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Remo A. Mondazzi

Publications and source records attributed to Remo A. Mondazzi.

5 recordsLinked to original sources

Borehole geophysical investigation of a formerly used defense site, Machiasport, Maine, 2003-2006

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, collected borehole geophysical logs in 18 boreholes and interpreted the data along with logs from 19 additional boreholes as part of an ongoing, collaborative investigation at three environmental restoration sites in Machiasport, Maine. These sites, located on hilltops overlooking the seacoast, formerly were used for military defense. At each of the sites, chlorinated solvents, used as part of defense-site operations, have contaminated the fractured-rock aquifer. Borehole geophysical techniques and hydraulic methods were used to characterize bedrock lithology, fractures, and hydraulic properties. In addition, each geophysical method was evaluated for effectiveness for site characterization and for potential application for further aquifer characterization and (or) evaluation of remediation efforts. Results of borehole geophysical logging indicate the subsurface is highly fractured, metavolcanic, intrusive, metasedimentary bedrock. Selected geophysical logs were cross-plotted to assess correlations between rock properties. These plots included combinations of gamma, acoustic reflectivity, electromagnetic induction conductivity, normal resistivity, and single-point resistance. The combined use of acoustic televiewer (ATV) imaging and natural gamma logs proved to be effective for delineating rock types. Each of the rock units in the study area could be mapped in the boreholes, on the basis of the gamma and ATV reflectivity signatures. The gamma and mean ATV reflectivity data were used along with the other geophysical logs for an integrated interpretation, yielding a determination of quartz monzonite, rhyolite, metasedimentary units, or diabase/gabbro rock types. The interpretation of rock types on the basis of the geophysical logs compared well to drilling logs and geologic mapping. These results may be helpful for refining the geologic framework at depth. A stereoplot of all fractures intersecting the boreholes indicates numerous fractures, a high proportion of steeply dipping fractures, and considerable variation in fracture orientation. Low-dip-angle fractures associated with unloading and exfoliation are also present, especially at a depth of less than 100 feet below the top of casing. These sub-horizontal fractures help to connect the steeply dipping fractures, making this a highly connected fracture network. The high variability in the fracture orientations also increases the connectivity of the fracture network. A preliminary comparison of all fracture data from all the boreholes suggests fracturing decreases with depth. Because all the boreholes were not drilled to the same depth, however, there is a clear sampling bias. Hence, the deepest boreholes are analyzed separately for fracture density. For the deepest boreholes in the study, the intensity of fracturing does not decline significantly with depth. It is possible the fractures observed in these boreholes become progressively tighter or closed with depth, but this is difficult to verify with the borehole methods used in this investigation. The fact that there are more sealed fractures at depth (observed in optical televiewer logs in some of the boreholes) may indicate less opening of the sealed fractures, less water moving through the rock, and less weathering of the fracture infilling minerals. Although the fracture orientation remained fairly constant with depth, differences in the fracture patterns for the three restoration sites indicate the orientation of fractures varies across the study area. The fractures in boreholes on Miller Mountain predominantly strike northwest-southeast, and to a lesser degree they strike northeast. The fractures on or near the summit of Howard Mountain strike predominantly east-west and dip north and south, and the fractures near the Transmitter Site strike northeast-southwest and dip northwest and southeast. The fracture populations for the boreholes on or near the summit of Howard Mountain show more variation than at the other two sites. This variation may be related to the proximity of the fault, which is northeast of the summit of Howard Mountain. In a side-by-side comparison of stereoplots from selected boreholes, there was no clear correspondence between fracture orientation and proximity to the fault. There is, however, a difference in the total populations of fractures for the boreholes on or near the summit of Howard Mountain and the boreholes near the Transmitter Site. Further to the southwest and further away from the fault, the fractures at the Transmitter Site predominantly strike northeast-southwest and northwest-southeast.Heat-pulse flowmeter (HPFM) logging was used to identify transmissive fractures and to estimate the hydraulic properties along the boreholes. Ambient downflow was measured in 13 boreholes and ambient upflow was measured in 9 boreholes. In nine other bedrock boreholes, the HPFM did not detect measurable vertical flow. The observed direction of vertical flow in the boreholes generally was consistent with the conceptual flow model of downward movement in recharge locations and upward flow in discharge locations or at breaks in the slope of land surface. Under low-rate pumping or injection rates [0.25 to 1 gallon per minute (gal/min)], one to three inflow zones were identified in each borehole. Two limitations of HPFM methods are (1) the HPFM can only identify zones within 1.5 to 2 orders of magnitude of the most transmissive zone in each borehole, and (2) the HPFM cannot detect flow rates less than 0.010 + or - 0.005 gal/min, which corresponds to a transmissivity of about 1 foot squared per day (ft2/d). Consequently, the HPFM is considered an effective tool for identifying the most transmissive fractures in a borehole, down to its detection level. Transmissivities below that cut-off must be measured with another method, such as packer testing or fluid-replacement logging. Where sufficient water-level and flowmeter data were available, HPFM results were numerically modeled. For each borehole model, the fracture location and measured flow rates were specified, and the head and transmissivity of each fracture zone were adjusted until a model fit was achieved with the interpreted ambient and stressed flow profiles. The transmissivities calculated by this method are similar to the results of an open-hole slug test; with the added information from the flowmeter, however, the head and transmissivity of discrete zones also can be determined. The discrete-interval transmissivities ranged from 0.16 to 330 ft2/d. The flowmeter-derived open-hole transmissivity, which is the combined total of each of the transmissive zones, ranged from 1 to 511 ft2/d. The whole-well open-hole transmissivity values determined with HPFM methods were compared to the results of open-hole hydraulic tests. Despite the fact that the flowmeter-derived transmissivities consistently were lower than the estimates derived from open-hole hydraulic tests alone, the correlation was very strong (with a coefficient of determination, R2, of 0.9866), indicating the HPFM method provides a reasonable estimate of transmissivities for the most transmissive fractures in the borehole. Geologic framework, fracture characterization, and estimates of hydraulic properties were interpreted together to characterize the fracture network. The data and interpretation presented in this report should provide information useful for site investigators as the conceptual site groundwater flow model is refined. Collectively, the results and the conceptual site model are important for evaluating remediation options and planning or implementing the design of a well field and borehole completions that will be adequate for monitoring flow, remediation efforts, groundwater levels, and (or) water quality. Similar kinds of borehole geophysical logging (specifically the borehole imaging, gamma, fluid logs, and HPFM) should be conducted in any newly installed boreholes and integrated with interpretations of any nearby boreholes. If boreholes are installed close to existing or other new boreholes, cross-hole flowmeter surveys may be appropriate and may help characterize the aquifer properties and connections between the boreholes.

Maine

Hydrogeology and numerical simulation of the unconsolidated glacial aquifer in the Pootatuck River Basin, Newtown, Connecticut

A study of the groundwater and stream-aquifer interaction in the Pootatuck River Basin, Newtown, Connecticut, was conducted to analyze the effect of production wells on the groundwater levels and streamflow in the Pootatuck River as part of a cooperative program between the U.S. Geological Survey and Newtown, Connecticut. This study will help address concerns about the increasing competition for water for human uses and protection of aquatic habitat. The groundwater-flow model developed in the study was designed for use as a tool to assist planners in assessing the effects of potential future development, which will change the amount and distribution of recharge available to the groundwater system. Several different techniques were used to investigate the interconnection between the stream and the aquifer. Temperature, groundwater levels, stream stage, and stable-isotope data collected during aquifer tests at the principal production wells in the Pootatuck River Basin, as well as groundwater-flow simulations of the system, indicate that more than half of the water pumped from the wells comes from the Pootatuck River. This finding potentially has a large effect on approaches for protecting the water quality of the pumped water. Increases in the amount of impervious surface from future development will reduce and redistribute recharge to the groundwater system. The simulation of future development scenarios showed a decrease in the simulated base flow in the main stem of the Pootatuck River and in all of the 26 simulated subbasins, with some of the subbasins showing a decrease of more than 20 percent when new development had 85 percent impervious area. The groundwater-flow model and particle tracking were used to determine areas that contribute recharge to the five production wells available for use in the Pootatuck River Basin. These areas included narrow portions of the aquifer that extended beyond the immediate upgradient areas, probably because of deeper groundwater-flow paths.

Scientific Investigations Report

Aquifer chemistry and transport processes in the zone of contribution to a public-supply well in Woodbury, Connecticut, 2002-06

A glacial aquifer system in Woodbury, Connecticut, was studied to identify factors that affect the groundwater quality in the zone of contribution to a community public-supply well. Water samples were collected during 2002-06 from the public-supply well and from 35 monitoring wells in glacial stratified deposits, glacial till, and fractured bedrock. The glacial aquifer is vulnerable to contamination from a variety of sources due to the short groundwater residence times and the urban land use in the contributing recharge area to the public-supply well. The distribution and concentrations of pH, major and trace elements, stable isotope ratios, recharge temperatures, dissolved organic carbon (DOC), and volatile organic compounds (VOCs), and the oxidation-reduction (redox) conditions, were used to identify recharge source areas, aquifer source material, anthropogenic sources, chemical processes, and groundwater-flow paths from recharge areas to the public-supply well, PSW-1. The major chemical sources to groundwater and the tracers or conditions used to identify them and their processes throughout the aquifer system include (1) bedrock and glacial stratified deposits and till, characterized by high pH and concentrations of sulfate (SO42-), bicarbonate, uranium (U), radon-222, and arsenic (As) relative to those of other wells, reducing redox conditions, enriched delta sulfur-34 (d34S) and delta carbon-13 (d13C) values, depleted delta oxygen-18 (d18O) and delta deuterium (dD) values, calcite near saturation, low recharge temperatures, and groundwater ages of more than about 9 years; (2) natural organic matter, either in sediments or in an upgradient riparian zone, characterized by high concentrations of DOC or manganese (Mn), low concentrations of dissolved oxygen (DO) and nitrate (NO3-), enriched d34S values, and depleted d18O and dD values; (3) road salt (halite), characterized by high concentrations of sodium (Na), chloride (Cl-), and calcium (Ca), and indicative chloride/bromide (Cl:Br) mass concentration ratios; (4) septic-system leachate, characterized by high concentrations of NO3-, DOC, Na, Cl-, Ca, and boron (B), delta nitrogen-15 (d15N) and d18O values, and indicative Cl:Br ratios; (5) organic solvent spills, characterized by detections of perchloroethene (PCE), trichloroethene (TCE), and 1,1-dichloroethene (1,1-DCE); (6) gasoline station spills, characterized by detections of fuel oxygenates and occasionally benzene; and (7) surface-water leakage, characterized by enriched d18O and dD values and sometimes high DOC and Mn-reducing conditions. Evaluation of Cl- concentrations and Cl:Br ratios indicates that most samples were composed of mixtures of groundwater and some component of road salt or septic-system leachate. Leachate from septic-tank drainfields can cause locally anoxic conditions with NO3- concentrations of as much as 19 milligrams per liter (mg/L as N) and may provide up to 15 percent of the nitrogen in water from well PSW-1, based on mixing calculations with d15N of NO3-. Most of the water that contributes to PSW-1 is young (less than 7 years) and derived from the glacial stratified deposits. Typically, groundwater is oxic, but localized reducing zones that result from abundances of organic matter can affect the mobilization of trace elements and the degradation of VOCs. Groundwater from fractured bedrock beneath the valley bottom, which is old (more than 50 years), and reflects a Mn-reducing to methanic redox environment, constitutes as much as 6 percent of water samples collected from monitoring wells screened at the bottom of the glacial aquifer. Dissolved As and U concentrations generally are near the minimum reporting level (MRL) (0.2 micrograms per liter or ?g/L and 0.04 ?g/L, respectively), but water from a few wells screened in glacial deposits, likely derived from underlying organic-rich Mesozoic rocks, contain As concentrations up to 7 ?g/L. At one location, concentrations of As and U were high

Scientific Investigations Report

Borehole-geophysical and hydraulic investigation of the fractured-rock aquifer near the University of Connecticut Landfill, Storrs, Connecticut, 2000 to 2001

An integrated borehole-geophysical and hydraulic investigation was conducted at the former landfill area near the University of Connecticut in Storrs, Connecticut, where solvents and landfill leachate have contaminated a fractured-bedrock aquifer. Borehole-geophysical techniques and hydraulic methods were used to characterize the site bedrock lithology and structure, fractures, and hydraulic properties. The geophysical and hydraulic methods included conventional logs, borehole imaging, borehole radar, flowmeter under ambient- and stressed hydraulic conditions, and discrete-zone hydraulic testing, sampling, and monitoring. The conventional geophysical-logging methods included caliper, deviation, electromagnetic induction, gamma, specific conductance, and fluid temperature. The advanced methods included optical and acoustic imaging of the borehole wall, heat-pulse flowmeter, and directional radar reflection. Borehole-geophysical methods were used to further define conductive features identified with surface-geophysical methods in the first phase of the investigation. The results of the surface- and borehole-geophysical logging were evaluated in an iterative and integrated manner to develop a conceptual model of ground-water flow at the site. The rock type, foliation, and fractures at the site were characterized from high-resolution optical televiewer (OTV) images of rocks penetrated by the boreholes and were compared to drilling logs and conventional geophysical logs. The rocks are interpreted as fine- to mediumgrained quartz-feldspar-biotite-garnet gneiss and schist with local intrusions of quartz diorite and pegmatite and minor concentrations of sulfide mineralization similar to rocks described as the Bigelow Brook Formation on regional geologic maps. Layers containing high concentrations of sulfide minerals appear as high electrical conductivity zones on electromagnetic-induction and borehole-radar logs. Foliation in the rocks generally strikes to the southwest and northeast, and dips to the northwest and southeast consistent with previous investigations in this area. The orientation of foliation, however, varies locally and with depth in some of the boreholes. These results are consistent with geologic mapping that has identified small-scale folding. The orientations of the transmissive fractures identified in the six boreholes logged for this investigation are similar to the fracture orientations mapped in a previous investigation. Many of these fractures are oriented with a north-northwest strike and have a shallow dip to the west. Other transmissive fractures have a southwest strike and dip at shallow angles to the northwest, and some strike roughly east-west and dip to the north and south. Flowmeter logging was used to identify transmissive fractures and to estimate the hydraulic properties in the boreholes. Ambient down flow was measured in one borehole, and ambient up flow and down flow were measured in another borehole. The other four bedrock boreholes did not have measurable vertical flow. Under low-rate pumping conditions (0.25 to 0.5 gallons per minute), one to three inflow zones were identified in each well. Commonly, fractures that are active under ambient conditions contribute to the well under pumping conditions. The ambient conditions were incorporated into the determination of the relative proportions of transmissivity. Specific capacity and transmissivity were determined for these open-hole low-rate pumping tests. Quasi-steady-state water levels were reached in four of the boreholes, including MW201R, MW204R, MW302R, and W202-NE. When pumped at low-rate conditions for 0.5 to 4 hours, the specific capacity ranged from 0.03 to 0.18 gallons per minute per foot. The open-hole transmissivity estimates ranged from 4.9 to 30 feet squared per day (ft2/d). Open-hole transmissivity was determined for boreholes that did not reach quasi-steady-state conditions under low-rate pumping conditions. Transmissivity was estimated for MW201R, MW202R, and MW203R using non-equilibrium methods, pumping rate, and the transient drawdown data to estimate the open-hole transmissivity. Transmissivity in these boreholes ranged from 0.98 to 3.2 ft 2 /d. The transmissivity and head of individual fractures or zones of fractures were estimated from heat-pulse flowmeter data acquired under ambient and stressed conditions. In the absence of ambient flow, data from two profiles of heat-pulse flowmeter data under two different stressed conditions were used to estimate the transmissivity and head of individual fracture zones. Only two boreholes, MW302R and W202-NE, had sufficient data for these analyses. The estimated transmissivity of individual transmissive zones ranged from 1.2 to 9.2 ft 2 /d. The transmissivity values determined by this numerical simulation method were less than the open-hole estimations, which were 15 and 30 ft 2 /d. Transmissivity also was measured directly over discrete intervals of the borehole using a straddle-packer apparatus and constant-rate pumping tests. Pumping rates were less than or equal to 0.25 gallons per minute. These discretezone single-hole pumping tests were conducted over a short period of time, usually about 30 minutes to 1 hour in duration. Pumping continued until the test zone reached a steady-state water level or until it was determined that the zone could not yield water at the pumped rate. The estimated transmissivity of individual transmissive zones ranged from about 0.21 to 11 ft 2 /d. The zone at a depth of 197 feet in W202-NE was the only zone that had discrete-interval testing with a straddle packer and sufficient heat-pulse flowmeter data for modeling the flow and estimating transmissivity and head. The two methods produced similar results. The straddle-packer method estimated a transmissivity of 4.7 ft 2 /d, and the heat-pulse flowmeter modeling results estimated a transmissivity of 6.9 ft 2 /d. A comparison of the transmissivity estimates indicate estimates typically are within an order of magnitude. The heat-pulse flowmeter methods used in this investigation to determine transmissivity of the boreholes and the individual fractures measure only the upper two or three orders of magnitude of transmissivity. Hence, other fractures in these boreholes permit the movement of water; their transmissivities, however, are lower than the detection limits of the methods that were used for this investigation and very small compared to the transmissive fractures that were studied. The data collected in this investigation were used to design discrete-zone monitoring systems for four of the boreholes used for monitoring. The results of the investigation are useful for refining the conceptual site model of ground-water flow, and for providing critical information for interpreting the results of water-quality sampling.

Connecticut

Combined use of borehole geophysics and packers to site potable wells in a contaminated area in Montville, Connecticut

A leaking underground gasoline tank contaminated a crystalline bedrock aquifer in Montville, Connecticut, USA with MTBE and benzene. At the original residential bedrock supply wells, the median MTBE concentration was 165 micrograms per liter (mg/L), and the median benzene concentration was 320 mg/L. The maximum concentrations of MTBE and benzene were 4,300 mg/l and 1,700 mg/L, respectively. Because of the unavailability of a public water supply and the long-term expense of point-of-use (on-site) treatment systems, the Connecticut Department of Environmental Protection Leaking Underground Storage Tank Program considered drilling replacement wells for water supply, if suitable drill sites could be located. Borehole geophysical methods were used as part of the investigation to find suitable drill sites. The U.S. Geological Survey performed borehole radar logging in three of the most contaminated wells. Other geophysical logs were run in two of the wells to enhance the hydrogeological characterizations. These data, combined with straddle-packer testing provided by a drilling contractor, formed the basis of a conceptual model used in the search for discrete fractures with better water quality than provided by an open-hole sample. At Property A, a single transmissive fracture was identified at the bottom of the well. This well, although having historically lower gasoline concentrations than the other two wells, had persistent high iron bacteria fouling of the filtration system. By 2002, concentrations of MTBE and benzene had decreased to 59 and 3 mg/L, respectively, and the water was treatable except for the iron. Because no water-bearing fractures were encountered above the well bottom, an alternate well site was selected based on a set of vertical fractures observed in a nearby outcrop, rather than on the geophysical data. The new well, sited along the strike of these fractures, yielded 9 gallons per minute (gpm) but was found to be more contaminated than the original well. MTBE and benzene were detected at 224 and 7 mg/L, respectively. At Property B, the isolated fractures associated with four radar reflections contained MTBE in concentrations ranging from 460 to 680 mg/L, with concentration increasing with depth. A new well site was selected based upon topography and physical limitations of the property. A target drilling depth was selected to avoid encountering the most contaminated fracture, as projected from the radar data in the contaminated well. A new well, drilled to the target depth, yielded 2 gpm, which was sufficient for domestic supply. No contaminants were detected during 7 years of annual sampling. Over the next 2 years, MTBE was detected twice at 2 and 8 mg/L. At Property C, the isolated fractures associated with 12 radar reflections and acoustic televiewer images yielded MTBE concentrations ranging from 47 to 1,200 mg/L and benzene concentrations from 6 to 1,000 mg/L, with concentrations generally increasing with depth. A new well site was selected based upon physical limitations of the site. A target drilling depth was chosen to avoid encountering the most contaminated fractures, as projected from the radar data in the contaminated well. A new well, drilled to the target depth, yielded 6 gpm. MTBE was detected at concentrations ranging from trace levels to 12 mg/L for 6 years. Benzene was not detected. These case histories suggest that the combined use of borehole geophysics and discrete-fracture sampling can, in some cases, be used to predict the locations of less contaminated or uncontaminated fractures, at distances of tens of feet from contaminated bedrock wells. This information may be used to improve the chances of successfully siting alternate potable water wells. Likewise, the same data and approach potentially could be used for targeting specific fractures for remediation.

Connecticut