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Geology topics

Nadia Carmosini

Publications and source records attributed to Nadia Carmosini.

2 recordsLinked to original sources

Field performance evaluation of a bayluscide 20-percent suspension concentrate formulation

Petromyzon marinus (sea lamprey) is a parasitic, invasive fish of the Laurentian Great Lakes. Since the late 1950s, the Great Lakes Fishery Commission has implemented an integrated Sea Lamprey Control Program (SLCP) that relies on two lampricidal chemicals: 3-(trifluoromethyl)-4-nitrophenol (TFM) and niclosamide. Niclosamide is applied using a bayluscide 20-percent emulsifiable concentrate; however, a solvent in this formulation, N -methyl-2-pyrrolidone, has been linked with worker safety concerns and has contributed to equipment degradation and clogging. To address these limitations, the U.S. Geological Survey, in collaboration with Battelle UK, developed a bayluscide 20-percent suspension concentrate (SC) as a potential alternative formulation. In this study, we evaluated the field performance of SC on the Indian River in Schoolcraft County, Michigan. The objective was to assess the formulation’s compatibility with SLCP application procedures and equipment, and to determine its ability to deliver precise lampricide concentrations in a timely manner. SC was found to dilute easily with stream water and readily combined with TFM. As a result, target lampricide concentrations in the stream were achieved within 1 hour of initiating delivery. Moreover, concentrations remained within 9 percent of target values, with less than 2 percent variation across the width of the stream, demonstrating consistent and uniform distribution. These findings indicate that SC can support accurate and timely lampricide applications. When considered alongside previous research highlighting its favorable selectivity for sea lamprey and improved environmental safety, the results support the pursuit of registration and adoption of SC as a new tool for controlling invasive sea lamprey.

Michigan

Determination of antimycin–a in a liquid formulation by high performance liquid chromatography–mass spectrometry

Pesticide formulations containing the active ingredient antimycin–a (ANT–A) have been used by fisheries and aquaculture managers for several decades to remove nuisance fish species. Analytical methods for measuring ANT–A during pesticide treatments have been done using high performance liquid chromatography (HPLC) paired with multiple detection methods (for example, electrochemical, ultraviolet, fluorescence, mass spectrometry). However, instruments and analytical chemistry methods can advance over time because of the need to develop timely, reliable, cost effective, and reproducible methods. Subsequently, ANT–A analytical chemistry methods and sample processing techniques also have improved over the past several decades. In the present study, we describe a liquid chromatography–mass spectrometry method and its verification across three analysts. Each analyst group created a single calibration curve and verified ANT–A in a liquid formulation using the averaged total response of all major ANT–A homologs (A1, A3, A3, A4). The advantage of this technique is that it creates a more resilient ANT–A quantification method amendable to batch-batch differences in major homologs. The method demonstrated how ANT–A can be effectively measured with high accuracy (98–99 percent), precision (2.7–16.2 percent), and specificity within a pesticide liquid formulation using a method applicable for Federal registration requirements.

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