USGS ScienceSearch

Geology topics

Qian Zhang

Publications and source records attributed to Qian Zhang.

At least 19 recordsLinked to original sources

Fifteen years of WRTDS for advancing water-quality science: A critical review of methodological developments and global applications

Contamination by nutrients, major ions, and metals poses a major threat to global water sustainability. Understanding how these pollutants vary across time and space requires long-term monitoring and robust statistical approaches. Traditional methods, however, often struggle to account for streamflow variability, seasonality, and nonlinear responses. Introduced in 2010, the Weighted Regressions on Time, Discharge, and Season (WRTDS) method offers a flexible, data-driven framework that generates both observed and flow-normalized estimates of concentration and load. Over the past 15 years, WRTDS has become a state-of-the-art tool for water-quality science and management, with applications spanning a wide range of hydrologic, climatic, and policy contexts─including major watersheds across North America, Europe, Asia, Australia, and the Arctic. In this review of WRTDS, we document the method’s major advancements, examine its expanding geographic and thematic applications, and summarize its relevance to water-quality management programs and policies worldwide. We also discuss its performance relative to other regression and machine-learning approaches. Finally, we identify key priorities for future development to support the continued evolution of WRTDS as a trusted and practical tool for scientists and managers working to protect and sustain water resources.

Environmental Science and Technology

Lower Eastern Shore Tributary summary: A summary of trends in tidal water quality and associated factors, 1985-2023

The Lower Eastern Shore Tributary Summary outlines change over time according to a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period 1985 – 2023, and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring (March-May) and summer (July-September) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO4), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in an Appendix B. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as winddriven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submersed aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the Lower Eastern Shore. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who use tidal water quality to inform management decisions, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. The Tributary Summary documents are sources of readily available background for change over time in tidal water quality observed with monitoring data. They help answer questions related to water quality, show how landscape factors drive water-quality changes over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Maryland, Virginia

The US EPA’s National Nutrient Inventory: Critical shifts in US nutrient pollution sources from 1987 to 2017

Efforts to constrain the negative environmental impacts of excess nitrogen (N) and phosphorus (P) are costly and challenging, due in part to inconsistent reporting of nutrient sources at temporal and spatial scales relevant for local decision making. To meet this challenge, the U.S. Environmental Protection Agency’s National Nutrient Inventory provides estimates of major agricultural, urban, atmospheric, and natural nutrient fluxes for the contiguous United States at county and HUC12 scales annually from 1987 (from 1950 for agriculture) to 2017. Since the late 1980s, total N emissions and atmospheric N deposition have declined 22% and 15%, respectively, despite increased agricultural emissions. Over the same period, municipal wastewater N and P loads remained largely stable, despite population increases, through wastewater treatment upgrades and the phaseout of phosphorus-containing detergents. Improved agricultural efficiency allowed for dramatic increases in agricultural production and crop harvest since 1987 (∼25% for N and P), with little change in surplus nutrients left on fields. Overall, a combination of innovative technologies and management has stemmed or even decreased major sources of nutrient pollution to the environment over the last several decades, representing an important shift that, if continued, may contribute to improved air, land, and water quality and human health.

contiguous United States

Potomac Tributary Summary: A summary of trends in tidal water quality and associated factors, 1985 - 2022

The Potomac Tributary Summary outlines change over time for a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period of 1985 to 2022, and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring (March-May) and summer (July-September) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO4), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in Appendix B. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as wind driven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submerged aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the Potomac River. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who are looking at tidal water quality data and trying to understand why patterns are occurring, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. Our goal is for the Tributary Summary documents to be sources of readily available background for change over time in tidal water quality observed with monitoring data. The intended purpose of the Tributary Summary documents is to help answer questions related to water quality, show how landscape factors drive water quality change over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Maryland, Pennsylvania, Virginia, West Virginia

METRIC: An interactive framework for integrated visualization and analysis of monitored and expected load reductions for nitrogen, phosphorus, and sediment in the Chesapeake Bay watershed

Reductions of nitrogen, phosphorus, and sediment loads have been the focus of watershed restoration in many regions for improving water quality, including the Chesapeake Bay. Watershed models and riverine monitoring data can provide important information on the progress of load reductions but do not always generate consistent interpretations. A new framework for integrated visualization and analysis of monitoring and modeling data, named “Monitored and Expected Total Reduction Indicator for the Chesapeake (METRIC),” was developed to provide spatially explicit trends for the subwatersheds of the Chesapeake Bay. METRIC contains up-to-date information on nitrogen, phosphorus, and sediment at 83, 66, and 66 stations, respectively, which can help watershed managers gauge expectations on the trajectory and pace of progress at localized scales. These results were further synthesized to better understand the spatial patterns of the response classes ( i.e. , agreement between the expected and monitored trends) across the Chesapeake Bay watershed.

Chesapeake Bay watershed

Leveraging artificial intelligence and machine learning to advance Chesapeake Bay research and management: A review of status, challenges, and opportunities

The Chesapeake Bay and its watershed (hereafter “Chesapeake Bay region”) have been the focus of extensive restoration efforts for several decades. These restoration efforts are guided by the Chesapeake Bay Watershed Agreement (Chesapeake Executive Council 2014) which outlines 10 goals and 31 measurable outcomes. The Chesapeake Bay is globally recognized as a model for coastal restoration due to long-term investments in monitoring, modeling, implementation and research by the Chesapeake Bay Program (CBP) partnership. These monitoring network spans tidal and non-tidal regions and provides data across multiple scales. Artificial intelligence (AI), particularly machine-learning (ML) and deep learning (DL), has emerged as a powerful tool for analyzing large, complex datasets. These techniques have gained widespread adoption across various disciplines, including ecology, hydrology, and environmental science. In the Bay context, AI/ML is increasingly being used to explore drivers of environmental change, analyze system dynamics, and predict conditions in areas with limited monitoring. The CBP partnership, particularly its Scientific and Technical Advisory Committee (STAC), has increasingly recognized the growing role of AI/ML in watershed and estuarine management. Recent Chesapeake Community Research Symposium sessions and initiatives such as the Chesapeake Global Collaboratory highlight increasing regional momentum to apply big data and AI/ML for environmental solutions. Together, these developments underscore the timely need to explore how AI/ML can help advance Chesapeake Bay restoration and management. This STAC workshop, titled “Leveraging Artificial Intelligence and Machine learning to Advance Chesapeake Bay Research and Management: A review of status, challenges, and opportunities,” was held from February 24-25, 2025, in Edgewater, Maryland to bring together over 50 federal, state, and academic scientists and partners to synthesize the current state of AI/ML applications and identify research gaps in Chesapeake Bay research and management. The workshop focused on three main objectives: 1. Summarize recent AI/ML applications and lessons learned in both tidal and nontidal areas of the Chesapeake Bay region. 2. Identify challenges and gaps in applying AI/ML approaches to Chesapeake Bay data. Such challenges and gaps may include data limitations, harmonization issues, ineffective communication of AI/ML insights, and a lack of coordination among research and management institutions. 3. Develop recommendations and identify opportunities for leveraging AI/ML to address issues across the Chesapeake Bay region. Key areas of focus may include generating new information to support watershed management, delivering AI/MLgenerated insights to managers in a clear and actionable way, and fostering greater collaboration among stakeholders within the CBP Partnership. Workshop participants engaged in science presentations and breakout sessions to develop recommendations for advancing the integration of AI/ML techniques into research and management across the Chesapeake Bay region. By synthesizing current applications, identifying challenges, and exploring new opportunities, the workshop has provided valuable insights and recommendations for better leveraging AI/ML approaches to support the success of Bay restoration efforts. Together, these recommendations provide a roadmap for enhancing data-driven, science-based decision making aligned with the goals and outcomes of the Chesapeake Bay Watershed Agreement.

Delaware, Maryland, Virginia

Evaluating water-quality trends in agricultural watersheds prioritized for management-practice implementation

Many agricultural watersheds rely on the voluntary use of management practices (MPs) to reduce nonpoint source nutrient and sediment loads; however, the water-quality effects of MPs are uncertain. We interpreted water-quality responses from as early as 1985 through 2020 in three agricultural Chesapeake Bay watersheds that were prioritized for MP implementation, namely, the Smith Creek (Virginia), Upper Chester River (Maryland), and Conewago Creek (Pennsylvania) watersheds. We synthesized patterns in MPs, climate, land use, and nutrient inputs to better understand factors affecting nutrient and sediment loads. Relations between MPs and expected water-quality improvements were not consistently identifiable. The number of MPs increased in all watersheds since the early 2010s, but most monitored nutrient and sediment loads did not decrease. Nutrient and sediment loads increased or remained stable in Smith Creek and the Upper Chester River. Sediment loads and some nutrient loads decreased in Conewago Creek. In Smith Creek, a 36-year time-series model suggests that changes in manure affected flow-normalized total nitrogen loads. We hypothesize that increases in nutrient applications may overshadow some expected MP effects. MPs might have stemmed further water-quality degradation, but improvements in nutrient loads may rely on reducing manure and fertilizer applications. Our results highlight the importance of assessing MP performance with long-term monitoring-based studies.

Journal of the American Water Resources Assocation

Integrating monitoring and modeling information to develop an indicator of watershed progress toward nutrient reduction goals

Eutrophication has been a major environmental issue in many coastal and inland ecosystems, which is primarily attributed to excessive anthropogenic inputs of nutrients. Restoration efforts have therefore focused on the reduction of watershed nutrient loads, including in the Chesapeake Bay (USA). To facilitate watershed management, watershed models are often developed and used to assess the expected impact of scenarios of past and future management policies and practices and the impact of watershed conditions. However, the level of load reductions estimated using monitoring data often does not match with model predictions, which may cast doubt on the effectiveness of the restoration efforts, the reliability of the model, and the prospect of achieving pre-established reduction goals. To better reconcile such inconsistencies between expectation (i.e., modeling estimates) and reality (i.e., monitoring information), a watershed-wide indicator was developed for the Chesapeake Bay watershed to explicitly quantify the progress toward nutrient reduction goals in the context of the Chesapeake Bay Total Maximum Daily Load (TMDL). Results of the indicator show that since 1995 long-term progress has been made toward the TMDL planning targets for both nitrogen and phosphorus. Specifically, management practices that are implemented and realized (in monitoring data) have been increasing over time, whereas management practices that need to be implemented in the future to meet the goals have been decreasing. In addition, the progress of nutrient reduction toward meeting the goals has varied with source sectors and watershed locations: i.e., point source management has been fully or nearly fully implemented, whereas nonpoint source management has been implemented by 50%-70%. In summary, this indicator, which is largely based on monitoring data, can provide at least four benefits: (1) evaluating the validity of the modeled estimates of nutrient reductions by comparing them to monitoring information; (2) placing the monitored riverine trends into a management context; (3) comparing progress between different nutrient source sectors and watershed locations; and (4) facilitating communication of the progress to the Chesapeake Bay Program Partnership and the public. Although we focus on the indicator development and interpretation for the Chesapeake Bay watershed, the framework can be transferred to watersheds within and beyond this watershed, where similar modeling and monitoring information exists, to gauge expectations on the trajectory and pace of the progress toward meeting restoration goals.

Chesapeake Bay watershed

Legacy sediment as a potential source of orthophosphate: Preliminary conceptual and geochemical models for the Susquehanna River, Chesapeake Bay watershed, USA

Nutrient pollution from agriculture and urban areas plus acid mine drainage (AMD) from legacy coal mines are primary causes of water-quality impairment in the Susquehanna River, which is the predominant source of freshwater and nutrients entering the Chesapeake Bay. Recent increases in the delivery of dissolved orthophosphate (PO 4 ) from the river to the bay may be linked to long-term increases in pH, decreased acidity of precipitation, and decreased acidity, iron, and aluminum loading from widespread AMD. Since the 1950s, baseline pH increased from ~6.5 to ~8 in the West Branch and “North Branch” of the Susquehanna River, which drain bituminous and anthracite coalfields of Pennsylvania. A current baseline pH of ~8 and daily maxima exceeding 9 have been documented along the lower Susquehanna River. In response to improved river quality, bioavailable PO 4 now may be released into solution from legacy sediment that has filled major impoundments in lower reaches of the river. At typical pH (5–8) of natural water, aqueous PO 4 species tend to be adsorbed by hydrous iron, aluminum, and manganese oxides that coat soil and sediment particles; however, PO 4 may be substantially desorbed at pH >8. We created a geochemical model that simulates equilibrium aqueous/solid distributions of PO 4 as pH and other solution characteristics change. Considering current conditions in the lower Susquehanna River, the model demonstrates potential for extensive release of adsorbed PO 4 at pH >8. Empirical data from laboratory experiments corroborate model results. The transfer of PO 4 into the water column may increase algae growth, which removes CO 2 and drives pH to higher values, facilitating additional PO 4 release and exacerbating the potential for harmful algal blooms. Thus, legacy sediment is a currently unquantified source of PO 4 that warrants consideration by resource managers and programs collaborating to reduce phosphorus loads to the bay and similar settings worldwide.

Chesapeake Bay watershed

Rappahannock tributary summary: A summary of trends in tidal water quality and associated factors, 1985-2022

The Rappahannock Tributary Summary outlines change over time for a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period of 1985 to 2022, and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring (March-May) and summer (JulySeptember) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO 4 ), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in Appendix B. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as winddriven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submerged aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the Rappahannock River. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who are looking at tidal water quality data and trying to understand why patterns are occurring, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. Our goal is for the Tributary Summary documents to be sources of readily available background for change over time in tidal water quality observed with monitoring data. The intended purpose of the Tributary Summary documents is to help answer questions related to water quality, show how landscape factors drive water quality change over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Virginia

Progress in reducing nutrient and sediment loads to Chesapeake Bay: Three decades of monitoring data and implications for restoring complex ecosystems

For over three decades, Chesapeake Bay (USA) has been the focal point of a coordinated restoration strategy implemented through a partnership of governmental and nongovernmental entities, which has been a classical model for coastal restoration worldwide. This synthesis aims to provide resource managers and estuarine scientists with a clearer perspective of the magnitude of changes in water quality within the Bay watershed, including nitrogen (N), phosphorus (P), and sediment for the River Input Monitoring (RIM) watershed and the unmonitored below-RIM watershed. The flow-normalized N load from the RIM watershed has declined in the period of 1985–2017, but P and sediment loads have lacked progress. Reductions of riverine N are largely driven by reductions of point sources and atmospheric deposition. Future reductions will require significant progress in managing agricultural nonpoint sources. The below-RIM watershed, which comprises a disproportionately high fraction of inputs to the Bay, has shown long-term declines in major sources, including point sources (N and P), atmospheric deposition (N), manure (N and P) and fertilizer (P), based on a combination of monitoring and modeling assessments. To date, the Bay cleanup efforts have achieved some progress toward reducing nutrients from the watershed, which have resulted in improving water quality in the estuary. However, further reductions are critical to achieve the Chesapeake Bay Total Maximum Daily Load goals, and emerging challenges due to Conowingo Reservoir, legacy nutrients, climate change, and population growth should be considered. Continued monitoring, modeling, and assessment are critically important for informing the restoration of this complex ecosystem.

Chesapeake Bay watershed

James Tributary summary: A summary of trends in tidal water quality and associated factors, 1985-2021

The James Tributary Summary outlines change over time for a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period 1985 – 2021 and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring and summer (June, July, August) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO4), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in an Appendix. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as wind-driven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submerged aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the James River. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who are looking at tidal water quality data and trying to understand why patterns are occurring, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. Our goal is for the Tributary Summary documents to be sources of readily available background for change over time in tidal water quality observed with monitoring data. The intended purpose of the Tributary Summary documents is to help answer questions related to water quality, show how landscape factors drive water quality change over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Virginia

Major point and nonpoint sources of nutrient pollution to surface water have declined throughout the Chesapeake Bay watershed

Understanding drivers of water quality in local watersheds is the first step for implementing targeted restoration practices. Nutrient inventories can inform water quality management decisions by identifying shifts in nitrogen (N) and phosphorus (P) balances over space and time while also keeping track of the likely urban and agricultural point and nonpoint sources of pollution. The Chesapeake Bay Program's Chesapeake Assessment Scenario Tool (CAST) provides N and P balance data for counties throughout the Chesapeake Bay watershed, and these data were leveraged to create a detailed nutrient inventory for all the counties in the watershed from 1985–2019. This study focuses on three primary watershed nutrient balance components—agricultural surplus, atmospheric deposition, and point source loads—which are thought to be the leading anthropogenic drivers of nutrient loading trends across the watershed. All inputs, outputs, and derived metrics (n=53) like agricultural surplus and nutrient use efficiency, were subjected to short- and long-term trend analyses to discern how sources of pollution to surface water have changed over time. Across the watershed from 1985–2019, downward trends in atmospheric deposition were ubiquitous. Though there are varying effects, long-term declines in agricultural surplus were observed, likely because nutrients are being managed more efficiently. Multiple counties' point source loads declined, primarily associated with upgrades at major cities that discharge treated wastewater directly to tidal waters. Despite all of these positive developments, recent increases in agricultural surpluses from 2009–2019 highlight that water quality gains may soon be reversed in many agricultural areas of the basin. Besides tracking progress and jurisdictional influence on pollution sources, the nutrient inventory can be used for retrospective water quality analysis to highlight drivers of past improvement/degradation of water quality trends and for decision makers to develop and track their near- and long-term watershed restoration strategies.

Chesapeake Bay watershed

A water quality barometer for Chesapeake Bay: Assessing spatial and temporal patterns using long-term monitoring data

This paper develops a barometer that indexes water quality in the Chesapeake Bay and summarizes quality over spatial regions and temporal periods. The barometer has a basis in risk assessment and hydrology, and is a function of three different metrics of water quality relative to numerical criteria: relative frequency of criterion attainment; magnitude of deviation from a numerical criterion; and duration of criterion attainment. Metrics associated with these features are calculated at the station level, allowing flexibility for simultaneously evaluating multiple stressors, different designated uses, and physical characteristics of the water. The barometer score is then created as a geometric mean of the three metrics. The water quality barometer (WQB) station scores may be spatially aggregated to report habitat scores across a spectrum of spatial resolutions (e.g., management segment, tidal subsystem, or the whole tidal bay). Dissolved oxygen measurements in the Chesapeake Bay collected during summer seasons of 1985 to 2020 are used to evaluate water quality. The WQB score and its bootstrapped confidence interval are reported at the station, segment, tidal subsystem and whole tidal bay levels. Notably, water quality interpreted through application of the WQB with dissolved oxygen concentration data and averaged over the 29-year period of record is good (i.e. protects aquatic living resources) in tributaries such as the James River, Rappahannock River and others; but is not as good in areas such as the Upper Tributaries and the York River. Recent summaries indicate that while the water quality is improving in much of the bay and its tidal tributaries, however, there is an indication of decline in quality in the period 20182020, especially in the upper regions of the Bay. The barometer is designed around using the time series data produced by the Chesapeake Bay Programs annual monitoring strategy; the approach has application to other large water bodies with large scale monitoring programs with extended time series or for integrating information from environmental sensor systems.

Maryland, Virginia

Nutrient limitation of phytoplankton in three tributaries of Chesapeake Bay: Detecting responses following nutrient reductions

Many coastal ecosystems suffer from eutrophication, algal blooms, and dead zones due to excessive anthropogenic inputs of nitrogen (N) and phosphorus (P). This has led to regional restoration efforts that focus on managing watershed loads of N and P. In Chesapeake Bay, the largest estuary in the United States, dual nutrient reductions of N and P have been pursued since the 1980s. However, it remains unclear whether nutrient limitation – an indicator of restriction of algal growth by supplies of N and P – has changed in the tributaries of Chesapeake Bay following decades of reduction efforts. Toward that end, we analyzed historical data from nutrient-addition bioassay experiments and data from the Chesapeake Bay long-term water-quality monitoring program for six stations in three tidal tributaries (i.e., Patuxent, Potomac, and Choptank Rivers). Classification and regression tree (CART) models were developed using concurrent collections of water-quality parameters for each bioassay monitoring location during 1990-2003, which satisfactorily predicted the bioassay-based measures of nutrient limitation (classification accuracy = 96%). Predictions from the CART models using water-quality monitoring data showed enhanced nutrient limitation over the period of 1985-2020 at four of the six stations, including the downstream station in each of these three tributaries. These results indicate detectable, long-term water-quality improvements in the tidal tributaries. Overall, this research provides a new analytical tool for detecting signs of ecosystem recovery following nutrient reductions. More broadly, the approach can be adapted to other waterbodies with long-term bioassays and water-quality data sets to detect ecosystem recovery.

Delaware, Maryland, Pennsylvania, Virginia, West V

Nutrient improvements in Chesapeake Bay: Direct effect of load reductions and implications for coastal management

In Chesapeake Bay in the United States, decades of management efforts have resulted in modest reductions of nutrient loads from the watershed, but corresponding improvements in estuarine water quality have not clearly materialized. Generalized additive models were used to directly link river flows and nutrient loads from the watershed to nutrient trends in the estuary on a station-by-station basis, which allowed for identification of exactly when and where responses are happening. Results show that Chesapeake Bay total nitrogen and total phosphorus conditions are mostly improving after accounting for variation in freshwater flow. Almost all of these improving nutrient concentrations in the estuary can be explained by reductions in watershed loads entering through 16 rivers and 145 nearby point sources. These two major types of loads from multiple locations across the watershed are together necessary and responsible for improving estuarine nutrient conditions, a finding that is highly relevant to managing valuable estuarine resources worldwide.

Maryland, Virginia

Nitrogen in the Chesapeake Bay watershed—A century of change, 1950–2050

Foreword Sustaining the quality of the Nation’s water resources and the health of our diverse ecosystems depends on the availability of sound water-resources data and information to develop effective, science-based policies. Effective management of water resources also brings more certainty and efficiency to important economic sectors. Taken together, these actions lead to immediate and long-term economic, social, and environmental benefits that will make a difference to the lives of the almost 400 million people projected to live in the United States by 2050. The Chesapeake Bay is the largest and most productive estuary in the United States and is a vital environmental and economic resource. Approximately half of the water volume of the Chesapeake Bay originates from streams and rivers that drain the 64,243 mi 2 Chesapeake Bay watershed. The Bay and its tributaries have been degraded by excessive nutrients, such as nitrogen, from contributing watersheds. Inputs of nitrogen to the Bay lead to increased algal growth, decreased dissolved oxygen, and declining fisheries. In 2000, the Chesapeake Bay was listed as impaired under the Clean Water Act and Total Maximum Daily Loads (TMDLs) for nutrients and sediment have been established to assist with management actions aimed at nutrient reductions. Effective nutrient management requires an understanding of past, present, and future nutrient sources, fate, and transport in the watershed. The Chesapeake Bay community has been a pioneer in science, management, and regulation to improve water quality. Factors like climate, hydrology, source inputs, and management controls play a vital role in determining the delivery and magnitude of nitrogen inputs to the Bay. Science in the form of monitoring data, predictive tools, and interpretive reports can help inform decisions to better balance the use and control of nitrogen in coastal areas. The findings in this report can contribute to effective management of the Bay and its watershed by providing a synthesis of the understanding of how human activities and environmental change in the watershed in the past, present, and future will influence the export of nitrogen to the Bay. We hope this publication will provide you with insights and information to meet your water resource needs and will foster increased civilian awareness and involvement in the protection and restoration of our Nation’s waters. The information in this report is intended primarily for those interested or involved in resource management and protection, conservation, regulation, and policymaking at the regional and national levels.

Chesapeake Bay watershed