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Geology topics

M. Tatsumoto

Publications and source records attributed to M. Tatsumoto.

At least 37 records · Page 2Linked to original sources

REE and Sr, Nd, Pb isotopic geochemistry of Huangyishan basalt, Kuandian, Liaoning, Northeast China

In the light of major element geochemistry, mineral chemistry and REE and isotopic data, the small but apparent isotopic differences between the Cenozoic volcanic rocks east and west of the Tancheng-Lujiang fault are believed to be caused by the mixing and metasomatism of crustal and mantle material in the mantle source region in response to Pacific plate subduction. The presence of phlogopite and pargasite in mantle xenoliths lends strong support to mantle metasomatism. ?? 1990.

Science in China (Scientia Sinica) Series B

Sr, Nd, Pb Isotope geochemistry and magma evolution of the potassic volcanic rocks, Wudalianchi, Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in eastern China. Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolution. They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.87Sr /86 Sr is higher and143Nd/144Nd is lower than the undifferentiated global values. In comparison to continental potash volcanic rocks, Pb isotopes are apparently lower. These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material. The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition. ?? 1989 Institute of Geochemistry, Chinese Academy of Sciences.

Chinese Journal of Geochemistry

Assessment of the U-Th-Pb system in two Archean metabasalts: Deciphering the complex histories of sulphides and silicates using acid leaching methods

A U-Th-Pb study of Archean metabasalts from two greenstone belts in the eastern Wawa Subprovince of the Canadian shield indicated variable disturbances had occurred in both whole rock systems. Changes in the Pb content appear to predominate over loss of parent elements, and meaningful Pb isochron ages could not be obtained from either of the metabasalts. Detailed leaching experiments on the rocks and analysis of associated disseminated sulphides indicate that the Pb isotopic compositions of the whole rocks are dominated by updated, but for the most part cogenetic, sulphides. Model ages for Pb released by sulphides and metabasalt acid leaches suggest that the sulphide Pb has been updated or remobilized during discrete (thermal ?) episodes. The validity of the inferred events is supported by ages indicated by other isotopic systems for nearby rocks. The silicate residues of the acid leached volcanics give well-defined Pb isochron ages. The Gamitagama belt metabasalt has a Pb isochron age of 2694 ± 54 Ma . Zircons from this rock unit have been dated by U-Pb at 2691 Ma, demonstrating that the acid leaching technique on whole rocks can isolate residues which give meaningful ages. Sulphides in this metabasalt appear to be affected by an event at 2.55 Ga. A similar rock from the Michipicoten belt has undergone a multistage history and yields a Pb isochron age of 2761 ± 36 Ma , consistent with a zircon U-Pb date for overlying felsic metavolcanic rocks. Later events affecting this basalt occurred at approximately 2.4, 2.2 and 1.6 Ga. The results show that through acid leaching, the primary ages of metabasalts and their later overprinting histories can be approximated. Initial Pb ratios for these metabasalts have been estimated. It appears that both depleted and enriched mantle reservoirs contributed to volcanism in this area. Acid leaching, combined with measurement of U and Th contents, appears to be a useful tool for better understanding the Pb isotope systematics of Archean metabasalts.

Geochimica et Cosmochimica Acta

Major- and minor-metal composition of three distinct solid material fractions associated with Juan de Fuca hydrothermal fluids (northeast Pacific), and calculation of dilution fluid samples

Three distinct types of solid material are associated with each sample of the hydrothermal fluid that was collected from the vents of the Southern Juan de Fuca Ridge. The solid materials appear to be representative of deposits on ocean floors near mid-ocean ridges, and interpretation of the chemistry of the hydrothermal solutions requires understanding of them. Sr isotopic evidence indicates that at least two and probably all three of these solid materials were removed from the solution with which they are associated, by precipitation or adsorption. This occurred after the "pure" hydrothermal fluid was diluted and thoroughly mixed with ambient seawater. The three types of solid materials, are, respectively, a coarse Zn- and Fe-rich material with small amounts of Na and Ca; a finer material also rich in Zn and Fe, but with alkali and alkaline-earth metals; and a scum composed of Ba or Zn, with either considerable Fe or Si, and Sr. Mineral identification is uncertain because of uncertain anion composition. Only in the cases of Ba and Zn were metal masses greater in solid materials than in the associated fluids. For all other metals measured, masses in fluids dwarf those in solids. The fluids themselves contain greater concentrations of all metals measured, except Mg, than seawater. We discuss in detail the relative merits of two methods of determining the mixing proportions of "pure" hydrothermal solution and seawater in the fluids, one based on Sr isotopes, and another previously used method based on Mg concentrations. Comparison of solute concentrations in the several samples shows that degree of dilution of "pure" hydrothermal solutions by seawater, and amounts of original solutes that were removed from it as solid materials, are not related. There is no clear evidence that appreciable amounts of solid materials were not conserved (lost) either during or prior to sample collection. ?? 1988.

Chemical Geology

Isotope geochemistry of recent magmatism in the Aegean arc: Sr, Nd, Hf, and O isotopic ratios in the lavas of Milos and Santorini-geodynamic implications

In this comparative study of variations in the isotopic compositions (Sr, Nd, O and Hf) of the calc-alkaline magmas of the largest two volcanoes, Milos and Santorini, of the Aegean arc (eastern Mediterranean) we demonstrate the complexity of the processes governing the evolution of the magmas on the scale both of the arc and of each volcano. On Santorini, the crustal contamination processes have been limited, effecting the magma gradually during its differentiation. The most differentiated lavas (rhyodacite and pumice) are also the most contaminated. On Milos, by contrast, these processes are very extensive. They are expressed in the 143 Nd/ 144 Nd vs. 87 Sr/ 86 Sr diagram as a continuous mixing curve between a mantle and a crustal end member pole defined by schists and metavolcanic rocks outcropping on these volcanoes. In contrast with Santorini, the least differentiated lavas on Milos are the most contaminated. These isotopic singularities can be correlated with the geodynamic evolution of the Aegean subduction zone, consisting of alternating tectonic phases of distension and compression. The genesis of rhyolitic magmas can be linked to the two phases of distension, and the contamination of the calc-alkaline mantle-derived magmas with the intermediate compressive phase. The isotopic characteristics of uncontaminated calc-alkaline primitive magmas of Milos and Santorini are directly comparable to those of magmas generated in subduction zones for which a contribution of subducted sediments to partial melts from the mantle is suggested, such as in the Aleutian, Sunda, and lesser Antilles island arcs. However, in spite of the importance of the sediment pile in the eastern Mediterranen oceanic crust (6–10 km), the contribution of the subducted terrigenous materials remains of limited amplitude.

Earth and Planetary Science Letters

Nd-Sr-Pb isotope constraints on the sources of west Maui volcano, Hawaii

The origin of the Emperor-Hawaiian volcanic chain is attributed to the northwesterly movement of the Pacific plate over a stationary mantle plume (hotspot)1. There has been considerable controversy as to the nature and number of sources of Hawaiian hotspot volcanism. Thus far, most geochemical models have been based on rock suites that are not representative of fully developed volcanoes. Nd and Sr isotope ratios and trace element concentrations of volcanics from Haleakala (Maui), where all three volcanic stages are developed, have been interpreted as reflecting a mixing process of two isotopically distinct sources2,3. In an attempt to test our earlier multiple-source model4, we have analysed Pb, Sr and Nd isotope ratios in volcanics from West Maui, the only other volcano with a complete volcanic record. Our results, presented here, indicate at least three isotopically distinct sources, one of which is heterogeneous with respect to Pb. Furthermore, the inferred depleted source for post-erosional volcanics has a Pb and Sr isotope composition intermediate between those of depleted and enriched mid-ocean ridge basalts (MORB, N-type and P-type), suggesting that this source is also heterogeneous. ?? 1986 Nature Publishing Group.

Hawaii

Precambrian tholeiitic-dacitic rock-suites and Cambrian ultramafic rocks in the Pennine nappe system of the Alps: Evidence from Sm-Nd isotopes and rare earth elements

Major element, trace element and Sm-Nd isotope analyses were made of polymetamorphic hornblendefelses, plagioclase amphibolites and banded amphibolites from the Berisal complex in the Simplon area (Italy, Switzerland) to determine their age, origin and genetic relationships. In light of major and rare earth element data, the hornblendefelses are inferred to have originally been pyroxene-rich cumulates, the plagioclase amphibolites and the dark layers of the banded amphibolites to have been tholeiitic basalts and the light layers dacites. The Sm-Nd isotope data yield isochron ages of 475??81 Ma for the hornblendefelses, 1,018??59 Ma for the plagioclase amphibolites and 1,071??43 Ma for the banded amphibolites. The 1 Ga magmatic event is the oldest one ever found in the crystalline basement of the Pennine nappes. The Sm -Nd isotope data support the consanguinity of the tholeiitic dark layers and the dacitic light layers of the banded amphibolites with the tholeiitic plagioclase amphibolites and the ultramafic hornblendefelses. The initial e{open}Nd values indicate that all three rock types originated from sources depleted in light rare earth elements. We suggest that plagioclase and banded amphibolites were a Proterozoic tholeiite-dacite sequence that was strongly deformed and flattened during subsequent folding. The hornblendefelses are thought to be Cambrian intrusions of pyroxene-rich material. ?? 1985 Springer-Verlag.

Contributions to Mineralogy and Petrology

An estimate of hydrothermal fluid residence times and vent chimney growth rates based on 210Pb Pb ratios and mineralogic studies of sulfides dredged from the Juan de Fuca Ridge

The 210 PbPb ratios across two sulfide samples dredged from the Juan de Fuca Ridge are used to estimate the growth rate of the sulfide material and the residence time of the hydrothermal fluid within the oceanic crust from the onset of basalt alteration. 210 Pb is added to the hydrothermal fluid by two processes: (1) high-temperature alteration of basalt and (2) if the residence time of the fluid is on the order of the 22.3-year half-life of 210 Pb, by in-situ growth from 222 Rn ( Krishnaswami and Turekian, 1982 ). Stable lead is derived only from the alteration of basalt. The 210 Pb/Pb ratio across one sample was ∼ 0.5 dpm/10 −6 g Pb, and across the other it was ∼ 0.4 dpm/10 −6 g Pb. These values are quite close to the 238 UP/b ratios of basalts from the area, suggesting that the residence time of the hydrothermal fluid from the onset of basalt alteration is appreciably less than the mean life of 210 Pb, i.e., the time required for ingrowth from the radon. An apparent growth rate of 1.2 cm/yr is derived from the slope of the 210 Pb/Pb curve for one of the samples. This is consistent with its mineralogy and texture which suggest an accretionary pattern of development. There is no obvious sequential growth pattern, and virtually no gradient in 210 Pb/Pb across the second sample. This is consistent with alteration of the original 210 Pb/Pb distribution by extensive remobilization reactions which are inferred from the mineralogic and textural relationships of the sample.

Earth and Planetary Science Letters

Sm-Nd, K-Ar and petrologic study of some kimberlites from eastern United States and their implication for mantle evolution

We provide new data on Sm-Nd systematics, K-Ar dating and the major element chemistry of kimberlites from the eastern United States (mostly from central New York State) and their constituent mineral phases of olivine, clinopyroxene, garnet, phlogopite and perovskite. In addition, we report Nd-isotopes in a few kimberlites from South Africa, Lesotho and from the eastern part of China. The major element compositions of the New York dike rocks and of their constituent minerals including a xenolith of eclogite are comparable with those from the Kimberley area in South Africa. The K-Ar age of emplacement of the New York dikes is further established to be 143 Ma. We have analyzed the Nd-isotopic composition of the following kimberlites and related rocks: Nine kimberlite pipes from South Africa and Lesotho, two from southern India; one from the U.S.S.R., fifteen kimberlite pipes and related dike rocks from eastern and central U.S. and two pipes from the Shandong Province of eastern China. The age of emplacement of these kimberlites ranges from 1300 million years to 90 million years. The initial Nd-isotopic compositions of these kimberlitic rocks expressed as e{open}NdIwith respect to a chondritic bulk-earth growth-curve show a range between 0 and +4, with the majority of the kimberlites being in the range 0 to +2. This range is not matched by any other suite of mantle-derived igneous rocks. This result strengthens our earlier conclusion that kimberlitic liquids are derived from a relatively primeval and unique mantle reservoir with a nearly chondritic Sm/Nd ratio. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology

Samarium-neodymium data on two late Proterozoic ophiolites of Saudi Arabia and implications for crustal and mantle evolution

Whole-rock and mineral samples from the Jabal al Wask and Jabal Ess ophiolites, northwestern Saudi Arabia, yield Sm-Nd isochron ages of 743+24 Ma and 782??38 Ma, respectively. These formation ages, which provide maximum limits for possible obduction ages, are in broad but not precise agreement with the previously known geologic history of the Arabian Shield. They indicate that the ophiolitic rocks are roughly coeval with nearby volcanic and plutonic rocks, supporting a back-arc origin for the two ophiolites. We suggest that the Jabal al Wask and Jabal Ess ophiolites were parts of the same northeast-southwest trending ophiolite belt, now offset along the Najd fault system. Initial e{open}Nd values range from +6.6 to+ 7.6, indicating derivation from a mantle source that has been LIL-depleted for at least 2 Ga. Reported e{open}Nd values from the Arabian Shield that are lower than this suggest the presence of older, reworked continental crust. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology

Age and origin of anorthosites, charnockites, and granulites in the Central Virginia Blue Ridge: Nd and Sr isotopic evidence

Rb-Sr isotopic data for anorthosites, charnockites, ferrodioritic to quartz monzonitic plutons, and high-grade gneisses of the Blue Ridge of central Virginia show evidence of post-emplacement metamorphism, but in some cases retain Grenville ages. The Pedlar River Charnockite Suite yields an isochron age of 1021 +/-36 Ma, (initial 87Sr/86Sr ratio of 0.7047 +/-6), which agrees with published U-Pb zircon ages. Five samples of that unit which contain Paleozoic mylonitic fabrics define a regression line of 683 Ma, interpreted as a mixing line with no age significance. Samples of the Roseland Anorthosite Complex show excessive scatter on a Rb-Sr evolution diagram probably due to Paleozoic (475 m.y.) metamorphism. Data from the ferrodioritic to quartz monzonitic plutons of the area yield an age of 1009 +/-26 Ma (inital ratio=0.7058 +/-4), which is in the range of the U-Pb zircon ages of 1000-1100 Ma. The Stage Road Layered Gneiss yields an age of 1147 +/-34 Ma (initial ratio of 0.7047 +/- 5). Sm-Nd data for the Pedlar River Charnockite Suite reflect a pre-Grenville age of 1489 +/-118 Ma (e{open}Nd=+6.7 +/-1.2). Data for the Roseland Anorthosite Complex and the ferrodioritic to quartz monzonitic plutons yield Grenville isochron ages of 1045 +/44 Ma (e{open}Nd=+1.0 +/-0.3) and 1027 +/-101 Ma (e{open}Nd=+1.4 +/-1.0), respectively. Two Roseland Anorthosite samples plot far above the isochron, demonstrating the effects of post-emplacement disturbance of Sm-Nd systematics, while mylonitized Pedlar River Charnockite Suite samples show no evidence of Sm-Nd redistribution. The disparity of the Sm-Nd age and other isotopic ages for the Pedlar River Charnockite Suite probably reflects a Sm-Nd "source" age, suggesting the presence of an older crust within this portion of the ca. 1 Ga old basement. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology

40Ar/39Ar and U-Th-Pb dating of separated clasts from the Abee E4 chondrite

Determinations of 40 Ar/ 39 Ar and U-Th-Pb are reported for three clasts from the Abee (E4) enstatite chondrite, which has been the object of extensive consortium investigations. The clasts give 40 Ar/ 39 Ar plateau ages and/or maximum ages of 4.5 Gy, whereas two of the clasts give average ages of 4.4 Gy. Within the range of 4.4–4.5 Gy these data do not resolve any possible age differences among the three clasts. 206 Pb measured in these clasts is only ∼1.5–2.5% radiogenic, which leads to relatively large uncertainties in the Pb isochron age and in the 207 Pb/ 206 Pb model ages. The Pb data indicate that the initial 207 Pb/ 206 Pb was no more than 0.08±0.07% higher than this ratio in Can˜on Diablo troilite. The U-Th-Pb data are consistent with the interpretation that initial formation of these clasts occurred 4.58 Gy ago and that the clasts have since remained closed systems, but are contaminated with terrestrial Pb. The 40 Ar/ 39 Ar ages could be gas retention ages after clast formation or impact degassing ages. The thermal history of Abee deduced from Ar data appears consistent with that deduced from magnetic data, and suggests that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, and experienced no appreciable subsequent heating.

Earth and Planetary Science Letters

Evolution of continental crust and mantle heterogeneity: Evidence from Hf isotopes

We present initial 176Hf/177 Hf ratios for many samples of continental crust 3.7-0.3 Gy old. Results are based chiefly on zircons (1% Hf) and whole rocks: zircons are shown to be reliable carriers of essentially the initial Hf itself when properly chosen on the basis of U-Pb studies. Pre-3.0 Gy gneisses were apparently derived from an unfractionated mantle, but both depleted and undepleted mantle are evident as magma sources from 2.9 Gy to present. This mantle was sampled mainly from major crustal growth episodes 2.8, 1.8 and 0.7 Gy ago, all of which show gross heterogeneity of 176Hf/177Hf in magma sources from ??Hf=0 to +14, or about 60% of the variability of the present mantle. The approximate ??Hf=2??Nd relationship in ancient and modern igneous rocks shows that 176Lu/177Hf fractionates in general twice as much as 147Sm/144Nd in mantle melting processes. This allows an estimation of the relative value of the unknown bulk solid/liquid distribution coefficient for Hf. DLu/DHf=??? 2.3 holds for most mantle source regions. For garnet to be an important residual mantle phase, it must hold Hf strongly in order to preserve Hf-Nd isotopic relationships. The ancient Hf initials are consistent with only a small proportion of recycled older cratons in new continental crust, and with quasi-continuous, episodic growth of the continental crust with time. However, recycling of crust less than 150 My old cannot realistically be detected using Hf initials. The mantle shows clearly the general positive ??Hf resulting from a residual geochemical state at least back to 2.9 Gy ago, and seems to have repeatedly possessed a similar degree of heterogeneity, rather than a continuously-developing depletion. This is consistent with a complex dynamic disequilibrium model for the creation, maintenance and destruction of heterogeneity in the mantle. ?? 1981 Springer-Verlag.

Contributions to Mineralogy and Petrology

A routine high-precision method for Lu-Hf isotope geochemistry and chronology

A method for chemical separation of Lu and Hf from rock, meteorite and mineral samples is described, together with a much improved mass spectrometric running technique for Hf. This allows (i) geo- and cosmochronology using the176Lu???176Hf+??- decay scheme, and (ii) geochemical studies of planetary processes in the earth and moon. Chemical yields for the three-stage ion-exchange column procedure average 90% for Hf. Chemical blanks are <0.2 ng for Lu and Hf. From 1 ??g of Hf, a total ion current of 0.5??10-11 Ampere can be maintained for 3-5 h, yielding 0.01-0.03% precision on the ratio176Hf/177Hf. Normalisation to179Hf/177Hf=0.7325 is used. Extensive results for the Johnson Matthey Hf standard JMC 475 are presented, and this sample is urged as an international mass spectrometric standard; suitable aliquots, prepared from a single batch of JMC 475, are available from Denver. Lu-Hf analyses of the standard rocks BCR-1 and JB-1 are given. The potential of the Lu-Hf method in isotope geochemistry is assessed. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology

Nd-isotopes in selected mantle-derived rocks and minerals and their implications for mantle evolution

The Sm-Nd systematics in a variety of mantle-derived samples including kimberlites, alnoite, carbonatite, pyroxene and amphibole inclusions in alkali basalts and xenolithic eclogites, granulites and a pyroxene megacryst in kimberlites are reported. The additional data on kimberlites strengthen our earlier conclusion that kimberlites are derived from a relatively undifferentiated chondritic mantle source. This conclusion is based on the observation that the e{open}Nd values of most of the kimberlites are near zero. In contrast with the kimberlites, their garnet lherzolite inclusions show both time-averaged Nd enrichment and depletion with respect to Sm. Separated clinopyroxenes in eclogite xenoliths from the Roberts Victor kimberlite pipe show both positive and negative e{open}Nd values suggesting different genetic history. A whole rock lower crustal scapolite granulite xenolith from the Matsoku kimberlite pipe shows a negative e{open}Nd value of -4.2, possibly representative of the base of the crust in Lesotho. It appears that all inclusions, mafic and ultramafic, in kimberlites are unrelated to their kimberlite host. The above data and additional Sm-Nd data on xenoliths in alkali basalts, alpine peridotite and alnoite-carbonatites are used to construct a model for the upper 200 km of the earth's mantle - both oceanic and continental. The essential feature of this model is the increasing degree of fertility of the mantle with depth. The kimberlite's source at depths below 200 km in the subcontinental mantle is the most primitive in this model, and this primitive layer is also extended to the suboceanic mantle. However, it is clear from the Nd-isotopic data in the xenoliths of the continental kimberlites that above 200 km the continental mantle is distinctly different from their suboceanic counterpart. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology