USGS Science⌕ Search

Geology topics

M. E. Brigham

Publications and source records attributed to M. E. Brigham.

16 recordsLinked to original sources
USGS2012

Landscape controls on total and methyl Hg in the Upper Hudson River basin, New York, USA

Approaches are needed to better predict spatial variation in riverine Hg concentrations across heterogeneous landscapes that include mountains, wetlands, and open waters. We applied multivariate linear regression to determine the landscape factors and chemical variables that best account for the spatial variation of total Hg (THg) and methyl Hg (MeHg) concentrations in 27 sub-basins across the 493 km 2 upper Hudson River basin in the Adirondack Mountains of New York. THg concentrations varied by sixfold, and those of MeHg by 40-fold in synoptic samples collected at low-to-moderate flow, during spring and summer of 2006 and 2008. Bivariate linear regression relations of THg and MeHg concentrations with either percent wetland area or DOC concentrations were significant but could account for only about 1/3 of the variation in these Hg forms in summer. In contrast, multivariate linear regression relations that included metrics of (1) hydrogeomorphology, (2) riparian/wetland area, and (3) open water, explained about 66% to >90% of spatial variation in each Hg form in spring and summer samples. These metrics reflect the influence of basin morphometry and riparian soils on Hg source and transport, and the role of open water as a Hg sink. Multivariate models based solely on these landscape metrics generally accounted for as much or more of the variation in Hg concentrations than models based on chemical and physical metrics, and show great promise for identifying waters with expected high Hg concentrations in the Adirondack region and similar glaciated riverine ecosystems.

New York↗
USGS2012

Characterizing mercury concentrations and fluxes in a Coastal Plain watershed: Insights from dynamic modeling and data

Mercury (Hg) is one of the leading water quality concerns in surface waters of the United States. Although watershed-scale Hg cycling research has increased in the past two decades, advances in modeling watershed Hg processes in diverse physiographic regions, spatial scales, and land cover types are needed. The goal of this study was to assess Hg cycling in a Coastal Plain system using concentrations and fluxes estimated by multiple watershed-scale models with distinct mathematical frameworks reflecting different system dynamics. We simulated total mercury (Hg T , the sum of filtered and particulate forms) concentrations and fluxes from a Coastal Plain watershed (McTier Creek) using three watershed Hg models and an empirical load model. Model output was compared with observed in-stream Hg T . We found that shallow subsurface flow is a potentially important transport mechanism of particulate Hg T during periods when connectivity between the uplands and surface waters is maximized. Other processes (e.g., stream bank erosion, sediment re-suspension) may increase particulate Hg T in the water column. Simulations and data suggest that variable source area (VSA) flow and lack of rainfall interactions with surface soil horizons result in increased dissolved Hg T concentrations unrelated to DOC mobilization following precipitation events. Although flushing of DOC-Hg T complexes from surface soils can also occur during this period, DOC-complexed Hg T becomes more important during base flow conditions. TOPLOAD simulations highlight saturated subsurface flow as a primary driver of daily Hg T loadings, but shallow subsurface flow is important for Hg T loads during high-flow events. Results suggest limited seasonal trends in Hg T dynamics.

South Carolina↗
USGS2010

Mercury trends in fish from rivers and lakes in the United States, 1969-2005

A national dataset on concentrations of mercury in fish, compiled mainly from state and federal monitoring programs, was used to evaluate trends in mercury (Hg) in fish from US rivers and lakes. Trends were analyzed on data aggregated by site and by state, using samples of the same fish species and tissue type, and using fish of similar lengths. Site-based trends were evaluated from 1969 to 2005, but focused on a subset of the data from 1969 to 1987. Data aggregated by state were used to evaluate trends in fish Hg concentrations from 1988 to 2005. In addition, the most recent Hg fish data (1996–2005) were compared to wet Hg deposition data from the Mercury Deposition Network (MDN) over the same period. Downward trends in Hg concentrations in fish from data collected during 1969–1987 exceeded upward trends by a ratio of 6 to 1. Declining Hg accumulation rates in sediment and peat cores reported by many studies during the 1970s and 1980s correspond with the period when the most downward trends in fish Hg concentrations occurred. Downward Hg trends in both sediment cores and fish were also consistent with the implementation of stricter regulatory controls of direct releases of Hg to the atmosphere and surface waters during the same period. The southeastern USA had more upward Hg trends in fish than other regions for both site and state aggregated data. Upward Hg trends in fish from the southeastern USA were associated with increases in wet deposition in the region and may be attributed to a greater influence of global atmospheric Hg emissions in the southeastern USA. No significant trends were found in 62% of the fish species from six states from 1996 to 2005. A lack of Hg trends in fish in the more recent data was consistent with the lack of trends in wet Hg deposition at MDN sites and with relatively constant global emissions during the same time period. Although few significant trends were observed in the more recent Hg concentrations in fish, it is anticipated that Hg concentrations in fish will respond to changes in atmospheric Hg deposition, however, the magnitude and timing of the response is uncertain.

Environmental Monitoring and Assessment↗
USGS2009

Mercury cycling in stream ecosystems. 1. Water column chemistry and transport

We studied total mercury (THg) and methylmercury (MeHg) in eight streams, located in Oregon, Wisconsin, and Florida, that span large ranges in climate, landscape characteristics, atmospheric Hg deposition, and water chemistry. While atmospheric deposition was the source of Hg at each site, basin characteristics appeared to mediate this source by providing controls on methylation and fluvial THg and MeHg transport. Instantaneous concentrations of filtered total mercury (FTHg) and filtered methylmercury (FMeHg) exhibited strong positive correlations with both dissolved organic carbon (DOC) concentrations and streamflow for most streams, whereas mean FTHg and FMeHg concentrations were correlated with wetland density of the basins. For all streams combined, whole water concentrations (sum of filtered and particulate forms) of THg and MeHg correlated strongly with DOC and suspended sediment concentrations in the water column.

Environmental Science & Technology↗
USGS2006

Mercury in soils, lakes, and fish in Voyageurs National Park (Minnesota): Importance of atmospheric deposition and ecosystem factors

Concentrations of methylmercury in game fish from many interior lakes in Voyageurs National Park (MN, U.S.A.) substantially exceed criteria for the protection of human health. We assessed the importance of atmospheric and geologic sources of mercury to interior lakes and watersheds within the Park and identified ecosystem factors associated with variation in methylmercury contamination of lacustrine food webs. Geologic sources of mercury were small, based on analyses of underlying bedrock and C-horizon soils, and nearly all mercury in the O- and A-horizon soils was derived from atmospheric deposition. Analyses of dated sediment cores from five lakes showed that most (63% ?? 13%) of the mercury accumulated in lake sediments during the 1900s was from anthropogenic sources. Contamination of food webs was assessed by analysis of whole, 1-year-old yellow perch (Perca flavescens), a regionally important prey fish. The concentrations of total mercury in yellow perch and of methylmercury in lake water varied substantially among lakes, reflecting the influence of ecosystem processes and variables that affect the microbial production and abundance of methylmercury. Models developed with the information-theoretic approach (Akaike Information Criteria) identified lake water pH, dissolved sulfate, and total organic carbon (an indicator of wetland influence) as factors influencing methylmercury concentrations in lake water and fish. We conclude that nearly all of the mercury in fish in this seemingly pristine landscape was derived from atmospheric deposition, that most of this bioaccumulated mercury was from anthropogenic sources, and that both watershed and lacustrine factors exert important controls on the bioaccumulation of methylmercury. ?? 2006 American Chemical Society.

Environmental Science & Technology↗
USGS2002

Methylmercury in flood-control impoundments and natural waters of northwestern Minnesota, 1997-99

We studied methylmercury (MeHg) and total mercury (HgT) in impounded and natural surface waters in northwestern Minnesota, in settings ranging from agricultural to undeveloped. In a recently constructed (1995) permanent-pool impoundment, MeHg levels typically increased from inflow to outflow during 1997; this trend broke down from late 1998 to early 1999. MeHg levels in the outflow reached seasonal maxima in mid-summer (maximum of 1.0 ng L −1 in July 1997) and late-winter (maximum of 6.6 ng L −1 in February 1999), and are comparable to high levels observed in new hydroelectric reservoirs in Canada. Spring and autumn MeHg levels were typically about 0.1–0.2 ng L −1 . Overall, MeHg levels in both the inflow (a ditch that drains peatlands) and outflow were significantly higher than in three nearby reference natural lakes. Eleven older permanent-pool impoundments and six natural lakes in northwestern Minnesota were sampled five times. The impoundments typically had higher MeHg levels (0.071–8.36 ng L −1 ) than natural lakes. Five of six lakes MeHg levels typical of uncontaminated lakes (0.014–1.04 ng L −1 ) with highest levels in late winter, whereas a hypereutrophic lake had high levels (0.37–3.67 ng L −1 ) with highest levels in mid-summer. Seven temporary-pool impoundments were sampled during summer high-flow events. Temporary-pool impoundments that retained water for about 10–15 days after innundation yielded pronounced increases in MeHg from inflow to outflow, in one case reaching 4.6 ng L −1 , which was about 2 ng L −1 greater than the mean inflow concentration during the runoff event.

Minnesota↗
USGS1998

Water quality in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1992-95

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the River River of the North basin study unit and to relate these findings to water-quality issues of regional and national concern. The information in primarily intended for those who are involved in water-resource management. Yet the information contained here may also interest those who simply wish to know more about the quality of water in the rivers and aquifers in the area where they live.

Circular↗
USGS1998

Trace elements and organic chemicals in stream-bottom sediments and fish tissues, Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1992-95

Stream-bottom sediment and fish-tissue samples from the Red River of the North Basin, were analyzed for a large suite of chemical elements and organic chemicals. Cadmium, lead, and mercury were widespread in sediments, at concentrations not indicative of acute contamination. Mercury, the element of greatest health concern in the region, was detected at low concentrations in 38 of 43 sediment samples (<0.02-0.13 micrograms per gram) and all of eleven fish-liver samples (0.03-0.6 micrograms per gram dry weight, or 0.0066-0.13 micrograms per gram wet weight). Concentrations of many elements appeared to be controlled by mineral rather than anthropogenic sources. DDT and its metabolites were the most frequently detected synthetic organochlorines: p , p '-DDE was detected in 9 of 38 sediment samples (concentration range: <1-16 nanograms per gram) and also frequently in whole-fish samples. Total DDT (the sum of DDT and its metabolites) concentrations ranged from <5 to 217 nanograms per gram, and at least one component of total DDT was detected in 19 of 23 fish samples. Concentrations of DDT and its metabolites in stream sediments were significantly higher in the intensively cropped Red River Valley Lake Plain, compared to upland areas, probably because of greater historical DDT usage in the lake plain. Several polycyclic aromatic hydrocarbons were detected in stream-bottom sediments. Although the potentially toxic chemicals measured in this study were at low levels, relative to more contaminated areas of the Nation, maximum concentrations of some chemicals are of concern because of their possible effects on aquatic biota and human health.

Minnesota, North Dakota, South Dakota↗
USGS1997

Ground-water sampling methods and quality-control data for the Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1993-95

Ground-water-quality samples were collected for the intensive data-collection phase of the Red River of the P Torth Basin study unit, one of 60 study units of the National Water Quality Assessment (NAWQA) Program throughout the United States. The sampling protocols used were designed for the NAWQA Program. The protocols include sampling equipment, cleaning procedures, sample-collection methods, and quality-control plans to monitor the accuracy of the data collected. One of the goals of the NAWQA Program was to collect data using similar methcds to build a nationally consistent water-quality data base. Quality-control data demonstrated that most constituents measured for this study yielded reproducible data, with low to undetectable contamination from the sampling and analytical procedures. Several constituents were occasionally or frequently detected in blank samples at levels similar to low-concentration ground-water-quality samples. For example, iron was detected in 75 percent of the blank samples, with a maximum concentration of 27 [ig/L, indicating that iron contamination may interfere with its determination at low levels in ground waters. Copper, aluminum, and dissolved organic carbon concentrations in blank samples overlap those determined in ground-waterquality samples, thereby precluding quantitative reporting of those constituents. Most pesticide data are reproducible, with minimal bias. Some pesticides had low but consistent recoveries; these data may be useful if spike and surrogate data are carefully considered. Data for some pesticides measured in this study should not be quantitatively reported or used, because they may underestimate the concentrations of those pesticides in ground waters.

Minnesota, North Dakota, South Dakota↗
USGS1997

Nutrients, suspended sediment, and pesticides in streams in the Red River of the North basin, Minnesota, North Dakota, and South Dakota, 1993-95

Fifteen stream sites in the Red River of the North Basin were sampled during 1993-95 to assess levels of nutrients, organic carbon, and suspended sediment, and five sites were sampled for pesticides. Concentrations varied seasonally and were related to periods of fertilizer and pesticide application, and to runoff. Concentrations of several constituents were related to the physiographic area the stream drains, but other factors such as local land use frequently complicated that relation. Median dissolved nitrogen concentrations were highest in streams influenced by the Red River Valley Lake Plain physiographic area. Organic nitrogen comprised the largest part of the dissolved nitrogen in streams. Ammonia was negligible most of the year, but accumulated under ice in late winter. Nitrate concentrations generally were highest during snowmelt and rainfall runoff. Phosphorus in streams mostly was in the dissolved form, which is readily available to biota. Streams draining the Moraine and Lake-Washed Till Plain had the lowest concentrations of total phosphorus, while Drift Prairie and Red River Valley Lake Plain streams had the highest concentrations. Concentrations of both dissolved and suspended phosphorus increased substantially during runoff of snowmelt and rainfall. The Bois de Sioux River Basin had the highest nitrogen yield. High nitrogen and phosphorus yields probably were related to agricultural practices in the Bois de Sioux River Basin. High phosphorus concentrations in the Pembina River probably result from agricultural practices and runoff from the steep terrain in the basin. Improved wastewater treatment appears to have reduced ammonia concentrations in streams, but has resulted in increased nitrate concentrations. The loads of nitrogen and phosphorus in the Red River of the North during this study were about twice as high as historical loads, but still were only about 4.1 and 2.4 percent, respectively, of the amounts introduced to the study unit. Dissolved organic carbon concentrations above 15 mg/L were common in streams draining peatlands. Suspended organic carbon concentrations were highly variable and generally were highest during runoff. Most suspended sediment in streams was clay and silt sized particles. The Pembina River had the highest concentrations and yields of suspended sediment, probably the result of erosion along this relatively high-gradient stream. Streams having an abundance of lakes, reservoirs, and wetlands in their watersheds had the lowest sediment concentrations and yields. Several pesticides were frequently detected. Atrazine and other triazine compounds were detected in most stream-water samples throughout the study. Concentrations of triazine herbicides were highest in streams draining southern parts of the study unit where they are applied to corn. Triallate was commonly detected in northern streams where it is applied to small grains and sunflowers. Simazine and prometon were commonly detected, but generally are used only for nonagricultural purposes. Few insecticides were detected in stream-water samples. Carbofuran was the most commonly detected insecticide and was found in 16 percent of the samples. The most heavily used herbicides, 2,4-D and MCPA, were infrequently detected in stream-water samples. Of the estimated applications of atrazine, triallate, and 2,4-D, about 0.9, 0.06, and 0.02 percent of each of these compounds, respectively, was carried out of the study unit by the Red River of the North during 1993-95.

Minnesota, North Dakota, South Dakota↗
USGS1996

Trace elements and organic contaminants in stream sediments from the Red River of the North Basin

To assess the presence and distribution of a variety of hydro-phobic chemicals in streams in the Red River of the North Basin, bottom sediments were analyzed for trace elements, organochlorines, and polycyclic aromatic hydrocarbons (PAHs). Glaciolacustrine clays and carbonate minerals are common in fine sediments of the region, and can help explain the distribution of many elements. Aluminum (Al), an indicator of glaciolacustrine clay minerals, correlates strongly (r>0.75, p<0.05) with Cr, Co, Fe, La, Li, K, Sc, and Ti; and moderately (0.55<r<0.75) with Ce, Cu, Ga, Nd, Ni, Th, V, and Y. Excluding the tributary Pembina River Basin, Eu, Nb, Ce, La, Nd, and Ni also have strong correlations with Al. Al correlates negatively with major elements associated with carbonate minerals (Ca, Mg, and inorganic carbon). No significant correlations with Al, Ca, or Mg were observed for As, Pb, Mn, Hg, Se, or Ag, which implies that these elements have different environmental sources or behaviors than glaciolacustrine clays or carbonate minerals. Reduction-oxidation processes may influence Mn distribution. Lead (Pb) and mercury (Hg) are known to be anthropogenically enriched in the environment--their distribution may indicate environmental enrichment in Red River of the North Basin streams. Organochlorines detected are limited to traces of DDT and its metabolites (mostlyp,p'-DDE). Fourteen PAHs, which are constituents of fossil fuels and of combustion byproducts, were detected in at least halfthe sediment samples; pyrene and fluoranthene were detected in about 90 percent of samples. The contaminants detected in this study were present at low levels, likely indicative of diffuse or remote sources; they occur widely in the environment.

Minnesota, North Dakota, South Dakota↗
USGS1994

Nutrients, suspended sediment, and pesticides in waters of the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-90

Available data on nutrients (phosphorus and nitrogen), suspended sediment, and pesticides in the Red River of the North Basin, a study unit under the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, are reviewed. These data were collected by several agencies during 1970-90. Nutrient concentrations in surface water are higher downgradient from agricultural and urban areas than in other areas, but generally do not exceed U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Levels (MCLs). The 10 milligram per liter (mg/L) drinking water MCL for nitrate (as nitrogen) was rarely exceeded. Some of the largest nutrient inputs to the surface-water system appear to come from the Fargo-Moorhead area. The highest nitrogen concentrations usually were found in the Red River of the North. Nitrogen composition was mostly organic nitrogen with some nitrate. Ammonia nitrogen was negligible except during mid-winter, when concentrations could exceed 1.0 mg/L. Streams draining the corn-dominated cropland in the southern part of the basin had relatively high nitrogen concentrations compared to parts of the basin where small-grain crops, forests, and wetlands predominate. The Pembina River in the northern part of the basin had a large range in nitrogen concentrations that often exceeded those in the Red River of the North. The highest phosphorus concentrations generally were found in of the Red River of the North, although tributary streams occasionally had peak concentrations that exceeded those in the Red River of the North. Median nitrate concentrations in ground water were less than 1.0 mg/L as nitrogen in all counties in the basin except in Otter Tail and Decker Counties in Minnesota. Half of the wells in Otter Tail County had nitrate-nitrogen concentrations exceeding 2.8 mg/L. Shallow, surficial aquifers tended to have the highest nitrate concentrations. Median suspended-sediment concentrations were less than 100 mg/L except in the Red River of the North near the Canadian border at Emerson, Manitoba and the Pembina River. The Pembina River occasionally had high suspended sediment concentrations; about 10 percent of the samples exceeded 2,000 mg/L. For both surface and ground water, available pesticide data were limited in spatial and temporal coverage. The majority of pesticide analyses for the Red River of the North Basin show no concentrations above laboratory reporting limits. Reported concentrations usually were below USEPA MCLs. Only a few analyses of pesticides in ground water had concentrations above laboratory reporting limits. Wells that had reportable levels are mainly in the southern and southeastern part of the basin, where atrazine was the most commonly detected pesticide. A relatively large fraction of stream samples had detectable quantities of 2,4-D, a- and y-HCH, and atrazine. These samples covered time spans of as much as 15 years and were from sites downstream from large drainage basins; however, concentrations were well below US EPA MCLs. One county-level study showed higher 2,4-D concentrations at upstream sites than at the outlet from a small basin. This indicates that downstream sites may fail to show impaired water-quality and the fate of pesticides used in the basin. Following the 1972 ban on DDT, concentrations of DDT in fish samples from the Red River of the North quickly decreased. Fish concentrations of DDE and DDD decreased more slowly. Low levels of DDE and DDD were detected in fish 14 years after the DDT ban.

Minnesota, North Dakota, South Dakota↗