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Rachel Lynn Mixon

Publications and source records attributed to Rachel Lynn Mixon.

5 recordsLinked to original sources

Tracking the sources of metals to the San Juan River, Four Corners Region, USA: An introduction to the thematic issue

Surface water quantity and quality is important for arid and semi-arid regions where many people, including underserved and Indigenous communities, rely on a scarce resource for drinking water, irrigation, livestock and ceremonial uses. The southwestern United States, and specifically the Four Corners Region (Colorado, Arizona, New Mexico and Utah), is an example of this situation. Elevated concentrations of metals including aluminium, arsenic and lead were identified in previous studies and this study in the San Juan River from below the Navajo Dam, through the Navajo Nation to Mexican Hat, Utah. An interdisciplinary team applied approaches and principles of geology, geochemistry, geomorphology, hydrology and statistics to gain a better understanding of the tributaries supplying the source(s) of metals to the San Juan River. This introductory paper provides an overview of the ‘Metal geochemical fingerprinting to identify sub-watershed source contributions to surface water at a regional arid watershed scale, Four Corners Region, USA’ thematic collection . An overview of sampling sites, techniques and potential sources of metals is provided. Approaches used in this study could be applied to investigations in similar systems globally.

Four Corners region

Evaluating sediment transport and metal sorption in the San Juan River watershed

The physical and chemical characteristics of sediment influence the transport of metals in rivers. The San Juan River and its tributaries are located in the Four Corners Region in the southwestern United States and the watershed contains a wide variety of potential metal sources. Comparisons of past and present sediment data provide insight into the effects of seasonality and storm events on the transport of sediment within a watershed. Comparisons suggest finer (<0.63 µm) sediment particles increase at a greater rate during intense storm events than coarser sediment particles. These fine, clay-sized sediments have a greater potential for metal sorption. Statistical analyses compared upper and lower portions of the San Juan River. Results show that total elemental concentration decreases in sediments (1785.15 μ g l −1 ) and that concentrations increase in the aqueous phase (2063.08 μ g l −1 ) downstream in the San Juan River. Analyses using geochemical and scanning electron microscopy with energy dispersive spectroscopy suggest that sediment clay particles are the most likely constituent to transport metals in the San Juan River. Metal transport is further aided by metal oxide coatings that develop on the surfaces of larger particles. Increases in aggregation of fine-grained particles in the downstream portions of the San Juan River are also likely to bind elements within sediments, which can act as both a source and sink for metals in the lower watershed. CEC , geochemistry , PSD

Arizona, Colorado, New Mexico, Utah

Applying geological unit distribution and chemical weathering indices to evaluate potential lithological sources of Al, As and Pb to the San Juan River, Four Corners region, USA

In arid to semi-arid landscapes, sporadic monsoonal events, varying widely in scale and distribution, can generate overland flow resulting in streamflow in ephemeral channels. These channels may contain metal-laden sediments that are a by-product of the weathering and erosion of local geological units. To evaluate the potential for local geology to contribute aluminium (Al), arsenic (As) and lead (Pb) to the San Juan River, northwestern New Mexico, USA, the distributions of geological units were delineated for 12 hydrological basins within the greater San Juan River watershed. Concentrations of Al, As and Pb in the predominant geological units were compiled from data in the National Geochemical Database. Chemical indices of weathering (CIW) were calculated for geological units with greater than 5% coverage in the entire San Juan River watershed. Based on CIWs of the major geological units, the Mesaverde Group (CIW = 95.2), Chinle and Dolores Formations ( combined ) (CIW = 93.3), and Mancos Shale ( combined ) (CIW = 82.6) are the most likely units to weather, erode and contribute sediments with elevated concentrations of Al, As and Pb to the San Juan River. The results of this study show the importance of understanding geological sources of sediments because they could be substantial contributors of constituents of concern to water, especially in arid environments where surface water may be the only source of water in the region.

Arizona, Colorado, New Mexico, Utah

Morphometric and geological characterization with statistical correlations for 33 tributary drainage basins of the San Juan River watershed in the Four Corners region, USA

Basin morphometry, climate and geology control how a hydrological network evolves over time, controlling the efficiency of weathering of elements from geological materials, and ultimately the input of sediment and dissolved constituents to river systems. Exceedances to the Navajo Nation surface water quality standards for trace metals have been reported in the San Juan River watershed. Because metals are transported adsorbed to fine-grain sediment, the identification of areas with elevated sources of trace metals and/or areas with increased erosion and sediment transport potential is an important first step in protecting water quality. Physical factors such as elevation, slope, relief and stream order were used to quantify morphometric parameters that effect the contribution of trace metals into the stream network. By correlating these parameters with water quality data that were collected from tributaries along the San Juan River, we identified statistically significant regressions between morphometric parameters and total Al, Pb, U, Fe and Mn in surface water. Positive correlations with trace metals include tributary drainage basin perimeter, pour point elevation and total number of streams, while negative correlations include stream length ratio, ruggedness number and longest basin axis. Stream reach measurements within geological units that contain known trace metal constituents reveal that Gallegos Canyon and Desert Creek are the most susceptible to sediment mobilization and transport, while other tributary drainage basins, such as Desert, Recapture and Salt creeks, are associated with naturally elevated concentrations of Al, As, Pb and U.

Arizona, Colorado, New Mexico, Utah

Geochemical assessment of the suitability of converting a coal-fired power plant reservoir to a drinking-water reservoir

There is an increasing need for additional water storage in the United States, especially in arid regions. Alternatives like decommissioned power plant raw-water reservoirs would be cheaper to use than creating new reservoirs; however, the biogeochemical pollution risk of these reservoirs is not well understood. The San Juan Generating Station power plant and the associated reservoir will be used as a sediment-settling basin to store drinking water. To evaluate whether the reservoir is appropriate for this use, inorganic and organic constituents of concern were measured in reservoir sediment cores, pore water, and reservoir water in 2020. Forty-six percent of sediment arsenic concentrations measured in core subsamples (8 to 12 mg/kg) were slightly above the New Mexico residential cancer threshold for soil of 7.07 mg/kg. One sediment sample contained elevated total barium concentrations (6020 mg/kg). The organic compounds analyzed were either below detection limits or below regulatory thresholds. Reservoir water had one sample with arsenic greater than the drinking water standard (10 µg/L). Overall, the reservoir sediment inorganic and organic analyte concentrations are within acceptable ranges. The few samples that have elevated concentrations are not of a sufficient magnitude that dilution and/or treatment processes would preclude the use of the reservoir for water storage. Our findings show potential for use of former coal power station raw-water reservoirs as drinking-water reservoirs after plant closure.

New Mexico