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R. M. Yager

Publications and source records attributed to R. M. Yager.

15 recordsLinked to original sources

Comparison of alternative representations of hydraulic-conductivity anisotropy in folded fractured-sedimentary rock: Modeling groundwater flow in the Shenandoah Valley (USA)

A numerical representation that explicitly represents the generalized three-dimensional anisotropy of folded fractured-sedimentary rocks in a groundwater model best reproduces the salient features of the flow system in the Shenandoah Valley, USA. This conclusion results from a comparison of four alternative representations of anisotropy in which the hydraulic-conductivity tensor represents the bedrock structure as (model A) anisotropic with variable strikes and dips, (model B) horizontally anisotropic with a uniform strike, (model C) horizontally anisotropic with variable strikes, and (model D) isotropic. Simulations using the US Geological Survey groundwater flow and transport model SUTRA are based on a representation of hydraulic conductivity that conforms to bedding planes in a three-dimensional structural model of the valley that duplicates the pattern of folded sedimentary rocks. In the most general representation, (model A), the directions of maximum and medium hydraulic conductivity conform to the strike and dip of bedding, respectively, while the minimum hydraulic-conductivity direction is perpendicular to bedding. Model A produced a physically realistic flow system that reflects the underlying bedrock structure, with a flow field that is significantly different from those produced by the other three models.

Hydrogeology Journal↗

Effect of natural gas exsolution on specific storage in a confined aquifer undergoing water level decline

The specific storage of a porous medium, a function of the compressibility of the aquifer material and the fluid within it, is essentially constant under normal hydrologic conditions. Gases dissolved in ground water can increase the effective specific storage of a confined aquifer, however, during water level declines. This causes a reduction in pore pressure that lowers the gas solubility and results in exsolution. The exsolved gas then displaces water from storage, and the specific storage increases because gas compressibility is typically much greater than that of water or aquifer material. This work describes the effective specific storage of a confined aquifer exsolving dissolved gas as a function of hydraulic head and the dimensionless Henry's law constant for the gas. This relation is applied in a transient simulation of ground water discharge from a confined aquifer system to a collapsed salt mine in the Genesee Valley in western New York. Results indicate that exsolution of gas significantly increased the effective specific storage in the aquifer system, thereby decreasing the water level drawdown.

Ground Water↗

Effects of model sensitivity and nonlinearity on nonlinear regression of ground water flow

Nonlinear regression is increasingly applied to the calibration of hydrologic models through the use of perturbation methods to compute the Jacobian or sensitivity matrix required by the Gauss-Newton optimization method. Sensitivities obtained by perturbation methods can be less accurate than those obtained by direct differentiation, however, and concern has arisen that the optimal parameter values and the associated parameter covariance matrix computed by perturbation could also be less accurate. Sensitivities computed by both perturbation and direct differentiation were applied in nonlinear regression calibration of seven ground water flow models. The two methods gave virtually identical optimum parameter values and covariances for the three models that were relatively linear and two of the models that were relatively nonlinear, but gave widely differing results for two other nonlinear models. The perturbation method performed better than direct differentiation in some regressions with the nonlinear models, apparently because approximate sensitivities computed for an interval yielded better search directions than did more accurately computed sensitivities for a point. The method selected to avoid overshooting minima on the error surface when updating parameter values with the Gauss-Newton procedure appears for nonlinear models to be more important than the method of sensitivity calculation in controlling regression convergence.

Ground Water↗

Further biogeochemical characterization of a trichloroethene-contaminated fractured dolomite aquifer: Electron source and microbial communities involved in reductive dechlorination

A recent article presented geochemical and microbial evidence establishing metabolic adaptation to and in-situ reductive dechlorination of trichloroethene (TCE) in a fractured dolomite aquifer. This study was designed to further explore site conditions and microbial populations and to explain previously reported enhancement of reductive dechlorination by the addition of pulverized dolomite to laboratory microcosms. A survey of groundwater geochemical parameters (chlorinated ethenes, ethene, H2, CH4, DIC, DOC, and ??13C values for CH4, DIC, and DOC) indicated that in situ reductive dechlorination was ongoing and that an unidentified pool of organic carbon was contributing, likely via microbial respiration, to the large and relatively light onsite DIC pool. Petroleum hydrocarbons associated with the dolomite rock were analyzed by GC/MS and featured a characteristically low ??13C value. Straight chain hydrocarbons were extracted from the dolomite previously found to stimulate reductive dechlorination; these were particularly depleted in hexadecane (HD). Thus, we hypothesized that HD and related hydrocarbons might be anaerobically respired and serve both as the source of onsite DIC and support reductive dechlorination of TCE. Microcosms amended with pulverized dolomite demonstrated reductive dechlorination, whereas a combusted dolomite amendment did not. HD-amended microcosms were also inactive. Therefore, the stimulatory factor in the pulverized dolomite was heat labile, but that component was not HD. Amplified Ribosomal DNA Restriction Analysis (ARDRA) of the microbial populations in well waters indicated that a relatively low diversity, sulfur-transforming community outside the plume was shifted toward a high diversity community including Dehalococcoides ethenogenes-type microorganisms inside the zone of contamination. These observations illustrate biogeochemical intricacies of in situ reductive dechlorination reactions.

Environmental Science & Technology↗

Infiltration and hydraulic connections from the Niagara River to a fractured-dolomite aquifer in Niagara Falls, New York

The spatial distribution of hydrogen and oxygen stable-isotope values in groundwater can be used to distinguish different sources of recharge and to trace groundwater flow directions from recharge boundaries. This method can be particularly useful in fractured-rock settings where multiple lines of evidence are required to delineate preferential flow paths that result from heterogeneity within fracture zones. Flow paths delineated with stable isotopes can be combined with hydraulic data to form a more complete picture of the groundwater flow system. In this study values of ??D and ??18O were used to delineate paths of river-water infiltration into the Lockport Group, a fractured dolomite aquifer, and to compute the percentage of fiver water in groundwater samples from shallow bedrock wells. Flow paths were correlated with areas of high hydraulic diffusivity in the shallow bedrock that were delineated from water-level fluctuations induced by diurnal stage fluctuations in man-made hydraulic structures. Flow paths delineated with the stable-isotope and hydraulic data suggest that fiver infiltration reaches an unlined storm sewer in the bedrock through a drainage system that surrounds aqueducts carrying river water to hydroelectric power plants. This finding is significant because the storm sewer is the discharge point for contaminated groundwater from several chemical waste-disposal sites and the cost of treating the storm sewer's discharge could be reduced if the volume of infiltration from the river were decreased.The spatial distribution of hydrogen and oxygen stable-isotope values in groundwater can be used to distinguish different sources of recharge and to trace groundwater flow directions from recharge boundaries. This method can be particularly useful in fractured-rock settings where multiple lines of evidence are required to delineate preferential flow paths that result from heterogeneity within fracture zones. Flow paths delineated with stable isotopes can be combined with hydraulic data to form a more complete picture of the groundwater flow system. In this study values of ??D and ??18O were used to delineate paths of river-water infiltration into the Lockport Group, a fractured dolomite aquifer, and to compute the percentage of river water in groundwater samples from shallow bedrock wells. Flow paths were correlated with areas of high hydraulic diffusivity in the shallow bedrock that were delineated from water-level fluctuations induced by diurnal stage fluctuations in man-made hydraulic structures. Flow paths delineated with the stable-isotope and hydraulic data suggest that river infiltration reaches an unlined storm sewer in the bedrock through a drainage system that surrounds aqueducts carrying river water to hydroelectric power plants. This finding is significant because the storm sewer is the discharge point for contaminated groundwater from several chemical waste-disposal sites and the cost of treating the storm sewer's discharge could be reduced if the volume of infiltration from the river were decreased.

Journal of Hydrology↗

Metabolic adaptation and in situ attenuation of chlorinated ethenes by naturally occurring microorganisms in a fractured dolomite aquifer near Niagara Falls, New York

A combination of hydrogeological, geochemical, and microbiological methods was used to document the biotransformation of trichloroethene (TCE) to ethene, a completely dechlorinated and environmentally benign compound, by naturally occurring microorganisms within a fractured dolomite aquifer. Analyses of groundwater samples showed that three microbially produced TCE breakdown products (cis-1,2-dichloroethene, vinyl chloride, and ethene) were present in the contaminant plume. Hydrogen (H2) concentrations in groundwater indicated that iron reduction was the predominant terminal electron-accepting process in the most contaminated geologic zone of the site. Laboratory microcosms prepared with groundwater demonstrated complete sequential dechlorination of TCE to ethene. Microcosm assays also revealed that reductive dechlorination activity was present in waters from the center but not from the periphery of the contaminant plume. This dechlorination activity indicated that naturally occurring microorganisms have adapted to utilize chlorinated ethenes and suggested that dehalorespiring rather than cometabolic, microbial processes were the cause of the dechlorination. The addition of pulverized dolomite to microcosms enhanced the rate of reductive dechlorination, suggesting that hydrocarbons in the dolomite aquifer may serve as electron donors to drive microbially mediated reductive dechlorination reactions. Biodegradation of the chlorinated ethenes appears to contribute significantly to decontamination of the site.A combination of hydrogeological, geochemical, and microbiological methods was used to document the biotransformation of trichloroethene (TCE) to ethene, a completely dechlorinated and environmentally benign compound, by naturally occurring microorganisms within a fractured dolomite aquifer. Analyses of groundwater samples showed that three microbially produced TCE breakdown products (cis-1,2-dichloroethene, vinyl chloride, and ethene) were present in the contaminant plume. Hydrogen (H2) concentrations in groundwater indicated that iron reduction was the predominant terminal electron-accepting process in the most contaminated geologic zone of the site. Laboratory microcosms prepared with groundwater demonstrated complete sequential dechlorination of TCE to ethene. Microcosm assays also revealed that reductive dechlorination activity was present in waters from the center but not from the periphery of the contaminant plume. This dechlorination activity indicated that naturally occurring microorganisms have adapted to utilize chlorinated ethenes and suggested that dehalorespiring rather than cometabolic, microbial processes were the cause of the dechlorination. The addition of pulverized dolomite to microcosms enhanced the rate of reductive dechlorination, suggesting that hydrocarbons in the dolomite aquifer may serve as electron donors to drive microbially mediated reductive dechlorination reactions. Biodegradation of the chlorinated ethenes appears to contribute significantly to decontamination of the site.

Environmental Science & Technology↗

Nitrogen transport in a shallow outwash aquifer at Olean, Cattaraugus County, New York

Groundwater beneath an industrial park at Olean, New York, contained nitrogen compounds in concentrations that in 1983 ranged from 10 to 1,280 mg/L as nitrogen, mainly in the form of ammonium. Continuous pumping from an industrial well field creates a cone of depression that prevents the nitrogen compounds from migrating to municipal-supply wells, 7,000 ft away. A two-dimensional solute transport model was used to simulate changes in nitrogen concentrations that would result from a permanent shutdown of the well field. The model assumed the nitrogen source decayed at an exponential rate with a decay constant of 0.3/year to account for nitrogen removed from the aquifer by pumping during 1978-84. The source of contamination was found to be sensitive to the volume of pumpage at the industrial well field, which altered the rate of groundwater flow through the contaminated area. Simulations of a permanent shutdown of the well field, assuming nitrogen migrates as a conservative solute, indicated that nitrogen-bearing groundwater would reach the municipal well field within 5 years and the peak concentrations at the municipal well field would range from 2 to 5 mg/L. Simulations of Langmuir adsorption of the dissolved ammonium with a one-dimensional model indicated that the arrival of the solute front at the municipal well field would be retarded by a factor of three.

New York↗

Geohydrologic conditions at the nuclear-fuels reprocessing plant and waste-management facilities at the Western New York Nuclear Service Center, Cattaraugus County, New York

A nuclear-fuel reprocessing plant, a high-level radioactive liquid-waste tank complex, and related waste facilities occupy 100 hectares (ha) within the Western New York Nuclear Service Center near West Valley, N.Y. The facilities are underlain by glacial and postglacial deposits that fill an ancestrial bedrock valley. The main plant facilities are on an elevated plateau referred to as the north plateau. Groundwater on the north plateau moves laterally within a surficial sand and gravel from the main plant building to areas northeast, east, and southeast of the facilities. The sand and gravel ranges from 1 to 10 m thick and has a hydraulic conductivity ranging from 0.1 to 7.9 m/day. Two separate burial grounds, a 4-ha area for low-level radioactive waste disposal and a 2.9-ha area for disposal of higher-level waste are excavated into a clay-rich till that ranges from 22 to 28 m thick. Migration of an organic solvent from the area of higher level waste at shallow depth in the till suggests that a shallow, fractured, oxidized, and weathered till is a significant pathway for lateral movement of groundwater. Below this zone, groundwater moves vertically downward through the till to recharge a lacustrine silt and fine sand. Within the saturated parts of the lacustrine unit, groundwater moves laterally to the northeast toward Buttermilk Creek. Hydraulic conductivity of the till, based on field and laboratory analyses , ranges from 0.000018 to 0.000086 m/day.

New York↗

Simulation of ground-water flow near the nuclear-fuel reprocessing facility at the Western New York Nuclear Service Center, Cattaraugus County, New York

A two-dimensional finite-difference model was developed to simulate groundwater flow in a surficial sand and gravel deposit underlying the nuclear fuel reprocessing facility at Western New York Nuclear Service Center near West Valley, N.Y. The sand and gravel deposit overlies a till plateau that abuts an upland area of siltstone and shale on its west side, and is bounded on the other three sides by deeply incised stream channels that drain to Buttermilk Creek, a tributary to Cattaraugus Creek. Radioactive materials are stored within the reprocessing plant and are also buried within a till deposit at the facility. Tritiated water is stored in a lagoon system near the plant and released under permit to Franks Creek, a tributary to Buttermilk Creek. Groundwater levels predicted by steady-state simulations closely matched those measured in 23 observation wells, with an average error of 0.5 meter. Simulated groundwater discharges to two stream channels and a subsurface drain were within 5% of recorded values. Steady-state simulations used an average annual recharge rate of 46 cm/yr; predicted evapotranspiration loss from the ground was 20 cm/yr. The lateral range in hydraulic conductivity obtained through model calibration was 0.6 to 10 m/day. Model simulations indicated that 33% of the groundwater discharged from the sand and gravel unit (2.6 L/sec) is lost by evapotranspiration, 3% (3.0 L/sec) flows to seepage faces at the periphery of the plateau, 20% (1.6 L/sec) discharges to stream channels that drain a large wetland area near the center of the plateau, and the remaining 8% (0.6 L/sec) discharges to a subsurface french drain and to a wastewater treatment system. Groundwater levels computed by a transient-state simulation of an annual climatic cycle, including seasonal variation in recharge and evapotranspiration, closely matched water levels measured in eight observation wells. The model predicted that the subsurface drain and the stream channel that drains the wetland would intercept most of the recharge originating near the reprocessing plant. (Lantz-PTT)

Water-Resources Investigations Report↗

Quantity and quality of urban storm runoff in the Irondequoit Creek basin near Rochester, New York: Part 2,.Quality of storm runoff and atmospheric deposition, rainfall-runoff-quality modeling and potential of wetlands for sediment and nutrient retention

Water quality data collected at 17 sites in urbanized and rural parts of the 438 sq km Irondequoit Creek basin from July 1980 through August 1981 were used to compute annual loads of eight selected constituents. Of the total annual loads of these constituents, 50 to 70% was transported to Irondequoit Bay during a 3.5-month period from late January to early May. Of six mixed-land-use subbasins, the two most highly urbanized had the highest loads of all constituents. Of the four sites representing single land uses, the high density residential site and the housing construction site had the highest loads of all constituents except cadmium. A rainfall-runoff model was used to predict quantity and quality of storm runoff leaving one commercial site, two residential sites, and a large mixed-land-use subbasin. Predicted volume and peak discharges were within 10 to 30% of the measured values; predicted runoff loads of most constituents were within 40 to 60% of measured values. Stormflow modification in the Irondequoit Creek wetlands by two hypothetical control structures was simulated. Results indicate that outflow from the upper wetland could be decreased and stormflows dispersed to a greater part of the upper wetland to increase retention of suspended solids and associated chemical constituents.

New York↗

Simulation of ground-water flow and infiltration from the Susquehanna River to a shallow aquifer at Kirkwood and Conklin, Broome County, New York

A four-layer finite difference model was developed to simulate groundwater flow and induced infiltration to an aquifer underlying the Susquehanna River in the Towns of Kirkwood and Conklin in Broome County, NY. The aquifer consists of sand and gravel deposited in an ancestral river valley during the recession of glacial ice and is in hydraulic connection with the Susquehanna River. In 1984, he aquifer supplied 1.2 million gal/day to well fields in Kirkwood and Conklin. Horizontal hydraulic conductivity of the sand and gravel in the calibrated model ranges from 50 to 10,000 ft/day. Vertical hydraulic conductivity ranges from 1.0 to 80 ft/day. The riverbed thickness was estimated from results of piezometer tests to be 2 ft; the hydraulic conductivity of the riverbed was estimated to be 0.2 ft/day. Root-mean-square differences between computed drawdowns and drawdowns measured in observation wells and piezometers during aquifer tests at the Kirkwood well field ranged from 17% to 24%. The sizes of the well field catchment areas were estimated from a model generated flow net showing the direction and rate of groundwater flow. The Kirkwood catchment area was estimated to be 250 acres, and the Conklin catchment area was 51 acres. Groundwater budgets computed by steady-state simulations showed that 58% of the groundwater withdrawn by the Kirkwood well field is derived from the Susquehanna River during the periods of low river stage and low recharge. The factor to which induced-infiltration rate and size of well field catchment areas are most sensitive, is riverbed hydraulic conductivity.

New York↗

Quantity and quality of storm runoff in the Irondequoit Creek basin near Rochester, New York; Part 1. Data-collection network and methods, quality-assurance program, and description of available data

A 14-month data collection program of quantity and quality of storm precipitation and runoff was conducted in the Irondequoit Creek basin, a 438-sq km area along the south shore of Lake Ontario in north-central New York, from July 1980 through August 1981. The data from a basis for study of nutrient inflow to Irondequoit Bay. This report describes the methods used to collect and verify the data and includes some representative examples of the data base. Stream discharge and water quality data were collected at 17 sites representing rural and urban land uses. Precipitation data were collected at five continuous-record gages and 11 daily total gages. Evaporation data were collected at one site; chemical quality of precipitation and dustfall data were collected at four sites. Tables list watershed characteristics, precipitation data (including chemical quality of atmospheric deposition, monthly precipitation, and evaporation), and annual loadings of eight selected nutrients and heavy metals from the five major subbasins and three discrete land-use site. Examples of computer printouts of streamflow, precipitation, and water quality data available from the Geological Survey 's WATSTORE computer system are included. (USGS)

New York↗