Geology topics

Keith C. Hackley

Publications and source records attributed to Keith C. Hackley.

16 recordsLinked to original sources

USGS2017

Pyrolysis-combustion 14C dating of soil organic matter

Radiocarbon (14C) dating of total soil organic matter (SOM) often yields results inconsistent with the stratigraphic sequence. The onerous chemical extractions for SOM fractions do not always produce satisfactory 14C dates. In an effort to develop an alternative method, the pyrolysis-combustion technique was investigated to partition SOM into pyrolysis volatile (Py-V) and pyrolysis residue (Py-R) fractions. The Py-V fractions obtained from a thick glacigenic loess succession in Illinois yielded 14C dates much younger but more reasonable than the counterpart Py-R fractions for the soil residence time. Carbon isotopic composition (??13C) was heavier in the Py-V fractions, suggesting a greater abundance of carbohydrate- and protein-related constituents, and ??13C was lighter in the Py-R fractions, suggesting more lignin- and lipid-related constituents. The combination of 14C dates and ??13C values indicates that the Py-V fractions are less biodegradation resistant and the Py-R fractions are more biodegradation resistant. The pyrolysis-combustion method provides a less cumbersome approach for 14C dating of SOM fractions. With further study, this method may become a useful tool for analyzing unlithified terrestrial sediments when macrofossils are absent. ?? 2003 University of Washington. Published by Elsevier Inc. All rights reserved.

Quaternary Research↗

USGS2017

Climate change in southern Illinois, USA, based on the age and δ 13 C of organic matter in cave sediments

Matrix-supported diamicton and uniform to laminated, silty, fine-grained sediment deposited from about 42,500 to 27,600 cal yr B.P. under slackwater conditions nearly filled two caves in southwestern Illinois. At some point, most of the sediment was flushed from the caves and from about 22,700 to 4000 cal yr B.P., floods deposited a drape of sandy and silty sediment on remnant slackwater successions, cobbly alluvium, and bedrock (especially from 7700 to 4000 cal yr B.P.). Clay mineral analyses of the slackwater cave sediment reveal a provenance of chiefly Petersburg Silt, a smectite- and illite-rich proglacial lacustrine unit present in the overlying Illinois Episode glacial succession. Today, remnants of the ancient subterranean slackwater deposits nearly fill several secondary passages and, in at least two locations, cover a cobble-mantled strath terrace 1.3 to 1.5 m above active stream channels. Slumping and sinkhole formation appear to have been important mechanisms for deposition of the ancient subterranean deposits. Slumping of these surficial deposits and associated vegetation can occur along the flanks of sinkholes (in addition to sinkhole formation) and enter caves; however, the finer organics, some of them comminuted during transport into the caves, become part of the cave alluvium. This finer organic fraction is the modern analog of the humified organic matter disseminated in slackwater sediment dated in this investigation by radiocarbon methods. Twenty-four 14C ages on humified organic matter provide chronologic control. The ??13C values of the organic matter reflect the proportion of C4-type to C3-type vegetation growing in and around swallets and sinkholes at the time of redeposition. Drought-tolerant C4-type vegetation was more prevalent relative to C3-type vegetation from 42,500 to 31,200 cal yr B.P. compared to conditions from 28,800 cal yr B.P. to the present. The ??13C values are consistent with the results from other investigations of speleothems and organic matter from loessial paleosols. ?? 2004 University of Washington. All rights reserved.

Quaternary Research↗

USGS2010

Using chloride and other ions to trace sewage and road salt in the Illinois Waterway

Chloride concentrations in waterways of northern USA are increasing at alarming rates and road salt is commonly assumed to be the cause. However, there are additional sources of Cl - in metropolitan areas, such as treated wastewater (TWW) and water conditioning salts, which may be contributing to Cl - loads entering surface waters. In this study, the potential sources of Cl - and Cl - loads in the Illinois River Basin from the Chicago area to the Illinois River's confluence with the Mississippi River were investigated using halide data in stream samples and published Cl - and river discharge data. The investigation showed that road salt runoff and TWW from the Chicago region dominate Cl - loads in the Illinois Waterway, defined as the navigable sections of the Illinois River and two major tributaries in the Chicago region. Treated wastewater discharges at a relatively constant rate throughout the year and is the primary source of Cl - and other elements such as F - and B. Chloride loads are highest in the winter and early spring as a result of road salt runoff which can increase Cl - concentrations by up to several hundred mg/L. Chloride concentrations decrease downstream in the Illinois Waterway due to dilution, but are always elevated relative to tributaries downriver from Chicago. The TWW component is especially noticeable downstream under low discharge conditions during summer and early autumn when surface drainage is at a minimum and agricultural drain tiles are not flowing. Increases in population, urban and residential areas, and roadways in the Chicago area have caused an increase in the flux of Cl - from both road salt and TWW. Chloride concentrations have been increasing in the Illinois Waterway since around 1960 at a rate of about 1 mg/L/a. The increase is largest in the winter months due to road salt runoff. Shallow groundwater Cl - concentrations are also increasing, potentially producing higher base flow concentrations. Projected increases in population and urbanization over the next several decades suggest that the trend of increasing Cl - concentrations and loads will continue. Given the susceptibility of aquatic ecosystems to increasing Cl - concentrations, especially short-term spikes following snow melts, deleterious effects on riverine ecosystems would be expected. ?? 2010 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

USGS2009

Major earthquakes recorded by Speleothems in Midwestern U.S. caves

Historic earthquakes generated by the New Madrid seismic zone represent some of the largest recorded in the United States, yet prehistoric events are recognized only through deformation in late-Wisconsin to Holocene-age, near surface sediments (liquefaction, monoclinal folding, and changes in river meanders). In this article, we show that speleothems in caves of southwestern Illinois and southeastern Missouri may constitute a previously unrecognized recorder of large earthquakes in the U.S. midcontinent region. The timing of the initiation and regrowth of stalagmites in southwestern Illinois and southeastern Missouri caves is consistent with the historic and prehistoric record of several known seismic events in the U.S. midcontinent region. We conclude that dating the initiation of original stalagmite growth and later postearthquake rejuvenation constitutes a new paleoseismic method that has the potential for being applied to any region around the world in the vicinity of major seismic zones where caves exist. Use of this technique could expand the geographical distribution of paleoseimic data, document prehistoric earthquakes, and help improve interpretations of paleoearthquakes.

Bulletin of the Seismological Society of America↗

USGS2008

Sources and fate of nitrate in the Illinois River Basin, Illinois

We conducted a two-year investigation into the sources and fate of nitrate (NO3-) in the Illinois River from the Chicago area to the river's confluence with the Mississippi River. Samples from waterways in the Chicago area (Des Plaines River and the Sanitary and Ship Canal) had relatively high concentrations of nitrogen (N) species and NO3- isotopic compositions indicative of treated wastewater (TWW). Downstream of the Brandon Road Lock and Dam, NO3- in tributaries discharging to the Illinois River primarily comes from tiles draining row crops. Nitrate isotopic signatures from these tributaries as well as drain tiles were indicative of synthetic fertilizer and/or soil organic matter (SOM) at various stages of denitrification. Nitrate-N concentrations generally decreased in the Illinois River with distance from the Chicago area primarily due to dilution. The decrease in NO3-N concentrations was especially conspicuous during the summer, when there is minimal discharge from drain tiles and NO3-N concentrations in the tributaries were low. In August 2005, when conditions were very dry, NO3-N concentrations decreased from 7.4 mg/L in the Chicago area to less than 1 mg/L near where the Illinois River discharges to the Mississippi River. The isotopic composition of NO3- in water samples from the Illinois River were a mixture of three end members: (1) fertilizer and/or SOM in drain tile water, typically showing the least amount of denitrification, (2) fertilizer and/or SOM in deeper ground water, showing the highest degree of denitrification, and (3) TWW. There was seasonal variability, depending on the volume of water flowing in the Illinois River. During high flow periods, river water samples plotted closest to those of tile drain samples; during low flow periods, a greater influence of TWW was observed in the isotopic composition. A subset of summer samples from the Chicago waterways had isotopic values plotting near and within the domain that characterizes manure and sewage. Nitrate in the Chicago area is primarily derived from TWW, with its isotopic signature evident downstream at least as far as Pekin during most of the year and all the way to the Mississippi River during periods of low flow. Denitrification occurs predominantly in groundwater between and away from drain tiles, although there is evidence that in-stream denitrification and/or biological uptake of NO3- occurs in the Peoria Lake reach of the Illinois River, at least during periods of low flow in the summer. We calculated that the river was losing about half of its NO3-N load in Peoria Lake in August 2005 (a period of very low flow), at a rate of about 7500 kg/day.

Journal of Hydrology↗

USGS2006

Estimating background and threshold nitrate concentrations using probability graphs

Because of the ubiquitous nature of anthropogenic nitrate (NO 3-) in many parts of the world, determining background concentrations of NO3- in shallow ground water from natural sources is probably impossible in most environments. Present-day background must now include diffuse sources of NO3- such as disruption of soils and oxidation of organic matter, and atmospheric inputs from products of combustion and evaporation of ammonia from fertilizer and livestock waste. Anomalies can be defined as NO3- derived from nitrogen (N) inputs to the environment from anthropogenic activities, including synthetic fertilizers, livestock waste, and septic effluent. Cumulative probability graphs were used to identify threshold concentrations separating background and anomalous NO3-N concentrations and to assist in the determination of sources of N contamination for 232 spring water samples and 200 well water samples from karst aquifers. Thresholds were 0.4, 2.5, and 6.7 mg/L for spring water samples, and 0.1, 2.1, and 17 mg/L for well water samples. The 0.4 and 0.1 mg/L values are assumed to represent thresholds for present-day precipitation. Thresholds at 2.5 and 2.1 mg/L are interpreted to represent present-day background concentrations of NO3-N. The population of spring water samples with concentrations between 2.5 and 6.7 mg/L represents an amalgam of all sources of NO3- in the ground water basins that feed each spring; concentrations >6.7 mg/L were typically samples collected soon after springtime application of synthetic fertilizer. The 17 mg/L threshold (adjusted to 15 mg/L) for well water samples is interpreted as the level above which livestock wastes dominate the N sources. Copyright ?? 2006 The Author(s).

Ground Water↗

USGS2006

Isotopic evidence of nitrate sources and denitrification in the Mississippi River, Illinois

Anthropogenic nitrate (NO3-) within the Mississippi-Atchafalaya River basin and discharge to the Gulf of Mexico has been linked to serious environmental problems. The sources of this NO 3- have been estimated by others using mass balance methods; however, there is considerable uncertainty in these estimates. Part of the uncertainty is the degree of denitrification that the NO3- has undergone. The isotopic composition of NO3- in the Mississippi River adjacent to Illinois and tile drain (subsurface drain) discharge in agricultural areas of east-central Illinois was examined using N and O isotopes to help identify the major sources of NO 3- and assess the degree of denitrification in the samples. The isotopic evidence suggests that most of the NO3- in the river is primarily derived from synthetic fertilizers and soil organic N, which is consistent with published estimates of N inputs to the Mississippi River. The 1:2 relationship between ??18O and ??15N also indicate that, depending on sample location and season, NO3- in the river and tile drains lias undergone significant denitrification, ranging from about 0 to 55%. The majority of the denitrification appears to have occurred before discharge into the Mississippi River. ?? ASA, CSSA, SSSA.

Journal of Environmental Quality↗

USGS2006

Potential effects of recurrent low oxygen conditions on the Illinois Cave amphipod

The caves of Illinois' sinkhole plain are the sole habitat of the Illinois Cave amphipod (Gammarus acherondytes), a federally endangered species. The sinkhole plain is a hydrologically-connected sequence of karstified limestone that constitutes an extensive karst aquifer which serves as an important source of potable water for area residents. During this investigation, we examined the ground-water quality in caves within two ground-water basins: 1) Illinois Caverns, where the amphipod is now present after previously reported to have been extirpated from the lower reaches, and 2) Stemler Cave, where the amphipod is reported to have been extirpated. The chemical composition of cave streams in Illinois Caverns and Stemler Cave were compared to determine which parameters, if any, could have contributed to the loss of G. acherondytes from Stemler Cave. Stream water in Stemler Cave contained higher concentrations of organic carbon, potassium, silica, chloride, fluoride, sulfate, iron and manganese than Illinois Caverns. Perhaps most importantly, dissolved oxygen (DO) concentrations in Stemler Cave were, during periods of low flow, substantially lower than in Illinois Caverns. Based on land use, there are probably at least eight times more private septic systems in the Stemler Cave ground-water basin than in the Illinois Caverns ground-water basin. Low DO concentrations were likely the result of microbial breakdown of soil organic matter and wastewater treatment system effluent, and the oxidation of pyrite in bedrock. The near-hypoxic DO in Stemler Cave that occurred during low-flow conditions, and, we speculate, a limited range of G. acherondytes within the Stemler Cave ground-water basin due to a metabolic advantage of the stygophilic aquatic invertebrates over the stygobitic G. acherodytes, resulted in the apparent loss of G. acherondytes from Stemler Cave.

Journal of Cave and Karst Studies↗

USGS2005

Radiogenic 4He as a conservative tracer in buried‐valley aquifers

The accumulation of 4 He in groundwater can be a powerful tool in hydrogeologic investigations. However, the use of 4 He often suffers from disagreement or uncertainty related to in situ and external sources of 4 He. In situ sources are quantified by several methods, while external sources are often treated as calibration parameters in modeling. We present data from direct laboratory measurements of 4 He release from sediments and field data of dissolved 4 He in the Mahomet Aquifer, a well‐studied buried‐valley aquifer in central Illinois. The laboratory‐derived accumulation rates (0.13–0.91 μcm 3 STP kg water −1 yr −1 ) are 1–2 orders of magnitude greater than the accumulation rates based on the U and Th concentrations of the sediments (0.004–0.009 μcm 3 STP kg water −1 yr −1 ). The direct measurement of accumulation rates are more consistent with dissolved concentrations of 4 He in the groundwater. We suggest that the direct measurement method is applicable in a variety of hydrogeologic settings. The patterns of accumulation of 4 He are consistent with the conceptual model of flow in the aquifer based on hydraulic and geochemical evidence and show areas where in situ production and external sources of 4 He are dominant. In the southwestern part of the study area, Ne concentrations are less than atmospheric solubility, indicating gases have been lost from the groundwater. Available evidence indicates that the gases are lost as groundwater passes by pockets of CH 4 in glacial deposits overlying the aquifer. However, the external flux from the underlying bedrock appears to dominate the accumulation of radiogenic 4 He in the aquifer in the southwestern part of the study area, and the loss or gain of helium as groundwater passes through the overlying sediments is minor in comparison.

Water Resources Research↗

USGS2005

Characterization and identification of Na-Cl sources in ground water

Elevated concentrations of sodium (Na+) and chloride (Cl -) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br-), and iodide (I-) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I- and Br-; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources. Copyright ?? 2005 National Ground Water Association.

Ground Water↗

USGS2005

Hydrochemistry of the Mahomet Bedrock Valley Aquifer, East-Central Illinois: Indicators of recharge and ground-water flow

A conceptual model of the ground-water flow and recharge to the Mahomet Bedrock Valley Aquifer (MVA), east-central Illinois, was developed using major ion chemistry and isotope geochemistry. The MVA is a “basal” fill in the east-west trending buried bedrock valley composed of clean, permeable sand and gravel to thicknesses of up to 61 m. It is covered by a thick sequence of glacial till containing thinner bodies of interbedded sand and gravel. Ground water from the MVA was found to be characterized by clearly defined geochemical regions with three distinct ground-water types. A fourth ground-water type was found at the confluence of the MVA and the Mackinaw Bedrock Valley Aquifer (MAK) to the west. Ground water in the Onarga Valley, a northeastern tributary of the MVA, is of two types, a mixed cation-SO 4 2- type and a mixed cation-HCO 3 type. The ground water is enriched in Na + Ca 2+ , Mg 2+ , and SO 4 2- which appears to be the result of an upward hydraulic gradient and interaction of deeper ground water with oxidized pyritic coals and shale. We suggest that recharge to the Onarga Valley and overlying aquifers is 100% from bedrock (leakage) and lateral flow from the MVA to the south. The central MVA (south of the Onarga Valley) is composed of relatively dilute ground water of a mixed cation-HC0 3 type, with low total dissolved solids, and very low concentrations of Cl - and SO 4 2- . Stratigraphie relationships of overlying aquifers and ground-water chemistry of these and the MVA suggest recharge to this region of the MVA (predominantly in Champaign County) is relatively rapid and primarily from the surface. Midway along the westerly flow path of the MVA (western MVA), ground water is a mixed cation-HCO 3 - type with relatively high Cl - , where Cl - increases abruptly by one to two orders of magnitude. Data suggest that the increase in Cl - is the result of leakage of saline ground water from bedrock into the MVA. Mass-balance calculations indicate that approximately 9.5% of recharge in this area is from bedrock. Concentrations of Na + , HCO 3 - , As, and TDS also increase in the western MVA. Ground water in the MAK is of a Ca 2+ -HCO 3 2- type. Mass-balance calculations, using Cl - as a natural, conservative tracer, indicate that approximately 17% of the ground water flowing from the confluence area is derived from the MVA.

Groundwater↗

USGS2005

Environmental Isotope Characteristics of Landfill Leachates and Gases

The isotopic characteristics of municipal landfill leachate and gases (carbon dioxide and methane) are unique relative to the aqueous and gaseous media in most other natural geologic environments. The δ 13 C of the CO 2 in landfills is significantly enriched in 13 C, with values as high as +20 ‰ reported. The δ 13 C and δD values of the methane fall within a range of values representative of microbial methane produced primarily by the acetate-fermentation process. The δD of landfill leachate is strongly enriched in deuterium, by approximately 30 ‰ to nearly 60 ‰ relative to local average precipitation values. This deuterium enrichment is undoubtedly due to the extensive production of microbial methane within the limited reservoir of a landfill. The concentration of the radiogenic isotopes, 14 C and 3 H, are significantly elevated in both landfill leachate and methane. The 14 C values range between approximately 120 and 170 pMC and can be explained by the input of organic material that was affected by the increased 14 C content of atmospheric CO2 caused by atmospheric testing of nuclear devices. The tritium measured in leachate, however, is often too high to be explained by previous atmospheric levels and must come from material buried within the landfill. The unique isotopic characteristics observed in landfill leachates and gases provide a very useful technique for confirming whether contamination is from a municipal landfill or some other local source.

Groundwater↗

USGS2001

Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators

The sources of nitrate (NO-3) in groundwater of the shallow karst aquifer in southwestern Illinois' sinkhole plain were investigated using chemical and isotopic techniques. The groundwater in this aquifer is an important source of potable water for about half of the residents of the sinkhole plain area. Previous work has shown that groundwater from approximately 18% of the wells in the sinkhole plain has NO-3 concentrations in excess of the USEPA's drinking water standard of 10 mg N/1. Relative to background levels, the NO-3 concentrations in water from 52% of the wells, and probably all of the springs in the study area, are anomalously high, suggesting that sources other than naturally occurring soil organic matter have contributed additional NO-3 to groundwater in the shallow karst aquifer. This information, and the dominance of agriculture in the study area, suggest that agrichemical contributions may be significant. To test this hypothesis, water samples from 10 relatively large karst springs were collected during four different seasons and analyzed for inorganic constituents, dissolved organic carbon, atrazine, and ??15N and ??18O of the NO-3 ions. The isotopic data were most definitive and suggested that the sources of NO-3 in spring water are dominated by N-fertilizer with some possible influence of atmospheric NO-3 and, to a much lesser extent, human and/or animal waste. Differences in the isotopic composition of NO-3 and some of the chemical characteristics were observed during the four consecutive seasons in which spring water samples were collected. Isotopic values for ??15N and ??18O of the NO-3 ranged from 3.2??? to 19.1??? and from 7.2??? to 18.7???, respectively. The trend of ??15N and ??18O data for NO-3 also indicated that a significant degree of denitrification is occurring in the shallow karst hydrologic system (within the soil zone, the epikarst and the shallow karst aquifer) prior to discharging to springs. ?? 2001 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

USGS1999

Isotopic identification of the source of methane in subsurface sediments of an area surrounded by waste disposal facilities

The major source of methane (CH4) in subsurface sediments on the property of a former hazardous waste treatment facility was determined using isotopic analyses measured on CH4 and associated groundwater. The site, located on an earthen pier built into a shallow wetland lake, has had a history of waste disposal practices and is surrounded by landfills and other waste management facilities. Concentrations of CH4 up to 70% were found in the headspace gases of several piezometers screened at 3 different depths (ranging from 8 to 17 m) in lacustrine and glacial till deposits. Possible sources of the CH4 included a nearby landfill, organic wastes from previous impoundments and microbial gas derived from natural organic matter in the sediments. Isotopic analyses included ??13C, ??D, 14C, and 3H on select CH4 samples and ??D and ??18O on groundwater samples. Methane from the deepest glacial till and intermediate lacustrine deposits had ??13C values from -79 to -82???, typical of natural 'drift gas' generated by microbial CO2-reduction. The CH4 from the shallow lacustrine deposits had ??13C values from -63 to -76???, interpreted as a mixture between CH4 generated by microbial fermentation and the CO2-reduction processes within the subsurface sediments. The ??D values of all the CH4 samples were quite negative ranging from -272 to -299???. Groundwater sampled from the deeper zones also showed quite negative ??D values that explained the light ??D observed for the CH4. Radiocarbon analyses of the CH4 showed decreasing 14C activity with depth, from a high of 58 pMC in the shallow sediments to 2 pMC in the deeper glacial till. The isotopic data indicated the majority of CH4 detected in the fill deposits of this site was microbial CH4 generated from naturally buried organic matter within the subsurface sediments. However, the isotopic data of CH4 from the shallow piezometers was more variable and the possibility of some mixing with oxidized landfill CH4 could not be completely ruled out.

Applied Geochemistry↗

USGS1993

SEM-EDX and isotope characterization of the organic sulfur in macerals and chars in Illinois Basin coals

Two samples of the Herrin (Illinois No. 6) Coal and one sample of the Colchester (Illinois No. 2) Coal from the Illinois Basin were studied to evaluate the spatial distribution of organic sulfur within macerals occurring next to pyrite grains, both in the raw coal and their chars. The chars were produced by pyrolysing the coal at 250–550°C in a nitrogen atmosphere. Representative splits of the coals and their chars were mounted in epoxy and polished for optical microscopy and scanning electron microscopy-energy dispersive x-ray spectroscopy (SEM-EDX). Determinations of organic sulfur concentrations were made at 996 locations within macerals, mostly vitrinite, around 115 grains of pyrite and at 50 locations around 5 pores in chars. The pyrite considered here is restricted to the disseminated type within macerals. On the average, the organic sulfur content increased near pyrite grains after the coals were charred at 550°C, indicating that some of the pyritic sulfur released during charring was retained within the organic matrix rather than being emitted to the atmosphere. One of the coal samples and its chars were isotopically characterized by chemically separating the pyritic and organic sulfur fractions, followed by analyzing the isotopes of the sulfur forms with a Nuclide 6–60 ratio mass spectrometer. The sulfur isotope (δ 34 S) data confirmed the movement of pyritic sulfur into the macerals after charring to 550°C. About 18% of the organic sulfur that remained in the 550°C char had originally been pyritic sulfur in the untreated coal.

Organic Geochemistry↗

USGS1987

Use of stable sulphur isotopes to monitor directly the behaviour of sulphur in coal during thermal desulphurization

A method has been developed using stable sulphur isotope analyses to monitor the behaviour of sulphur forms in a coal during thermal desulphurization. In this method, the natural stable isotopic composition of the pyritic and organic sulphur in coal is used as a tracer to follow their mobility during the desulphurization process. This tracer method is based on the fact that the isotopic compositions of pyritic and organic sulphur are significantly different in some coals. Isotopic results of pyrolysis experiments at temperatures ranging from 350 to 750 °C indicate that the sulphur released with the volatiles is predominantly organic sulphur. The pyritic sulphur is evolved in significant quantities only when pyrolysis temperatures exceed 500 °C. The presence of pyrite seems to have no effect on the amount of organic sulphur evolved during pyrolysis. The chemical and isotopic mass balances achieved from three different samples of the Herrin (No. 6) coal of the Illinois Basin demonstrate that this stable isotope tracer method is quantitative. The main disadvantage of this tracing technique is that not all coals contain isotopically distinct organic and pyritic sulphur.

Illinois, Indiana, Kentucky↗