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Geology topics

P. L. Hageman

Publications and source records attributed to P. L. Hageman.

At least 19 recordsLinked to original sources
USGS2011

Simultaneous speciation of arsenic, selenium, and chromium: species, stability, sample preservation, and analysis of ash and soil leachates

An analytical method using high-performance liquid chromatography separation with inductively coupled plasma mass spectrometry (ICP-MS) detection previously developed for the determination of Cr(III) and Cr(VI) has been adapted to allow the determination of As(III), As(V), Se(IV), Se(VI), Cr(III), and Cr(VI) under the same chromatographic conditions. Using this method, all six inorganic species can be determined in less than 3 min. A dynamic reaction cell (DRC)-ICP-MS system was used to detect the species eluted from the chromatographic column in order to reduce interferences. A variety of reaction cell gases and conditions may be utilized with the DRC-ICP-MS, and final selection of conditions is determined by data quality objectives. Results indicated all starting standards, reagents, and sample vials should be thoroughly tested for contamination. Tests on species stability indicated that refrigeration at 10° C was preferential to freezing for most species, particularly when all species were present, and that sample solutions and extracts should be analyzed as soon as possible to eliminate species instability and interconversion effects. A variety of environmental and geological samples, including waters and deionized water [leachates] and simulated biological leachates from soils and wildfire ashes have been analyzed using this method. Analytical spikes performed on each sample were used to evaluate data quality. Speciation analyses were conducted on deionized water leachates and simulated lung fluid leachates of ash and soils impacted by wildfires. These results show that, for leachates containing high levels of total Cr, the majority of the chromium was present in the hexavalent Cr(VI) form. In general, total and hexavalent chromium levels for samples taken from burned residential areas were higher than those obtained from non-residential forested areas. Arsenic, when found, was generally in the more oxidized As(V) form. Selenium (IV) and (VI) were present, but typically at low levels.

Analytical and Bioanalytical Chemistry↗
USGS2011

Mineralogic sources of metals in leachates from the weathering of sedex, massive sulfide, and vein deposit mining wastes

Weathered mine waste consists of oxidized primary minerals and chemically unstable secondary phases that can be sources of readily soluble metals and acid rock drainage. Elevated concentrations of metals such as Cd, Cu, Fe, Mn, Ni, Pb, and Zn are observed in deionized water-based leachate solutions derived from complex sedex and Cu-Pb-Zn mine wastes. Leachate (USGS FLT) from the Elizabeth mine, a massive sulfide deposit, has a pH of 3.4 and high concentrations of Al (16700 ug/L), Cu (440 ug/L), and Zn (8620 ug/L). Leachate from the sedex Faro mine has a pH of 3.5 and high concentrations of Al (2040 ug/L), Cu (1930 ug/L), Pb (2080 ug/L), and Zn (52900 ug/L). In contrast, higher-pH leachates produced from tailings of polymetallic vein deposits have order of magnitude lower metal concentrations. These data indicate that highly soluble secondary mineral phases exist at the surface of waste material where the samples were collected. Sulfide minerals from all sites exhibit differential degrees of weathering, from dissolution etched grain rims, to rinds of secondary minerals, to skeletal remnants. These microscale mineral-dissolution textures enhance weathering and metal teachability of waste material. Besides the formation of secondary minerals, sulfide grains from dried tailings samples may be coated by amorphous Fe-Al-Si minerals that also adsorb metals such as Cu, Ni, and Zn.

Conference Paper↗
USGS2006

Comparative evaluation of short-term leach tests for heavy metal release from mineral processing waste

Evaluation of metal leaching using a single leach test such as the Toxicity Characteristic Leaching Procedure (TCLP) is often questionable. The pH, redox potential (Eh), particle size and contact time are critical variables in controlling metal stability, not accounted for in the TCLP. This paper compares the leaching behavior of metals in mineral processing waste via short-term extraction tests such as TCLP, Field Leach Test (FLT) used by USGS and deionized water extraction tests. Variation in the extracted amounts was attributed to the use of different particle sizes, extraction fluid and contact time. In the controlled pH experiments, maximum metal extraction was obtained at acidic pH for cationic heavy metals such as Cu, Pb and Zn, while desorption of Se from the waste resulted in high extract concentrations in the alkaline region. Precipitation of iron, caused by a pH increase, probably resulted in co-precipitation and immobilization of Cu, Pb and Zn in the alkaline pH region. A sequential extraction procedure was performed on the original waste and the solid residue from the Eh-pH experiments to determine the chemical speciation and distribution of the heavy metals. In the as-received waste, Cu existed predominantly in water soluble or sulfidic phases, with no binding to carbonates or iron oxides. Similar characteristics were observed for Pb and Zn, while Se existed mostly associated with iron oxides or sulfides. Adsorption/co-precipitation of Cu, Se and Pb on precipitated iron hydroxides was observed in the experimental solid residues, resulting in metal immobilization above pH 7.

Science of the Total Environment↗
USGS1999

Using imaging spectroscopy to map acidic mine waste

The process of pyrite oxidation at the surface of mine waste may produce acidic water that is gradually neutralized as it drains away from the waste, depositing different Fe-bearing secondary minerals in roughly concentric zones that emanate from mine-waste piles. These Fe-bearing minerals are indicators of the geochemical conditions under which they form. Airborne and orbital imaging spectrometers can be used to map these mineral zones because each of these Fe-bearing secondary minerals is spectrally unique. In this way, imaging spectroscopy can be used to rapidly screen entire mining districts for potential sources of surface acid drainage and to detect acid producing minerals in mine waste or unmined rock outcrops. Spectral data from the AVIRIS instrument were used to evaluate mine waste at the California Gulch Superfund Site near Leadville, CO. Laboratory leach tests of surface samples show that leachate pH is most acidic and metals most mobile in samples from the inner jarosite zone and that leachate pH is near-neutral and metals least mobile in samples from the outer goethite zone.

Environmental Science & Technology↗
USGS1998

EPA method 1312 (synthetic precipitation leaching procedure); leachate chemistry data for solid mine waste composite samples from Silverton and Leadville, Colorado

The EPA Method 1312 Synthetic Precipitation Leaching Procedure (SPLP) leachate chemistry data for mine waste samples is presented. Four mine waste composite samples were collected from Silverton (YUK and MAY) and Leadville (SUN and VEN), Colorado and were extracted following the EPA Method 1312 procedure. Leachate pH values ranged from 2.68 to 3.37 and the samples were ranked by increasing pH: VEN < SUN < YUK < MAY. Specific conductivity values ranged from 203 µS to 1080 µS and the samples were ranked by increasing specific conductivity: MAY < YUK < SUN < VEN. For selected metal concentrations, no consistent pattern presented itself. MAY is the sample that typically has the lowest metal concentrations with the exception of nickel, zinc, and lead. The samples had SPLP leachate concentrations below the EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) regulatory levels.

Colorado↗
USGS1995

The effect of acidic, metal-enriched drainage from the Wightman Fork and Alamosa River on the composition of selected wetlands in San Luis Valley, Colorado

The biogeochemistry of selected wetlands in the San Luis Valley, Colorado, was examined to assess the effect of acidic, metal-enriched water draining mineralized areas near and around the Summitville Mine. The sampling protocols, analytical methods, and chemical composition of water and stream bed sediment from the Wightman Fork and Alamosa River as well as water, surface sediment or cores, and rooted aquatic vegetation from wetland sites within and west of the Alamosa National Wildlife Refuge are presented. The data indicate that As, Co, Cr, Cu, Ni, and Zn are tracers of drainage from mineralized areas around the Summitville Mine. Sediments and aquatic plants in wetlands in the San Luis Valley that receive surface water from the Alamosa River tend to have larger concentrations of certain tracer elements (e.g., Co and Cu) than wetlands that receive water from other sources. Larger concentrations of Cu, Ni, and Zn in the sediments of wetlands receiving Alamosa River water appear to be related to the presence of larger amounts of Fe oxyhydroxides. However, there is little to no variation in the concentrations of tracer elements with depth in wetlands that receive Alamosa River water. This observation suggests that the geochemistry of these wetlands has not been significantly affected by recent mining activities at the Summitville Mine.

Colorado↗