Novel geophysical and geochemical techniques used to study submarine groundwater discharge in Biscayne Bay, Florida
Introduction Submarine groundwater discharge (SGD) is a problem of major proportions on a world-wide scale. The ubiquitous nature of SGD along varied coastlines and its importance to coastal water and geochemical budgets have recently been thrust into the global spotlight . For example, the discharge of nutrient-enriched groundwater into coastal waters may cause nutrient imbalances that can lead to eutrophication or near-shore micro-organism blooms . Similarly, SGD can also directly affect threatened coastal freshwater resources and impact fragile coastal ecosystems, such as coral reefs. Recently, much effort has been devoted to developing and adapting new tracer techniques and methods for the identification and quantification of SGD. As the discharge of coastal groundwater most often occurs as diffuse seepage rather than through a single vent feature, assessing SGD has remained difficult for both oceanographers and hydrologists alike. Burnett and colleagues have developed a systematic approach to investigate SGD by using a combination of both physical seepage measurements and a suite of naturally occurring isotopic tracers in the U/Th decay chain – 222 Rn and 223,224,226,228 Ra. Manheim et al. further extended SGD investigations by adapting geophysical resistivity techniques to examine fine-scale change in conductivity fields within coastal sediments. Such streaming resistivity profiling has been successfully applied to identify sites of SGD, as well as the dynamic position of the fresh water/saltwater interface.