USGS ScienceSearch

Geology topics

R. J. Wagner

Publications and source records attributed to R. J. Wagner.

11 recordsLinked to original sources

Mercury species and other selected constituent concentrations in water, sediment, and biota of Sinclair Inlet, Kitsap County, Washington, 2007-10

This report presents data collected for two U.S. Geological Survey field sampling projects related to mercury (Hg) in Sinclair Inlet: (1) the Watersheds Sources Project that evaluated the sources of mercury to Sinclair Inlet during December 2007 to March 2010, and (2) the Methylation and Bioaccumulation Project, a comprehensive examination of mercury biogeochemistry in sediment, water, and zooplankton during August 2008–February 2010. For the Watershed Sources project, nonpoint and point sources of mercury to Sinclair Inlet from the Bremerton naval complex (BNC) were evaluated by using filtered total mercury and particulate total mercury measured in water samples collected from 11 wells, 2 dry dock sump discharges, and a steam plant's effluent at the BNC. Methylmercury sources to the inlet were examined by determining filtered methylmercury concentrations in water samples collected from five wells, two dry dock sump discharges, a steam plant's effluent, five intertidal piezometers, and three stormwater drains on the BNC, as well as in samples from five creeks, two wastewater treatment facilities, and three stormwater drains in the Sinclair Inlet watershed outside of the BNC. An improved understanding of tidally modulated mercury migration to Sinclair Inlet from the BNC was gained through three intensive nearshore (tidal) sampling events of mercury species in groundwater and a nearby stormwater drain. The Methylation and Bioaccumulation Project included a comprehensive field study of mercury biogeochemistry in marine sediment, water, and zooplankton in Sinclair Inlet. Mercury, iron, and sulfur species in sediment porewater from six sites within and three sites outside of Sinclair Inlet were measured to provide insight into the processes that produce methylmercury in the sediments. Total mercury, methylmercury, dissolved organic carbon, and redox-sensitive species were measured in porewaters in the top 2 centimeters of sediment, and these data were paired with sedimentary flux measurements from core incubation experiments to connect sedimentary processes to the water column. A broad-scale study of mercury methylation potential and mercury species at 20-plus stations in Sinclair Inlet was conducted in February 2009 and 2010, June 2009, and August 2009. Sedimentary flux measurements and analysis of mercury and biogeochemicals in sediment porewater and bottom water were made at six of the broad-scale stations. Bioaccumulation processes in the water column in the context of the sedimentary flux of methylmercury were examined using monthly survey data collected between August 2008 and August 2009. The survey data included concentrations of methylmercury and isotope ratios of carbon and nitrogen in bulk zooplankton measured at four stations in Sinclair Inlet in the context of the population of bulk zooplankton ascertained by taxonomical identification. The analysis of filtered total mercury, total particulate mercury, filtered methylmercury, particulate methylmercury, chlorophyll a, isotopes of carbon and nitrogen in suspended matter, and other biogeochemical data will facilitate the examination of the biogeochemistry of mercury in Sinclair Inlet.

Washington

Quality of water in the White River and Lake Tapps, Pierce County, Washington, May-December 2010

The White River and Lake Tapps are part of a hydropower system completed in 1911–12. The system begins with a diversion dam on the White River that routes a portion of White River water into the southeastern end of Lake Tapps, which functioned as a storage reservoir for power generation. The stored water passed through the hydroelectric facilities at the northwestern end of the lake and returned to the White River through the powerhouse tailrace. Power generation ceased in January 2004, which altered the hydrology of the system by reducing volumes of water diverted out of the river, stored, and released through the powerhouse. This study conducted from May to December 2010 created a set of baseline data collected under a new flow regime for selected reaches of the White River, the White River Canal (Inflow), Lake Tapps Diversion (Tailrace) at the powerhouse, and Lake Tapps. Three sites, one on the White River at Headworks, one on the White River at R Street, and one on the Tailrace, were equipped for continuous recording of water-quality data, and three sites (Headworks, White River Canal Inflow, and Tailrace) were sampled for discrete water-quality data. Nine lake sites were measured for physical and water-quality properties and samples were collected for analyses of nutrients, suspended solids, and fecal-coliform bacteria concentrations. Samples from the lake also were analyzed for concentrations of chlorophyll a and organic chemicals. Discrete samples indicated that water from the White River, White River Canal Inflow, and Tailrace sites generally was turbid, warm, chemically dilute, and well-oxygenated. Exceptions occurred at the sites when flow to the White River Canal was suspended or when little or no flow was released from the lake into the Tailrace. The quality of physical properties and concentrations in water measured continuously at the three sites generally was good and met the freshwater criteria designated by Washington State Department of Ecology for recreational and aquatic-life uses, with several exceptions. The 7-day average of daily maximum temperatures (7–DADMax) was greater than the freshwater aquatic life criterion of 16 degrees Celsius (°C) for core summer salmonid habitat on 6 days at the Headworks site and 37 days at the R-Street site during the study. The 7-DADMax temperatures were greater than the 13°C criterion for spawning, rearing, and incubation on 6 days at the Headworks site and 20 days at the R-Street site. The freshwater aquatic life criterion for dissolved oxygen of 9.5 milligrams per liter (mg/L) for core summer salmonid habitat was not met at the Headworks and R-Street sites for periods during July and August 2010. Exceptions also occurred at the Headworks site for measurements of pH, which were greater than the aquatic life upper limit of 8.5 pH units during July 2010. Aquatic life pH criteria were not met at the Tailrace site during June, July, and August 2010, when pH was greater than 8.5 pH units, and during August 2010 when pH decreased to less than 6.5 pH units. Lake Tapps water near the surface was relatively clear, warm, and well oxygenated. The clearest water of the nine lake sites was at the Deep site with a median Secchi disk transparency measurement of 6.05 m (meters), which represents a two- to six-fold increase over historical measurements of transparency at this location. Median water temperatures were 18.2–18.9°C and maximums were from 22.9–25.0°C. Median dissolved oxygen concentrations were greater than 8.42 mg/L and minimums generally were not lower than 7.4 mg/L. By early July 2010, weak thermal stratification developed at most lake sites into at least a warm surface layer overlying a small thermocline. A well-defined hypolimnion developed below the thermocline only at the Deep site. With the development of thermal stratification, hypolimnion water became anoxic at several sites (Deep, Tapps Island, Snag Island, and Lake Outlet). By late September 2010, an anoxic layer about 15 m thick had formed in the hypolimnion of the Deep site. Mixing during autumn overturn in late November re-oxygenated the water column of all the sites with about 10–12 mg/L of dissolved oxygen. On the basis of pH and specific conductance measurements, Lake Tapps water is pH neutral and chemically dilute. Median pH values for water in the epilimnion and the hypolimnion ranged from 6.84 to 7.64 pH units and maximums did not exceed 7.8 pH units at any site. Median specific conductance was typically less than 70 microsiemens per centimeter at 25°C for the epilimnion and the hypolimnion. Concentrations of nutrients and chlorophyll a in Lake Tapps were low. At most of the sites and in most of the samples from the epilimnion, total phosphorus concentrations were less than the Washington State Department of Ecology phosphorus criterion of 0.01 mg/L for maintaining oligotrophic conditions. Median concentrations of total nitrogen (unfiltered water) ranged from about 0.14 mg/L (Deep, Tapps Island, and Dike 2B sites) to about 0.18 mg/L (Allan Yorke and Lake Inlet sites). Chlorophyll a concentrations were low with median concentrations of 2.16 micrograms per liter (mg/L) or less. The majority of chlorophyll a concentrations were well below the Oregon Department of Environmental Quality action level of 10 mg/L. Using the Carlson Trophic-Status Index and average measures of transparency, chlorophyll a , and total phosphorus data from this study, Lake Tapps generally fits within the oligotrophic classification, but with a few exceptions. At Allan Yorke, Lake Inlet, and Southeast Arm sites, the chlorophyll a and total phosphorus indexes of nearly 40 approach the upper limit of oligotrophic conditions. In addition, average concentrations of total phosphorus at Lake Inlet and Southeast Arm are at Nürnberg's (1996) threshold concentration of 0.01 mg/L, which suggests a slight tendency towards mesotrophic conditions at these two sites during summer July–September. On the basis of epilimnetic nitrogen to phosphorus concentration ratios of greater than 17, Lake Tapps primary production is phosphorus limited at all but two study sites. At the Lake Inlet and Southeast Arm sites, ratios of 15 and 16, respectively, for the summer period suggest either nitrogen or phosphorus (or both) may limit algal growth. Water samples collected at the Allan Yorke, Snag Island, and Lake Outlet study sites were screened for the presence of more than 250 organic chemicals. A total of 14 compounds were detected in trace amounts (or determined to be present) at one or more of the 3 sites. The Allan Yorke site had 9 detections, the Snag Island site had 10 detections, and the Lake Outlet site had 5 detections of compounds mostly belonging to the group of wastewater indicator chemicals. Compounds detected (or with verified presence) at all three sites included the herbicide 2,4-D, the insecticide and mosquito repellant DEET, the herbicide fluridone used for Eurasian watermilfoil eradication, and the herbicide prometon. The largest concentrations of these compounds were in samples from the Allan Yorke site; the lowest concentrations were from the Lake Outlet site.

Washington

Scientific Framework for Stormwater Monitoring by the Washington State Department of Transportation

The Washington State Department of Transportation municipal stormwater monitoring program, in operation for about 8 years, never has received an external, objective assessment. In addition, the Washington State Department of Transportation would like to identify the standard operating procedures and quality assurance protocols that must be adopted so that their monitoring program will meet the requirements of the new National Pollutant Discharge Elimination System municipal stormwater permit. As a result, in March 2009, the Washington State Department of Transportation asked the U.S. Geological Survey to assess their pre-2009 municipal stormwater monitoring program. This report presents guidelines developed for the Washington State Department of Transportation to meet new permit requirements and regional/national stormwater monitoring standards to ensure that adequate processes and procedures are identified to collect high-quality, scientifically defensible municipal stormwater monitoring data. These include: (1) development of coherent vision and cooperation among all elements of the program; (2) a comprehensive approach for site selection; (3) an effective quality assurance program for field, laboratory, and data management; and (4) an adequate database and data management system.

Open-File Report

Contributions of rainfall to constituent loads in storm runoff from urban catchments

Rainfall is a significant source of some constituents, particularly nitrogen species, in storm runoff from urban catchments. Median contributions of rainfall to storm runoff loads of 12 constituents from 31 urban catchments, representing eight geographic locations within the United States, ranged from 2 percent for suspended solids to 74 percent for total nitrite plus nitrate nitrogen. The median contribution of total nitrogen in rainfall to runoff loads was 41 percent. Median contributions of total-recoverable lead in rainfall to runoff loads varied by as much as an order of magnitude between catchments in the same geographic location. This indicates that average estimates of rainfall contributions to constituent loading in storm runoff may not be suitable in studies requiring accurate constituent mass-balance computations.

Journal of the American Water Resources Associatio

Areal extent of petroleum-related compounds from a gasoline and diesel-fuel leak in ground water at a site in Yakima, Washington, 1984-89

A gasoline and diesel-fuel leak was discovered in the early 1980's at a service station in Yakima, Washington, and an attempt to recover the flee-floating petroleum product was unsuccessful. From 1984 through 1989, data were collected from observation wells drilled near the site of the leak and from nearby domestic wells during three separate studies. Between February 1985 and November 1986, benzene, toluene, xylenes, and other soluble compounds of petroleum origin were found at concentrations that exceeded standards for drinking water in all samples from observation wells within 300 feet of the service station. These compounds also were found in smaller concentrations in some samples from domestic wells as far as 1,500 feet downgradient of the service station. Concentrations of these soluble compounds in ground-water samples collected in March 1989 had decreased, and areal distribution of the compounds was smaller than when monitoring began in 1984.

Water-Resources Investigations Report

Water-quality assessment of the central Columbia Plateau in Washington and Idaho: Analysis of available nutrient and pesticide data for ground water, 1942-92

Analysis of available nutrient and pesticide data from more than a thousand wells shows that shallow ground water (less than 300 feet) in the Central Columbia Plateau has been contaminated with nitrate, particularly in the southwest. Water samples collected from one-fifth of public-supply wells in the southwest, and one-tenth elsewhere, have nitrate concentrations that exceed the maximum contaminant levels for nitrate in drinking water. Eleven pesticides also have been detected, and one of them (EDB) was detected in 10 wells at concentrations above the maximum contaminant level for drinking water. Nitrate concentrations in ground water are influenced most by agricultural use of fertilizers and by recharge rates and sources. Concentrations are higher where fertilizers are most heavily applied and are higher in shallow ground water than in deeper aquifers. Trends observed in wells with long periods of record show increases in nitrate concentration beginning in the early 1950's, after the use of nitrogen compounds as fertilizers became widespread. Ground-water recharge affects nitrate concentrations in two ways: it transports nitrate into the ground-water system, raising nitrate concentrations in ground water; and it lowers concentrations by dilution when fresh water recharges in sufficient quantities. Dilution is especially evident near canals where fresh irrigation water enters the ground-water system. More data would be needed to investigate possible relations between phosphate or pesticide concentrations and land use or depth. Phosphate concentrations in ground water are low--the median in the study unit is 0.02 milligram per liter as phosphorous. Detection of pesticides in ground water correlates with the solubility of the compounds in water and other related physico-chemical properties. Compounds that were detected have higher solubilities than compounds that were not detected.

Idaho, Washington

Agricultural pesticide applications and observed concentrations in surface waters from four drainage basins in the Central Columbia Plateau, Washington and Idaho, 1993-94

As part of the U.S. Geological Survey's National Water-Quality Assessment Program, the use and occurrence of agricultural pesticides were investigated in four drainage basins--two dominated by irrigated agriculture and two by dryland agriculture--in the Central Columbia Plateau of eastern Washington. For this study, 85 pesticides or pesticide metabolites were selected for analysis from a list of nearly 400 compounds commonly used in the United States. Pesticide-use data included estimates of the total quantity of herbicides, insecticides, and fungicides applied to croplands in each of the four drainage basins and reported times of application for selected pesticides. Pesticide-occurrence data included concentrations of pesticides in samples collected at one surface-water site at or near the outflow of each of the four drainage basins, where surface waters were sampled one to five times a month from March 1993 through May 1994. Of the 85 pesticides or pesticide metabolites targeted for analysis, a total of 45 different compounds were detected in samples from the four sites, ranging in concentration from at or near the limit of detection (as low as 0.001 microgram per liter) to a maximum of 8.1 micrograms per liter. None of the concentrations of pesticides exceeded the U.S. Environmental Protection Agency (USEPA) drinking water standards, but concentrations of five pesticides exceeded the USEPA freshwater-chronic criteria for the protection of aquatic life. Forty-one different pesticides or pesticide metabolites were detected in surface waters sampled at the two sites representing irrigated agriculture drainage basins. The herbicides atrazine, DCPA, and EPTC were detected most frequently at the two sampling sites. Not all pesticides that were applied were detected, however. For example, disulfoton, phorate, and methyl parathion accounted for 15 percent of the insecticides applied in the two irrigated drainage basins, yet none of these pesticides were detected in samples from the two irrigated-agricultural sites. Concentrations of pesticides found in surface waters at the two sites representing irrigated agriculture did not exceed drinking water standards, but some concentrations of the insecticides carbaryl, chlorpyrifos, diazinon, and azinphos-methyl exceeded the freshwater-chronic criteria for the protection of aquatic life. Twenty-three different pesticides or pesticide metabolites were detected in samples from the two sites representing dryland agricultural drainage basins. Herbicides were the type of pesticides most heavily applied in these drainage basins, and the herbicides atrazine, triallate, and simazine were detected most frequently in samples. Some herbicides, for example triallate in the Palouse River drainage basin, were both heavily applied and frequently detected. Others, like atrazine and simazine, were not typically applied to cropland, but were frequently detected in surface-water samples. Several insecticides (Lindane, ethoprop, carbaryl, and azinphos-methyl) were detected in samples from the two sites, although they were not reported as commonly applied to croplands in the dryland agricultural drainage basins. Concentrations of pesticides found in surface waters at the two sites did not exceed drinking water guidelines, but concentrations of the insecticides diazinon and azinphos-methyl and the herbicide triallate exceeded freshwater-chronic criteria for the protection of aquatic life.

Water-Resources Investigations Report

Selected ground-water information for the Columbia Plateau Regional Aquifer System, Washington and Oregon, 1982-1985; Volume III, Ground-water quality data

The data report presents ground-water information collected and analyzed as part of the U.S. Geological Survey's Columbia Plateau Regional Aquifer-System Analysis Program. The information was gathered from July 1982 through September 1985 in the part of the aquifer system located in central and eastern Washington and north-central and northeastern Oregon. The report consists of three volumes: volume I, geohydrology; volume II, water levels; and volume III, ground-water quality. This volume, III, presents ground-water quality data gathered from about 570 wells during the study.

Open-File Report