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Paul F. Woods

Publications and source records attributed to Paul F. Woods.

12 recordsLinked to original sources
USGS2006

Interactive effects of dissolved zinc and orthophosphate on phytoplankton from Coeur d'Alene Lake, Idaho

Within the longitudinal chemical-concentration gradient in Coeur d'Alene Lake, generated by inputs from the St. Joe and Coeur d'Alene Rivers, two dominant algal species, Chlorella minutissima and Asterionella formosa, were isolated and cultured in chemically defined media to examine growth response to a range of dissolved orthophosphate concentrations and zinc-ion activities representative of the region within- and up-gradient of the Coeur d'Alene River inlet to the lake. Although zinc is an essential micronutrient, the toxicity of algal species to elevated concentrations of uncomplexed zinc has been demonstrated, and affects the metabolism of phosphorus (Kuwabara, 1985a; Kuwabara and others, 1986), the limiting nutrient in the lake. This interaction between solutes could be of management interest. As an extension of field work conducted in August, 1999 (Kuwabara and others, 2003b), the water column and benthos of Coeur d'Alene Lake were sampled in August 2001, June 2004 and June 2005 (Fig. 1; Table 1) to provide the biological characterization in terms of phytoplankton community composition, benthic macroinvertebrate community composition and benthic chlorophyll concentrations, as well as chemical characterizations at six sites (three depths per site) within the lake. This work, in support of the Idaho Department of Environmental Quality and regional tribal organizations, provides the first phytoplankton response models in a format that may be incorporated into a process-interdependent water-quality model like CAEDYM (Fig. 2; Brookes and others, 2004; Centre for Water Research, 2006) as a management tool for the lake. This study provides information in support of developing process-interdependent solute-transport models for the watershed (that is, models integrating physical, geochemical and biological processes), and hence in support of subsequent evaluation of remediation or load-allocation strategies. The following two questions are posed: Are dissolved zinc and orthophosphate concentrations interactively associated with growth parameters of dominant phytoplankton species within the longitudinal concentration gradient of Coeur d'Alene Lake? If so, can these interactions be quantitatively incorporated into a water-quality model for the lake?

Idaho↗
USGS2001

Concentrations and loads of cadmium, lead, and zinc measured on the ascending and descending limbs of the 1999 snowmelt-runoff hydrographs for nine water-quality stations, Coeur d'Alene River basin, Idaho

The Remedial Investigation/Feasibility Study conducted by the U.S. Environmental Protection Agency within the Spokane River Basin of northern Idaho and eastern Washington included extensive data-collection activities to determine the nature and extent of trace-element contamination within the basin. The U.S. Geological Survey designed and implemented synoptic sampling of a high-flow runoff event at selected water-quality stations during the 1999 water year. The objective was to quantify spatial and temporal differences in constituent concentrations and loads over the ascending and descending limbs of a hydrograph depicting a high-flow runoff event. Discharge and water-quality data were collected during spring 1999 snowmelt runoff (May through early June) at nine water-quality stations, one on the North Fork Coeur d’Alene River and eight on the South Fork Coeur d’Alene River. The nine stations were sam- pled for whole-water recoverable and dissolved concentrations and loads of cadmium, lead, and zinc. The concentrations and loads sampled during the 1999 snowmelt-runoff event represented near-normal conditions, not flood conditions, in that the recurrence interval for discharge near the hydrograph peak was about 2 years. The general trend among the nine stations was an inverse relation between discharge and dissolved concentrations of cadmium, lead, and zinc, and a direct relation between discharge and whole-water recoverable concentrations of these constituents. The smallest loads of dissolved and whole-water recoverable cadmium, lead, and zinc were measured at South Fork Coeur d’Alene River above Deadman Gulch; constituent concentrations at this site were some of the smallest among those sampled, and discharge was also relatively small. The largest loads of dissolved and whole-water recoverable cadmium, lead, and zinc were measured at South Fork Coeur d’Alene River at Pinehurst; constituent concentrations at this site were large and discharge was the second-largest of all the discharge measurements. Hysteresis effects on concentrations and loads over the ascending and descending limbs of the snowmelt-runoff hydrograph were quite apparent, especially for whole-water recoverable constituents. Hysteresis is present when a property, such as constituent concentration or load, has different values for a given discharge over the ascending and descending limbs of a hydrograph. During this study, loads of whole-water recoverable constituents on the ascending limb were between 1.5 and 3.6 times larger than those mea- sured on the descending limb at nearly equal discharge. In contrast, dissolved constituents showed minimal hysteresis effects.

Idaho↗
USGS2000

Concentrations and loads of cadmium, lead, and zinc measured near the peak of the 1999 snowmelt-runoff hydrographs for 42 water-quality stations, Coeur d'Alene River basin, Idaho

The Remedial Investigation/Feasibility Study conducted by the U.S. Environmental Protection Agency within the Spokane River Basin of northern Idaho and eastern Washington included extensive data-collection activities to determine the nature and extent of trace-element contamination within the basin. The U.S. Geological Survey designed and implemented synoptic sampling of the 1999 snowmelt-runoff event at 42 water- quality stations during the 1999 water year. The distribution of the 42 stations was as follows: North Fork Coeur d’Alene River and tributaries, 4 stations; South Fork Coeur d’Alene River, 13 stations; Canyon, Ninemile, and Pine Creeks, 4 stations each; other tributaries to South Fork Coeur d’Alene River, 10 stations; and main stem Coeur d’Alene River, 3 stations. The objective was to synoptically collect discharge and water-quality data in order to significantly improve the estimation of trace-element loads from multiple contributing source areas during the snowmelt-runoff event. Discharge and water-quality data were collected near the peak discharge during late May 1999. Each station was sampled for whole-water recoverable and dissolved concentrations and loads of cadmium, lead, and zinc. Three general concentration levels of cadmium, lead, and zinc were noted among the 42 stations. Dissolved cadmium concentrations were less than 1 microgram per liter (μg/L) at 26 stations, exceeded 10 μg/L at 1 station, and ranged from 1 to 10 μg/L at the remaining 15 stations. Whole-water recoverable cadmium concentrations were less than 1 μg/L at 23 stations, exceeded 10 μg/L at 4 stations, and ranged from 1 to 10 μg/L at the remaining 15 stations. Dissolved lead concentrations were less than 1 μg/L at 22 stations, exceeded 10 μg/L at 7 stations, and ranged from 1 to 10 μg/L at the remaining 13 stations. Whole-water recoverable lead concentrations were less than 10 μg/L at 13 stations, exceeded 500 μg/L at 20 stations, and ranged from 10 to 500 μg/L at the remaining 9 stations. Dis- solved zinc concentrations were less than 10 μg/L at 14 stations, exceeded 500 μg/L at 6 stations, and ranged from 10 to 500 μg/L at the remaining 22 stations. Whole-water recoverable zinc concentrations were less than 10 μg/L at 9 stations, exceeded 500 μg/L at 15 stations, and ranged from 10 to 500 μg/L at the remaining 18 stations. The accounting of tributary loads between two South Fork stations at O’Brien Gulch and Pinehurst revealed differences between dissolved and whole-water recoverable loads, as well as differences among the three trace elements. Tributary loads accounted for an average of 29 percent (range of 27 to 31.6 percent) of the differences in whole-water recoverable loads of the three trace elements between the O’Brien Gulch and Pinehurst stations. This result implies that the main stem of the South Fork Coeur d’Alene River is an important source of sediment-associated trace elements under elevated streamflows. In the case of dissolved loads of cadmium and zinc, the tributary loads accounted for about one-half (range of 47.3 to 55 percent) of the differences between the two South Fork stations. As with whole-water recoverable loads, this result indicates an important source of dissolved cadmium and zinc within the main stem. The picture is much different for dissolved lead loads: About 94 percent of the load difference between the O’Brien Gulch and Pinehurst stations was accounted for by loads from the 13 tributaries. The Coeur d’Alene River near Harrison transported 924 pounds of dissolved lead per day, of which 82.8 pounds came from the South Fork and 11.7 pounds from the North Fork. Only 10.2 percent of the load at Harrison was measured at the Pinehurst and Enaville stations; therefore, a substantial load of dissolved lead is being contributed downstream from the confluence of the North and South Forks.

Idaho↗
USGS2000

Transport of suspended and bedload sediment at eight stations in the Coeur d'Alene River basin, Idaho

The Remedial Investigation/Feasibility Study conducted by the U.S. Environmental Protection Agency within the Spokane River Basin of northern Idaho and eastern Washington included extensive data-collection activities to determine the nature and extent of trace-element contamination within the basin. As part of the investigation, the U.S. Geological Survey designed and implemented a sampling program to assess sediment transport in the Coeur d’Alene River Basin. Suspended and bedload sediments were sampled at four stations at or near base flow and at eight stations during low, moderate, and high discharge conditions between February 1999 and April 2000. The concentrations and loads of suspended and bedload sediment at all stations were directly related to stream discharge. To quantify these relationships, a power function was used to develop sediment-transport curves at all stations. Although the transport curves for most of the stations indicate a good log-log relationship between stream discharge and suspended- and bedload-sediment discharge, there was a fair amount of scatter about the best-fit regression at most stations. For suspended-sediment discharge, the scatter can be primarily attributed to a hysteresis effect in the concentration of suspended sediment as stream discharge rises and falls. The effects of hysteresis on bedload-sediment discharge were difficult to assess because of a paucity of samples collected over the stream hydrograph. At most of the stations, and at the stream discharges sampled, the transport characteristics for fine- and sand-sized suspended sediment were similar. However, at the two main-stem Coeur d’Alene River stations, Rose Lake and Harrison, the suspended-sediment load was primarily composed of fine-grained sediment at stream discharges of less than 15,000 cubic feet per second. These two stations are characterized by relatively slow water velocities, which appear to be insufficient to transport sand-sized sediment at lower stream discharge. At most of the stations, and at the stream discharges sampled, the bedload was primarily composed of material greater than 2 millimeters in diameter, the break between sand and gravel. A predominance of sand-sized bedload was noted at only a few stations, and generally only during low stream discharge. The particle-size distribution of bedload sediment at most stations became proportionately coarser as stream discharge increased. During the peak of snowmelt runoff for water years 1999 and 2000, gravel-sized material between 2 and 64 millimeters in diameter comprised more than 70 percent of the bedload transport at most stations. However, at the station on the Coeur d’Alene River at Rose Lake, the bedload was predominantly composed of fine-grained material of less than 1 millimeter in diameter for all measured stream discharges. The slow water velocities at Rose Lake accounted for the predominance of fine-grained sediment transport.

Idaho↗
USGS2000

Benthic flux of metals and nutrients into the water column of Lake Coeur d'Alene, Idaho: Report of an August, 1999, pilot study

A field study was conducted between August 16-27, 1999, to provide the first direct measurements of the benthic flux of dissolved (0.2-micron filtered) solutes between the bottom sediment and water column at two sites in Lake Coeur d'Alene, Idaho. Trace metals (namely, cadmium, copper, manganese, mercury species, and zinc) and nutrients (namely, ammonia, nitrate plus nitrite, oxygen, orthophosphate and silica) were solutes of primary interest. Benthic flux (sometimes referred to as internal recycling) represents the transport of dissolved chemical species between the water column and the underlying sediment.

Idaho↗
USGS1997

Trace-element concentrations and transport in the Coeur d'Alene river, Idaho, water years 1993-94

for almost a century, the U.S. Geological Survey has collected hydrologic data at a network of stream-gaging stations throughout the Coeur d'Alene Lake and River drainage basin. Since 1990, extensive water-quality data have been collected for a comprehensive study of potential eutrophication of Coeur d'Alene Lake and for assessment of the environmental effects of past mining and ore-processing activities in the South Fork Coeur d'Alene River valley. Although the South Fork Coeur d'Alene River provided only about 20 percent of the Coeur d'Alene River's annual discharge to Coeur d'Alene Lake, it contributed as much as 84 percent of the annual cadmium and 83 percent of the annual zinc loads entering the Lake. The South Fork contributed at most 14 percent of the annual lead and 21 percent of the copper loads carried by the Coeur d'Alene River to Coeur d'Alene Lake. Cadmium, copper, and zinc loads more than doubled between the upstream and downstream boundaries of the Bunker Hill (Kellogg, Idaho) Superfund site in water years 1993 and 1994; lead load increased 24 percent and 33 percent, respectively, in water years 1993 and 1994. Zinc was transported primarily in a dissolved or colloidal phase, the major source being the South Fork Coeur d'Alene River valley, downstream from the Elizabeth Park gaging station. Lead was transported primarily as particulate material, the major source being sediments eroded from the main-stem Coeur d'Alene River channel and flood plain. Annual lead and zinc loads at Rose Lake were significantly larger than at Harrison or Cataldo, indicating entrainment of trace elements in the reach between Cataldo and Rose Lake, and subsequent deposition or loss in the reach between Rose Lake and Harrison.

Idaho↗
USGS1997

Eutrophication potential of Payette Lake, Idaho

Payette Lake was studied during water years 1995-96 to determine the 20.5-square-kilometer lake's assimilative capacity for nutrients and, thus, its eutrophication potential. The study included quantification of hydrologic and nutrient budgets, characterization of water quality in the limnetic and littoral zones, development of an empirical nutrient load/lake response model, and estimation of the limnological effects of a large-scale forest fire in the lake's 373-square-kilometer watershed during the autumn of 1994. Streamflow from the North Fork Payette River, the lake's primary tributary, delivered about 73 percent of the lake's inflow over the 2 years. Outflow from the lake, measured since 1908, was 128 and 148 percent of the long-term average in 1995 and 1996, respectively. The larger volumes of outflow reduced the long-term average water- residence time of 2.35 years to 1.84 and 1.42 years for 1995 and 1996, respectively. The lake retained 54 percent of its 1995-96 influent load of nitrogen and 79 percent of its influent load of phosphorus. The North Fork Payette River contributed an average of 69.4 percent of the lake's nitrogen load and 28.2 percent of its phosphorus load. The 1994 forest fires substantially increased the loads of nitrogen and phosphorus delivered to the lake; however, only nitrogen concentrations were noticeably increased in the lake. Payette Lake was classified as oligotrophic on the basis of annual geometric mean concentrations, in micrograms per liter, of total phosphorus (4.7), total nitrogen (225), and chlorophyll- a (1.3) during 1995-96. Secchi-disc transparencies ranged from 2.3 to 8.0 meters, indicative of mesotrophic conditions. Median ratios of dissolved inorganic nitrogen to dissolved orthophosphorus ranged from 38 to 254, thereby indicating phosphorus limitation of phytoplankton growth. Phytoplankton populations were taxonomically dominated by diatoms; blue-green algae were rare. One diatom, Tabellaria fenestrata , contributed 52 percent of the biovolume. Within the littoral zone, median periphyton production, normalized to photosynthetically active radiation input, ranged from 0.0007 to 0.02 milligrams of chlorophyll- a per square meter per Einstein, a difference of 28.6 times. Multiple linear regression analysis failed to detect any significant relation between periphyton production and various indices of nearshore development. Nine genera of aquatic macrophytes were identified, including Eurasian milfoil ( Myriophyllum spicatum var. spicatum ), which is considered a nuisance aquatic plant. Despite its oligotrophy, Payette Lake had substantial dissolved-oxygen deficits in 1995-96, which led to 4-month periods of anoxia in the near-bottom waters of its southwest basin. The hypolimnetic dissolved-oxygen deficit was much larger than that predicted by the nutrient load/lake response model. The southwest basin's propensity for developing anoxia was related to the lengthy water-residence time and incomplete water-column circulation and reaeration during the spring and autumn, coupled with a long-term accumulation of oxygen- demanding organic matter produced within the lake or delivered by its watershed.

Idaho↗
USGS1997

Nutrient and trace-element enrichment of Coeur d'Alene Lake, Idaho

The limnological characteristics and geochemistry of lakebed sediments in Coeur d'Alene Lake were assessed during 1991-92 because of the possible interaction of nutrient enrichment with the highly enriched trace-element concentrations stored in the lakebed. The scope included characterization of physical, chemical, and biological variables; quantification of hydrologic, nutrient, and trace-element budgets; development of an empirical nutrient load/lake response model; and characterization of trace elements in surficial and subsurface lakebed sediments.

Water Supply Paper↗
USGS1992

Limnology of Big Lake, south-central Alaska, 1983-84

The limnological characteristics and trophic state of Big Lake in south-central Alaska were determined from the results of an intensive study during 1983-84. The study was begun in response to concern over the potential for eutrophication of Big Lake, which has experienced substantial residential development and recreational use because of its proximity to Anchorage. The east and west basins of the 1,213 square-hectometer lake were each visited 36 times during the 2-year study to obtain a wide variety of physical, chemical, and biological data. During 1984, an estimate was made of the lake's annual primary production. Big Lake was classified as oligotrophic on the basis of its annual mean values for total phosphorus (9.5 micrograms per liter), total nitrogen (209 micrograms per liter), chlorophyll-a (2.5 micrograms per liter), secchi-disc transparency (6.3 meters), and its mean daily integral primary production of 81.1 milligrams of carbon fixed per square meter. The lake was, however, uncharacteristic of oligotrophic lakes in that a severe dissolved-oxygen deficit developed within the hypolimnion during summer stratification and under winter ice cover. The summer dissolved-oxygen deficit resulted from the combination of strong and persistent thermal stratification, which developed within 1 week of the melting of the lake's ice cover in May, and the failure of the spring circulation to fully reaerate the hypolimnion. The autumn circulation did reaerate the entire water column, but the ensuing 6 months of ice and snow cover prevented atmospheric reaeration of the water column and led to development of the winter dissolved-oxygen deficit. The anoxic conditions that eventually developed near the lake bottom allowed the release of nutrients from the bottom sediments and facilitated ammonification reactions. These processes yielded hypolimnetic concentrations of nitrogen and phosphorus compounds, which were much larger than the oligotrophic concentrations measured within the epilimnion. An analysis of nitrogen-to-phosphorus ratios showed that nitrogen was the nutrient most likely to limit phytoplankton growth during the summer. Although mean chlorophyll-a concentrations were at oligotrophic levels, concentrations did peak at 46.5 micrograms per liter in the east basin. During each year and in both basins, the peak chlorophyll-a concentrations were measured within the hypolimnion because the euphotic zone commonly was deeper than the epilimnion during the summer. The annual integral primary production of Big Lake in 1984 was 29.6 grams of carbon fixed per square meter with about 90 percent of that produced during May through October. During this time period, the lake received 76 percent of its annual input of solar irradiance. Monthly integral primary production, in milligrams of carbon fixed per square meter, ranged from 1.5 in January to 7,050 in July. When compared with the range of annual integral primary production measured in 50 International Biological Program lakes throughout the world, Big Lake had a low value of annual integral primary production. The results of this study lend credence to the concerns about the potential eutrophication of Big Lake. Increases in the supply of oxygen-demanding materials to Big Lake could worsen the hypolimnetic dissolved-oxygen deficit and possibly shift the lake's trophic state toward mesotrophy or eutrophy.

Water Supply Paper↗
USGS1982

Annual Nutrient Loadings, Primary Productivity, and Trophic State of Lake Koocanusa, Montana and British Columbia, 1972-80

Limnological data collected at Lake Koocanusa were used to investigate the relationship of nutrient loadings, primary productivity, and trophic state of the reservoir during 1972-80. The reservoir, on the Kootenai River, was impounded by Libby Dam on March 21, 1972. Manipulation of the 7.16-cubic-kilometer reservoir for flood control, its primary function, created large fluctuations in reservoir volume and produced annual lake-filling times that ranged from 0.14 to 0.66 year. Loadings of nitrogen and phosphorus prior to and following impoundment of Lake Koocanusa were found to be large enough to predict eutrophic conditions. Beginning in 1976, total phosphorus loadings, but not total nitrogen loadings, were substantially reduced following improvements in waste-water treatment at a fertilizer plant located upstream from the reservoir. The closure of Libby Dam substantially reduced loadings of nitrogen and phosphorus downstream from Lake Koocanusa. On the average, the reservoir retained 63 percent of its influent loading of total phosphorus and 25 percent of its influent loading of total nitrogen. Daily areal and volumetric primary productivity varied widely in each year at four sampled limnological stations. During the 9 years studied, daily areal primary productivity, in milligrams of carbon fixed per square meter, ranged from 0.4 to 420.0; the mean of the 313 sampled days was 128.5. Annual areal primary productivity ranged from 23.2 to 38.5 grams of carbon fixed per square meter and thereby categorized Lake Koocanusa as oligotrophic. The relationship of annual areal primary productivity and 12 selected environmental variables was determined by multiple regression analysis. One of the models that was derived used two variables-annual euphotic zone depth and annual areal phosphorus loading-and accounted for 62.0 percent of the variation in annual areal primary productivity. The distribution of chlorophyll a within the water column indicated that, on the average, more than one-half of the phytoplankton in the reservoir was beneath the euphotic zone. These results support the hypothesis that the reservoir's weak thermal structure had allowed circulation of phytoplankton out of the euphotic zone. The trophic state of Lake Koocanusa was categorized as eutrophic when based on the relationship of the nutrient loadings and the reservoir's ratio of mean depth to hydraulic-residence time. This result conflicted with the oligotrophic ranking the reservoir received based on its areal primary productivity. The discrepancy in trophic state was attributed mainly to the failure of nutrient loading models to adequately account for physical processes within reservoirs. Part of the nutrient loading that entered Lake Koocanusa was unavailable to phytoplankton because the nutrients were carried beneath the euphotic zone by large volumes of interflow and underflow. Another part of the nutrient loading was adsorbed to suspended sediment and removed from the water column. Thus, phytoplankton primary productivity was controlled not only by nutrients, but also by other limno logical processes.

Professional Paper↗
USGS1981

Documentation of a dissolved-solids model of the Tongue River, southeastern Montana

A model has been developed for assessing potential increases in dissolved solids of the Tongue River as a result of leaching of overburden materials used to backfill pits in surface coal-mining operations. The model allows spatial and temporal simulation of streamflow and dissolved-solids loads and concentrations under user-defined scenarios of surface coal mining and agricultural development. The model routes an input quantity of streamflow and dissolved solids from the upstream end to the downstream end of a stream reach while algebraically accounting for gains and losses of streamflow and dissolved solids within the stream reach. Input data needed to operate the model include the following: simulation number, designation of hydrologic conditions for each simulated month, either user-defined or regression-defined concentrations of dissolved solids input by the Tongue River Reservoir, number of irrigated acres, number of mined acres, dissolved-solids concentration of mine leachates and quantity of other water losses. A listing of the Fortran computer program, definitions of all variables in the model, and an example output permit use of the model by interested persons. (USGS)

Open-File Report↗