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Mortimer H. Staatz

Publications and source records attributed to Mortimer H. Staatz.

8 recordsLinked to original sources

Rare earths, thorium, and other minor elements in sphene from some plutonic rocks in west-central Alaska

Sphene is an abundant accessory mineral in some abnormally radioactive plutonic rocks in west-central Alaska. Seven samples of sphene from four different areas in west-central Alaska contained from 20350 to 39180 parts per million total rare earths and 390 to 2000 ppm thorium. The lanthanide content in six of the seven sphenes is chiefly the light rare earths and is similar to that of crustal abundance; a seventh sphene from the Darby Mountains, however, contains above average amounts of the heavy rare earths. A comparison of the lanthanide distribution in sphene from several areas indicates that the structure of sphene will accommodate whatever lanthanides are available when the mineral crystallizes. The amount of thorium and rare earths in sphene is also affected by the presence of other accessory minerals. Sphene in rocks containing either allanite or zircon has a lower thorium content than in rocks that do not contain allanite or zircon. Sphene, because of its abundance, may contain the greater part of the rare earths and thorium in some of the plutonic rocks of west-central Alaska.

Alaska

Brown, yellow, orange, and greenish-black thorites from the Seerie pegmatite, Colorado

Four types of thorite - brown, yellow, orange, and greenish-black - occur together in narrow fracture fillings rich in brown fluorite near the outer edge of the Seerie pegmatite. The brown thorite is by far the most abundant. The thorites are remarkably similar in composition except for their Fe 2 O 3 and UO 2 contents. The common brown thorite contains about 5 percent Fe 2 O 3 , but the other types have only about 0.3 percent. The greenish-black thorite contains about 15 percent UO 2 ; the yellow and orange, about 7 percent; and the brown, about 3 percent. All four thorites have high total rare-earth oxide contents, which vary from 17.3 to 20 percent. The rare-earth assemblage is unusual in that the heavy rare earths predominate, ytterbium being the most abundant lanthanide. Unheated brown and yellow thorites gave thorite X-ray patterns, but the orange and greenish-black types are metamict. All the thorites gave a ThO 2 -UO 2 X-ray pattern as well as a thorite pattern after heating in air for 1- and 2-hour periods at 1,000°C. In addition, the pattern of the greenish-black thorite contained peaks which we ascribe to a second UO 2 compound. Minute black inclusions present in the greenish-black thorite were identified as uraninite by microprobe analysis.

Colorado

Distribution and occurrence of rare earths in the thorium veins on Hall Mountain, Idaho

Rare earths, although equal to or more abundant than thorium in many thorium veins, are much less abundant than thorium in the veins on Hall Mountain, Idaho. Total rare-earth content of these veins ranges from 0.00111 to 0.197 percent in 12 samples from 10 veins; the thoria (ThO 2 ) content, from 0.011 to 5.84 percent. The rare-earth oxide to thoria ratios range from 0.0019 to 3.22. Only two samples contained more rare earths than thorium, and these two samples came from veins related to a fault near the base of a thick sill; the others came from veins near the top of the same sill. The relative amounts of the individual lanthanides are remarkably similar in the Hall Mountain veins, although cerium, gadolinium, or dysprosium are the most abundant in different samples. These veins differ in lanthanide distribution both from the Earth's crust and from the thorium veins of the Lemhi Pass district, Idaho and Montana, in that they contain chiefly yttrium-group rare earths. Most of the rare earths occur in thorite, whose atomic structure will accommodate wide-ranging proportions of the rare earths. Cenosite, one of the few minerals with a high content of the yttrium group of rare earths, was found in one vein.

Idaho

Geology and beryl deposits of the Peerless pegmatite, Pennington County, South Dakota

The Peerless pegmatite, half a mile south of Keystone, Pennington County, S. Dak., has been a large source of scrap mica and beryl. Feldspar, amblygonite, tantalite-columbite, and cassiterite also have been recovered. The pegmatite is intrusive into Precambrian quartz-mica schist. Much of the schist contains staurolite and chlorite. Staurolite has been partly altered to mica, quartz, and chlorite, especially near pegmatite contacts. The pegmatite is generally discordant with the schist, but in many places secondary schistosity has been developed parallel to the contact. Tourmaline and muscovite, presumably introduced by pegmatitic solutions, are characteristic of the wall rock near discordant contacts. At the surface the pegmatite is tadpole-shaped and is 580 feet long and 360 feet wide. In cross-section the pegmatite has an anticlinal form that suggests control of the intrusion by fractures bearing N. 30°W. and dipping 45°NE. and SW. Dike-like apophyses extending from the main pegmatite have various attitudes. The Peerless pegmatite is a complex pegmatite consisting of seven zones, two replacement units, and two types of fracture-fillings. These are: Zone 1, quartz-muscovite-plagioclase pegmatite (border zone); Zone 2, albite-quartz-muscovite pegmatite (wall zone); Zone 3, cleavelandite-quartz-muscovite pegmatite (first intermediate zone); Zone 4, perthite-cleavelandite-quartz pegmatite (second intermediate zone); Zone 5, clevelandite-quartz pegmatite (third intermediate zone); Zones 6a and b, quartz-microcline pegmatite and quartz pegmatite (fourth intermediate zone); Zone 7, lithia mica-cleavelandite pegmatite (core); lithia mica-cleavelandite-quartz replacement unit; muscovite-cleavelandite replacement unit; quartz fracture-fillings; and tourmaline-quartz fracture-fillings. Zones 1 and 2 consist of alternating layers of different texture and mineralogy that are parallel to the contact. The layers contain differing proportions of quartz, plagioclase, muscovite, perthite, and accessory minerals. Sugary albite-quartz aggregates are important constituents of some layers. Layers of similar composition may occur two, three, or perhaps more times. The overall mineralogic composition of Zones 1 and 2 is similar to the composition of wall zones in many other Black Hills pegmatite, Zones 3 to 7 are in the normal sequence of zones in Black Hills pegmatites. The structural, textural, and mineralogic data confirm previously published evidence from other Black Hills pegmatites that indicates crystallization of a magma-like fluid from the wall inward. Repetition of layers in Zones 1 and 2 indicates changes in composition of the fluid at the crystallizing face. These changes may have been caused by addition of new material from below, by loss of material to the wall rocks, or by failure of convection to maintain equilibrium throughout the fluid in the pegmatite chamber. Zone 3 to 7 are in the normal sequence of zoned pegmatites that indicates crystallization from a restricted or nearly closed system. The lithia mica-cleavelandite replacement unit, which extends outward from the core, shows that in, the very late stages of crystallization a pneumatolytic or hydrothermal fluid escaped outward and replaced previously crystallized pegmatite. Accessory minerals of the pegmatite include tourmaline, beryl, apatite, amblygonite (variety, montebrasite), lithia mica, cassiterite, tantalite-columbite, garnet, spodumene, svanbergite, loellingite (?), vivianite (?), triploidite (?), dahllite, and vari-colored phosphate minerals of the lithiophilitetriphylite group and their alteration products. The chemical composition of the pegmatite has been determined by estimating the mineral, constitution of the various units and by calculating the tonnage of these units by use of successive geologic sections. The principal constituents are: SiO 2 (77.0 percent), Al 2 O 3 (13.7 percent), Na 2 O (5.0 percent), and K 2 O (1.7 percent). Chemical composition has also been determined for four subdivisions of the pegmatite: (A) Zones 1 and 2, (B) Zones 3 and 4, (C) Zone 5, and (D) Zones 6 and 7 and the replacement units. The content of Si0 2 increases and the content of Al 2 O 3 decreases from the outer pan of the pegmatite inward. Na 2 O forms only 0.4 percent of the inner subdivision (D), but 4 .7 to 6.5 percent of the other subdivisions. K 2 O forms 4.0 percent of subdivision (B), but only 0.7 to 1.3 percent of the other subdivisions. Zone 3, the principal minable unit, contains 1. 7 percent beryl and 28 percent scrap mica. Beryl also constitutes more than 1 percent of parts of the wall zone, especially albite-rich layers of the inner part of the unit in the upper part of the pegmatite. Beryl is a less important constituent of other units of the pegmatite. Potash feldspar is mined chiefly from Zone 4. Clevelandite that can be hand-cobbed and sold as soda-feldspar occurs in Zones 3, 4, and 5. Amblygomlte forms between 0.5 and 1.0 percent of Zone 5. Reserves of beryl, scrap mica, potash feldspar, and amblygonite are one to six times past production.

South Dakota

Geology of the Quartz Creek Pegmatite District, Gunnison County Colorado

The Quartz Creek pegmatite district includes an area about 29 square miles in the vicinity of Quartz Creek in Gunnison County,. Colo. This area contains 1,803 pegmatites that are intruded into pre-Cambrian rocks. The rocks exposed in the district range in age from pre-Cambrian to Recent. The oldest pre-Cambrian rocks are chiefly quartzites interbedded with a few arkoses and conglomerates. These rocks are surrounded by more abundant hornblende gneiss and tonalite. A small body of biotite tonalite was intruded and two thin layers of dacitic pillow lava were extruded into this series. The hornblende gneiss and tonalite have the same composition and differ only in texture. The older material (hornblende gneiss) has a well-marked lineation, whereas the younger (tonalite) is equigranular. Subsequently, a large body of quartz monzonite was intruded along the northern boundary of the mapped area. Later, coarse-grained granite was intruded into the southern part of the area. Dikes of fine-grained granite cut the coarse-grained variety. The last period of intrusive activity in pre-Cambrian time is marked by a large number of pegmatites. The pre-Cambrian rocks were tilted and eroded, and the flatlying Jurassic Morrison formation was deposited on the irregular surface. This formation is conformably overlain by the Cretaceous Dakota sandstone. Faulting produced a vertical offset of 410 feet in the Mesozoic sediments along the only large fault in the area. At the end of Mesozoic time there was another period of erosion. Tertiary (?) tuff is exposed in small, scattered areas in the southern part of the district. It overlies both the Dakota sandstone and pre-Cambrian formations. Glacial till occurs along the edges of Quartz Creek and Wood Gulch. Quaternary alluvium fills the valley bottoms. Although the composition of the country rock has little effect on the shape of the pegmatites, the foliation imposed on this rock has a localizing effect and in part controls the ultimate shape of pegmatites. Zoned and related internal structures are not well developed in the pegmatites of this region. Many of the pegmatites are homogeneous and those that are zoned usually contain a large wall zone and small discontinuous cores. In addition to the more common homogeneous and zoned pegmatites, 7 percent of the pegmatites show a layered structure of textural and mineralogical units not repeated on the opposite side of the pegmatite. Other internal structural units include pegmatites which vary in composition along strike, multiple or “line-rock pegmatites” and fracture fillings. The mineralogy of the pegmatites is described in detail. Specific attention was given to most of the 27 observed minerals. A study of the index of refraction of 439 specimens of plagioclase showed that the variation from zone to zone and layer to layer is minor and that there is no systematic variation in respect to the entire district. No correlation could be found between the refractive index of plagioclase in the pegmatites and the type country rock, or the presence of various accessory minerals. Index of refraction determinations on 95 specimens of muscovite showed no constant variation from wall zone to core or from layer to layer. Curved muscovite has identical optical properties with the flat variety. The index of refraction was determined for 189 beryl specimens. The beryl in the pegmatites containing only a wall zone and a core showed no difference between zones, but in pegmatites that have intermediate zones, the indices of refraction of the beryl showed an inward increase in the alkali content from the contact. Beryl occurs with almost all of the pegmatite minerals and is not restricted in its mineral associations. Tourmaline, except the black variety, is associated with lepidolite. Dark green and blue tourmaline is found in the outer zones of pegmatites containing lepidolite, and the pink and light green varieties are found in direct contact with lepidolite. Lepidolite occurs in aggregates of fine grains, in flat plates, and in curved plates; the three varieties are optically identical. The lighter-colored varieties have higher indices of refraction and contain less lithia than the darker varieties. In addition, the occurrence of the following minerals is described in detail: perthite, quartz, martite, biotite, garnet, columbite-tantalite, monazite, microlite, topaz, gahnite, allanite, and an unidentified mineral. The lack of alteration in the wall rocks adjacent to the pegmatites is interpreted as indicating that the original pegmatite magma did not have an excess of materials such as B, OH-, and P that are needed to form alteration minerals. Because of their low concentration, the above materials were available only in the pegmatitic magma during its crystallization. Pegmatites that contain the rare minerals such as beryl, tourmaline, curved muscovite, biotite, magnetite, monazite, columbite-tantalite, cleavelandite, topaz, lepidolite, and microlite show a grouping in clusters within the district. Beryl-bearing pegmatites occur most abundantly in hornblende gneiss and are only rarely found in either granite or quartz monzonite. The types of minerals that form in a pegmatite appear to be determined by the character of the material segregated from the original magma and the period in which it segregated. The elements escape at one period and may be from only-a specific pocket in the magma. These liquids tend to form groups of pegmatites in which the later bodies contain a high proportion of volatiles. Inferred reserves of the district are estimated for beryl, scrap mica, both hand-cobbing and milling feldspar, lepidolite, columbite-tantalite, topaz, monazite, and microlite. No sheet mica was found. Reserves are small and transportation costs are high so substantial production of low-priced feldspar and scrap mica will depend on the adoption of economica milling techniques for recovering the large quantities of feldspar available. Beryl is irregularly distributed and its recovery as a byproduct will depend on the establishment of a stable market for feldspar and scrap mica. Lepidolite reserves are small low grade.

Colorado