USGS Science⌕ Search

Geology topics

Michael McHale

Publications and source records attributed to Michael McHale.

13 recordsLinked to original sources
USGS2021

The Biscuit Brook and Neversink Reservoir Watersheds: Long-term investigations of stream chemistry, soil chemistry, and aquatic ecology in the Catskill Mountains, New York, USA, 1983 to 2020

This data note describes the Biscuit Brook and Neversink Reservoir watershed Long-Term Monitoring Data that includes: 1) stream discharge, (1983 – 2020 for Biscuit Brook and 1937 – 2020 for the Neversink Reservoir watershed), 2) stream water chemistry, 1983-2020, at 4 stations, 3) fish survey data from 16 locations in the watershed 1990-2019, 4) soil chemistry data from 2 headwater sub-watersheds, 1993-2012, and 5) periodic stream water chemistry sampling data from 364 locations throughout the watershed, 1983-2020. The Neversink Reservoir watershed in the Catskill Mountains of New York, USA drains an area of 172.5 km 2 . The watershed feeds one of 6 reservoirs in New York City's West of Hudson water supply, which accounts for about 90% of the city's water supply. Biscuit Brook is a 9.63 km 2 tributary sub-watershed within the Neversink Reservoir watershed.

New York↗
USGS2021

Have sustained acidic deposition decreases led to increased calcium availability in recovering watersheds of the Adirondack region of New York, USA?

Soil calcium depletion has been strongly linked to acidic deposition in eastern North America and recent studies have begun to document the recovery of soils in response to large decreases in acidic deposition. However, increased calcium availability has not yet been seen in the B horizon, where calcium depletion has been most acute, but mineral weathering is critically important for resupplying ecosystem calcium. This study provides new data in seven watersheds in the Adirondack region (New York, USA), where acidic deposition impacts on soils and surface waters have been substantial and recovery remains slow. Initial sampling in 1997–1998 and 2003–2004 was repeated in 2009–2010, 2014, 2016 and 2017. Exchangeable calcium concentrations increased by an average of 43% in the Oe horizon of three watersheds where this horizon was sampled (10.7–15.3 cmol c kg −1 ). Changes in calcium were not seen in the individual watersheds of the Oa and B horizons, but as a group, a significant increase in calcium was measured in the upper B horizon. Liming of a calcium-depleted watershed also tripled calcium concentration in the upper B horizon in 5 years. However, stream calcium in unlimed watersheds decreased over the study period. Small increases in B-horizon calcium may be underway

New York↗
USGS2021

Trends in precipitation chemistry across the U.S. 1985–2017: Quantifying the benefits from 30 years of Clean Air Act amendment regulation

Acid rain was first recognized in the 1970s in North America and Europe as an atmospheric pollutant that was causing harm to ecosystems. In response, the U.S. Congress enacted Title IV of the Clean Air Act Amendments (CAA) in 1990 to reduce sulfur and nitrogen emissions from fossil fuel burning power plants. This study reports trends in wet-precipitation chemistry in response to emissions reductions implemented as part of the CAA. Trends were calculated for sulfate (SO 4 ), nitrate (NO 3 ) and ammonium (NH 4 ) from 1985 to 2017 at 168 stations operated by the National Atmospheric Deposition Program (NADP); stations were divided into 9 regions across the United States. Trend analyses were conducted for three time periods: Period 1 (1985–1999), Period 2 (2000–2017), and the entire study period (1985–2017). Seasonal and regional Kendall trend analyses reveal significant decreasing trends in mean wet-precipitation SO 4 concentrations in all 9 regions during the entire study period. The largest decreasing trends in monthly mean SO 4 precipitation-weighted concentrations were measured in the Mid-Atlantic (−1.29 μeq/l/yr), Midwest (−1.15 μeq/l/yr), and Northeast regions (−1.10 μeq/l/yr). The trends in monthly mean NO 3 concentrations were not as strong as those for SO 4 , but all of the regions had significant decreasing trends in NO 3 and again the Mid-Atlantic (−0.53 μeq/l/yr), Midwest (−0.44 μeq/l/yr), and Northeast regions (−0.50 μeq/l/yr) had the strongest trends. Trends were steepest during Period 2 for SO 4 and NO 3 , in fact for NO 3 86% of the stations had significant decreasing trends during Period 2 while only 8% of the stations had significant decreasing trends during Period 1. The stations with the highest concentrations of SO 4 and NO 3 at the beginning of the study had the strongest decreasing trends and the relations were stronger during Period 2 than Period 1. For NH 4 , 22% of the stations had statistically significant increasing trends in concentration during Period 1. The largest increasing trends in wet-precipitation NH 4 concentration occurred in the North-Central region during Period 1, Period 2 and throughout the entire study. By comparison, NH 4 trends in the Rocky-North and Rocky-South regions were about half as steep and trends in the South-Central and Midwest regions were about one-third as steep. We compared trends in SO 4 and NO 3 concentrations from NADP stations to emissions of sulfur dioxide and nitrogen oxides, respectively to determine whether there was a relation between emissions and wet-precipitation concentration trends within proximity to NADP stations. There was a statistically significant relation (r 2 = 0.62–0.69, p < 0.01) between the trend in SO 4 concentrations at individual NADP stations and total and mean sulfur dioxide (SO 2 ) emissions from power plants within a range of 750 km and 1000 km from each station. There were also significant relations between NO 3 concentration trends at NADP stations and power plant emissions of nitrogen oxides, but they were not nearly as strong (r 2 = 0.18–0.36, p < 0.01) as those for SO 4 and were strongest for emissions within a range of 1000 km and 1500 km from each NADP station. Decreases in wet-precipitation SO 4 concentrations were more consistent across regions and through time than decreases in NO 3 and SO 4 trends were more closely linked to stationary emissions sources than NO 3 trends. There were statistically significant increases in NH 4 wet-precipitation concentrations, as have been reported in previous studies, but this study found that those increases were strongest during Period 1 and were not consistent across the United States. During the first 3 years of the study period, wet-precipitation acidity was dominated by SO 4 in 8 of the 9 regions; by 2017 NO 3 dominated the acidity of wet-precipitation in 7 of the 9 regions. There has also been a downward shift in the NO 3 :NH 4 ratio of wet-precipitation as the emissions of nitrogen oxides have declined while ammonia emissions have remained essentially constant. This shift has resulted in an increase in wet-precipitation total nitrogen concentrations in 7 of the 9 regions and indicate that efforts to control NH 3 emissions will become increasingly important as emissions of nitrogen oxides continue to decline.

Atmospheric Environment↗
USGS2021

Biological and chemical recovery of acidified Catskill Mountain streams in response to the Clean Air Act Amendments of 1990

Decades of acidic deposition have adversely affected aquatic and terrestrial ecosystems in acid-sensitive watersheds in parts of the eastern United States. The national Acid Rain Program (Title IV of the 1990 Clean Air Act Amendments - CAAA) helped reduce emissions of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) and resulted in sharp decreases in the acidity of atmospheric deposition. The decrease in acidic deposition produced a steady decline in the acidity of streams in many poorly buffered waters across the western Adirondacks and parts of the Catskill Mountains of New York. Until recently, however, there has been little evidence of biological recovery in most acid-sensitive streams in both regions. Long-term deposition and stream-chemistry records and fish-community data from quantitative surveys done during 1991–93 and again during 2012–19 at 13 sites in the upper Neversink River and its tributaries were evaluated to determine if chemical and biological recovery were evident in this Catskill Mountain watershed and if they could be linked to regional declines in acidic deposition. Between 1991 and 2019, large decreases in sulfate and nitrate deposition in the basin mirrored declines in total nationwide SO 2 and NO x emissions. There were corresponding decreases in sulfate and nitrate concentrations in deposition at a National Trends Network station at Frost Valley (NY68) and coincident declines in sulfate concentrations at four long-term monitoring sites in the Neversink River watershed. Mean acid neutralizing capacity and pH increased and inorganic aluminum (Al i ) concentrations from routine summertime samples decreased significantly at most moderately to severely acidified sites between the two study periods. Richness, density, and biomass of fish communities increased at most sites, while the density and biomass of brook trout Salvelinus fontinalis populations increased at fewer sites that were undergoing chemical recovery. Although recovery is far from complete, trends in deposition chemistry, water quality, and fish assemblages in streams of the upper Neversink watershed indicate that the 1990 CAAA is having positive impacts on aquatic ecosystems in the Catskill Mountain region, New York.

New York↗
USGS2018

Long-term changes in soil and stream chemistry across an acid deposition gradient in the northeastern United States

D eclines in acidic deposition across Europe and North America have led to decreases in surface water acidity and signs of chemical recovery of soils from acidification. To better understand the link between recovery of soils and surface waters, chemical trends in precipitation, soils, and streamwater were investigated in three watersheds representing a depositional gradient from high to low across the northeastern United States. Significant declines in concentrations of H + (ranging from −1.2 to −2.74 microequivalents [μeq] L −1 yr −1 ), NO 3 − (ranging from −0.6 to −0.84 μeq L −1 yr −1 ), and SO 4 2− (ranging from −0.95 to −2.13 μeq L −1 yr −1 ) were detected in precipitation in the three watersheds during the period 1999 to 2013. Soil chemistry in the A horizon of the watershed with the greatest decrease in deposition showed significant decreases in exchangeable Al and increases in exchangeable bases. Soil chemistry did not significantly improve during the study in the other watersheds, and base saturation in the Oa and upper B horizons significantly declined in the watershed with the smallest decrease in deposition. Streamwater SO 4 2− concentrations significantly declined in all three streams (ranging from −2.01 to −2.87 μeq L −1 yr −1 ) and acid neutralizing capacity increased (ranging from 1.38 to 1.60 μeq L −1 yr −1 ) in the two streams with the greatest decreases in deposition. Recovery of soils has likely been limited by decades of acid deposition that have leached base cations from soils with base-poor parent material.

Journal of Environmental Quality↗
USGS2017

The response of soil and stream chemistry to decreases in acid deposition in the Catskill Mountains, New York, USA

The Catskill Mountains have been adversely impacted by decades of acid deposition, however, since the early 1990s, levels have decreased sharply as a result of decreases in emissions of sulfur dioxide and nitrogen oxides. This study examines trends in acid deposition, stream-water chemistry, and soil chemistry in the southeastern Catskill Mountains. We measured significant reductions in acid deposition and improvement in stream-water quality in 5 streams included in this study from 1992 to 2014. The largest, most significant trends were for sulfate (SO 4 2− ) concentrations (mean trend of −2.5 μeq L −1 yr −1 ); hydrogen ion (H + ) and inorganic monomeric aluminum (Al im ) also decreased significantly (mean trends of −0.3 μeq L −1 yr −1 for H + and −0.1 μeq L −1 yr −1 for Al im for the 3 most acidic sites). Acid neutralizing capacity (ANC) increased by a mean of 0.65 μeq L −1 yr −1 for all 5 sites, which was 4 fold less than the decrease in SO 4 2− concentrations. These upward trends in ANC were limited by coincident decreases in base cations (−1.3 μeq L −1 yr −1 for calcium + magnesium). No significant trends were detected in stream-water nitrate (NO 3 − ) concentrations despite significant decreasing trends in NO 3 − wet deposition. We measured no recovery in soil chemistry which we attributed to an initially low soil buffering capacity that has been further depleted by decades of acid deposition. Tightly coupled decreasing trends in stream-water silicon (Si) (−0.2 μeq L −1 yr −1 ) and base cations suggest a decrease in the soil mineral weathering rate. We hypothesize that a decrease in the ionic strength of soil water and shallow groundwater may be the principal driver of this apparent decrease in the weathering rate. A decreasing weathering rate would help to explain the slow recovery of stream pH and ANC as well as that of soil base cations.

New York↗
USGS2017

Trends in snowmelt-related streamflow timing in the conterminous United States

Changes in snowmelt-related streamflow timing have implications for water availability and use as well as ecologically relevant shifts in streamflow. Historical trends in snowmelt-related streamflow timing (winter-spring center volume date, WSCVD) were computed for minimally disturbed river basins in the conterminous United States. WSCVD was computed by summing daily streamflow for a seasonal window then calculating the day that half of the seasonal volume had flowed past the gage. We used basins where at least 30 percent of annual precipitation was received as snow, and streamflow data were restricted to regionally based winter-spring periods to focus the analyses on snowmelt-related streamflow. Trends over time in WSCVD at gages in the eastern U.S. were relatively homogenous in magnitude and direction and statistically significant; median WSCVD was earlier by 8.2 days (1.1 days/decade) and 8.6 days (1.6 days/decade) for 1940–2014 and 1960–2014 periods respectively. Fewer trends in the West were significant though most trends indicated earlier WSCVD over time. Trends at low-to-mid elevation (<1600 m) basins in the West, predominantly located in the Northwest, had median earlier WSCVD by 6.8 days (1940–2014, 0.9 days/decade) and 3.4 days (1960–2014, 0.6 days/decade). Streamflow timing at high-elevation (⩾1600 m) basins in the West had median earlier WSCVD by 4.0 days (1940–2014, 0.5 days/decade) and 5.2 days (1960–2014, 0.9 days/decade). Trends toward earlier WSCVD in the Northwest were not statistically significant, differing from previous studies that observed many large and (or) significant trends in this region. Much of this difference is likely due to the sensitivity of trend tests to the time period being tested, as well as differences in the streamflow timing metrics used among the studies. Mean February–May air temperature was significantly correlated with WSCVD at 100 percent of the study gages (field significant, p < 0.0001), demonstrating the sensitivity of WSCVD to air temperature across snowmelt dominated basins in the U.S. WSCVD in high elevation basins in the West, however, was related to both air temperature and precipitation yielding earlier snowmelt-related streamflow timing under warmer and drier conditions.

Journal of Hydrology↗
USGS2016

Methods of soil resampling to monitor changes in the chemical concentrations of forest soils

Recent soils research has shown that important chemical soil characteristics can change in less than a decade, often the result of broad environmental changes. Repeated sampling to monitor these changes in forest soils is a relatively new practice that is not well documented in the literature and has only recently been broadly embraced by the scientific community. The objective of this protocol is therefore to synthesize the latest information on methods of soil resampling in a format that can be used to design and implement a soil monitoring program. Successful monitoring of forest soils requires that a study unit be defined within an area of forested land that can be characterized with replicate sampling locations. A resampling interval of 5 years is recommended, but if monitoring is done to evaluate a specific environmental driver, the rate of change expected in that driver should be taken into consideration. Here, we show that the sampling of the profile can be done by horizon where boundaries can be clearly identified and horizons are sufficiently thick to remove soil without contamination from horizons above or below. Otherwise, sampling can be done by depth interval. Archiving of sample for future reanalysis is a key step in avoiding analytical bias and providing the opportunity for additional analyses as new questions arise.

Journal of Visualized Experiments↗
USGS2016

Streamflow

This indicator describes trends in the amount of water carried by streams across the United States, as well as the timing of runoff associated with snowmelt.

Report↗
USGS2014

Reflections on a vision for integrated research and monitoring after 15 years

In May of 1998, Owen Bricker and his co-author Michael Ruggiero introduced a conceptual design for integrating the Nation’s environmental research and monitoring programs. The Framework for Integrated Monitoring and Related Research was an organizing strategy for relating data collected by various programs, at multiple spatial and temporal scales, and by multiple science disciplines to solve complex ecological issues that individual research or monitoring programs were not designed to address. The concept nested existing intensive monitoring and research stations within national and regional surveys, remotely sensed data, and inventories to produce a collaborative program for multi-scale, multi-network integrated environmental monitoring and research. Analyses of gaps in data needed for specific issues would drive decisions on network improvements or enhancements. Data contributions to the Framework from existing networks would help indicate critical research and monitoring programs to protect during budget reductions. Significant progress has been made since 1998 on refining the Framework strategy. Methods and models for projecting scientific information across spatial and temporal scales have been improved, and a few regional pilots of multi-scale data-integration concepts have been attempted. The links between science and decision-making are also slowly improving and being incorporated into science practice. Experiments with the Framework strategy since 1998 have revealed the foundational elements essential to its successful implementation, such as defining core measurements, establishing standards of data collection and management, integrating research and long-term monitoring, and describing baseline ecological conditions. They have also shown us the remaining challenges to establishing the Framework concept: protecting and enhancing critical long-term monitoring, filling gaps in measurement methods, improving science for decision support, and integrating the disparate integrated science efforts now underway. In the 15 years since the Bricker and Ruggiero (Ecol Appl 8(2):326–329, 1998) paper challenged us with a new paradigm for bringing sound and comprehensive science to environmental decisions, the scientific community can take pride in the progress that has been made, while also taking stock of the challenges ahead for completing the Framework vision.

Aquatic Geochemistry↗
USGS2011

A whole ecosystem approach to studying climate change in interior Alaska

Yukon River Basin Principal Investigators Workshop; Portland, Oregon, 18-20 January 2011; High latitudes are known to be particularly susceptible to climate warming, leading to an emphasis of field and modeling research on arctic regions. Subarctic and boreal regions such as the Yukon River Basin (YRB) of interior Alaska and western Canada are less well studied, although they encompass large areas that are vulnerable to changes in forest composition, permafrost distribution, and hydrology. There is an urgent need to understand the resiliency and vulnerability of these complex ecosystems as well as their feedbacks to the global climate system. Consequently, U.S. Geological Survey scientists, with other federal agency, university, and private industry partners, is focusing subarctic interdisciplinary studies on the Beaver Creek Wild and Scenic River watershed (http://www.blm.gov/pgdata/content/ak/en/prog/nlcs/beavercrk_nwsr.html) and Yukon Flats National Wildlife Refuge (http://yukonflats.fws.gov/) in the YRB, south and west of Fort Yukon, Alaska. These areas are national treasures of wetlands, lakes, and uplands that support large populations of wildlife and waterfowl and are home to vibrant native Alaskan communities that depend on the area for a subsistence lifestyle.

Alaska↗
USGS2007

Factors controlling nitrogen release from two forested catchments with contrasting hydrochemical responses

Quantifying biogeochemical cycles of nitrogen (N) and the associated fluxes to surface waters remains challenging, given the need to deal with spatial and temporal variability and to characterize complex and heterogeneous landscapes. We focused our study on catchments S14 and S15 located in the Adirondack Mountains of New York, USA, which have similar topographic and hydrologic characteristics but contrasting stream nitrate ($\hbox{NO}_{3}^{-}$) concentrations. We characterized the mechanisms by which $\hbox{NO}_{3}^{-}$ reaches the streams during hydrological events in these catchments, aiming to reconcile our field data with our conceptual model of factors that regulate nutrient exports from forested catchments. Combined hydrometric, chemical and isotopic (δ$\hbox{NO}_{3}^{-}$) data showed that the relative contributions of both soil and ground water sources were similar between the two catchments. Temporal patterns of stream chemistry were markedly different between S14 and S15, however, because the water sources in the two catchments have different solute concentrations. During late summer/fall, the largest source of $\hbox{NO}_{3}^{-}$ in S14 was till groundwater, whereas shallow soil was the largest $\hbox{NO}_{3}^{-}$ source in S15. $\hbox{NO}_{3}^{-}$ concentrations in surface water decreased in S14, whereas they increased in S15 because an increasing proportion of stream flow was derived from shallow soil sources. During snowmelt, the largest sources of $\hbox{NO}_{3}^{-}$were in the near‐surface soil in both catchments. Concentrations of $\hbox{NO}_{3}^{-}$ increased as stream discharge increased and usually peaked before peak discharge, when shallow soil water sources made the largest contribution to stream discharge. The timing of peaks in stream $\hbox{NO}_{3}^{-}$concentrations was affected by antecedent moisture conditions. By elucidating the factors that affect sources and transport of N, including differences in the soil nutrient cycling and hydrological characteristics of S14 and S15, this study contributes to the overall conceptualization of $\hbox{NO}_{3}^{-}$ release from temperate forested catchments.

Hydrological Processes↗