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Larry L. Jackson

Publications and source records attributed to Larry L. Jackson.

5 recordsLinked to original sources

Alternate drop pulse polarography

The new technique of alternate drop pulse polarography is presented. An experimental evaluation of alternate drop pulse polarography shows complete compensation of the capacitative background due to drop expansion. The capillary response phenomenon was studied in the absence of faradaic reaction and the capillary response current was found to depend on the pulse width to the -0.72 power. Increased signal-to-noise ratios were obtained using alternate drop pulse polarography at shorter drop times.

Analytical Chemistry↗

Constant potential pulse polarography

The new technique of constant potential pulse polarography, In which all pulses are to be the same potential, is presented theoretically and evaluated experimentally. The response obtained is in the form of a faradaic current wave superimposed on a constant capacitative component. Results obtained with a computer-controlled system exhibit a capillary response current similar to that observed In normal pulse polarography. Calibration curves for Pb obtained using a modified commercial pulse polarographic instrument are in good accord with theoretical predictions.

Analytical Chemistry↗

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

Circular↗

Hydrological, geomorphological, and chemical effects of Hurricane Andrew on coastal marshes of Louisiana

Hydrological conditions are reported for the hurricane-induced storm surge at marsh sites in Terrebonne and Barataria Basins. There was a 6 hour or greater delay in the arrival of the storm surge at interior marsh sites compared to coastal locations. A water surge of about 1.5 m with a salinity of 10–15‰ was recorded at an intermediate salinity marsh site in Terrebonne Basin where significant geomorphological changes occurred with lateral movement and stacking of marsh vegetation and sediment, erosion, and the conversion of wetlands to open water. A residual salt wedge attributed to the storm surge was detected in sediments at this intermediate marsh site about 55 days after the hurricane. In the pore water, at 30 cm in depth, there were increases in alkalinity, ammonia, phosphate, and manganese, but not iron or sulfide, although there was a significant depletion of sulfur with respect to chloride. The increases in concentration of these species in the pore water suggests that there was an increase in organic matter decomposition. Although increases in sulfide phytotoxicity were not obvious, the residual salinity of pore water may influence wetland loss through longer-term impacts on macrophyte production. Storm-induced sediment deposition, which will help ameliorate wetland loss, was observed at a salt marsh site in Terrebonne Basin.

Louisiana↗