Coal petrographic laboratory procedures and safety manual
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Geology topics
Publications and source records attributed to R.W. Stanton.
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This study attempts to quantify some of the various origins of mineral matter. Data developed for the Upper Freeport coal bed indicates that mineral matter other than pyrite and calcite is primarily derived from the vegetal matter that ultimately became coal. Cathodoluminesence was used to verify that the quartz in the Upper Freeport coal is dominantly authigenic and not detrital in origin. Sulfur variability in coal beds of the central Appalachian Basin was investigated stratagraphically.
Elements other than organically derived and bound C, H, N, O, and S constitute mineral matter in coal. Mineral matter may consist of discrete minerals such as calcite, quartz, clays, and pyrite, and/or organic compounds that contain organically bonded elements such as Ca and CI. Processes that may affect the association and content of mineral matter are operable from the initial peat-forming stage to the time of utilization of the coal. However, the objective of this paper is to discuss some of the various geologic processes that may influence content and associations in unmined coal.
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A method using the gas-comparison pycnometer with helium gas as the penetrating medium measures precisely the true volume of a pulverized coal sample. The true density of a solid is calculated as the true unit volume of the solid exclusive of its pore space which is divided into the weight of the sample. The method is similar to that used to determine the density of refractory materials but the procedure is modified to yield precise density determinations of coal samples. These modifications diminish effects of trapped moisture and gases on the volume measurement. The helium gas-comparison pycnometer method is rapid, reliable, precise, and requires minimal analytical equipment and sample preparation, and also is non-destructive to the coal sample. Using this method, densities can be determined on coal samples of subbituminous to low-volatile bituminous rank and perhaps also on samples of lignite. The density of anthracite samples has not been determined by this method.
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