Summary of data for onsite and laboratory analyses of precipitation runoff from carbonate-rock surfaces, National Acid Precipitation Assessment Program, June 1984 to September 1986
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Geology topics
Publications and source records attributed to Michael M. Reddy.
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In this paper the authors describe an experimental research program, conducted in conjunction with the National Acidic Precipitation Assessment Program (NAPAP), to quantify acid-rain damage to commercial and cultural carbonate-rock resources. Initial results of this experiment show that carbonate-rock dissolution and associated surface recession increase with increasing acid deposition to the rock surface. A statistically significant linear relation has been found between carbonate-rock surface-recession rate and hydrogen ion loading to the rock surface.
A highly reproducible seeded growth technique was used to study calcite crystallization from calcium bicarbonate solutions at 25°C and fixed carbon dioxide partial pressures between 0.03 and 0.3 atm. The results are not consistent with empirical crystallization models that have successfully described calcite growth at low P CO 2 (< 10 −3 atm). Good agreement was found between observed crystallization rates and those calculated from the calcite dissolution rate law and mechanism proposed by Plummer et al . (1978).