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N. Williams

Publications and source records attributed to N. Williams.

2 recordsLinked to original sources

An examination of soil crusts on the floor of Jezero crater, Mars

Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser-induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine-grained soils also show a visible/near infrared (VISIR) 1.9 µm H 2 O absorption feature. The Planetary Instrument for X-ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg-sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg-sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.

Journal of Geophysical Research: Planets

Ocean acidification in the Gulf of Mexico: Drivers, impacts, and unknowns

Ocean acidification (OA) has resulted in global-scale changes in ocean chemistry, which can disturb marine organisms and ecosystems. Despite its extensively populated coastline, many marine-dependent communities, and valuable economies, the Gulf of Mexico (GOM) remains a relatively understudied region with respect to acidification. In general, the warm waters of the GOM are better buffered from acidification compared to higher latitude seas, yet long-term acidification has been documented in several GOM regions. OA within the GOM is recognized as spatially variable, particularly within the coastal zone where numerous physical and biogeochemical processes contribute to carbonate chemistry dynamics. The historical progression of OA within the entire GOM is difficult to assess because only a few dedicated long-term monitoring sites have recently been established, and full-water column observations are limited. However, environmental drivers on smaller scales that affect GOM acidification were found to include freshwater, nutrient, and carbonate discharge from large rivers; ocean warming, circulation and residence times; and episodic extreme weather events. GOM marine ecosystems provide essential services, including coastline protection and carbon dioxide removal, and habitats for many marine species that are economically and ecologically important. However, organismal and ecosystem responses to OA are not well constrained for the GOM due to a lack of studies examining the specific effects of OA on regionally relevant species under contemporary and projected conditions. Tackling the vast number of remaining scientific unknowns in this region can be best coordinated through regional capacity networks, such as the Gulf of Mexico Coastal Acidification Network (GCAN), working to achieve a system-wide understanding of Gulf OA and its impacts. Here we synthesize the current peer-reviewed literature on GOM acidification across the ocean-estuarine continuum and identify critical knowledge, research, and monitoring gaps that require future attention.

Progress in Oceanography