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R.J. Poreda

Publications and source records attributed to R.J. Poreda.

8 recordsLinked to original sources
USGS2010

Inferring shallow groundwater flow in saprolite and fractured rock using environmental tracers

The Ridge and Valley Province of eastern Tennessee is characterized by (1) substantial topographic relief, (2) folded and highly fractured rocks of various lithologies that have low primary permeability and porosity, and (3) a shallow residuum of medium permeability and high total porosity. Conceptual models of shallow groundwater flow and solute transport in this system have been developed but are difficult to evaluate using physical characterization or short‐term tracer methods due to extreme spatial variability in hydraulic properties. In this paper we describe how chlorofluorocarbon 12, 3 H, and 3 He were used to infer groundwater flow and solute transport in saprolite and fractured rock near Oak Ridge, Tennessee. In the shallow residuum, fracture spacings are <0.05 m, suggesting that concentrations of these tracers in fractures and in the matrix have time to diffusionally equilibrate. The relatively smooth nature of tracer concentrations with depth in the residuum is consistent with this model and quantitatively suggests recharge fluxes of 0.2 to 0.4 m yr −1 . In contrast, groundwater flow within the unweathered rock appears to be controlled by fractures with spacings of the order of 2 to 5 m, and diffusional equilibration of fractures and matrix has not occurred. For this reason, vertical fluid fluxes in the unweathered rock cannot be estimated from the tracer data.

Water Resources Research↗
USGS2004

The helium isotopic chemistry of Lake Bonney, Taylor Valley, Antarctica: Timing of late holocene climate change in Antarctica

To better understand the long-term climate history of Antarctica, we studied Lake Bonney in Taylor Valley, Southern Victoria Land (78?? S). Helium isotope ratios and He, Ne, Ar and N2 concentration data, obtained from hydrocasts in the East (ELB) and West (WLB) Lobesof Lake Bonney, provided important constraints on the lake's Holocene evolution. Based on very low concentrations of Ar and N2 in the ELB bottom waters, ELB was free of ice until 200 ?? 50 years ago. After which, low salinity water flowing over the sill from WLB to ELB, covered ELB and formed a perennial ice cover, inhibiting the exchange of gases with the atmosphere. In contrast to the ELB, the WLB retained an ice cover through the Holocene. The brine in the WLB bottom waters has meteoric N2 and Ar gas concentrations indicating that it has not been significantly modified by atmospheric exchange or ice formation. The helium concentrations in the deep water of WLB are the highest measured in non-thermal surface water. By fitting a diffusional loss to the 3He/4He, helium, and Cl profiles, we calculate a time of ???3000 years for the initiation of flow over the sill separating the East and West Lobes. To supply this flux of helium to the lake, a helium-rich sediment beneath the lake must be providing the helium by diffusion. If at any time during the last million years the ice cover left WLB, there would be insufficient helium available to provide the current flux to WLB. The variations in water levels in Lake Bonney can be related to climatic events that have been documented within the Southern Victoria Land region and indicate that the lakes respond significantly to regional and, perhaps, global climate forcing. ?? 2004 Kluwer Academic Publishers.

Aquatic Geochemistry↗
USGS2004

Geochemical discrimination of five pleistocene lava-dam outburst-flood deposits, western Grand Canyon, Arizona

Pleistocene basaltic lava dams and outburst‐flood deposits in the western Grand Canyon, Arizona, have been correlated by means of cosmogenic 3 He ( 3 He c ) ages and concentrations of SiO 2 , Na 2 O, K 2 O, and rare earth elements. These data indicate that basalt clasts and vitroclasts in a given outburst‐flood deposit came from a common source, a lava dam. With these data, it is possible to distinguish individual dam‐flood events and improve our understanding of the interrelations of volcanism and river processes. At least five lava dams on the Colorado River failed catastrophically between 100 and 525 ka; subsequent outburst floods emplaced basalt‐rich deposits preserved on benches as high as 200 m above the current river and up to 53 km downstream of dam sites. Chemical data also distinguishes individual lava flows that were collectively mapped in the past as large long‐lasting dam complexes. These chemical data, in combination with age constraints, increase our ability to correlate lava dams and outburst‐flood deposits and increase our understanding of the longevity of lava dams. Bases of correlated lava dams and flood deposits approximate the elevation of the ancestral river during each flood event. Water surface profiles are reconstructed and can be used in future hydraulic models to estimate the magnitude of these large‐scale floods.

Arizona↗
USGS2003

Scrubbing masks magmatic degassing during repose at Cascade-Range and Aleutian-Arc volcanoes

Between 1992 and 1998, we sampled gas discharges from ≤173°C fumaroles and springs at 12 quiescent but potentially restless volcanoes in the Cascade Range and Aleutian Arc (CRAA) including Mount Shasta, Mount Hood, Mount St. Helens, Mount Rainier, Mount Baker, Augustine Volcano, Mount Griggs, Trident, Mount Mageik, Aniakchak Crater, Akutan, and Makushin. For each site, we collected and analyzed samples to characterize the chemical (H2O, CO2, H2S, N2, CH4, H2, HCl, HF, NH3, Ar, O2, He) and isotopic (δ13C of CO2, 3He/4He, 40Ar/36Ar, δ34S, δ13C of CH4, δ15N, and δD and δ18O of water) compositions of the gas discharges, and to create baseline data for comparison during future unrest. The chemical and isotopic data show that these gases contain a magmatic component that is heavily modified from scrubbing by deep hydrothermal (150° - 350°C) water (primary scrubbing) and shallow meteoric water (secondary scrubbing). The impact of scrubbing is most pronounced in gas discharges from bubbling springs; gases from boiling-point fumaroles and superheated vents show progressively less impact from scrubbing. The most effective strategies for detecting gas precursors to future CRAA eruptions are to measure periodically the emission rates of CO2 and SO2, which have low and high respective solubilities in water, and to monitor continuously CO2 concentrations in soils around volcanic vents. Timely resampling of fumaroles can augment the geochemical surveillance program by watching for chemical changes associated with drying of fumarolic pathways (all CRAA sites), increases in gas geothermometry temperatures (Mount Mageik, Trident, Mount Baker, Mount Shasta), changes in δ13C of CO2 affiliated with magma movement (all CRAA site), and increases in 3He/4He coupled with intrusion of new magma (Mount Rainier, Augustine Volcano, Makushin, Mount Shasta). Repose magmatic degassing may discharge substantial amounts of S and Cl into the edifices of Mount Baker and several other CRAA volcanoes that is trapped by primary and secondary scrubbing. The consequent acidic fluids produce ongoing alteration in the 0.2- to 3-km-deep hydrothermal systems and in fields of boiling-point fumaroles near the surface. Such alteration may influence edifice stability and contribute to the formation of more-hazardous cohesive debris flows. In particular, we recommend further investigation of the volume, extent, and hazards of hydrothermal alteration at Mount Baker. Other potential hazards associated with the CRAA volcano hydrothermal systems include hydrothermal eruptions and, for deeper systems intruded by magma, deep-seated edifice collapse.

Alaska;British Columbia;California;Oregon;Washingt↗
USGS1999

Cosmogenic 3He ages and frequency of late Holocene debris flows from Prospect Canyon, Grand Canyon, USA

Lava Falls Rapid, which was created and is maintained by debris flows from Prospect Canyon, is the most formidable reach of whitewater on the Colorado River in Grand Canyon and is one of the most famous rapids in the world. Debris flows enter the Colorado River at tributary junctures, creating rapids. The frequency of debris flows is an important consideration when management of regulated rivers involves maintenance of channel morphology. We used cosmogenic 3He, 14C, and historical photographs to date 12 late Holocene and historic debris flows from Prospect Canyon. The highest and oldest deposits from debris flows on the debris fan yielded a 3He date of about 3 ka, which indicates predominately late Holocene aggradation of one of the largest debris fans in Grand Canyon. The deposit, which has a 25-m escarpment caused by river reworking, crossed the Colorado River and raised its base level by 30 m for an indeterminate although likely short period. We mapped depositional surfaces of 11 debris flows that occurred after 3 ka. Two deposits inset against the highest deposit yielded 3He ages of about 2.2 ka, and at least two others followed shortly afterwards. At least one of these debris flows also dammed the Colorado River. The most recent prehistoric debris flow occurred no more than 0.5 ka. The largest historic debris flow, which constricted the river by 80%, occurred in 1939. Five other debris flows occurred after 1939; these debris flows constricted the Colorado River by 35-80%. Assuming the depositional volumes of late Holocene debris flows can be modeled using a lognormal distribution, we calculated recurrence intervals of 15 to more than 2000 years for debris flows from Prospect Canyon.

Geomorphology↗
USGS1995

High-3He plume origin and temporal-spatial evolution of the Siberian flood basalts

An olivine nephelinite from the lower part of a thick alkalic ultrabasic and mafic sequence of volcanic rocks of the northeastern part of the Siberian flood basalt province (SFBP) yielded a 40 Ar/ 39 Ar plateau age of 253.3 ± 2.6 million years, distinctly older than the main tholeiitic pulse of the SFBP at 250.0 million years. Olivine phenocrysts of this rock showed 3 He/ 4 He ratios up to 12.7 times the atmospheric ratio; these values suggest a lower mantle plume origin. The neodymium and strontium isotopes, rare earth element concentration patterns, and cerium/lead ratios of the associated rocks were also consistent with their derivation from a near-chondritic, primitive plume. Geochemical data from the 250-million-year-old volcanic rocks higher up in the sequence indicate interaction of this high- 3 He SFBP plume with a suboceanic-type upper mantle beneath Siberia.

Science↗