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R.E. Criss

Publications and source records attributed to R.E. Criss.

14 recordsLinked to original sources

Age and origin of base and precious metal veins of the Coeur d'Alene mining district, Idaho

Ore-bearing quartz-carbonate veins of the Coeur d'Alene mining district yield 87Sr/86Sr ratios of 0.74 to >1.60 for low Rb/Sr, carbonate gangue minerals, similar to current ranges measured in Middle Proterozoic, high Rb/Sr rocks of the Belt Supergroup. Stable isotope and fluid inclusion studies establish a genetic relationship between vein formation and metamorphic-hydrothermal systems of the region. These extraordinary 87Sr/86Sr ratios require accumulation of radiogenic 87Sr in a high Rb/Sr system over an extended period prior to incorporation of Sr into the hydrothermal veins. Evaluation of the age and composition of potential sources of highly radiogenic Sr indicates that the ore-bearing veins of the Coeur d'Alene district formed during the Cretaceous from components scavenged from rocks of the Belt Supergroup, the primary host rocks of the district. Proterozoic Pb isotope ratios observed in galena from many Coeur d'Alene veins were established when Pb separated from uranium during deposition or diagenesis of the Belt Supergroup at 1400 to 1500 Ma, possibly as disseminated syngenetic deposits. K-Ar and Rb-Sr apparent ages and ??18O values of Belt Supergroup rocks decrease from the Coeur d'Alene district toward the Idaho and Kaniksu batholiths, approximately normal to the trends of metamorphic isograds, fold axes, foliation, and the major reverse faults of the district. Isoclinal folding, thrust faulting, high-temperature metamorphism, granitic plutonism, and regional-scale metamorphic-hydrothermal activity is documented in the region between 140 and 45 Ma, representing the only such combination of events in the Coeur d'Alene region subsequent to about 1300 Ma. The Sr and oxygen results and geologic evidence favor formation of the ore-bearing carbonate veins by fluids related to a complex metamorphic-hydrothermal system during the Cretaceous. Pb with Proterozoic isotopic compositions was probably mobilized and incorporated like other metals into the hydrothermal veins during this event. The ore-bearing veins were sheared and displaced during early Tertiary northwest-trending dextral strike-slip faulting along the Osburn fault and related structures of the Lewis and Clark line.

Economic Geology↗

Three-dimensional oxygen isotope imaging of convective fluid flow around the Big Bonanza, Comstock lode mining district, Nevada

Oxygen isotope analyses of propylitized andesites from the Con Virginia and California mines allow construction of a detailed, three-dimensional image of the isotopic surfaces produced by the convective fluid flows that deposited the famous Big Bonanza orebody. On a set of intersecting maps and sections, the δ 18 O isopleths clearly show the intricate and conformable relationship of the orebody to a deep, ~500 m gyre of meteoric-hydrothermal fluid that circulated along and above the Comstock fault, near the contact of the Davidson Granodiorite. The core of this gyre (δ 18 O = 0 to 3.8‰) encompasses the bonanza and is almost totally surrounded by rocks having much lower δ 18 O values (–1.0 to –4.4‰). This deep gyre may represent a convective longitudinal roll superimposed on a large unicellular meteoric-hydrothermal system, producing a complex flow field with both radial and longitudinal components that is consistent with experimentally observed patterns of fluid convection in permeable media.

Nevada↗

Genesis of the Silsilah tin deposit, Kingdom of Saudi Arabia

The Silsilah tin deposit (lat 25 degrees 06' N, long 42 degrees 40' E) consists of a group of pervasively greisenized, flat-topped granite cupolas within a 12-km-diam ring complex. The greisens contain varying amounts of disseminated cassiterite and wolframite. Several types of quartz veins are peripheral to the greisens; some of these contain minor wolframite. The deposit is genetically associated with a highly differentiated, peraluminous alkali-feldspar granite (587 + or - 8 Ma) that is part of a mostly peralkaline, igneous ring complex intruded into Late Proterozoic, immature sandstones of the Murdama Group. We recognize four distinct phases of the peraluminous granite. Only the smallest, most highly differentiated cupolas contain significant tin greisen mineralization. Greisens developed beneath aplitic carapaces that overlie the granite and created impermeable barriers to rising volatiles. The geometry of a cupola correlates strongly with the intensity of alteration; cupolas with the smallest cross sectional areas and steepest marginal contacts have the most intensely greisenized apexes. The paragenetic sequence can be divided into five stages: pegmatite formation, locally pervasive albitization, locally pervasive greisenization and deposition of cassiterite, deposition of quartz-wolframite veins, and deposition of quartz veins with minor base metal sulfides. Pressure-corrected fluid inclusion filling temperatures indicate that the hydrothermal system generally cooled as it evolved and that the delta 18 O values of the hydrothermal quartz increased from 10.8 to 15.7 per mil. Calculated delta 18 O values of the hydrothermal fluid varied concomitantly from the pegmatite stage (delta 18 O fluid approximately 8.6ppm; T [asymp] 550 degrees C) to the greisen stage (5.4 and 5.6[ppm; T [asymp] 360 degrees C), the quartz-wolframite vein stage (6.3 and 7.5ppm; T [asymp] 390 degrees C), and the late vein stage (4.0 and 5.1ppm; T [asymp] 270 degrees C). This evolution probably reflects the admixture of generally increasing amounts of meteoric or formation water having a lower delta 18 O value into the cooling magmatic hydrothermal system. In delta 18 O -delta 18 O plots for mineral separates from fresh to altered samples of the peraluminous granite the values for quartz and feldspar conform to a steep, positive-sloped disequilibrium trend that indicates interaction with high 18 O hydrothermal fluid, mirrored by a negative-sloped disequilibrium trend for quartz and mica. These complementary trends suggest strongly that individual granite cupolas were essentially closed systems during alteration. To our knowledge, this is the first oxygen isotope demonstration of a closed-system, hydrothermal metal deposit. The sandstone country rock has whole-rock delta 18 O values of 12.4 + or - 2.0 per mil. The highest values (>13ppm) form a approximately 3-km-wide high delta 18 O annulus immediately peripheral to the ring complex. The data suggest that the country rocks were pervasively exchanged with an outward-migrating, high delta 18 O fluid moving down a temperature gradient. This fluid was probably formation water that flowed radially inward toward the pluton at a deeper level, forming a largely horizontal, unicellular flow system that had fluid-flow lines nearly vertical next to the intrusion, and directed upward and outward at higher levels. Low delta 18 O fluids that formed quartz associated with the tin-tungsten mineralization and later veins are inferred to be the result of a subsequent and distinct phase of the hydrothermal system. Almost all the geologic processes necessary for the formation of an economically viable tin deposit occurred at Silsilah, but the lack of a strong localizing mechanism for cassiterite mineralization resulted in an economically marginal deposit. If the greisenized cupolas had been vertically stacked, as are the intrusions and ore zones in Climax-type molybdenum deposits, or if the mineralizing fluids had been channeled into veins, as in the tin deposits in Cornwall, England, a higher grade deposit might have formed. The generally closed-system behavior of the hydrothermal system at Silsilah may have prevented additional scavenging of metals and the formation of a larger, richer deposit.

Economic Geology↗

Geochemistry of tectonically expelled fluids from the northern Coast ranges, Rumsey Hills, California, USA

Tectonic compression has created abnormally high pressure on deep basinal fluids causing their expulsion from areally exposed Upper Cretaceous rock along the eastern margin of the California Coast ranges. The fluids emerge as near-neutral, perennial sodium chloride springs at high elevations with flow rates as high as 10 L per min. Higher spring discharges are more common around the exposure of a west-vergent fault propagation fold axis. Spring waters range from ~1000 to 27,000 mg/L TDS. The least saline water ( δ 18 O = −7.5‰ "> δ 18 O = −7.5‰ ) closely represents local meteoric water that mixes with saline fluid ( δ 18 O = +5.3‰ "> δ 18 O = +5.3‰ ) and forms a slope of ~3.5 on a δD vs. δ 18 O plot. A Na (125 to 8000 mg/L) vs. Cl (150 to 17,000 mg/L) plot shows a linear dilution trend that extends close to, but below, the values for modern seawater. Calcium (75–3000 mg/L) is considerably enriched relative to seawater and forms a nonlinear trend with chloride. In detail, the “Na deficit,” defined by the difference between the measured Na content and the Na concentration on a hypothetical seawater dilution line, is approximately balanced by the Ca excess, similarly defined by the seawater dilution line. This relationship strongly suggests that the fluid is diluted seawater that is being modified by active albitization of plagioclase at different depths. Simultaneous B and 18 O enrichment of the fluids, accompanied by deuterium depletion, further suggest that the seawater modification is influenced by clay diagenesis. Bicarbonate and SiO 2 concentrations show an inverse correlation with Cl, with most waters being saturated or slightly oversaturated with calcite and quartz at the discharge temperatures. Some freshwater springs with near-meteoric stable isotope values may represent mixing of young groundwater from perched aquifers, but in many cases, the freshwater springs emerge along the same structures and have the same perennial nature as the saline fluids, and expulsion of an older fresh groundwater component that is under abnormal fluid pressures cannot be ruled out. Basinal fluids elsewhere commonly show dilution trends with local meteoric water, and in the case of the Rumsey Hills, some of the dilute saline waters may indicate deep penetration of meteoric water (> 1 km) in the Pleistocene before the latest tectonic uplift. Geothermometry of the spring waters (maximum ~90°C) suggest an origin from as deep as 4.0 km. This depth is consistent with the depth of the core of a fault propagation anticline below the surface of the Rumsey Hills developed by active internal deformation of an east-tapering wedge beneath the southwestern Sacramento Valley. Active tectonic compression causes near-lithostatic fluid pressures in the shallow subsurface below the Rumsey Hills and volume strain within the core of the anticline that results in upward expulsion of the saline fluids from the indicated depths.

California↗

Geology and genesis of the Baid Al Jimalah tungsten deposit, Kingdom of Saudi Arabia

The Baid al Jimalah tungsten deposit in Saudi Arabia (lat 25 degrees 09'N, long 42 degrees 41'E) consists predominantly of swarms of steeply dipping, subparallel, tungsten-bearing quartz veins and of less abundant, smaller stockwork veins. It is spatially, temporally, and genetically associated with a 569 Ma, highly differentiated, porphyritic, two-feldspar granite that intrudes Late Proterozoic immature sandstones.Paragenetic data from crosscutting veins demonstrate unambiguously a single cycle of magma intrusion and hydrothermal mineralization. Hypogene mineralization can be divided into three periods: (1) early quartz-molybdenite stockwork veining, (2) wolframite- and scheelite-bearing, greisen-bordered veining, and (3) late, quartz-carbonate-fluorite veining. The first two of these three periods can be further divided into several stages that are transitional to each other. The greisen-bordered veins, in particular, show replacement of earlier mineral assemblages by later ones. Precious and base metal veins at Baid al Jimalah East, approximately 1.5 km east of the Baid al Jimalah tungsten deposit, are genetically related to the tungsten deposit and probably formed contemporaneously with the greisenized tungsten-bearing veins.Fluid inclusion and oxygen isotope data indicate that the Baid al Jimalah deposit formed over a temperature range of 120 degrees to 550 degrees C, from low salinity magmatic and metamorphic fluids, and at a depth of about 4.2 km. Early stockwork veins (period 1) formed at low magmatic temperatures (ca. 550 degrees C) from magma-derived (delta 18 O = 9.6-9.7ppm), low-salinity (1-2 wt % NaCl equiv) fluid. This hydrothermal fluid was generally low density and CO 2 rich. All other veins were formed from regionally derived fluid in equilibrium with metamorphic rocks (delta 18 O = 7.9 + or - 1.0ppm at the site of deposition). This fluid probably scavenged most of the period 2 ore-mineral components from a postulated granite batholith whose existence is indicated by a 6-mGal gravity low centered on the deposit. The greisen-bordered tungsten veins (period 2) formed from fluids in the liquid state at temperatures mostly between 380 degrees and 440 degrees C with salinities between 4.5 and 10.9 wt percent NaCl equiv. Late, barren veins (period 3) formed from liquids with salinities between 0.0 and 3.5 wt percent NaCl equiv at temperatures as low as 120 degrees C. The veins at Baid al Jimalah East formed from liquids with salinities between 0 and 4.2 wt percent NaCl equiv at temperatures mostly between about 340 degrees and 390 degrees C. Important volatile constituents in some hydrothermal fluids were CO 2 and CH 4 , in addition to H 2 O and HF. The delta 18 O data on mineral separates of fresh and altered Bald al Jimalah granite, and whole-rock delta 18 O data on country-rock samples as far as 16 km from the deposit, indicate that the rocks in the Bald al Jimalah area were pervasively infiltrated by a fluid with relatively high delta 18 O values. Interaction and exchange of the country rocks with this delta 18 O fluid led to an increase in the delta 18 O values of volcanic rocks of the Jurdhawiyah Group but to a decrease in the delta 18 O values of the high value delta 18 O Murdama Group sandstones, resulting in a hydrothermal anomaly exceeding 100 km 2 in area. This fluid had an estimated delta 18 O value of about 6 to 8 per mil, essentially identical to that of the metamorphic water calculated from the vein quartz, thus strongly supporting the conclusion that all of the mineral deposits at Baid al Jimalah (except for the early-stage quartz-molybdenite veins), as well as the 12-km 2 geochemical anomaly surrounding the deposit, were from the same metamorphic fluid.Bald al Jimalah is similar in character and origin to Phanerozoic tungsten-tin greisen deposits throughout the world, especially the Hemerdon deposit in Devon, England. It is also analogous to Climax-type molybdenum deposits, which contain virtually identical mineral assemblages, but with the relative proportions of molybdenum and tungsten mineralization reversed, primarily owing to differences in oxygen fugacity. This similarity in mineralization styles and fluid histories indicates that metallogenic processes in granite-related deposits in the late Precambrian were similar to those seen in the Phanerozoic.

Economic Geology↗

Oxygen isotope map of the giant metamorphic-hydrothermal system around the northern part of the Idaho batholith, U.S.A.

Determinations of δ 18 O values from 100 outcrops of Belt Supergroup (Wallace Fm.) metasedimentary rocks in the Idaho panhandle reveal a regular regional pattern that was produced by pervasive fluid infiltration and isotopic exchange. Low grade argillites at large distances (60 km) from the Idaho batholith have high δ 18 O values +15, compatible with their probable primary values. Pelitic rocks with anomalously low δ 18 O values of + 8.7 to + 12.7‰ occur in the following zones: (1) in a 5000 km 2 zone of schist and gneiss peripheral to the Idaho batholith, generally coincident with high-grade (sillimanite-bearing) assemblages; (2) in high-grade metasedimentary roof pendants within the Idaho batholith; (3) peripheral to small Cretaceous stocks; and (4) within and near the scapolite-bearing zone south-west of St. Regis. On δ 18 O−δ 18 O plots, data from coexisting minerals define trends with unit slopes, indicating that the reductions in 18 O occurred under high-grade metamorphic conditions. This metamorphism culminated in the emplacement of the Idaho batholith, probably as a consequence of profound crustal thickening associated with the Cretaceous accretion of the Wallowa-Seven Devils arc terranes with North America. The huge low- 18 O region is bounded by a “steep” δ 18 O gradient (0.1–0.5‰/km) that occurs in low-grade rocks along and near the Lewis and Clark Line, well below the biotite isograd. This boundary zone may be analogous to, but is not nearly as sharp as, those of meteoric-hydrothermal systems in many regions. The important ore deposits of the Coeur d'Alene district are located in this peripheral zone, suggesting that the metamorphic-hydrothermal system may have been intimately involved in their formation. In addition, the metamorphic-hydrotermal system in Idaho is larger, deeper and higher in temperature than typical meteoric-hydrothermal systems, and it involved fluids with much higher δ 18 O values that were probably dominantly derived from formation waters. Accordingly, this system produced rocks with δ 18 O values similar to those of the Idaho batholith, and mineral assemblages that approach isotopic equilibrium under high temperature conditions.

Idaho↗

Oxygen isotope exchange kinetics of mineral pairs in closed and open systems: Applications to problems of hydrothermal alteration of igneous rocks and Precambrian iron formations

The systematics of stable-isotope exchange between minerals and fluids are examined in the context of modal mineralogical variations and mass-balance considerations, both in closed and in open systems. On mineral-pair ??18O plots, samples from terranes that have exchanged with large amounts of fluid typically map out steep positively-sloped non-equilibrium arrays. Analytical models are derived to explain these effects; these models allow for different exchange rates between the various minerals and the external fluids, as well as different fluid fluxes. The steep arrays are adequately modelled by calculated isochron lines that involve the whole family of possible exchange trajectories. These isochrons have initially-steep near-vertical positive slopes that rotate toward a 45?? equilibrium slope as the exchange process proceeds to completion. The actual data-point array is thus analogous to the hand of an "isotopic clock" that measures the duration of the hydrothermal episode. The dimensionless ratio of the volumetric fluid flux to the kinetic rate parameter ( u k) determines the shape of each individual exchange trajectory. In a fluid-buffered system ( u k ??? 1), the solutions to the equations: (1) are independent of the mole fractions of the solid phases; (2) correspond to Taylor's open-system water/rock equation; and (3) yield straight-line isochrons that have slopes that approach 1 f, where f is the fraction reacted of the more sluggishly exchanging mineral. The isochrons for this simple exchange model are closely congruent with the isochrons calculated for all of the more complex models, thereby simplifying the application of theory to actual hydrothermal systems in nature. In all of the models an order of magnitude of time (in units of kt) separates steep non-equilibrium arrays (e.g., slope ??? 10) from arrays approaching an equilibrium slope of unity on a ??-?? diagram. Because we know the approximate lifetimes of many hydrothermal systems from geologic and heat-balance constraints, we can utilize the 18O 16O data on natural mineral assemblages to calculate the kinetic rate constants (k's) and the effective diffusion constants (D's) for mineral-H2O exchange: these calculated values (kqtz ??? 10-14, kfeld ??? 10-13-10-12) agree with experimental determinations of such constants. In nature, once the driving force or energy source for the external infiltrating fluid phase is removed, the disequilibrium mineral-pair arrays will either: (1) remain "frozen" in their existing state, if the temperatures are low enough, or (2) re-equilibrate along specific closed-system exchange vectors determined solely by the temperature path and the mineral modal proportions. Thus, modal mineralogical information is a particularly important parameter in both the open- and closed-system scenarios, and should in general always be reported in stable-isotopic studies of mineral assemblages. These concepts are applied to an analysis of 18O 16O systematics of gabbros (Plagioclase-clinopyroxene and plagioclase-amphibole pairs), granitic plutons (quartz-feldspar pairs), and Precambrian siliceous iron formations (quartz-magnetite pairs). In all these examples, striking regularities are observed on ??-?? and ??-?? plots, but we point out that ??-?? plots have many advantages over their equivalent ??-?? diagrams, as the latter are more susceptible to misinterpretation. Using the equations developed in this study, these regularities can be interpreted to give semiquantitative information on the exchange histories of these rocks subsequent to their formation. In particular, we present a new interpretation indicating that Precambrian cherty iron formations have in general undergone a complex fluid exchange history in which the iron oxide (magnetite precursor?) has exchanged much faster with low-temperature (< 400??C) fluids than has the relatively inert quartz. ?? 1989.

Chemical Geology↗

An oxygen isotope and geochemical study of meteoric-hydrothermal systems at Pilot Mountain and selected other localities, Carolina slate belt

Several epigenetic mineral deposits in the Ca1rolina slate belt are intimately related to meteoric-hydrothermal systems of late Precambrian and early Paleozoic age. At Pilot Mountain, low 18 O rocks correlate well with zones of strong silicic alteration and alkali leaching accompanied by high alumina minerals (sericite, pyrophyllite, andalusite + or - topaz) and anomalous concentrations of Cu, Mo, Sn, B, and Au. The alteration occurs within andesitic volcanic and volcaniclastic rocks and is associated with a subvolcanic(?) dacite porphyry stock on the southeastern slope of the mountain. Tilting and erosion have exposed an oblique section through the original system, interpreted to expose shallower rocks to the northwest. A 4-km 2 central zone of slight 18 O depletion (delta 18 O (sub whole rock) = 4.3-6.1ppm) occurs on the broad and resistant (silicifled) western flank of Pilot Mountain, predominantly within quartz-sericite schist and quartz granofels containing pods of high A1 minerals. A magmatic source for much of the sulfur and metal is likely, and a subordinate magmatic water component in the fluid of the central zone is possible. This central zone is surrounded by a >30-km 2 peripheral zone of low 18 O sericite schists, chlorite-sericite schists, and andesitic volcanic rocks (delta 18 O (sub whole rock) < 3.8ppm), with the lowest values (1.4ppm) occurring in intensely sericitized rocks on the eastern flank of Pilot Mountain, near the apex of the dacite porphyry stock. Rhyolites of the Uwharrie Formation (delta 18 O = 3.8-6.3ppm) are not as strongly altered as nearby andesites and may postdate the hydrothermal alteration. The fluid calculated to be in equilibrium with the lowest 18 O quartz veins and country rocks at 300 degrees + or - 50 degrees C would have delta 18 O approximately -4.5 + or - 2.0 per mil, whereas analyses of radiating pyrophyllite indicate equilibrium with a fluid having delta D approximately -30 per mil, consistent with a slightly 18 O-shifted, low-latitude meteoric water. Subsequent greenschist metamorphism caused intermineral isotopic reequilibration in several samples and may have modified preexisting alteration assemblages, but it did not destroy the large delta 18 O anomaly produced by meteoric-hydrothermal activity at Pilot Mountain. Reconnaissance studies of other alteration zones in the Carolina slate belt have so far disclosed the involvement of meteoric-hydrothermal fluids at the Snow Camp pyrophyllite deposit, at the Hoover Hill and Sawyer Au mines, and probably at the Haile and Brewer Au mines.

Economic Geology↗

Kinetic theory of oxygen isotopic exchange between minerals and water

Kinetic and mass conservation equations are used to describe oxygen isotopic exchange between minerals and water in "closed" and open hydrothermal systems. In cases where n coexisting mineral phases having different reaction rates are present, the exchange process is described by a system of n + 1 simultaneous differential equations consisting of n pseudo first-order rate equations and a conservation of mass equation. The simultaneous solutions to these equations generate curved exchange trajectories on ??-?? plots. Families of such trajectories generated under conditions allowing for different fluid mole fractions, different fluid isotopic compositions, or different fluid flow rates are connected by positive-sloped isochronous lines. These isochrons reproduce the effects observed in hydrothermally exchanged mineral pairs including 1) steep positive slopes, 2) common reversals in the measured fractionation factors (??), and 3) measured fractionations that are highly variable over short distances where no thermal gradient can be geologically demonstrated. ?? 1987.

Geochimica et Cosmochimica Acta↗

xygen isotope, aeromagnetic, and gravity anomalies associated with hydrothermally altered zones in the Yankee Fork mining district, Custer County, Idaho

Epithermal Ag-Au vein and disseminated deposits in the Yankee Fork district are hosted in altered volcanic rocks having low delta 18 O values, low magnetic susceptibilities, low remanent magnetizations, and relatively high densities. These isotopic and physical quantities provide sensitive indices of rock alteration that can be contoured over areas that are much larger than zones of strong visible alteration. Such contour maps reveal a marked spatial association between the ore deposits, the steepest delta 18 O gradients, and the perimeter of zones where the rocks have extremely low total magnetizations. The oxygen isotope results indicate that the ore zones coincide with steep gradients in temperature and water/rock ratio in two fossil hydrothermal convective systems that involved fluids derived from Tertiary meteoric waters. Our magnetic measurements suggest that these same high-gradient zones also coincide with oxidation-reduction boundaries. Low aeromagnetic intensities and positive Bouguer anomalies are also associated with the altered zones in the Yankee Fork district. The intensities of these geophysical features are consistent with the size of the altered zones and with the contrast in physical properties between altered and unaltered rocks. Contour maps of the magnetic and isotopic properties of host rocks should find application in exploration for a variety of types of hydrothermal ore deposits, as well as in the study of ore controls and conditions of mineralization.

Economic Geology↗

Strontium and oxygen isotopic variations in Mesozoic and Tertiary plutons of central Idaho

Regional variations in initial 87Sr/86Sr ratios (ri) of Mesozoic plutons in central Idaho locate the edge of Precambrian continental crust at the boundary between the late Paleozoic-Mesozoic accreted terranes and Precambrian sialic crust in western Idaho. The ri values increase abruptly but continuously from less than 0.704 in the accreted terranes to greater than 0.708 across a narrow, 5 to 15 km zone, characterized by elongate, lens-shaped, highly deformed plutons and schistose metasedimentary and metavolcanic units. The chemical and petrologic character of the plutons changes concomitantly from ocean-arc-type, diorite-tonalite-trondhjemite units to a weakly peraluminous, calcic to calcalkalic tonalite-granodiorite-granite suite (the Idaho batholith). Plutons in both suites yield Late Cretaceous ages, but Permian through Early Cretaceous bodies are confined to the accreted terranes and early Tertiary intrusions are restricted to areas underlain by Precambrian crust. The two major terranes were juxtaposed between 75 and 130 m.y. ago, probably between 80 and 95 m.y. Oxygen and strontium isotopic ratios and Rb and Sr concentrations of the plutonic rocks document a significant upper-crustal contribution to the magmas that intrude Precambrian crust. Magmas intruding the arc terranes were derived from the upper mantle/subducted oceanic lithosphere and may have been modified by anatexis of earlier island-arc volcanic and sedimentary units. Plutons near the edge of Precambrian sialic crust represent simple mixtures of the Precambrian wall-rocks with melts derived from the upper mantle or subducted oceanic lithosphere with ri of 0.7035. Rb/Sr varies linearly with ri, producing "pseudoisochrons" with apparent "ages" close to the age of the wall rocks. Measured ??18O values of the wall rocks are less than those required for the assimilated end-member by Sr-O covariation in the plutons, however, indicating that wall-rock ??18O was reduced significantly by exchange with circulating fluids. Metasedimentary rocks of the Belt Supergroup are similarly affected near the batholith, documenting a systematic depletion in 18O as much as 50 km from the margin of the batholith. Plutons of the Bitterroot lobe of the Idaho batholith are remote from the accreted terranes and represent mixtures of Precambrian wall-rocks with melts dominated by continental lower crust (ri>0.708) rather than mantle. "Pseudoisochrons" resulting from these data are actually mixing lines that yield apparent "ages" less than the true age of the wall rocks and meaningless "ri". Assimilation/ fractional-crystallization models permit only insignificant amounts of crystal fractionation during anatexis and mixing for the majority of plutons of the region. ?? 1985 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Casto Ring Zone: A 4,500-km2 fossil hydrothermal system in the Challis Volcanic Field, central Idaho

δ 18 O analyses of granitic and volcanic rocks reveal the largest hydrothermal system ever documented around a single granite pluton, occupying a 4,500-km 2 area in central Idaho. The remains of this meteoric-hydrothermal system are principally preserved within a sharply bounded, 15-km-wide, 70-km-diameter annulus of low δ 18 O rock (+2.0 to −8.8‰) termed the Casto Ring Zone. The zone centered on a less depleted (+4.5) core zone consisting of granitic rocks of the Casto pluton. This 700-km 2 Eocene subvolcanic batholith has intruded, domed, and hydrothermally metamorphosed a thick sequence of Challis Volcanics, the stratigraphically low rocks in the 2,000-km 2 Van Horn Peak and the 1,000-km 2 Thunder Mountain cauldron complexes being most strongly altered. Less extreme 18 O depletions occur in the youngest major ash-flow sheets of these complexes, indicating a vertical 18 O gradient. Water/rock ratios of geothermal systems are surprisingly insensitive to the circulation scale.

Geology↗