Geology topics

P.M. Buszka

Publications and source records attributed to P.M. Buszka.

5 recordsLinked to original sources

USGS2009

Waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water near Elkhart, Indiana, 2000-2002

Four wells downgradient from a landfill near Elkhart, Indiana were sampled during 2000–2002 to evaluate the presence of waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water. Compounds detected in leachate-affected ground water included detergent metabolites ( p -nonylphenol, nonylphenol monoethoxylate, nonylphenol diethoxylate, and octylphenol monoethoxylate), plasticizers (ethanol-2-butoxy-phosphate and diethylphthalate), a plastic monomer (bisphenol A), disinfectants (1,4-dichlorobenzene and triclosan), an antioxidant (5-methyl-1H-benzotriazole), three fire-retardant compounds (tributylphosphate and tri(2-chloroethyl)phosphate, and tri(dichlorisopropyl)phosphate), and several pharmaceuticals and metabolites (acetaminophen, caffeine, cotinine, 1,7-dimethylxanthine, fluoxetine, and ibuprofen). Acetaminophen, caffeine, and cotinine detections confirm prior indications of pharmaceutical and nicotinate disposal in the landfill.

Indiana↗

USGS1994

Organic compounds downstream from a treated-wastewater discharge near Dallas, Texas, March 1987

Water and streambed-sediment samples were collected on March 9 and 10,1987 from one site upstream and three sites downstream of the discharge from a municipal wastewater-treatment plant on Rowlett Creek near Dallas, Texas. To extract and separate organic compounds, purgeand-trap, closed-loop stripping, and pH-adjusted solvent extraction methods were used for water samples; and a Soxhlet-solvent extraction method was used for streambed sediment. These methods were combined with gas chromatography/mass spectrometry to identify organic compounds in Rowlett Creek. Results from this study confirm the persistence of many organic compounds in water as far as 13.5 kilometers downstream of the wastewater discharge. These include: (1) the volatile organic compounds chloroform, 1,2-dichlorobenzene, 1,4-dichlorobenzene, tetrachloroethene, and trichloroethene; (2) several linear alkylbenzene compounds, octyl phenol, and a tetramethylbutyl phenol isomer that are related to detergent use; (3) 9-phenyl-9H-carbazole, a compound related to coal tars and coal combustion residues; and (4) caffeine. The only compound present in water in concentrations greater than U.S. Environmental Protection Agency maximum contaminant levels for drinking water was tetrachloroethene (6.0 micrograms per liter) in a sample collected 13.5 kilometers downstream from the waste water discharge. Compounds identified from the streambed-sediment samples include a xylene isomer at 7.7 kilometers downstream and chrysene, fluoranthene, pyrene, and a xylene isomer at 13.5 kilometers downstream from the wastewater discharge. Comparison of instantaneous flux values of selected organic compounds in water from downstream sites indicates: (1) the formation of chloroform in the stream following the discharge of the treated effluent, and that (2) instream biodegradation may be decreasing concentrations of linear alkylbenzene compounds in water. The relative persistence of many of the selected organic compounds in Rowlett Creek downstream from the municipal wastewater-treatment plant indicates that they could be transported into Lake Ray Hubbard, a source of municipal water supply.

Texas↗

USGS1994

Characteristics of streams and aquifers and processes affecting the salinity of water in the upper Colorado River basin, Texas

The upper Colorado River and some of its tributaries between Lake J.B. Thomas and O.H. Ivie Reservoir contain saline water (defined as water having dissolved-solids concentrations greater than 1,000 milligrams per liter). Dissolved-solids loads at nine streamflow water-quality stations increased from 1986 to 1988. The largest increases were in Beals Creek and in the Colorado River downstream from Beals Creek as a result of outflow of saline water from Natural Dam Salt Lake. The outflow contained 654,000 tons of dissolved solids and had a mean dissolved-solids concentration of 7,900 milligrams per liter. This amount represents about 51 percent of the dissolved-solids load to E.V. Spence Reservoir during 1986-88. The concentration of dissolved solids in streamflow in the upper Colorado River, however, generally decreased in the downstream direction as flows increased in all reaches of the river and its tributaries. Diversion of low flows at a site on the Colorado River upstream from the E.V. Spence and O.H. Ivie Reservoirs decreased the dissolved-solids concentrations of inflow to the reservoirs by about 7 percent while removing only about 3 percent of the total flow. The estimated dissolved-solids concentration exceeded 1,000 milligrams per liter for water from about 233 of 386 wells and springs for which specific conductance was measured in 1986. The mean value of the estimated dissolved-solids concentration for water from the 386 wells and springs was about 1,750 milligrams per liter. Some of the dissolved-solids content of streamflow and shallow-aquifer water was attributed to evapotranspiration in areas where water was close to land surface, in irrigated areas, and along streams. The evapotranspiration was largely from phreatophytes and was comparable to the mean streamflow from the study area during 1969- 86. However, evapotranspiration was not considered to have an effect on the salinity of water in shallow aquifers on a regional scale. Dissolution of sulfur-bearing minerals such as gypsum and pyrite in shallow aquifers contributed to salinity because of their presence in soil and shallowaquifer formations. Mixing with brine associated with oil and gas production is a major process affecting the salinity of streamflow and shallow-aquifer water. Brines can move upward through the more than 20,000 abandoned oil- and gas-related boreholes, most of which were abandoned prior to current requirements for casing, cementing, and plugging. Leakage from pits, disposal wells, and secondary-recovery wells, which have been used to dispose of brine, a by-product of oil and gas production, also contributed to dissolved solids in streamflow and shallow-aquifer water. The ratio of brine production to oil production in the seven major oil-producing counties increased from 0.60 to 6.5 between 1957 and 1983. About 359 million barrels of brine were injected into oil-producing formations through secondary-recovery wells in 1983, compared to 11 million barrels through disposal wells. The chemical characteristics of the saline water in streams and shallow aquifers in the study area were compared to characteristics of water that would result from the probable processes affecting the salinity of water, such as evapotranspiration, mineral dissolution, and mixing of water from streams and shallow-aquifer water with brines from deep aquifers. Dissolution of halite or mixing with deep-aquifer water was the most common cause of increased salinity in 48.0 percent of 77 water samples from shallow aquifers, as classified using salt-norm analysis; the second most common cause was the weathering and dissolution of sulfur-bearing minerals. Mixing with water from soil-mineral dissolution was classified as the principal source of chloride in 28.4 percent of 67 water samples from shallow aquifers with nitrate determinations. Trace-species/chloride ratios indicated that mixing with water from deep aquifers in rocks of the Pennsylvanian System was the principal source of chloride in 24.4 percent of 45 shallow-aquifer samples lacking nitrate determinations.

Texas↗

USGS1994

Hydrogeology and selected water-quality aspects of the Hueco Bolson Aquifer at the Hueco Bolson Recharge Project area, El Paso, Texas

Samples of ground water and tertiary-treated water were evaluated to determine the distribution of injected water and trihalomethane compounds in the Hueco bolson aquifer near El Paso, Texas. Chloride and nitrate concentrations and oxygen-18/oxygen-16 (δ 18 O) values were used with end-member mixing analysis to estimate the fractional contributions of injected water, irrigation-affected water, saline ground water, and freshwater to ground-water chemistry. Several laterally continuous sand and gravel layers are the principal water-yielding lithologies in the aquifer. The potentiometric surface sloped toward the south and southwest during January 1990. Average linear ground-water velocities were as large as 1.4 feet per day near the zone of largest hydraulic conductivity and were substantially smaller farther south and east. Ground-water samples from as far as 2,900 feet from an injection well contained injectedwater tracers and trihalomethane compounds. Ground-water samples with injected-water tracers and no trihalomethane compounds may indicate infiltration from septic systems or oxidation ponds. Apparent breakthrough velocities of injected water in the aquifer ranged from 0.13 to 1.3 feet per day. Irrigation-affected water and saline water also were identified in water from several wells. Ground-water transport of bromoform and dibromochloromethane is attenuated relative to injected water, chloroform, and dichlorobromomethane. Microbial transformation of bromoform and dibromochloromethane probably was responsible for their disappearance from ground water. Chloroform and dichlorobromomethane concentrations were affected principally by advective and dispersive transport of injected water.

Texas↗

USGS1993

Hydrogeology, geochemistry, and quality of water of The Basin and Oak Spring areas of the Chisos Mountains, Big Bend National Park, Texas

Test drilling near two sewage lagoons in The Basin area of the Chisos Mountains, Big Bend National Park, Texas, has shown that the alluvium and colluvium on which the lagoons are located is not saturated in the immediate vicinity of the lagoons. A shallow aquifer, therefore, does not exist in this critical area at and near the lagoons. Should seepage outflow from the lagoons occur, the effluent from the lagoons might eventually be incorporated into shallow ground water moving westward in the direction of Oak Spring. Under these conditions such water could reach the spring. Test borings that bottomed in bedrock below the alluvial and colluvial fill material are dry, indicating that no substantial leakage from the lagoons was detected. Therefore, no contaminant plume was identified. Fill material in The Basin does not contain water everywhere in its extensive outcropping area and supplies only a small quantity of ground water to Window Pouroff, which is the only natural surface outlet of The Basin. Oak Spring, which is almost 2 miles downgradient from the lagoons, is the sole source of water for The Basin the principal tourist area in Big Bend National Park. Test drilling in the Oak Spring area revealed that the aquifer in the immediate vicinity of Oak Spring is a 5-foot thick sand bed hydraulically confined above and below by relatively thick, compact clay. The sand bed might be bounded locally by faults to the east and west of the spring. The test drilling and seismic surveys in the area also established the existence of a thick, extensive, surficial layer of colluvium consisting of large rhyolite boulders. The colluvial layer, which overlies sedimentary bedrock containing the Oak Spring aquifer, was unsaturated at the borehole sites. Information from drilling and from hydrogeologic observation indicates that the water from Oak Spring originates as precipitation in the Oak Spring area west of The Basin, with possibly a contribution originating as discharge from The Basin. The rhyolite boulder field in the Oak Spring area, which includes talus from Vernon Bailey Peak, is an effective receptacle for rapid recharge of precipitation. This water could then be efficiently routed into the Oak Spring aquifer in places to the east of Oak Spring where any shallow ground water in the boulder field might enter the subcropping truncated aquifer. Water-chemistry data, hydrochemical facies, and isotopic data also indicate that water from Oak Spring originates principally from precipitation onto the land surface of the Oak Spring area. Tritium data indicate that Oak Spring water is "modern," with an average age of recharge less than 14 years. The flow rates recorded almost continuously at Oak Spring beginning in December 1986 show a close relation between precipitation and discharge. The highest recorded spring flow of 167 gallons per minute in December 1986 is attributed to record high precipitation in the area during 1986. The lowest recorded flow of 22.4 gallons per minute, in December 1989, followed a period of 20 out of 26 months of below-normal precipitation. Flow at Oak Spring typically lags behind precipitation by about 1 month. This fairly rapid response indicates the spring is fed by a shallow aquifer having good permeability and effective recharge areas with the ability to absorb precipitation rapidly.

Texas↗