Geology topics
R. L. Hay
Publications and source records attributed to R. L. Hay.
Carbonatite tuffs in the Laetolil Beds of Tanzania and the Kaiserstuhl in Germany
Carbonatite lava and tephra are now well known. The only modern eruptive carbonatites, from Oldoinyo Lengai, Tanzania, are of alkali carbonatite, whereas all of the pre-modern examples are of calcite or dolomite. Chemical and stable isotope analyses were made of separate phases of Pliocene carbonatite tuffs of the Laetolil Beds in Tanzania and of Miocene carbonatite tuffs of the Kaiserstuhl in Germany in order to understand the reasons for this major difference. The Laetolil Beds contain numerous carbonatite and melilitite-carbonatite tuffs. It is proposed that the carbonatite ash was originally of alkali carbonate composition and that the alkali component was dissolved, leaving a residuum of calcium carbonate. The least recrystallized melilitite-carbonatite tuff contains early-deposited calcite cement and calcite pseudomorphs after nyerereite (?) that have contents of strontium and barium and ??18O and ??13C values suggestive of incomplete chemical and isotopic exchange during alteration and replacement of alkali carbonatite ash. Carbonatite tuffs of the Kaiserstuhl contain globules composed of calcite phenocrysts and microphenocrysts in a groundmass of calcite with a small amount of clay, apatite, and magnetite. The SrO contents of phenocrysts, microphenocrysts, and groundmass calcite average 0.90, 1.42, and 0.59 percent, respectively. The average ??18O and ??13C values of globules (+14.3 and -9.0, respectively) fall between those of coarse-grained intrusive Kaiserstuhl carbonatite (avg. +6.6, -5.8) and those of low-temperature calcite cement in the carbonatite tuffs (+21.8, -14.9). The phenocrysts and microphenocrysts are primary magmatic calcite, but several features indicate that the groundmass has been recrystallized and altered in contact with meteoric water, resulting in weathering of silicate to clay, leaching of strontium, and isotopic exchange. The weight of evidence favors an original high content of alkali carbonatite in the groundmass, with recrystallization following leaching of the alkalies. ?? 1983 Springer-Verlag.
18O 16O ratios in cherts associated with the saline lake deposits of East Africa
The cherts formed from sodium silicate precursors in East African saline, alkaline lakes have δ 18 O values ranging from 31.1 to 44.1. The δ 18 O values correlate in general with lake salinities as inferred from geologic evidence, indicating that most chert was formed from its precursor in contact with lake water trapped at the time of deposition. A few of the analyzed cherts probably formed in contact with dilute meteoric water. From the widely varying δ 18 O values we conclude that precursors were transformed to chert in fluids of widely varying salinity and a Na + /a H + ratio.
Geomagnetic polarity epochs: age and duration of the olduvai normal polarity event
New data show that the Olduvai normal geomagnetic polarity event is represented in Olduvai Gorge, Tanzania, by rocks covering a time span of roughly from 0.1 to 0.2 my and is no older than 2.0 my. Hence the long normal polarity event of this age that is seen in deep-sea sediment cores and in magnetic profiles over oceanic ridges should be called the Olduvai event. The lava from which the Gilsàevent was defined may have been erupted during the Olduvai event and, if so, the term Gilsàshould now be abandoned. Many dated lavas that were originally assigned to the Olduvai event represent one or two much shorter normal polarity events that preceded the Olduvai event; these are herein named the Réunion normal polarity events. This revision brings the geomagnetic reversal time scale into conformity with the one implied by assumptions of uniform sedimentation rates on the ocean floor and uniform rates of sea-floor spreading.
Palaeomagnetism and potassium-argon ages of volcanic rocks of Ngorongoro caldera, Tanzania
Natural remanent magnetization (NRM) has been measured in 21 lava flows and 1 tuff in the south-west wall of Ngorongoro caldera, Tanzania. The lowest three lavas are normally magnetized, the next two have intermediate directions, and the remainder are reversed; potassium-argon dating places the reversal at 2.45 My, corresponding to the Gauss Matuyama epoch boundary. Alternating-field demagnetization was effective in removing the ubiquitous lightning-produced secondary magnetizations, but partial thermal demagnetization was not. Curie temperatures of the lavas fell into two groups: 250°–350°C and 570°–585°C, probably corresponding to unoxidized and oxidized titanomagnetites respectively. NRM directions in the lavas occurred in several distinct and stratigraphically continuous groups, suggesting intermittent eruption of groups of lavas. No correspondence was found between NRM groups and other parameters, such as Curie temperatures. The dispersion of mean NRM directions is large in comparison with late Quaternary lavas from low latitudes in the Pacific basin, but probably is not large relative to the proportion of the geomagnetic field in Africa that is non-dipolar. The mean palaeomagnetic pole is offset 10.5° from the geographic pole, but because of the large dispersion, the difference is not considered significant.