Geochemical mapping of the Denver, Colorado (USA) urban area: A comparison of studies in 1972 and 2005
Explore the source record for details and available documents.
Colorado↗
Geology topics
R. G. Garrett
Publications and source records attributed to R. G. Garrett.
Pilot studies for the North American Soil Geochemical Landscapes Project - Site selection, sampling protocols, analytical methods, and quality control protocols
In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0-5 cm and a composite of each of the O, A, and C horizons. The <2-mm fraction of each sample was analyzed for Al, Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO 3 , HClO 4 , and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion. A separate sample of 0-5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of 19 organochlorine pesticides by gas chromatography. Only three of these samples had detectable pesticide concentrations. A separate sample of A-horizon soil was collected for microbial characterization by phospholipid fatty acid analysis (PLFA), soil enzyme assays, and determination of selected human and agricultural pathogens. Collection, preservation and analysis of samples for both organic compounds and microbial characterization add a great degree of complication to the sampling and preservation protocols and a significant increase to the cost for a continental-scale survey. Both these issues must be considered carefully prior to adopting these parameters as part of the soil geochemical survey of North America.
Applied Geochemistry↗
Continental-scale patterns in soil geochemistry and mineralogy: results from two transects across the United States and Canada
In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada (GSC) initiated a pilot study that involved collection of more than 1500 soil samples from 221 sites along two continental transects across Canada and the United States. The pilot study was designed to test and refine protocols for a soil geochemical survey of North America. The two transects crossed a wide array of soil parent materials, soil ages, climatic conditions, landforms, land covers and land uses. Sample sites were selected randomly at approximately 40-km intervals from a population defined as all soils of the continent. At each site, soils representing 0 to 5 cm depth, and the O, A, and C horizons, if present, were collected and analyzed for their near-total content of over 40 major and trace elements. Soils from 0–5 cm depth were also collected for analysis of organic compounds. Results from the transects confirm that soil samples collected at a 40-km spacing reveal coherent, continental- to subcontinental-scale geochemical and mineralogical patterns that can be correlated to aspects of underlying soil parent material, soil age and climate influence. The geochemical data also demonstrate that at the continental-scale the dominance of any of these major factors that control soil geochemistry can change across the landscape. Along both transects, soil mineralogy and geochemistry change abruptly with changes in soil parent materials. However, the chemical influence of a soil’s parent material can be obscured by changing climatic conditions. For the transects, increasing precipitation from west to east and increasing temperature from north to south affect both soil mineralogy and geochemistry because of climate effects on soil weathering and leaching, and plant productivity. Regional anomalous metal concentrations can be linked to natural variations in soil parent materials, such as high Ni and Cr in soils developed on ultramafic rocks in California or high P in soils formed on weathered Ordovician limestones in central Kentucky. On local scales, anomalous metal concentrations recognized in soil profiles, such as high P in soils from animal confinement sites, are consistent with local anthropogenic disturbances. At a larger scale, the distribution of Hg across the west to east transect demonstrates that it can be difficult to distinguish between natural or anthropogenic contributions and that many factors can contribute to an element’s spatial distribution. Only three samples in a subset of seventy-three 0–5 cm depth soil samples from the north to south transect had organochlorine pesticides values above the method detection limit, apparently related to historic usage of the pesticides DDT and dieldrin.
Applied Geochemistry↗
Water-quality and physical characteristics of streams in the Treyburn development area of Falls Lake watershed, North Carolina, 1994–98
Treyburn is a 5,400-acre planned, mixed-use development in the upper Neuse River Basin of North Carolina. The development, which began in 1986, is located in the Falls Lake watershed near three water-supply reservoirs-Lake Michie to the north, Falls Lake to the southeast, and Little River Reservoir to the west. A study began in 1988 to determine the water-quality characteristics of surface waters in and around the Treyburn development area. Data to characterize water quality at five different sites were collected from July 1994 through September 1998. Data from a previous study are available for some sites for the period 1988–93. The sites were selected to characterize water quality and quantity in and near the Treyburn development and included an undeveloped basin, a relatively small basin containing single-family residences and a golf course, a basin downstream from the western part of the development with some industrial land use, and two basins unaffected by the development where agricultural land is being converted to urban and forested land use. Suspended-sediment concentrations ranged from less than 1 to 581 milligrams per liter and were fairly uniform among the five sites. Median suspended-sediment concentrations ranged from 12 to 21 milligrams per liter. Few concentrations of metals and trace elements, except aluminum, iron, and manganese, exceeded the laboratory reporting levels or water-quality criteria. At one site, concentrations of silver exceeded both the action level and the reporting level; copper was detected at each site and exceeded the action level of 7 micrograms per liter at one site. The lowest range and median concentrations of total organic nitrogen, nitrate, ammonia, total phosphorus, and orthophosphorus occurred in the relatively undisturbed, forested site. The maximum concentration of organic nitrogen (1.97 milligrams per liter) occurred at one of the sites unaffected by the Treyburn development where agricultural land is being converted to urban land use. At all sites, ammonia concentrations ranged from less than 0.02 to 0.36 milligram per liter, and median concentrations were near the reporting level. Nitrate concentrations ranged from less than 0.05 to 0.80 milligram per liter. Phosphorus concentrations at all of the Treyburn study sites were low compared to phosphorus concentrations that typically exceed 0.1 milligram per liter at sites sampled nationally for the U.S. Geological Survey National Water-Quality Assessment Program, including the Albemarle-Pamlico study area in North Carolina. Total phosphorus concentrations ranged from less than 0.01 to 0.87 milligram per liter, and orthophosphorus concentrations ranged from less than 0.01 to 0.76 milligram per liter as phosphorus. The maximum concentrations of total phosphorus and orthophosphorus occurred at the Treyburn residential and golf-course site, likely as a result of the fertilizer applications associated with these two types of land use. Of the 119 different pesticides tested, 11 were detected in concentrations that exceeded the laboratory reporting levels, though in very low concentrations. Water samples from the residential and golf-course site contained the greatest number of pesticides (10). Five of six samples collected at this site had detectable concentrations of simazine, atrazine, and pendimethalin-all herbicides used to control weeds in crops or turf. Channel geometry was assessed at eight sites in the study area in February 1997. These sites were separated into three groups based on mean bank angle and mean channel width-to-depth ratios. Channel gradient ranged from 0.04 to 1.63 percent, and mean cross sectional area ranged from 31 to 1,227 square feet. Three macroinvertebrate samples were collected from each of 10 sites. These three samples were from areas designated as richest targeted habitats, depositional targeted habitats, and qualitative multitargeted habitats. Over 230 taxa were identified fromthese 10 sites. The North Carolina Biotic Indices ranged from 4.98 (excellent) to 6.82 (fair). River sites tended to have higher total taxa richness (91-108) than did the small, intermittent streams (49–84) or the midsize Mountain Creek (85). Intermittent streams represent fairly hostile environments for most aquatic organisms. Samples from richest targeted habitats typically were more than twice as rich as samples from depositional targeted habitats and represented from 50 to 75 percent of the taxa found at each site (mean of 62 percent). The industrial site lacked many of the mayfly taxa that were present at the undeveloped site. Mayflies are very sensitive to metals contamination, and their absence may indicate a possible problem. The supporting chemical information is not available for the industrial site, and additional study would be necessary to substantiate this possibility. The two sites with residential and golf-course land use tended to support more different types of sensitive invertebrates (that is, mayflies, stoneflies, and caddis flies) than did the forested/residential site, though the abundances of these taxa were very similar. Land-use effects were not evident based on a comparison among these sites. Indirect gradient analysis was used to determine patterns in the distribution of invertebrates and to examine the relations between these patterns and physical and chemical site characteristics determined in this study. This analysis supports the contention that the dominant factors accounting for the distribution of benthic invertebrates are associated with natural factors, such as basin size, rather than land use. Constituent loads at five study sites were calculated for nutrients, suspended sediment, and total organic carbon. The median annual total nitrogen yield ranged from 0.635 to 1.63 tons per square mile. The median annual phosphorus yield ranged from 0.046 to 0.619 ton per square mile, and the median annual orthophosphate yield ranged from 0.022 to 0.379 ton per square mile. Orthophosphate accounted for more than half of the phosphorus yield at the residential and golf-course site. The maximum suspended-sediment yield was 422 tons per square mile, and the minimum yield was 32 tons per square mile. The suspended-sediment yield at one of the sites unaffected by the Treyburn development where agricultural was being converted to urban land use was high compared to other forested basins in the Piedmont of North Carolina. Total organic carbon data sufficient for estimating loads were available at three of the five sites. Of these three sites, the undeveloped site had substantially more organic carbon yield than the other two sites. The only significant water-quality trend (alpha=0.05) was a downward trend for total nitrogen and organic nitrogen at the undeveloped site. The trend slope was small, only 0.019 milligram per liter as nitrogen or less than 9 percent of the median organic nitrogen concentration. No trend was observed for nitrite plus nitrate or for ammonia, indicating that the downward trend in total nitrogen was due only to organic nitrogen.
North Carolina↗
Precipitation, streamflow, and water-quality data from selected sites in the City of Charlotte and Mecklenburg County, North Carolina, 1995-97
Precipitation data were collected at 46 precipitation sites and 3 atmospheric deposition sites, and hydrologic data were collected at 9 stream sites in the vicinity of Charlotte and Mecklenburg County, North Carolina, from July 1995 through June 1997. Data were collected to identify the type, concentration, and amount of nonpoint-source stormwater runoff within the area. The data collected include measurements of precipitation; streamflow; physical characteristics, such as water temperature, pH, specific conductance, biochemical oxygen demand, oil and grease, and suspended sediment concentrations; and concentrations of nutrients, metals and minor constituents, and organic compounds. These data should provide valuable information needed for (1) planned watershed simulation models, (2) estimates of nonpoint-source constituent loadings to the Catawba River, and (3) characterization of water quality in relation to basin conditions. Streamflow and rainfall data have been used to provide early warning of possible flooding.
North Carolina↗
Precipitation, streamflow and water quality data from selected sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-95
Charlotte and Mecklenburg County from October 1993 through June 1995 to identify the type, concentration, and amount of nonpoint-source stormwater runoff within the area. The data collected include measurements of precipitation; streamflow; physical characteristics, such as water temperature, pH, specific conductance, biochemical oxygen demand, oil and grease, and suspended sediment concentrations; and concentrations of nutrients, metals and minor constituents, and organic compounds. These data should provide valuable information needed for (1) planned watershed simulation models, (2) early warning of possible flooding, (3) estimates of nonpoint-source constituent loadings to the Catawba River, and (4) characterization of water quality in relation to basin conditions.
North Carolina↗
Water-quality characteristics of streams in the Treyburn Development area of Falls Lake watershed, North Carolina, 1988-93
Treyburn is a 5,400 acre planned, mixed-use community located in the Falls Lake watershed in the upper Neuse River Basin of North Carolina. From February 1988 through 1993, hydrologic-data were collected at 17 study sites in or near the Treyburn development to compare the effects of varying types of land-use development on the water-quality of streams flowing in or near the development. The collected hydrologic data included measurements of streamflow and concentrations of major dissolved constituents, nutrients, minor elements, and organic compounds. Streamflow in the study basin was approximately 40 percent lower in 1992 and 40 percent higher in 1993 than the long-term annual mean of the long-term discharge records at Flat River in Bahama. Calcium and bicarbonate were the predominant cation and anion at all study sites except one. Mean total nitrogen and phosphorus concentrations at sites in the Treyburn development ranged from 0.5 to 0.8 and 0.03 to 0.10 milligrams per liter, respectively. Total aluminum, iron, and manganese were the metals most frequently detected in the 200 organic compunds analyzed. Dichloro- difluoromethane and methylene chloride were detected most often.
North Carolina↗
An interim report on flows in the lower Roanoke River, and water quality and hydrodynamics of Albermarle Sound, North Carolina, October 1989-April 1991
In 1990, a 3-year investigation was begun in North Carolina to: (1) develop a model for computing flows in the lower 67 mi of the Roanoke River; (2) characterize water-quality conditions in Albemarle Sound; and (3) describe the circulation regime of Albemarle Sound, particularly in relation to inflows. This report summarizes data and results obtained during the first year of the study. The water level in Albemarle Sound may affect flows in the Roanoke River as far as 60 mi upstream from the mouth of the river. The presence of higher water levels downstream relative to those upstream indicates that reverse flows likely occurred in the lower 20 mi of the Roanoke River in October and December 1990. A one-dimensional, unsteady flow model has been calibrated and validated for a 30-mi segment of the lower Roanoke River. Simulated and observed water levels typically differed by less than 0.5 ft, and simulated flows were generally within 10% of observed values. Near-surface and near-bottom specific conductances, near-surface water temperature, and near-surface, mid-depth, and near-bottom dissolved-oxygen concentrations were monitored at 10 locations in Albemarle Sound from October 1989 to April 1991. Observed salinities ranged from virtually 0 to more than 9 ppt, and maximum observed water temperatures were about 32C. Dissolved oxygen concentrations ranged from supersaturated to hypoxic conditions. The daily range in dissolved-oxygen concentrations was typically larger during the summer months than during the rest of the year, and the lowest dissolved-oxygen values were observed during the summer.
North Carolina↗
Water quality characteristics of inflow to and outflow from B. Everett Jordan Lake, North Carolina, 1982-86
B. Everett Jordan Lake, a 13,900-acre reservoir in the north-central Piedmont of North Carolina, was completed in February 1982. Hydrologic data were collected at four inflow sites and one outflow site to define water-quality characteristics. Data include streamflow data and 56 physical and chemical characteristics of streamwater. Concentrations of some constituents at inflow sites were as much as 83-times greater than background concentrations in streams relatively unaffected by man. At the outflow site, however, some of these constituents were only as much as 6-times greater. The minimum dissolved-oxygen concentration measured at an inflow site was 1.0 mg/L, whereas the minimum concentration measured at the outflow site was 4.9 mg/L. Significant differences in other physical characteristics between inflow and outflow sites include a reduction in maximum concentration of suspended sediment from 2,360 mg/L in an inflow sample to 130 mg/L at the outflow site and a reduction of maximum specific conductance values from more than 1,100 microsiemens/centimeter in an inflow sample to 301 microsiemens/centimeter in outflow. The maximum concentration of total nitrogen at inflow sites was 27.0 mg/L compared with 3.2 mg/L at the outflow site. The maximum total phosphorus concentration at inflow sites was 13.0 mg/L compared with 0.6 mg/L at the outflow site. Average annual loads of total nitrogen and total phosphorus in the outflow were as much as 67% and 40% of inflow loads, respectively. Maximum yields at an inflow site were 5.8 t/sq mi (tons per square mile) for nitrogen and 1.4 t/sq mi for phosphorus. Yields of these constituents at the outflow site were 1.5 and 0.2 t/mi, respectively.
North Carolina↗
Water-quality characteristics of inflow to and outflow from Falls Lake, North Carolina, 1982-87
Falls Lake, an 11,300-acre reservoir in the north-central Piedmont of North Carolina, was completed in December 1983. Hydrologic data were collected at seven inflow sites and one outflow site between 1982 and 1987 to define water-quality characteristics. Data include streamflow data and 56 physical and chemical characteristics of streamwater. Concentrations of some constituents at inflow sites were as much as 10-to 110-times greater than background concentrations in streams relatively unaffected by man. At the outflow site, these constituents generally were 2-to 3-times greater than background values. The minimum dissolved-oxygen concentration measured at an inflow site was 0.6 mg/L, whereas the minimum concentration measured at the outflow site was 6.7 milligrams per liter. Significant differences in other physical characteristics between inflow and outflow sites include a reduction in maximum concentration of suspended sediment from 1,850 milligrams per liter in an inflow sample to 100 milligrams per liter in an outflow sample, and a reduction of maximum specific-conductance values from more than 1,200 microsiemens/centimeter in an inflow sample to 140 microsiemens per centimeter in the outflow. The maximum concentration of total nitrogen at inflow sites was 33 milligrams per liter compared with 4.5 milligrams per liter at the outflow site. Similarly, the maximum total phosphorus concentration at inflow sites was 20 milligrams per liter, but 0.22 milligrams per liter at the outflow site. Average annual loads of nitrogen and phosphorus in the outflow were as much as 66 percent and 21 percent of inflow loads, respectively. Although maximum inflow yields were 13 tons per square mile for nitrogen and 2.8 tons per square mile for phosphorus, yields of these constituents at the outflow site were about 1.1 and 0.05 tons per square mile, respectively.
North Carolina↗
Workshop on Abundance Estimation
[No abstract available]
Journal of the International Association for Mathe↗