Geology topics

Molly S. Wood

Publications and source records attributed to Molly S. Wood.

26 records · Page 2Linked to original sources

USGS2013

Use of surrogate technologies to estimate suspended sediment in the Clearwater River, Idaho, and Snake River, Washington, 2008-10

Elevated levels of fluvial sediment can reduce the biological productivity of aquatic systems, impair freshwater quality, decrease reservoir storage capacity, and decrease the capacity of hydraulic structures. The need to measure fluvial sediment has led to the development of sediment surrogate technologies, particularly in locations where streamflow alone is not a good estimator of sediment load because of regulated flow, load hysteresis, episodic sediment sources, and non-equilibrium sediment transport. An effective surrogate technology is low maintenance and sturdy over a range of hydrologic conditions, and measured variables can be modeled to estimate suspended-sediment concentration (SSC), load, and duration of elevated levels on a real-time basis. Among the most promising techniques is the measurement of acoustic backscatter strength using acoustic Doppler velocity meters (ADVMs) deployed in rivers. The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, Walla Walla District, evaluated the use of acoustic backscatter, turbidity, laser diffraction, and streamflow as surrogates for estimating real-time SSC and loads in the Clearwater and Snake Rivers, which adjoin in Lewiston, Idaho, and flow into Lower Granite Reservoir. The study was conducted from May 2008 to September 2010 and is part of the U.S. Army Corps of Engineers Lower Snake River Programmatic Sediment Management Plan to identify and manage sediment sources in basins draining into lower Snake River reservoirs. Commercially available acoustic instruments have shown great promise in sediment surrogate studies because they require little maintenance and measure profiles of the surrogate parameter across a sampling volume rather than at a single point. The strength of acoustic backscatter theoretically increases as more particles are suspended in the water to reflect the acoustic pulse emitted by the ADVM. ADVMs of different frequencies (0.5, 1.5, and 3 Megahertz) were tested to target various sediment grain sizes. Laser diffraction and turbidity also were tested as surrogate technologies. Models between SSC and surrogate variables were developed using ordinary least-squares regression. Acoustic backscatter using the high frequency ADVM at each site was the best predictor of sediment, explaining 93 and 92 percent of the variability in SSC and matching sediment sample data within +8.6 and +10 percent, on average, at the Clearwater River and Snake River study sites, respectively. Additional surrogate models were developed to estimate sand and fines fractions of suspended sediment based on acoustic backscatter. Acoustic backscatter generally appears to be a better estimator of suspended sediment concentration and load over short (storm event and monthly) and long (annual) time scales than transport curves derived solely from the regression of conventional sediment measurements and streamflow. Changing grain sizes, the presence of organic matter, and aggregation of sediments in the river likely introduce some variability in the model between acoustic backscatter and SSC.

Idaho;Washington↗

USGS2013

Sediment transport in the lower Snake and Clearwater River Basins, Idaho and Washington, 2008–11

Sedimentation is an ongoing maintenance problem for reservoirs, limiting reservoir storage capacity and navigation. Because Lower Granite Reservoir in Washington is the most upstream of the four U.S. Army Corps of Engineers reservoirs on the lower Snake River, it receives and retains the largest amount of sediment. In 2008, in cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey began a study to quantify sediment transport to Lower Granite Reservoir. Samples of suspended sediment and bedload were collected from streamgaging stations on the Snake River near Anatone, Washington, and the Clearwater River at Spalding, Idaho. Both streamgages were equipped with an acoustic Doppler velocity meter to evaluate the efficacy of acoustic backscatter for estimating suspended-sediment concentrations and transport. In 2009, sediment sampling was extended to 10 additional locations in tributary watersheds to help identify the dominant source areas for sediment delivery to Lower Granite Reservoir. Suspended-sediment samples were collected 9–15 times per year at each location to encompass a range of streamflow conditions and to capture significant hydrologic events such as peak snowmelt runoff and rain-on-snow. Bedload samples were collected at a subset of stations where the stream conditions were conducive for sampling, and when streamflow was sufficiently high for bedload transport. At most sampling locations, the concentration of suspended sediment varied by 3–5 orders of magnitude with concentrations directly correlated to streamflow. The largest median concentrations of suspended sediment (100 and 94 mg/L) were in samples collected from stations on the Palouse River at Hooper, Washington, and the Salmon River at White Bird, Idaho, respectively. The smallest median concentrations were in samples collected from the Selway River near Lowell, Idaho (11 mg/L), the Lochsa River near Lowell, Idaho (11 mg/L), the Clearwater River at Orofino, Idaho (13 mg/L), and the Middle Fork Clearwater River at Kooskia, Idaho (15 mg/L). The largest measured concentrations of suspended sediment (3,300 and 1,400 mg/L) during a rain-on-snow event in January 2011 were from samples collected at the Potlatch River near Spalding, Idaho, and the Palouse River at Hooper, Washington, respectively. Generally, samples collected from agricultural watersheds had a high percentage of silt and clay-sized suspended sediment, whereas samples collected from forested watersheds had a high percentage of sand. During water years 2009–11, Lower Granite Reservoir received about 10 million tons of suspended sediment from the combined loads of the Snake and Clearwater Rivers. The Snake River accounted for about 2.97 million tons per year (about 89 percent) of the total suspended sediment, 1.48 million tons per year (about 90 percent) of the suspended sand, and about 1.52 million tons per year (87 percent) of the suspended silt and clay. Of the suspended sediment transported to Lower Granite Reservoir, the Salmon River accounted for about 51 percent of the total suspended sediment, about 56 percent of the suspended sand, and about 44 percent of the suspended silt and clay. About 6.2 million tons (62 percent) of the sediment contributed to Lower Granite Reservoir during 2009–11 entered during water year 2011, which was characterized by an above average winter snowpack and sustained spring runoff. A comparison of historical data collected from the Snake River near Anatone with data collected during this study indicates that concentrations of total suspended sediment and suspended sand in the Snake River were significantly smaller during water years 1972–79 than during 2008–11. Most of the increased sediment content in the Snake River is attributable to an increase of sand-size material. During 1972–79, sand accounted for an average of 28 percent of the suspended-sediment load; during 2008–11, sand accounted for an average of 48 percent. Historical data from the Clearwater River at Spalding indicates that the concentrations of total suspended sediment collected during 1972–79 were not significantly different from the concentrations measured during this study. However, the suspended-sand concentrations in the Clearwater River were significantly smaller during 1972–79 than during 2008–11. The increase in suspended-sand concentrations in the Snake and Clearwater Rivers are probably attributable to numerous severe forest fires that burned large areas of central Idaho from 1980–2010. Acoustic backscatter from an acoustic Doppler velocity meter proved to be an effective method of estimating suspended-sediment concentration and load for most streamflow conditions in the Snake and Clearwater Rivers. Models based on acoustic backscatter were able to simulate most of the variability in suspended-sediment concentrations in the Clearwater River at Spalding (coefficient of determination [R 2 ]=0.93) and the Snake River near Anatone (R 2 =0.92). Acoustic backscatter seems to be especially effective for estimating suspended-sediment concentration and load over short (monthly and single storm event) and long (annual) time scales when sediment load is highly variable. However, during high streamflow events acoustic surrogate tools may be unable to capture the contribution of suspended sand moving near the bottom of the water column and thus, underestimate the total load of suspended sediment. At the stations where bedload was collected, the particle-size distribution at low streamflows typically was unimodal with sand comprising the dominant particle size. At higher streamflows and during peak bedload discharge, the particle size typically was bimodal and was comprised primarily of sand and coarse gravel. About 55,000 tons of bedload was discharged from the Snake River to Lower Granite Reservoir during water years 2009–11, about 0.62 percent of the total sediment load delivered by the Snake River. About 9,500 tons of bedload was discharged from the Clearwater River to Lower Granite Reservoir during 2009–11, about 0.83 percent of the total sediment load discharged by the Clearwater River during 2009–11.

Idaho;Washington↗

USGS2013

Streamflow monitoring and statistics for development of water rights claims for Wild and Scenic Rivers, Owyhee Canyonlands Wilderness, Idaho, 2012

The U.S. Geological Survey, in cooperation with the Bureau of Land Management (BLM), collected streamflow data in 2012 and estimated streamflow statistics for stream segments designated "Wild," "Scenic," or "Recreational" under the National Wild and Scenic Rivers System in the Owyhee Canyonlands Wilderness in southwestern Idaho. The streamflow statistics were used by BLM to develop and file a draft, federal reserved water right claim in autumn 2012 to protect federally designated "outstanding remarkable values" in the stream segments. BLM determined that the daily mean streamflow equaled or exceeded 20 and 80 percent of the time during bimonthly periods (two periods per month) and the bankfull streamflow are important streamflow thresholds for maintaining outstanding remarkable values. Prior to this study, streamflow statistics estimated using available datasets and tools for the Owyhee Canyonlands Wilderness were inaccurate for use in the water rights claim. Streamflow measurements were made at varying intervals during February–September 2012 at 14 monitoring sites; 2 of the monitoring sites were equipped with telemetered streamgaging equipment. Synthetic streamflow records were created for 11 of the 14 monitoring sites using a partial‑record method or a drainage-area-ratio method. Streamflow records were obtained directly from an operating, long-term streamgage at one monitoring site, and from discontinued streamgages at two monitoring sites. For 10 sites analyzed using the partial-record method, discrete measurements were related to daily mean streamflow at a nearby, telemetered “index” streamgage. Resulting regression equations were used to estimate daily mean and annual peak streamflow at the monitoring sites during the full period of record for the index sites. A synthetic streamflow record for Sheep Creek was developed using a drainage-area-ratio method, because measured streamflows did not relate well to any index site to allow use of the partial-record method. The synthetic and actual daily mean streamflow records were used to estimate daily mean streamflow that was exceeded 80, 50, and 20 percent of the time (80-, 50-, and 20-percent exceedances) for bimonthly and annual periods. Bankfull streamflow statistics were calculated by fitting the synthetic and actual annual peak streamflow records to a log Pearson Type III distribution using Bulletin 17B guidelines in the U.S. Geological Survey PeakFQ program. The coefficients of determination (R 2 ) for the regressions between the monitoring and index sites ranged from 0.74 for Wickahoney Creek to 0.98 for the West Fork Bruneau River and Deep Creek. Confidence in computed streamflow statistics is highest among other sites for the East Fork Owyhee River and the West Fork Bruneau River on the basis of regression statistics, visual fit of the related data, and the range and number of streamflow measurements. Streamflow statistics for sites with the greatest uncertainty included Big Jacks, Little Jacks, Cottonwood, Wickahoney, and Sheep Creeks. The uncertainty in computed streamflow statistics was due to a number of factors which included the distance of index sites relative to monitoring sites, relatively low streamflow conditions that occurred during the study, and the limited number and range of streamflow measurements. However, the computed streamflow statistics are considered the best possible estimates given available datasets in the remote study area. Streamflow measurements over a wider range of hydrologic and climatic conditions would improve the relations between streamflow characteristics at monitoring and index sites. Additionally, field surveys are needed to verify if the streamflows selected for the water rights claims are sufficient for maintaining outstanding remarkable values in the Wild and Scenic rivers included in the study.

Idaho;Nevada;Oregon↗

USGS2012

Bathymetry and capacity of Blackfoot Reservoir, Caribou County, Idaho, 2011

The U.S. Geological Survey (USGS), in cooperation with the Shoshone-Bannock Tribes, surveyed the bathymetry and selected above-water sections of Blackfoot Reservoir, Caribou County, Idaho, in 2011. Reservoir operators manage releases from Government Dam on Blackfoot Reservoir based on a stage-capacity relation developed about the time of dam construction in the early 1900s. Reservoir operation directly affects the amount of water that is available for irrigation of agricultural land on the Fort Hall Indian Reservation and surrounding areas. The USGS surveyed the below-water sections of the reservoir using a multibeam echosounder and real-time kinematic global positioning system (RTK-GPS) equipment at full reservoir pool in June 2011, covering elevations from 6,090 to 6,119 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). The USGS used data from a light detection and ranging (LiDAR) survey performed in 2000 to map reservoir bathymetry from 6,116 to 6,124 ft NAVD 88, which were mostly in depths too shallow to measure with the multibeam echosounder, and most of the above-water section of the reservoir (above 6,124 ft NAVD 88). Selected points and bank erosional features were surveyed by the USGS using RTK-GPS and a total station at low reservoir pool in September 2011 to supplement and verify the LiDAR data. The stage-capacity relation was revised and presented in a tabular format. The datasets show a 2.0-percent decrease in capacity from the original survey, due to sedimentation or differences in accuracy between surveys. A 1.3-percent error also was detected in the previously used capacity table and measured water-level elevation because of questionable reference elevation at monitoring stations near Government Dam. Reservoir capacity in 2011 at design maximum pool of 6,124 ft above NAVD 88 was 333,500 acre-ft.

Idaho↗

USGS2011

Concentrations and loads of nutrients in the tributaries of the Lake Okeechobee watershed, south-central Florida, water years 2004-2008

Lake Okeechobee in south-central Florida is the second largest freshwater lake in the contiguous United States. Excessive phosphorus loading, harmful high and low water levels, and rapid expansion of non-native vegetation have threatened the health of the lake in recent decades. A study was conducted to monitor discharge and nutrient concentrations from selected tributaries into Lake Okeechobee and to evaluate nutrient loads. The data analysis was performed at 16 monitoring stations from December 2003 to September 2008. Annual and seasonal discharge measured at monitoring stations is affected by rainfall. Hurricanes affected three wet years (2004, 2005, and the latter part of 2008) and resulted in substantially greater discharge than the drought years of 2006, 2007, and the early part of 2008. Rainfall supplies about 50 percent of the water to Lake Okeechobee, discharge from the Kissimmee River supplies about 25 percent, and discharge from tributaries and groundwater seepage along the lake perimeter collectively provide the remaining 25 percent. Annually, tributary discharge from basins located on the west side of the Kissimmee River is about 5 to 6 times greater than that from basins located on the east side. For the purposes of this study, the basins on the east side of the Kissimmee River are called "priority basins" because of elevated phosphorus concentrations, while those on the west side are called "nonpriority" basins. Total annual discharge in the non-priority basins ranged from 245,000 acre-feet (acre-ft) in 2007 to 1,322,000 acre-ft in 2005, while annual discharge from the priority basins ranged from 41,000 acre-ft in 2007 to 219,000 acre-ft in 2005. Mean total phosphorus concentrations ranged from 0.10 to 0.54 milligrams per liter (mg/L) at the 16 tributaries during 2004–2008. Mean concentrations were significantly higher at priority basin sites than at non-priority basin sites, particularly at Arbuckle Creek and C 41A Canal. Concentrations of organic nitrogen plus ammonia ranged from 1.27 to 2.96 mg/L at the 16 tributaries during 2004–2008. Mean concentrations were highest at Fisheating Creek at Lake Placid (a non-priority site), and lowest at Wolff Creek, Taylor Creek near Grassy Island, and Otter Creek (three priority basin sites), and at Arbuckle Creek (a non-priority basin site). Mean concentrations of nitrite plus nitrate ranged from 0.01 to 0.55 mg/L at the 16 tributaries during 2004–2008. Mean concentrations measured in priority basins were significantly higher than those measured in non-priority basins. Nutrient concentrations were substantially lower in the non-priority basins; however, total loads were substantially higher due to discharge that was 5 to 6 times greater than from the priority basins. Total phosphorus, organic nitrogen plus ammonia, and nitrite plus nitrate loads from the non-priority basins were 1.5, 4.5, and 3.5 times greater, respectively, than were loads from the priority basins. In the non-priority basins, total phosphorus loads ranged from 35 metric tons (MT) in 2007 to 247 MT in 2005. In the priority basins, the loads ranged from 18 MT in 2007 to 136 MT in 2005. In the non-priority basins, organic nitrogen plus ammonia loads ranged from 337 MT in 2007 to 2,817 MT in 2005. In the priority basins, organic nitrogen plus ammonia loads ranged from 85 MT in 2007 to 503 MT in 2005. In the non-priority basins, nitrite plus nitrate loads ranged from 34 MT in 2007 to 143 MT in 2005. In the priority basins, nitrite plus nitrate loads ranged from 4 MT in 2007 to 27 MT in 2005.

Florida↗

USGS2011

Water-quality conditions near the confluence of the Snake and Boise Rivers, Canyon County, Idaho

Total Maximum Daily Loads (TMDLs) have been established under authority of the Federal Clean Water Act for the Snake River-Hells Canyon reach, on the border of Idaho and Oregon, to improve water quality and preserve beneficial uses such as public consumption, recreation, and aquatic habitat. The TMDL sets targets for seasonal average and annual maximum concentrations of chlorophyll- a at 14 and 30 micrograms per liter, respectively. To attain these conditions, the maximum total phosphorus concentration at the mouth of the Boise River in Idaho, a tributary to the Snake River, has been set at 0.07 milligrams per liter. However, interactions among chlorophyll- a , nutrients, and other key water-quality parameters that may affect beneficial uses in the Snake and Boise Rivers are unknown. In addition, contributions of nutrients and chlorophyll- a loads from the Boise River to the Snake River have not been fully characterized. To evaluate seasonal trends and relations among nutrients and other water-quality parameters in the Boise and Snake Rivers, a comprehensive monitoring program was conducted near their confluence in water years (WY) 2009 and 2010. The study also provided information on the relative contribution of nutrient and sediment loads from the Boise River to the Snake River, which has an effect on water-quality conditions in downstream reservoirs. State and site-specific water-quality standards, in addition to those that relate to the Snake River-Hells Canyon TMDL, have been established to protect beneficial uses in both rivers. Measured water-quality conditions in WY2009 and WY2010 exceeded these targets at one or more sites for the following constituents: water temperature, total phosphorus concentrations, total phosphorus loads, dissolved oxygen concentration, pH, and chlorophyll- a concentrations (WY2009 only). All measured total phosphorus concentrations in the Boise River near Parma exceeded the seasonal target of 0.07 milligram per liter. Data collected during the study show seasonal differences in all measured parameters. In particular, surprisingly high concentrations of chlorophyll- a were measured at all three main study sites in winter and early spring, likely due to changes in algal populations. Discharge conditions and dissolved orthophosphorus concentrations are key drivers for chlorophyll- a on a seasonal and annual basis on the Snake River. Discharge conditions and upstream periphyton growth are most likely the key drivers for chlorophyll- a in the Boise River. Phytoplankton growth is not limited or driven by nutrient availability in the Boise River. Lower discharges and minimal substrate disturbance in WY2010 in comparison with WY2009 may have caused prolonged and increased periphyton and macrophyte growth and a reduced amount of sloughed algae in suspension in the summer of WY2010. Chlorophyll- a measured in samples commonly is used as an indicator of sestonic algae biomass, but chlorophyll- a concentrations and fluorescence may not be the most appropriate surrogates for algae growth, eutrophication, and associated effects on beneficial uses. Assessment of the effects of algae growth on beneficial uses should evaluate not only sestonic algae, but also benthic algae and macrophytes. Alternatively, continuous monitoring of dissolved oxygen detects the influence of aquatic plant respiration for all types of algae and macrophytes and is likely a more direct measure of effects on beneficial uses such as aquatic habitat. Most measured water-quality parameters in the Snake River were statistically different upstream and downstream of the confluence with the Boise River. Higher concentrations and loads were measured at the downstream site (Snake River at Nyssa) than the upstream site (Snake River near Adrian) for total phosphorus, dissolved orthophosphorus, total nitrogen, dissolved nitrite and nitrate, suspended sediment, and turbidity. Higher dissolved oxygen concentrations and pH were measured at the upstream site (Snake River near Adrian) than the downstream site (Snake River at Nyssa). Contributions from the Boise River measured at Parma do not constitute all of the increase in nutrient and sediment loads in the Snake River between the upstream and downstream sites. Surrogate models were developed using a combination of continuously monitored variables to estimate concentrations of nutrients and suspended sediment when samples were not possible. The surrogate models explained from 66 to 95 percent of the variability in nutrient and suspended sediment concentrations, depending on the site and model. Although the surrogate models could not always represent event-based changes in modeled parameters, they generally were successful in representing seasonal and annual patterns. Over a longer period, the surrogate models could be a useful tool for measuring compliance with state and site-specific water-quality standards and TMDL targets, for representing daily and seasonal variability in constituents, and for assessing effects of phosphorus reduction measures within the watershed.

Idaho↗

USGS2009

Estimating Locations of Perennial Streams in Idaho Using a Generalized Least-Squares Regression Model of 7-Day, 2-Year Low Flows

Many State and Federal agencies use information regarding the locations of streams having intermittent or perennial flow when making management and regulatory decisions. For example, the application of some Idaho water quality standards depends on whether streams are intermittent. Idaho Administrative Code defines an intermittent stream as one having a 7-day, 2-year low flow (7Q2) less than 0.1 ft3/s. However, there is a general recognition that the cartographic representation of perennial/intermittent status of streams on U.S. Geological Survey (USGS) topographic maps is not as accurate or consistent as desirable from one map to another, which makes broad management and regulatory assessments difficult and inconsistent. To help resolve this problem, the USGS has developed a methodology for predicting the locations of perennial streams based on regional generalized least-squares (GLS) regression equations for Idaho streams for the 7Q2 low-flow statistic. Using these regression equations, the 7Q2 streamflow may be estimated for naturally flowing streams in most areas in Idaho. The use of these equations in conjunction with a geographic information system (GIS) technique known as weighted flow accumulation allows for an automated and continuous estimation of 7Q2 streamflow at all points along stream reaches. The USGS has developed a GIS-based map of the locations of streams in Idaho with perennial flow based on a 7Q2 of 0.1 ft3/s and a transition zone of plus or minus 1 standard error. Idaho State cooperators plan to use this information to make regulatory and water-quality management decisions. Originally, 7Q2 equations were developed for eight regions of similar hydrologic characteristics in the study area, using long-term data from 234 streamflow-gaging stations. Equations in five of the regions were revised based on spatial patterns observed in the initial perennial streams map and unrealistic behavior of the equations in extrapolation. The standard errors of prediction for the final equations ranged from a minimum of +75.0 to -42.9 percent in the central part of the study area to a maximum of +277 to -73.5 percent in the southern part of the study area. The equations are applicable only to unregulated, naturally-flowing streams and may produce unreliable results outside the range of explanatory variables used for equation development. Extrapolation outside the range of available data was necessary, however, to predict perennial flow initiation points and transition zones along stream reaches. The map of perennial streams was evaluated by comparing predicted stream classifications with four independent datasets, including field observations by other government agencies. Overall, 81 percent of the comparison data points agreed with the USGS perennial streams model. Regions with the highest number of disagreements had a high percentage of mountainous and forested area with potential mountain front recharge zones, and regions with the highest agreements had a high percentage of low gradient, low elevation area. As a whole, the USGS model predicted a higher number of perennial streams than predictions made with the independent datasets. Some disagreements were due to poor site location coordinates, timing of the comparison site visits during unusually wet or dry years, discrepancies in classification criteria, and variable ground water contributions to flow in some areas. The Idaho Department of Environmental Quality Beneficial Use Reconnaissance Program (BURP) dataset is considered the most representative dataset for comparison because it covered a range of climate conditions and the number of sites visited were consistent from year to year during the study period. Eighty-five percent of BURP comparison data points agreed with the USGS perennial streams model. Although site-specific flow data may be needed to correctly classify streams in some areas, this information rarely is available and is not always practical to o

Scientific Investigations Report↗

USGS2008

Coeur d'Alene Lake, Idaho: Insights gained From limnological studies of 1991-92 and 2004-06

More than 100 years of mining and processing of metal-rich ores in northern Idaho’s Coeur d’Alene River basin have resulted in widespread metal contamination of the basin’s soil, sediment, water, and biota, including Coeur d’Alene Lake. Previous studies reported that about 85 percent of the bottom of Coeur d’Alene Lake is substantially enriched in antimony, arsenic, cadmium, copper, lead, mercury, silver, and zinc. Nutrients in the lake also are a major concern because they can change the lake’s trophic status—or level of biological productivity—which could result in secondary releases of metals from contaminated lakebed sediments. This report presents insights into the limnological functioning of Coeur d’Alene Lake based on information gathered during two large-scale limnological studies conducted during calendar years 1991–92 and water years 2004–06. Both limnological studies reported that longitudinal gradients exist from north to south for decreasing water column transparency, loss of dissolved oxygen, and increasing total phosphorus concentrations. Gradients also exist for total lead, total zinc, and hypolimnetic dissolved oxygen concentrations, ranging from high concentrations in the central part of the lake to lower concentrations at the northern and southern ends of the lake. In the southern end of the lake, seasonal anoxia serves as a mechanism to release dissolved constituents such as phosphorus, nitrogen, iron, and manganese from lakebed sediments and from detrital material within the water column. Nonparametric statistical hypothesis tests at a significance level of α=0.05 were used to compare analyte concentrations among stations, between lake zones, and between study periods. The highest dissolved oxygen concentrations were measured in winter in association with minimum water temperatures, and the lowest concentrations were measured in the Coeur d’Alene Lake hypolimnion during late summer or autumn as prolonged thermal stratification restricted mixing of the oxygenated upper water column and the hypolimnion, where oxygen was consumed. Large differences in median concentrations of dissolved inorganic nitrogen were measured between the euphotic zone and hypolimnion in the deep areas of the lake. These differences in nitrogen concentrations were attributable to several limnological processes, including seasonal inflow plume routing, isolation from wind-driven circulation and associated hypolimnetic enrichment, phytoplanktonic assimilation during summer months, and benthic flux. Increased chlorophyll- a and total phosphorus concentrations were measured throughout the lake in the 2004–06 study compared with results from the 1991–92 study. No significant change in hypolimnetic dissolved inorganic nitrogen concentration throughout the lake was noted even though total nitrogen loads into the lake decreased between study periods. Total zinc and total lead decreased throughout the lake from the 1991-92 study to the 2004-06 study except in the southern part of the lake, where concentrations were typically low. Median detected nitrogen-to-phosphorus ratios decreased from the 1991–92 study to the 2004–06 study. Whereas the lake was clearly phosphorus-limited in 1991–92, in 2004–06 the lake may have been much closer to the boundary value of 7.2 that separates nitrogen from phosphorus limitation. However, due to changes in analytical reporting limits in the period between the two studies, the data are insufficiently certain to draw reliable conclusions with regard to limiting nutrients. For both studies, the trophic state of the lake was classified as oligotrophic (less productive) or mesotrophic (moderately productive), depending on the constituent used for classification. Internal circulation from wind-generated waves and changes in the lake’s thermocline are important processes for distribution of water-quality constituents throughout Coeur d’Alene Lake. Surficial distribution of trace metals throughout most of the lake, including bays, is relatively uniform. Even south of the Coeur d’Alene River mouth, lakebed sediments are contaminated with trace metals. Inflow plume routing of the two primary inflow sources, the Coeur d’Alene and St. Joe Rivers, also significantly affects the fate and transport of contaminants. Most riverine inflows appear to move through the lake as overflow during summer, interflow during spring and autumn, and underflow during winter. Benthic flux is another key transport process for contaminants in Coeur d’Alene Lake. The results of in situ benthic flux chamber experiments indicated movement of dissolved metals, nutrients, and dissolved organic carbon out of the lakebed sediments. However, the lake is an overall sink for these constituents when they are associated with particulate material.

Idaho↗