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Kent A. Elrick

Publications and source records attributed to Kent A. Elrick.

8 recordsLinked to original sources
USGS2013

Influence of estuarine processes on spatiotemporal variation in bioavailable selenium

Dynamic processes (physical, chemical and biological) challenge our ability to quantify and manage the ecological risk of chemical contaminants in estuarine environments. Selenium (Se) bioavailability (defined by bioaccumulation), stable isotopes and molar carbon-tonitrogen ratios in the benthic clam Potamocorbula amurensis, an important food source for predators, were determined monthly for 17 yr in northern San Francisco Bay. Se concentrations in the clams ranged from a low of 2 to a high of 22 μg g -1 over space and time. Little of that variability was stochastic, however. Statistical analyses and preliminary hydrodynamic modeling showed that a constant mid-estuarine input of Se, which was dispersed up- and down-estuary by tidal currents, explained the general spatial patterns in accumulated Se among stations. Regression of Se bioavailability against river inflows suggested that processes driven by inflows were the primary driver of seasonal variability. River inflow also appeared to explain interannual variability but within the range of Se enrichment established at each station by source inputs. Evaluation of risks from Se contamination in estuaries requires the consideration of spatial and temporal variability on multiple scales and of the processes that drive that variability.

Marine Ecology Progress Series↗
USGS2012

Concentrations and annual fluxes of sediment-associated chemical constituents from conterminous US coastal rivers using bed sediment data

Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment-associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment-associated chemical constituent concentrations for (1) baseline, (2) land-use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment-associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment-associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges:Atlantic rivers (49%)>Pacific rivers (40%)>Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources. Almost all the elevated sediment-associated chemical concentrations found in conterminous US coastal rivers are lower than worldwide averages.

Hydrological Processes↗
USGS2012

Annual fluxes of sediment-associated trace/major elements, carbon, nutrients, and sulfur from US coastal rivers

About 260–270 Mt of suspended sediment are discharged annually from the conterminous USA; approximately 69% derives from Gulf rivers (n = 36), 24% from Pacific rivers (n = 42), and 7% from Atlantic rivers (n = 54). Elevated sediment-associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges: Atlantic rivers (49%) > Pacific rivers (40%) > Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Zn) tend to occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated nutrient concentrations occur along both the Atlantic and Gulf coasts, but are dominated by rivers in the urban northeast and by southeastern and Gulf coast “blackwater” streams. Elevated Ca, Mg, K and Na levels appear to reflect local petrology whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have both natural and anthropogenic sources. Almost all the elevated sediment-associated chemical concentrations/fluxes are lower than worldwide averages.

United States coastal rivers↗
USGS2010

Selenium concentrations and stable isotopic compositions of carbon and nitrogen in the benthic clam Corbula amurensis from northern San Francisco Bay, California: May 1995–February 2010

The clam-based food webs of San Francisco Bay, California efficiently bioaccumlate selenium and thus provide pathways for exposure to predators important to the estuary. This study documents changes in monthly selenium concentrations for the clam Corbula amurensis , a keystone species of the estuary, at five locations in northern San Francisco Bay from 1995 through 2010. Samples were collected from designated U.S. Geological Survey stations and prepared and analyzed by U.S. Geological Survey methods. Stable isotopes of carbon and nitrogen in soft tissues of clams also were measured as an indicator of sources of selenium for the clams. These monitoring data indicate that clam selenium concentrations ranged from a low of 2 to a high of 22 micrograms per gram dry weight with strong spatial and seasonal variation over the period of study.

California↗
USGS2007

Effects of Hurricanes Katrina and Rita on the chemistry of bottom sediments in Lake Pontchartrain, La.

Concerns about the effect of pumping contaminated flood waters into Lake Pontchartrain following the hurricanes of 2005 prompted the U.S. Geological Survey (USGS) to sample street mud, canal-suspended sediment, and bottom sediment in Lake Pontchartain. The samples were analyzed for a wide variety of potential inorganic and organic contaminants. Results indicate that contamination of lake sediment relative to other urban lakes and to accepted sedimentquality guidelines was limited to a relatively small area offshore from the Metairie Outfall Canal (popularly known as the 17th Street Canal) and that this contamination is probably transient.

Louisiana↗
USGS2006

Effect of mining and related activities on the sediment trace element geochemistry of Lake Coeur D'Alene, Idaho, USA. Part I: Surface sediments

During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing. Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases. The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.

Idaho↗
USGS1992

Effect of membrane filtration artifacts on dissolved trace element concentrations

Among environment scientists, the current and almost universally accepted definition of dissolved constituents is an operational one-only those materials which pass through a 0.45-μm membrane filter are considered to be dissolved. Detailed laboratory and field studies on Fe and Al indicate that a number of factors associated with filtration, other than just pore size, can substantially alter “dissolved” trace element concentrations; these include: filter type, filter diameter, filtration method, volume of sample processed, suspended sediment concentration, suspended sediment grain-size distribution, concentration of colloids and colloidally-associated trace elements and concentration of organic matter. As such, reported filtered-water concentrations employing the same pore size filter may not be equal. Filtration artifacts may lead to the production of chemical data that indicate seasonal or annual “dissolved” chemical trends which do not reflect actual environmental conditions. Further, the development of worldwide averages for various dissolved chemical constituents, the quantification of geochemical cycles, and the determination of short- or long-term environmental chemical trends may be subject to substantial errors, due to filtration artifacts, when data from the same or multiple sources are combined. Finally, filtration effects could have a substantial impact on various regulatory requirements.

Georgia↗