Geology topics

M.A. Huebner

Publications and source records attributed to M.A. Huebner.

2 recordsLinked to original sources

USGS2004

Chapter 11 The phosphoria formation: A model for forecasting global selenium sources to the environment

Mining of the Permian Phosphoria Formation — a marine, oil-generating, phosphatic shale — provided the selenium (Se) source implicated in the recent deaths of livestock in southeast Idaho. Field studies and the geohydrologic balance of Se in southeast Idaho confirm risk to animals from exposure to Se through leaching of mined waste shale into streams, discharge of regional drainage, and impoundment of drainage in wetland areas. Forage grown to stabilize waste rock contoured into hills or used as cross-valley fill provides an additional mechanism of Se exposure for the environment (Mackowiak et al., Chapter 19). The average Se concentration of the Meade Peak Member of the Phosphoria Formation is an order of magnitude higher than those of other exploited marine shales that have been linked to incidences of Se toxicosis via oil refining and irrigation in the western United States. The Phosphoria Formation accumulated in an environment that preserved organic matter and contributed to the formation of economic-grade phosphate and oil deposits. The addition of this phosphate-mining case study enables a comprehensive approach to the identification of marine sedimentary Se sources and a more complete range of ecotoxic field studies on which to establish the conditions and anthropogenic connections that determine uptake, release, and recycling of Se in food webs. A constructed conceptual model of Se pollution indicates that ancient organic-rich depositional marine basins, unre- stricted by age, are linked to the contemporary global distribution of Se source rocks. A global plot shows (a) the areal association of major basins hosting phosphate deposits and petroleum source rocks and (b) the importance of paleo-latitudinal setting in influencing the composition of the deposits. Given the geographic patterns, Se emerges as a contami- nant within specific regions of the globe that may limit phosphate mining, oil refining, and drainage of agricultural lands because of potential ecological risks to vulnerable food webs. Selenium also may serve as a geochemical exploration tool that signals an ancient productive biological environment.

Handbook of Exploration and Environmental Geochemi↗

USGS2002

Tracing and quantifying magmatic carbon discharge in cold groundwaters: Lessons learned from Mammoth Mountain, USA

A major campaign to quantify the magmatic carbon discharge in cold groundwaters around Mammoth Mountain volcano in eastern California was carried out from 1996 to 1999. The total water flow from all sampled cold springs was ??? 1.8 ?? 107 m3/yr draining an area that receives an estimated 2.5 ?? 107 m3/yr of recharge, suggesting that sample coverage of the groundwater system was essentially complete. Some of the waters contain magmatic helium with 3He/4He ratios as high as 4.5 times the atmospheric ratio, and a magmatic component in the dissolved inorganic carbon (DIC) can be identified in virtually every feature sampled. Many waters have a 14C of 0-5 pmC, a ??13C near -5???, and contain high concentrations (20-50 mmol/1) of CO2(aq); but are otherwise dilute (specific conductance = 100-300 ??S/cm) with low pH values between 5 and 6. Such waters have previously escaped notice at Mammoth Mountain, and possibly at many other volcanoes, because CO2 is rapidly lost to the air as the water flows away from the springs, leaving neutral pH waters containing only 1-3 mmol/1 HCO-3. The total discharge of magmatic carbon in the cold groundwater system at Mammoth Mountain is ~ 20 000 t/yr (as CO2), ranging seasonally from about 30 to 90 t/day. Several types of evidence show that this high discharge of magmatic DIC arose in part because of shallow dike intrusion in 1989, but also demonstrate that a long-term discharge possibly half this magnitude (~ 10 000 t/yr) predated that intrusion. To sustain a 10 000 t/yr DIC discharge would require a magma intrusion rate of 0.057 km3 per century, assuming complete degassing of magma with 0.65 wt% CO2 and a density of 2.7 t/m3. The geochemical data also identify a small ( < 1 t/day) discharge of magmatic DIC that can be traced to the Inyo Domes area north of Mammoth Mountain and outside the associated Long Valley caldera. This research, along with recent studies at Lassen Peak and other western USA volcanoes, suggests that the amount of magmatic carbon in cold groundwaters is important to constraining rates of intrusion and edifice weathering at individual volcanoes and may even represent a significant fraction of the global carbon discharge from volcanoes. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗