local hydrology over time as the produced water is discharged through SDI. The focus of this investigation is the Headgate Draw SDI site, situated adjacent to the Powder River near the confluence of a major tributary, Crazy Woman Creek, in Johnson County, Wyoming. The SDI system was installed during the summer of 2008 and began operation in October of 2008. Ground, borehole, and helicopter electromagnetic (HEM) conductivity surveys were conducted at the site prior to the installation of the SDI system. After the installation of the subsurface drip irrigation system, ground EM surveys have been performed quarterly (weather permitting). The geophysical surveys map the heterogeneity of the near-surface geology and hydrology of the study area. The geophysical data are consistent between surveys using different techniques and between surveys carried out at different times from 2007 through 2011. This paper summarizes geophysical results from the 4-year monitoring study of the SDI system.

Wyoming

Maps showing mines, prospects, and exposures in the Beaver Creek Wilderness, McCreary County, Kentucky

The Beaver Creek Wilderness occupies an area of 4,791 acres within the cliffline bordering the Beaver Creek drainage in McCreary County, southeastern Kentucky. It is in the Daniel Boone National Forest and includes part of the Beaver Creek Cooperative Wildlife Management Area, which is managed by the U.S. Forest Service and the Kentucky Department of Fish and Wildlife Resources. The area is located about 11 mi southeast of Burnside, Ky., and is accessible from the north and south via U.S. Route 27 and Forest Service Road 50, located at its northwest border (index map). From the east, the area can be reached via State Route 90 and Forest Service Road 46, located at the eastern edge of the area. Access by foot into the interior is provided by an abandoned Forest Service road and by several primitive trails that extend along the major streams. The Beaver Creek Wilderness is located at the western edge of the Appalachian coal region and is within the highly dissected Cumberland Plateau section of the Appalachian Plateaus physiographic province. It is drained by Beaver Creek and its tributaries, which flow northeastward into Lake Cumberland, a .reservoir on the Cumberland River about 1 mi north of the wilderness. Altitudes range from about 730 ft on the lower part of Beaver Creek to about 1,200 ft at its headwaters.

Kentucky

Maps showing mines, quarries, prospects, and exposures in the Cheat Mountain Roadless Area, Randolph County, West Virginia

The Wilderness Act (Public Law 88-577, September 3, 1964) and related acts require the U.S. Geological Survey and the U.S. Bureau of Mines to survey certain areas on Federal lands to determine their mineral resource potential. Results must be made available to the public and be submitted to the President and the Congress. This report presents the results of a mineral survey of the Cheat Mountain Roadless Area in the Monongahela National Forest, Randolph County, West Virginia. The area was designated as a further planning area during the Second Roadless Area Review and Evaluation (RARE II) by the U.S. Forest Service, January 1979. The Cheat Mountain Roadless Area is in the Greenbrier Ranger District of the Monongahela National Forest, east-central West Virginia. It is located in Randolph County about 10 mi southeast of Elkins, W.Va., and is accessible there via U.S. 219-250 to Beverly, W.Va., and then southeastward along an improved country road. From the east, the study area can be reached via U.S. 33 and by a paved country road that extends from Alpena, W.Va. to the village of Bemis. Unimproved Forest service roads, abandoned logging railroad grades, and primitive trails provide access by foot or horseback into the interior of the study area. Physiographically, the Cheat Mountain Roadless Area is in the Allegheny Mountain section of the Appalachian Plateaus province and is situated at the eastern edge of the Appalachian coal region. Cheat Mountain, a northeast-trending ridge, is bordered on the west by the right fork of Files Creek and on the east by Shavers Fork and its tributaries. Most of the area occupies an elevated plateau capped by resistant sandstone and conglomerate. Altitudes range form 2,320 ft on Lime Kiln Run to more than 3,900 ft on Cheat Mountain. The topography ranges from relatively flat in the uplands to very steep in the canyons along tributaries of Shavers Fork. The area is heavily forested with vegetation varying from mixed hardwoods on the western slope of Cheat Mountain to thickets of conifers in the uplands. Hemlocks are sparsely interspersed and red spruce, the dominant tree at higher elevations prior to logging in the mid 1920's, is again reforesting upland areas. Rhododendron and laurel flourish in moist protected areas along drainage courses and in coves.

West Virginia