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M. J. Kleeschulte

Publications and source records attributed to M. J. Kleeschulte.

10 recordsLinked to original sources

Stratigraphy and vertical hydraulic conductivity of the St. Francois confining unit in townships 25-27 N. and ranges 01-02 W., southeastern Missouri

The St. Francois confining unit (DerbyDoerun Dolomite and Davis Formation) lies beneath the Ozark aquifer (Jefferson City Dolomite to the Potosi Dolomite) and impedes the circulation of water between the overlying Ozark aquifer and the underlying St. Francois aquifer (Bonneterre Formation and Lamotte Sandstone). The Bonneterre Formation is the potential host formation for lead-zinc deposits in the area. There is concern that mine dewatering in the Bonneterre Formation could lower water levels in the Ozark aquifer. To address this concern, the vertical hydraulic conductivity of the St. Francois confining unit in six townships (T. 25-27 N. and R. 01- 02 W.) of Oregon, Carter, and Ripley Counties of southeastern Missouri was evaluated by describing the stratigraphy and measuring the vertical hydraulic conductivity of core samples. The Davis Formation is an intrashelf basin facies consisting of a series of shales interbedded with shaley limestones, shale-free limestones, and local dolostones, and ranges from 24 to 320ft (feet) thick, but typically the thickness is 100 to 200 ft. Shale-dominant sequences can be tens of feet thick, and contain as much as 90 percent shale. Carbonate-dominant zones may be 70 ft thick or greater. The top of the Davis Formation (based on 56 data points) ranges from 620 to 2,022 ft deep and ranges in altitude from 40ft below sea level in the northern part of the study area to 1, 182 ft below sea level in the southern part of the study area. The Derby-Doerun Dolomite represents a pair of superimposed carbonate ramp cycles. Where present, the basal shaley sequence represents a transition with the Davis Formation. The formation (based on 50 data points) ranges from 50 to 386ft thick, but typically is 120 to 180ft thick in the study area. The top of the DerbyDoerun Dolomite ranges from 495 to 2,020 ft deep (based on 53 data points), and ranges in altitude from 85 ft above sea level to 94 7 ft below sea level. The St. Francois confining unit is thickest in the central and southern parts of the study area. The thickness, as determined by 51 core logs that completely penetrate the unit, ranges from less than 200ft in the northwestern and east-central parts of the study area to 411 ft in the central part, but typically ranges from 270 to 340 ft. The net shale thickness of the confining unit (based on 29 data points) ranges from 1. 7 ft in the east -central part of the study area to 89 ft in the southwest part. These net shale thickness values include the cumulative shale thickness of rock from the top of the Derby-Doerun Dolomite to the base of the False Davis. Vertical hydraulic conductivities of 35 rock core samples from the St. Francois confining unit in the study area range from 7.6 x 10 -15 to 2.1 x 10 -10 ft/s (foot per second). The logarithmic transformed vertical hydraulic conductivities of the Derby-Doerun Dolomite and Davis Formation are similar (p-value = 0.073) using the statistical twosample t-test; however, this p-value approaches the level of significance value of 0.05. The vertical hydraulic conductivity of the Derby-Doerun Dolomite is larger and less variable than the Davis Formation. When grouped by rock type, the vertical hydraulic conductivity of samples that contain carbonate, shale, or both carbonate and shale, are similar. A comparison on the ranked data using the Mann-Whitney test shows the confining unit in the study area is statistically different (p-value = 0.020) from the confining unit in the prospecting area (west and adjacent to the study area). The median value of the vertical hydraulic conductivity data from the study area (6.7 x 10 -13 ft/s) is three times larger than the median vertical hydraulic conductivity value for the prospecting area (2.2 x 10 -13 ft/s ). The interquartile range shows that the variability of the study area data spans one order of magnitude (2.0 x 10 -13 to 2.2 x 10 -12 ft/s) and that the corresponding data from the prospecting area spans nearly two orders of magnitude (3.2 x 10 -14 to 1.1 x 10 -12 ft/s). The ranked vertical hydraulic conductivities of the Derby-Doerun Dolomite in the two areas are statistically similar (p-value = 0.514). The median vertical hydraulic conductivity of the study area data ( 1.2 X 10 -12 ft/s) is about three times greater than the median value of the prospecting area data (4.4 x 10 -13 ft/s). The variability of the data, as shown by the interquartile range, is less in the study area (5.5 x 10 -13 to 2.2 x 10 -12 ft/s; spanning less than one order of magnitude) as compared to the prospecting area (3.2 x 10 -14 to 6.3 x 10 -10 ft/s; spanning over four orders of magnitude). The ranked vertical hydraulic conductivities of the Davis Formation in the two areas show these data sets are statistically similar (p-value = 0.076). The median vertical hydraulic conductivity value of study area samples ( 4.5 x 10 -13 ft/s) is three times greater than the median value of the prospecting area data (1.6 x 10 -13 ft/s). The interquartile range of the study area data spans one order of magnitude (1.2 x 10 -13 to 1.4 x 10 -12 ft/s) and the corresponding data from the prospecting area spans nearly 1.5 orders of magnitude (3.2 x 10 -14 to 7.4 x 10 -13 ft/s). The Mann-Whitney test shows the ranked vertical hydraulic conductivities of each rock type from the study area are statistically similar to the same rock type in the prospecting area [carbonates (p-value = 0.225), shales (p-value = 0.668), and carbonates and shales (p-value = 0.227)]. However, in each of the three cases the study area samples have larger median values and less variability than the prospecting area samples. Because the vertical hydraulic conductivity of the various rock types of the confining unit in the study area are statistically similar, the entire carbonate-shale thickness is the primary factor determining the effectiveness of the confining unit. The range of effective vertical hydraulic conductivity of the St. Francois confining unit in the study area using appropriate minimum and maximum thickness, net shale thickness, and vertical hydraulic conductivities is 3 X 10 -13 to 2 X 10 -12 ft/s. The vertical hydraulic conductivity of the confining unit is small, and the confining unit effectively impedes the ground-water flow between the Ozark aquifer and the St. Francois aquifer, unless preferred- path secondary permeability has developed along faults and fractures that extend through the confining unit.

Missouri↗

Hydrology and water-quality at the Weldon Spring radioactive waste-disposal sites, St. Charles County, Missouri

Water samples from five monitoring wells adjacent to raffinate pits storing low-level radioactive waste contained concentrations of nitrate as nitrogen ranging from 53 to 990 milligrams per liter. Most samples also had maximum concentrations of calcium (900 milligrams per liter), sodium (340 milligrams per liter), sulfate (320 milligrams per liter), lithium (1,700 micrograms), strontium (1,900 micrograms per liter), and uranium (86 micrograms per liter). The raffinate pits also had large concentrations of these constituents. A water balance made on the raffinate pits indicated a 0.04 to 0.08 inch per day decrease in the water level that cannot be attributed to meterological conditions. These data and seismically-detected areas of saturated overburden beneath one raffinate pit and possibly adjacent to three other pits indicate leakage from the pits.

Missouri↗

Hydrologic data for the Weldon Spring radioactive waste-disposal sites, St. Charles County, Missouri; 1984-1986

Hydrologic and water quality data were collected during an investigation of the Weldon Spring radioactive waste disposal sites and surroundings area in St. Charles County, Missouri, from 1984 to 1986. The data consists of water quality analyses of samples collected from 45 groundwater and 27 surface water sites. This includes analyses of water from four raffinate pits and from the Weldon Spring quarry. Also included in the report are the results of a seepage run on north flowing tributaries to Dardenne Creek from Kraut Run to Crooked Creek. Mean daily discharge from April 1985 to April 1986 is given for two springs located about 1.5 mi north of the chemical plant. (USGS)

Open-File Report↗

Compilation and preliminary interpretation of hydrologic data for the Weldon Spring radioactive waste-disposal sites, St Charles County, Missouri — A progress report

The Weldon Spring Chemical Plant is located just north of the drainage divide separating the Mississippi River and the Missouri River in St. Charles County, Missouri. From 1957 to 1966 the plant converted uranium-ore concentrates and recycled scrap to pure uranium trioxide, uranium tetrafluoride, and uranium metal. Residues from these operations were pumped to four large pits that had been excavated near the plant. Small springs and losing streams are present in the area. Water overlying the residue in the pits has a large concentration of dissolved solids and a different chemical composition compared to the native groundwater and surface water. This difference is indicated by the concentrations of calcium, sodium, sulfate, nitrate, fluoride, uranium, radium, lithium, molybdenum, strontium, and vanadium, all of which are greater than natural or background concentrations. Water from Burgermeister Spring, located about 1.5 miles north of the chemical plant area, contains uranium and nitrate concentrations greater than background concentrations. Groundwater in the shallow bedrock aquifer moves northward from the vicinity of the chemical plant toward Dardenne Creek. An abandoned limestone quarry several miles southwest of the chemical plant also has been used for the disposal of radioactive waste and rubble. Groundwater flow from the quarry area is southward through the alluvium, away from the quarry and toward the Missouri River. The St. Charles County well field is located in the Missouri River flood plain near the quarry and the large yield wells are open to the Missouri River alluvial aquifer. Water from a well 4,000 ft southeast of the quarry was analyzed; there was no indication of contamination from the quarry. Additional water quality and water level data are needed to determine if water from the quarry moves toward the well field. Observation wells need to be installed in the area between the chemical plant, pits, and Dardenne Creek. The wells would be used to provide access for measurements of depth to ground water and for the collection of water samples from the shallow bedrock aquifer.

Missouri↗