Geology topics

M. Caffee

Publications and source records attributed to M. Caffee.

5 recordsLinked to original sources

USGS2009

Chlorine-36 as a tracer of perchlorate origin

Perchlorate (ClO 4 − ) is ubiquitous in the environment. It is produced naturally by atmospheric photochemical reactions, and also is synthesized in large quantities for military, aerospace, and industrial applications. Nitrate-enriched salt deposits of the Atacama Desert (Chile) contain high concentrations of natural ClO 4 − , and have been exported worldwide since the mid-1800s for use in agriculture. The widespread introduction of synthetic and agricultural ClO 4 − into the environment has contaminated numerous municipal water supplies. Stable isotope ratio measurements of Cl and O have been applied for discrimination of different ClO 4 − sources in the environment. This study explores the potential of 36 Cl measurements for further improving the discrimination of ClO 4 − sources. Groundwater and desert soil samples from the southwestern United States (U.S.) contain ClO 4 − having high 36 Cl abundances ( 36 Cl/Cl = 3100 × 10 −15 to 28,800 × 10 −15 ), compared with those from the Atacama Desert ( 36 Cl/Cl = 0.9 × 10 −15 to 590 × 10 −15 ) and synthetic ClO 4 − reagents and products ( 36 Cl/Cl = 0.0 × 10 −15 to 40 × 10 −15 ). In conjunction with stable Cl and O isotope ratios, 36 Cl data provide a clear distinction among three principal ClO 4 − source types in the environment of the southwestern U.S.

Environmental Science & Technology↗

USGS2003

Temporally and spatially uniform rates of erosion in the southern Appalachian Great Smoky Mountains

We measured 10 Be in fluvial sediment samples ( n = 27) from eight Great Smoky Mountain drainages (1–330 km 2 ). Results suggest spatially homogeneous sediment generation (on the 10 4 –10 5 yr time scale and >100 km 2 spatial scale) at 73 ± 11 t km −2 yr −1 , equivalent to 27 ± 4 m/m.y. of bedrock erosion. This rate is consistent with rates derived from fission-track, long-term sediment budget, and sediment yield data, all of which indicate that the Great Smoky Mountains and the southern Appalachians eroded during the Mesozoic and Cenozoic at ∼30 m/m.y. In contrast, unroofing rates during the Paleozoic orogenic events that formed the Appalachian Mountains were higher (≥10 2 m/m.y.). Erosion rates decreased after termination of tectonically driven uplift, enabling the survival of this ancient mountain belt with its deep crustal root as an isostatically maintained feature in the contemporary landscape.

Tennessee, North Carolina↗

USGS2003

Erosion of an ancient mountain range, the Great Smoky Mountains, North Carolina and Tennessee

Analysis of 10 Be and 26 Al in bedrock (n=10), colluvium (n=5 including grain size splits), and alluvial sediments (n=59 including grain size splits), coupled with field observations and GIS analysis, suggest that erosion rates in the Great Smoky Mountains are controlled by subsurface bedrock erosion and diffusive slope processes. The results indicate rapid alluvial transport, minimal alluvial storage, and suggest that most of the cosmogenic nuclide inventory in sediments is accumulated while they are eroding from bedrock and traveling down hill slopes. Spatially homogeneous erosion rates of 25 - 30 mm Ky −1 are calculated throughout the Great Smoky Mountains using measured concentrations of cosmogenic 10 Be and 26 Al in quartz separated from alluvial sediment. 10 Be and 26 Al concentrations in sediments collected from headwater tributaries that have no upstream samples (n=18) are consistent with an average erosion rate of 28 ± 8 mm Ky −1 , similar to that of the outlet rivers (n=16, 24 ± 6 mm Ky −1 ), which carry most of the sediment out of the mountain range. Grain-size-specific analysis of 6 alluvial sediment samples shows higher nuclide concentrations in smaller grain sizes than in larger ones. The difference in concentrations arises from the large elevation distribution of the source of the smaller grains compared with the narrow and relatively low source elevation of the large grains. Large sandstone clasts disaggregate into sand-size grains rapidly during weathering and downslope transport; thus, only clasts from the lower parts of slopes reach the streams. 26 Al/ 10 Be ratios do not suggest significant burial periods for our samples. However, alluvial samples have lower 26 Al/ 10 Be ratios than bedrock and colluvial samples, a trend consistent with a longer integrated cosmic ray exposure history that includes periods of burial during down-slope transport. The results confirm some of the basic ideas embedded in Davis’ geographic cycle model, such as the reduction of relief through slope processes, and of Hack’s dynamic equilibrium model such as the similarity of erosion rates across different lithologies. Comparing cosmogenic nuclide data with other measured and calculated erosion rates for the Appalachians, we conclude that rates of erosion, integrated over varying time periods from decades to a hundred million years are similar, the result of equilibrium between erosion and isostatic uplift in the southern Appalachian Mountains.

Tennessee, North Carolina↗

USGS2000

Early Agriculture in the eastern Grand Canyon of Arizona, USA

Abandoned fields in Colorado River alluvium in the eastern Grand Canyon show signs of primitive agriculture. Presence of maize pollen in association with buried soils near Comanche Creek suggests that farming began prior to 3130 yr B.P. Cotton pollen, identified in buried soils near Nankoweap Creek, dates to 1310 yr B.P., approximately 500 years earlier than previously reported anywhere on the Colorado Plateau. Farming spanned three millennia in this reach of the canyon. Entrenchment, starting approximately 700 yr B.P., making water diversion to fields infeasible, was likely responsible for field abandonment.

Arizona↗

USGS1999

Mid-Pleistocene cosmogenic minimum-age limits for pre-Wisconsinan glacial surfaces in southwestern Minnesota and southern Baffin Island: A multiple nuclide approach

Paired 10Be and 26Al analyses (n = 14) indicate that pre-Wisconsinan, glaciated bedrock surfaces near the northern (Baffin Island) and southern (Minnesota) paleo-margins of the Laurentide Ice Sheet have long and complex histories of cosmic-ray exposure, including significant periods of partial or complete shielding from cosmic rays. Using the ratio, 26Al/10Be, we calculate that striated outcrops of Sioux Quartzite in southwestern Minnesota (southern margin) were last overrun by ice at least 500,000 years ago. Weathered bedrock tors on the once-glaciated uplands of Baffin Island (northern margin) are eroding no faster than 1.1 m Myr-1, the equivalent of at least 450,000 years of surface and near-surface exposure. Our data demonstrate that exposure ages and erosion rates calculated from single nuclides can underestimate surface stability dramatically because any intermittent burial, and the resultant lowering of nuclide production rates and nuclide abundances, will remain undetected.

Geomorphology↗