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Lan H. Tornes

Publications and source records attributed to Lan H. Tornes.

4 recordsLinked to original sources

Anthropogenic organic compounds in ground water and finished water of community water systems in the Greater Twin Cities metropolitan area, Minnesota and Wisconsin, 2004–05

As part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program, two Source Water-Quality Assessments (SWQAs) were conducted during 2004–05 in unconfined parts of the glacial aquifer system and in unconfined parts of the Prairie du Chien-Jordan aquifer in the Greater Twin Cities metropolitan area of Minnesota and Wisconsin. SWQAs are two-phased sampling activities in the NAWQA Program. The first phase evaluated the occurrence of 265 (258 are included in this report) anthropogenic organic compounds (AOCs) through monitoring source water in 30 of the largest-producing community water system wells completed in the aquifers underlying the Greater Twin Cities metropolitan area. The AOCs included volatile organic compounds (VOCs), pesticides, and other AOCs. During the second phase of the study, 15 of the original community water system wells, those with the greatest number of AOC detections, were resampled along with associated finished water. Results from the first phase of sampling indicated that 40 AOCs were detected, and 83 percent of the samples had at least one detected AOC. Concentrations of AOCs detected in the source water generally were low (defined in this report as concentrations less than 1.0 microgram per liter). Human-health benchmarks for these compounds (Maximum Contaminant Levels for regulated compounds or Health-Based Screening Levels for unregulated compounds, when they existed) typically were not exceeded. Fifteen VOCs were detected in the source-water samples. However, concentrations were low. Seventeen pesticide compounds were detected generally at concentrations less than concentrations for VOCs. Most of the pesticide compounds detected were triazine- or alachlor-parent compounds or their breakdown products. Eight other AOCs were detected in the source-water samples but generally at low concentrations. Results from the second phase of sampling indicated a total of 13 and 12 VOCs were detected in source-water and in finished-water samples, respectively. Most of the VOCs, except for those associated with disinfection by-products, were detected more frequently in source-water samples than in finished- water samples. Concentrations of most VOCs detected in either source water or finished water were less than human-health benchmarks. Twenty-one pesticide compounds were detected in either source water or finished water. Concentrations of detected pesticides in source-water and finished-water samples were low. The most frequently detected compounds in both the source and finished water were triazine-parent pesticides or their breakdown products and breakdown products of alachlor and metolachlor. In general, pesticides, if detected in source water, also were detected in the corresponding finished water. Concentrations of pesticides detected were less than human-health benchmarks in both source and finished water. A total of nine other AOCs were detected in the source-water or finished-water samples, and about the same number of compounds was detected in each of the sample groups in either source water or finished water. Detected concentrations of other AOCs were low. Water-quality results from source-water samples were compared to characterize differences between aquifers. VOC and other AOC detections were more frequent in water from the Prairie du Chien-Jordan aquifer compared to the glacial aquifer. Pesticides, however, were detected more frequently in the glacial aquifer. On the basis of study results, the hydrogeologic setting, land use, and aquifer productivity are important in explaining the occurrence of AOCs in community water system wells. Results of this study indicate that monitoring for pesticides in source water generally indicates the potential occurrence of pesticides in finished water but that this is not necessarily true of VOCs. Additional monitoring is needed to better understand the occurrence of other AOCs in source and finished waters.

Minnesota, Wisconsin

Water quality of streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

Data for the Red River of the North (Red River) Basin in Minnesota, North Dakota, and South Dakota were analyzed to determine whether the water quality of streams in the basin is adequate to meet future needs. For the Red River at Emerson, Manitoba, site, pH values, water temperatures, and dissolved-oxygen concentrations generally were within the criteria established for the protection of aquatic life. Dissolved-solids concentrations ranged from 245 to 1,100 milligrams per liter. Maximum sulfate and chloride concentrations were near, but did not exceed, the established secondary maximum contaminant level. The trace elements considered potentially harmful generally were at concentrations that were less than the established guidelines, standards, and criteria. The concentrations of lead that were detected may have occurred as a result of sample contamination. For the Red River upstream from Emerson, Manitoba, sites, pH and other field values rarely exceeded the criteria established for the protection of aquatic life. Many constituent concentrations for the Red River below Fargo, N. site exceeded water-quality guidelines, standards, and criteria. However, the trace-element exceedances could be natural or could be related to pollution or sample contamination. Many of the tributaries in the western part of the Red River Basin had median specific-conductance values that were greater than 1,000 microsiemens per centimeter. Sulfate concentrations occasionally exceeded the established drinking-water standard. Median arsenic concentrations were 6 micrograms per liter or less, and maximum concentrations rarely exceeded the 10-microgram-per-liter drinking-water standard that is scheduled to take effect in 2006. The small concentrations of lead, mercury, and selenium that occasionally were detected may have been a result of sample contamination or other factors. The tributaries in the eastern part of the Red River Basin had median specific-conductance values that were less than 1,000 microsiemens per centimeter. Concentrations of pesticides that were detected and that had regulatory limits were less than the cited water-quality guidelines, standards, and criteria. Concentrations of compounds that were detected generally were less than the sediment- quality standards and criteria. The data considered in this report generally provide a good baseline from which to evaluate changes in water-quality conditions. However, because many of the trace elements detected, including lead and mercury, may have been the result of sample contamination, additional data are needed to confirm that trace-element concentrations generally are low. Concentrations of major ions, including sulfate, and specific conductance may continue to approach drinking-water standards during periods of low flow because the streams, particularly those in the western part of the basin, are sustained mostly by ground-water discharge that generally has large dissolved-solids concentrations.

Scientific Investigations Report

Effects of rain gardens on the quality of water in the Minneapolis-St. Paul metropolitan area of Minnesota, 2002-04

Rain gardens are a popular method of managing runoff while attempting to provide aesthetic and environmental benefits. Five rain-garden sites in the Minneapolis – Saint Paul metropolitan area of Minnesota were instrumented to evaluate the effects of this water-management system on surface and subsurface water quality. Most of these sites were in suburban locations and frequently in newer developments. Because of this they were affected by changing hydrology during the course of this study. Less-than-normal precipitation during much of the study may have resulted in samples that may not be representative of normal conditions. However, the resulting data indicate that properly designed rain gardens enhance infiltration and can reduce concentrations of dissolved ions relative to background conditions. The runoff events in one rain garden and several runoff events in the other rain gardens produced no sampled overflow during this study because the gardens captured all of the inflow, which subsequently infiltrated beneath the land surface, evaporated, or transpired through garden vegetation. Where measured, overflow had reduced concentrations of suspended solids and most nutrient species associated with particulate material, as compared to inflow. Many of these materials settle to the bottom of the rain garden, and some nutrients may be assimilated by the plant community. Site design, including capacity relative to drainage area and soil permeability, is an important consideration in the efficiency of rain-garden operation. Vegetation type likely affects the infiltration capacity, nutrient uptake, and evapotranspiration of a rain garden and probably the resulting water quality. The long-term efficiency of rain gardens is difficult to determine from the results of this study because most are still evolving and maturing in relation to their hydrologic, biologic, and chemical setting. Many resource managers have questioned what long-term maintenance will be needed to keep rain gardens operating effectively. Additional or continued studies could address many of these concerns.

Minnesota

Using chemical, hydrologic, and age dating analysis to delineate redox processes and flow paths in the riparian zone of a glacial outwash aquifer‐stream system

A combination of chemical and dissolved gas analyses, chlorofluorocarbon age dating, and hydrologic measurements were used to determine the degree to which biogeochemical processes in a riparian wetland were responsible for removing NO 3 − from groundwaters discharging to the Otter Tail River in west central Minnesota. An analysis of river chemistry and flow data revealed that NO 3 − concentrations in the river increased in the lower half of the 8.3 km study reach as the result of groundwater discharge to the river. Groundwater head measurements along a study transect through the riparian wetland revealed a zone of groundwater discharge extending out under the river. On the basis of combined chemical, dissolved gas, age date, and hydrologic results, it was determined that water chemistry under the riparian wetland was controlled largely by upgradient groundwaters that followed flow paths up to 16 m deep and discharged under the wetland, creating a pattern of progressively older, more chemically reduced, low NO 3 − water the farther one progressed from the edge of the wetland toward the river. These findings pose challenges for researchers investigating biogeochemical processes in riparian buffer zones because the progressively older groundwaters entered the aquifer in earlier years when less NO 3 − fertilizer was being used. NO 3 − concentrations originally present in the groundwater had also decreased in the upgradient aquifer as a result of denitrification and progressively stronger reducing conditions there. The resulting pattern of decreasing NO 3 − concentrations across the riparian zone may be incorrectly interpreted as evidence of denitrification losses there instead of in the upgradient aquifer. Consequently, it is important to understand the hydrogeologic setting and age structure of the groundwaters being sampled in order to avoid misinterpreting biogeochemical processes in riparian zones.

Water Resources Research