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Geology topics

P.W. Swarzenski

Publications and source records attributed to P.W. Swarzenski.

At least 37 records · Page 2Linked to original sources
USGS2006

Combined time-series resistivity and geochemical tracer techniques to examine submarine groundwater discharge at Dor Beach, Israel

A high-resolution, stationary geophysical and geochemical survey was conducted at Dor Beach, Israel, to examine the shallow coastal hydrogeology and its control on the exchange of submarine groundwater with the shallow Mediterranean Sea. Time-series resistivity profiles using a new 56 electrode (112-m long) marine cable produced detailed profiles of the fresh water/salt water interface and the subtle response of this interface to tidal excursions and other forcing factors. Such information, when ground-truthed with representative pore water salinities and formation resistivity values, can provide unique information of the extent and rates of submarine groundwater discharge (SGD). Time-series 222Rn measurements of the adjacent coastal water column complemented these geophysical techniques and were modeled to yield integrated advective flow rates across the sediment/water interface, which at Dor Beach ranged from about 0 to 30 cm day-1 (mean = 7.1 cm d-1), depending on the tidal range. Such results suggest that the underlying hydrogeologic framework at Dor is favorable for substantial SGD. Extrapolating these SGD estimates across a 100-m wide coastal zone implies that the Rn-derived SGD rate would equal ???7.1 m3 d-1 per m of shoreline, and that the source of this discharging groundwater is a complex mixture of fresh groundwater derived from the upland Kurkar deposits, as well as locally recycled seawater. Copyright 2006 by the American Geophysical Union.

Geophysical Research Letters↗
USGS2006

Biogeochemical transport in the Loxahatchee River estuary, Florida: The role of submarine groundwater discharge

The distributions of dissolved organic carbon (DOC), Ba, U, and a suite of naturally occurring radionuclides in the U/Th decay series (222Rn, 223,224,226,228Ra) were studied during high- and low-discharge conditions in the Loxahatchee River estuary, Florida to examine the role of submarine groundwater discharge in estuarine transport. The fresh water endmember of this still relatively pristine estuary may reflect not only river-borne constituents, but also those advected during active groundwater/surface water (hyporheic) exchange. During both discharge conditions, Ba concentrations indicated slight non-conservative mixing. Such Ba excesses could be attributed either to submarine groundwater discharge or particle desorption processes. Estuarine dissolved organic carbon concentrations were highest at salinities closest to zero. Uranium distributions were lowest in the fresh water sites and mixed mostly conservatively with an increase in salinity. Suspended particulate matter (SPM) concentrations were generally lowest (< 5??mg L- 1) close to zero salinity and increased several-fold (??? 18??mg L- 1; low discharge) toward the seaward endmember, which may be attributed to dynamic resuspension of bottom sediments within Jupiter Inlet. Surface water-column 222Rn activities were most elevated (> 28??dpm L- 1) at the freshwater endmember of the estuary and appear to identify regions of the river most influenced by the discharge of fresh groundwater. Activities of four naturally occurring isotopes of Ra (223,224,226,228Ra) in this estuary and select adjacent shallow groundwater wells yield mean estuarine water-mass transit times of less than 1 day; these values are in close agreement to those calculated by tidal prism and tidal frequency. Submarine groundwater discharge rates to the Loxahatchee River estuary were calculated using a tidal prism approach, an excess 226Ra mass balance, and an electromagnetic seepage meter. Average SGD rates ranged from 1.0 to 3.8 ?? 105??m3 d- 1 (20-74??L m- 2 d- 1), depending on river-discharge stage. Such calculated SGD estimates, which must include both a recirculated as well as fresh water component, are in close agreement with results obtained from a first-order watershed mass balance. Average submarine groundwater discharge rates yield NH4+ and PO4- 3 flux estimates to the Loxahatchee River estuary that range from 62.7 to 1063.1 and 69.2 to 378.5????mol m- 2 d- 1, respectively, depending on river stage. SGD-derived nutrient flux rates are compared to yearly computed riverine total N and total P load estimates. ?? 2006 Elsevier B.V. All rights reserved.

Marine Chemistry↗
USGS2006

Uranium distribution in the coastal waters and pore waters of Tampa Bay, Florida

The geochemical reactivity of uranium (238U) and dissolved organic carbon (DOC), Fe, Mn, Ba, and V was investigated in the water column, pore waters, and across a river/estuarine mixing zone in Tampa Bay, Florida. This large estuary is impacted both by diverse anthropogenic activity and by extensive U-rich phosphatic deposits. Thus, the estuarine behavior of uranium may be examined relative to such known U enrichments and anthropogenic perturbations. Dissolved (< 0.45??m) uranium exhibited both removal and enrichment processes across the Alafia River/estuarine mixing zone relative to conservative mixing. Such non-conservative U behavior may be attributed to: i) physical mixing processes within the river; ii) U carrier phase reactivity; and/or iii) fluid exchange processes across sediment/water interface. In the bay proper, U concentrations were ?????2 to 3 times greater than those reported for other estuarine systems and are likely a result of erosional inputs from the extensive, underlying U-rich phosphatic deposits. Whereas dissolved U concentrations generally did not approach seawater values (13.6??nM) along the Alafia River salinity transect, water column U concentrations exceeded 16??nM in select regions of the bay. Within the hydrogeological framework of the bay, such enriched U may also be derived from advective fluid transport processes across the sediment/water interface, such as submarine groundwater discharge (SGD) or hyporheic exchange within coastal rivers. Pore water profiles of U in Tampa Bay show both a flux into and out of bottom sediments, and average, diffusive U pore water fluxes (Jdiff) ranged from - 82.0 to 116.6??mol d- 1. It is likely that negative U fluxes imply seawater entrainment or infiltration (i.e., submarine groundwater recharge), which may contribute to the removal of water column uranium. For comparison, a bay-wide, Ra-derived submarine groundwater discharge estimate for Tampa Bay (8??L m- 2 d- 1) yielded an average, advective (JSGD) U flux of 112.9??mol d- 1. In Tampa Bay, the estuarine distribution of U indicates a strong natural, geologic control that may also be influenced by enhanced fluid transport processes across the sediment/water interface. ?? 2006 Elsevier B.V. All rights reserved.

Marine Chemistry↗
USGS2006

Hurricanes, submarine groundwater discharge, and Florida's red tides

A Karenia brevis Harmful Algal Bloom affected coastal waters shallower than 50 m off west-central Florida from January 2005 through January 2006, showing a sustained anomaly of ???1 mg chlorophyll m-3 over an area of up to 67,500 km2. Red tides occur in the same area (approximately 26-29??N, 82-83??W) almost every year, but the intense 2005 bloom led to a widespread hypoxic zone (dissolved oxygen <2 mg L-1) that caused mortalities of benthic communities, fish, turtles, birds, and marine mammals. Runoff alone provided insufficient nitrogen to support this bloom. We pose the hypothesis that submarine groundwater discharge (SGD) provides the missing nutrients, and indeed can trigger and support the recurrent red tides off west-central Florida. SGD inputs of dissolved inorganic nitrogen (DIN) in Tampa Bay alone are ???35% of that discharged by all central Florida rivers draining west combined. We propose that the unusual number of hurricanes in 2004 resulted in high runoff, and in higher than normal SGD emerging along the west Florida coast throughout 2005, initiating and fueling the persistent HAB. This mechanism may also explain recurrent red tides in other coastal regions of the Gulf of Mexico. Copyright 2006 by the American Geophysical Union.

Geophysical Research Letters↗
USGS2006

Gulf of Mexico dead zone —The last 150 years

'Gulf of Mexico Dead Zone-The Last 150 Years' discusses the dead zone that forms seasonally in the northern Gulf of Mexico when subsurface waters become depleted in dissolved oxygen and cannot support most life.

Louisiana↗
USGS2006

Historical trace element distribution in sediments from the Mississippi River delta

Five sediment cores were collected on the shelf of the inner Mississippi Bight in June 2003 for a suite of radionuclides to establish geochronologies and trace elements to examine patterns of contaminant deposition and accumulation. Core sites were chosen to reflect a matrix of variable water depths, proximity to the Mississippi River mouth as the primary source for terrigenous particles, and extent and duration of summertime water column hypoxia. The vertical distribution of 239,240Pu and 210Pbxs (= 210Pbtotal - 226Ra) provided reliable geochronological age constraints to develop models for mass accumulation rates and historic trace element inputs and variations. Mass accumulation rates ranged from 0.27 to 0.87 g cm-2 yr-1 and were internally consistent using either 210Pbxs or 239,240Pu. Measured inventories of 137Cs, 239,240Pu, and 210Pbxs were compared to atmospheric deposition rates to quantify potential sediment focusing or winnowing. Observed variability in calculated mass accumulation rates may be attributed foremost to site-specific proximity to the river mouth (i.e., sediment source), variability in water depth, and enhanced sediment focusing at the Mississippi River canyon site. Trace element concentrations were first normalized to Al, and then Al-normalized enrichment factors (ANEF) were calculated based on preanthropogenic and crustal trace element abundances. These ANEFs were typically > 1 for V and Ba, while for most other elements studied, either no enrichment or depletion was observed. The enrichment of Ba may be related, in part, to the seasonal occurrence of oxygen-depleted subsurface waters off the Mississippi River delta, as well as being an ubiquitous by-product of the petroleum industry. ?? 2006 Estuarine Research Federation.

Estuaries and Coasts↗
USGS2005

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: I. An introduction to the project

We investigated paleolimnological records from a series of river deltas around the northeastern rim of Lake Tanganyika, East Africa (Tanzania and Burundi) in order to understand the history of anthropogenic activity in the lake's catchment over the last several centuries, and to determine the impact of these activities on the biodiversity of littoral and sublittoral lake communities. Sediment pollution caused by increased rates of soil erosion in deforested watersheds has caused significant changes in aquatic communities along much of the lake's shoreline. We analyzed the effects of sediment discharge on biodiversity around six deltas or delta complexes on the east coast of Lake Tanganyika: the Lubulungu River delta, Kabesi River delta, Nyasanga/Kahama River deltas, and Mwamgongo River delta in Tanzania; and the Nyamuseni River delta and Karonge/Kirasa River deltas in Burundi. Collectively, these deltas and their associated rivers were chosen to represent a spectrum of drainage-basin sizes and disturbance levels. By comparing deltas that are similar in watershed attributes (other than disturbance levels), our goal was to explore a series of historical "experiments" at the watershed scale, with which we could more clearly evaluate hypotheses of land use or other effects on nearshore ecosystems. Here we discuss these deltas, their geologic and physiographic characteristics, and the field procedures used for coring and sampling the deltas, and various indicators of anthropogenic impact. ?? Springer 2005.

Journal of Paleolimnology↗
USGS2005

Thallium isotope composition of the upper continental crust and rivers - An investigation of the continental sources of dissolved marine thallium

The thallium (Tl) concentrations and isotope compositions of various river and estuarine waters, suspended riverine particulates and loess have been determined. These data are used to evaluate whether weathering reactions are associated with significant Tl isotope fractionation and to estimate the average Tl isotope composition of the upper continental crust as well as the mean Tl concentration and isotope composition of river water. Such parameters provide key constraints on the dissolved Tl fluxes to the oceans from rivers and mineral aerosols. The Tl isotope data for loess and suspended riverine detritus are relatively uniform with a mean of ??205Tl = -2.0 ?? 0.3 (??205Tl represents the deviation of the 205Tl/203Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 104). For waters from four major and eight smaller rivers, the majority were found to have Tl concentrations between 1 and 7 ng/kg. Most have Tl isotope compositions very similar (within ??1.5 ??205Tl) to that deduced for the upper continental crust, which indicates that no significant Tl isotope fractionation occurs during weathering. Based on these results, it is estimated that rivers have a mean natural Tl concentration and isotope composition of 6 ?? 4 ng/kg and ??205Tl = -2.5 ?? 1.0, respectively. In the Amazon estuary, both additions and losses of Tl were observed, and these correlate with variations in Fe and Mn contents. The changes in Tl concentrations have much lower amplitudes, however, and are not associated with significant Tl isotope effects. In the Kalix estuary, the Tl concentrations and isotope compositions can be explained by two-component mixing between river water and a high-salinity end member that is enriched in Tl relative to seawater. These results indicate that Tl can display variable behavior in estuarine systems but large additions and losses of Tl were not observed in the present study. Copyright ?? 2005 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗
USGS2005

Reconstructing a 180 yr record of natural and anthropogenic induced low-oxygen conditions from Louisiana continental shelf sediments

Hypoxia on the Louisiana continental shelf is tied to nutrient Loading and freshwater stratification from the Mississippi River. Variations in the relative abundance of low-oxygen-tolerant benthic foraminifers in four sediment cores from the Louisiana shelf provide a proxy record of low-oxygen events. Core chronologies are obtained using 210Pb dating techniques. The foraminiferal data are consistent with previous studies indicating that the intensity of hypoxic events (oxygen <2 mg /L) has increased over the past 50 yr owing to the higher nutrient loading associated with the use of commercial fertilizer, and also reveal several low-oxygen events between A.D. 1817 and 1910, prior to the widespread use of fertilizer. The pre-1910 low-oxygen events are associated with high Mississippi River discharge rates, indicating that these low-oxygen episodes are related to natural variations in river drainage that enhance transport of nutrients and freshwater to the continental shelf. Our data show that the low-oxygen events of the past few decades were more extreme than any that occurred in the previous ???180 yr, and support the interpretation that the increased use of fertilizer has amplified an otherwise naturally occurring process. ?? 2005 Geological Society of America.

Geology↗
USGS2004

Recent increases in sediment and nutrient accumulation in Bear Lake, Utah/Idaho, USA

This study examines historical changes in sediment and nutrient accumulation rates in Bear Lake along the northeastern Utah/Idaho border, USA. Two sediment cores were dated by measuring excess 210Pb activities and applying the constant rate of supply (CRS) dating model. Historical rates of bulk sediment accumulation were calculated based on the ages within the sediment cores. Bulk sediment accumulation rates increased throughout the last 100 years. According to the CRS model, bulk sediment accumulation rates were <25mg cm-2 year-1 prior to 1935. Between 1935 and 1980, bulk sediment accumulation rates increased to approximately 40mg cm -2 year-1. This increase in sediment accumulation probably resulted from the re-connection of Bear River to Bear Lake. Bulk sediment accumulation rates accelerated again after 1980. Accumulation rates of total phosphorus (TP), total nitrogen (TN), total inorganic carbon (TIC), and total organic carbon (TOC) were calculated by multiplying bulk sediment accumulation rates times the concentrations of these nutrients in the sediment. Accumulation rates of TP, TN, TIC, and TOC increased as a consequence of increased bulk sediment accumulation rates after the re-connection of Bear River with Bear Lake.

Hydrobiologia↗
USGS2003

Role of colloidal material in the removal of 234Th in the Canada basin of the Arctic Ocean

The phase partitioning of 234Th between dissolved (< 10-kiloDalton, kD), colloidal (10 kD - 0.4 ??m), and particulate (???0.5 ??m) matter across a horizontal transect, from a coastal station to the deep Canada Basin, and a vertical profile in the deep Canada Basin of the western Arctic Ocean was investigated. Concentrations of suspended particulate matter (SPM), dissolved, colloidal and particulate organic carbon, particulate organic nitrogen and nutrients (silicate, phosphate and nitrate) were also measured to assess transport and scavenging processes. Total 234Th (colloidal + particulate + dissolved) indicated deficiencies relative to secular equilibrium with its parent, 238U in the upper 100 m, which suggests active scavenging of 234Th onto particle surfaces. In contrast, at depths > 200m, general equilibrium existed between total 234Th and 238U. The inventory of SPM and the specific activity of particulate 234Th in the Canada Basin was about an order of magnitude higher than the profile reported for the Alpha Ridge ice camp station. This higher concentration of SPM in the southwestern Canada Basin is likely derived from ice-rafted sedimentary particles. Inventories of nutrients, and dissolved organic carbon and nitrogen in the upper 100 m of the Canada Basin are comparable to the other estimates for the central Arctic Ocean. Comparison of the mass concentrations of colloidal and filter-retained particulate matter as well as the activity of 234Th in these phases indicates that only a very small component of the colloidal material is actively involved in Th scavenging. Lower values of the conditional partition coefficient between the colloidal and dissolved phase indicate that the Arctic colloids are less reactive than colloidal material from other regions. The conditional partition coefficient between the filter-retained and dissolved phases (Kf) is generally higher than that for other regions, which is attributed to the higher complexation capacity of glacio-marine sedimentary particles in these waters. The 234Th-derived export of POC for the shelf and deep Canada Basin ranges between 5.6 and 6.5 mmol m-2 d-1, and is in agreement with other estimates reported for the central Arctic Ocean and Beaufort Sea. ?? 2003 Elsevier Ltd. All rights reserved.

Deep-Sea Research Part I: Oceanographic Research P↗
USGS2003

A multi-level pore-water sampler for permeable sediments

The construction and operation of a multi - level piezometer (multisampler) designed to collect pore water from permeable sediments up to 230 cm below the sediment - water interface is described. Multisamplers are constructed from 1 1/2 inch schedule 80 PVC pipe. One-quarter-inch flexible PVC tubing leads from eight ports at variable depths to a 1 1/2 inch tee fitting at the top of the PVC pipe. Multisamplers are driven into the sediments using standard fence-post drivers. Water is pumped from the PVC tubing with a peristaltic pump. Field tests in Banana River Lagoon, Florida, demonstrate the utility of multisamplers. These tests include collection of multiple samples from the permeable sediments and reveal mixing between shallow pore water and overlying lagoon water .

Journal of Sedimentary Research↗
USGS2003

The behavior of U- and Th-series nuclides in groundwater

Groundwater has long been an active area of research driven by its importance both as a societal resource and as a component in the global hydrological cycle. Key issues in groundwater research include inferring rates of transport of chemical constituents, determining the ages of groundwater, and tracing water masses using chemical fingerprints. While information on the trace elements pertinent to these topics can be obtained from aquifer tests using experimentally introduced tracers, and from laboratory experiments on aquifer materials, these studies are necessarily limited in time and space. Regional studies of aquifers can focus on greater scales and time periods, but must contend with greater complexities and variations. In this regard, the isotopic systematics of the naturally occurring radionuclides in the U- and Th- decay series have been invaluable in investigating aquifer behavior of U, Th, and Ra. These nuclides are present in all groundwaters and are each represented by several isotopes with very different half-lives, so that processes occurring over a range of time-scales can be studied (Table 1 ⇓ ). Within the host aquifer minerals, the radionuclides in each decay series are generally expected to be in secular equilibrium and so have equal activities (see Bourdon et al. 2003 ). In contrast, these nuclides exhibit strong relative fractionations within the surrounding groundwaters that reflect contrasting behavior during release into the water and during interaction with the surrounding host aquifer rocks. Radionuclide data can be used, within the framework of models of the processes involved, to obtain quantitative assessments of radionuclide release from aquifer rocks and groundwater migration rates. The isotopic variations that are generated also have the potential for providing fingerprints for groundwaters from specific aquifer environments, and have even been explored as a means for calculating groundwater ages.

Reviews in Mineralogy and Geochemistry↗
USGS2003

The behavior of U- and Th-series nuclides in the estuarine environment

Rivers carry the products of continental weathering, and continuously supply the oceans with a broad range of chemical constituents. This erosional signature is, however, uniquely moderated by biogeochemical processing within estuaries. Estuaries are commonly described as complex filters at land-sea margins, where significant transformations can occur due to strong physico-chemical gradients. These changes differ for different classes of elements, and can vary widely depending on the geographic location. U- and Th-series nuclides include a range of elements with vastly different characteristics and behaviors within such environments, and the isotopic systematics provide methods for investigating the transport of these nuclides and other analog species across estuaries and into the coastal ocean.

Reviews in Mineralogy and Geochemistry↗
USGS2001

Measurement of 224Ra and 226Ra activities in natural waters using a radon-in-air monitor

We report a simple new technique for measuring low-level radium isotopes (224Ra and 226Ra) in natural waters. The radium present in natural waters is first preconcentrated onto MnO2-coated acrylic fiber (Mn fiber) in a column mode. The radon produced from the adsorbed radium is then circulated through a closed air-loop connected to a commercial radon-in-air monitor. The monitor counts alpha decays of radon daughters (polonium isotopes) which are electrostatically collected onto a silicon semiconductor detector. Count data are collected in energy-specific windows, which eliminate interference and maintain very low backgrounds. Radium-224 is measured immediately after sampling via 220Rn (216Po), and 226Ra is measured via 222Rn (218Po) after a few days of ingrowth of 222Rn. This technique is rapid, simple, and accurate for measurements of low-level 224Ra and 226Ra activities without requiring any wet chemistry. Rapid measurements of short-lived 222Rn and 224Ra, along with long-lived 226Ra, may thus be made in natural waters using a single portable system for environmental monitoring of radioactivity as well as tracing of various geochemical and geophysical processes. The technique could be especially useful for the on-site rapid determination of 224Ra which has recently been found to occur at elevated activities in some groundwater wells.

Environmental Science & Technology↗