USGS ScienceSearch

Geology topics

Keith A. Kvenvolden

Publications and source records attributed to Keith A. Kvenvolden.

At least 19 recordsLinked to original sources

Dipping reflectors in the Norwegian Sea—ODP Leg 104 drilling results: LEG 104 SCIENTIFIC PARTY

Ocean Drilling Program (ODP) Leg 104 successfully completed a number of deep drill holes on the Outer V0ring Plateau and the Vering Basin during July and August 1985 (Fig. 1; Eldholm, Thiede, Taylor et al. 1986). One of the principal objectives of the leg was to drill and sample a thick oceanward-dipping wedge of seismic reflectors, known to characterize much of the multichannel seismic (MCS) profile data recorded across ocean-continent transitions in the NE Atlantic north of 55°N. Elsewhere, these reflectors have previously been the target of deep drilling during Legs 48 and 81 of the International Phase of Ocean Drilling IPOD (Montadert, Roberts et al. 1979; Roberts, Schnitker et al. 1984). These efforts met with some success, sampling only the uppermost part of the sequence and identifying a series of tholeiitic lava flows. Over the Outer V~ring Plateau, a number of MCS profiles reveal a distinct change in seismic character at the base of the well-stratified dipping reflector sequence, where an irregular surface characterized by a band of low-frequency, high-amplitude reflectors occurs. This surface is referred to as K. Prior to Leg 104, therefore, relatively little was known regarding the variation in petrographic character of the flows at depth, their evolution and origin, and particularly the character of the material below the reflector sequence. A single deep drillhole (642E) successfully recovered a section through the

Journal of the Geological Society

California State Waters Map Series: Offshore of Coal Oil Point, California

In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow (to about 100 m) subsurface geology. The Offshore of Coal Oil Point map area lies within the central Santa Barbara Channel region of the Southern California Bight. This geologically complex region forms a major biogeographic transition zone, separating the cold-temperate Oregonian province north of Point Conception from the warm-temperate California province to the south. The map area is in the southern part of the Western Transverse Ranges geologic province, which is north of the California Continental Borderland. Significant clockwise rotation—at least 90°—since the early Miocene has been proposed for the Western Transverse Ranges province, and geodetic studies indicate that the region is presently undergoing north-south shortening. Uplift rates (as much as 2.0 mm/yr) that are based on studies of onland marine terraces provide further evidence of significant shortening. The cities of Goleta and Isla Vista, the main population centers in the map area, are in the western part of a contiguous urban area that extends eastward through Santa Barbara to Carpinteria. This urban area is on the south flank of the east-west-trending Santa Ynez Mountains, on coalescing alluvial fans and uplifted marine terraces underlain by folded and faulted Miocene bedrock. In the map area, the relatively low-relief, elevated coastal bajada narrows from about 2.5 km wide in the east to less than 500 m wide in the west. Several beaches line the actively utilized coastal zone, including Isla Vista County Park beach, Coal Oil Point Reserve, and Goleta Beach County Park. The beaches are subject to erosion each winter during storm-wave attack, and then they undergo gradual recovery or accretion during the more gentle wave climate of the late spring, summer, and fall months. The Offshore of Coal Oil Point map area lies in the central part of the Santa Barbara littoral cell, which is characterized by littoral drift to the east-southeast. Longshore drift rates have been reported to range from about 160,000 to 800,000 tons/yr, averaging 400,000 tons/yr. Sediment supply to the western and central parts of the littoral cell, including the map area, is largely from relatively small transverse coastal watersheds. Within the map area, these coastal watersheds include (from east to west) Las Llagas Canyon, Gato Canyon, Las Varas Canyon, Dos Pueblos Canyon, Eagle Canyon, Tecolote Canyon, Winchester Canyon, Ellwood Canyon, Glen Annie Canyon, and San Jose Creek. The Santa Ynez and Santa Maria Rivers, the mouths of which are about 100 to 140 km northwest of the map area, are not significant sediment sources because Point Conception and Point Arguello provide obstacles to downcoast sediment transport and also because much of their sediment load is trapped in dams. The Ventura and Santa Clara Rivers, the mouths of which are about 45 to 55 km southeast of the map area, are much larger sediment sources. Still farther east, eastward-moving sediment in the littoral cell is trapped by Hueneme and Mugu Canyons and then transported to the deep-water Santa Monica Basin. The offshore part of the map area consists of a relatively flat and shallow continental shelf, which dips gently seaward (about 0.8° to 1.0°) so that water depths at the shelf break, roughly coincident with the California’s State Waters limit, are about 90 m. This part of the Santa Barbara Channel is relatively well protected from large Pacific swells from the north and northwest by Point Conception and from the south and southwest by offshore islands and banks. The shelf is underlain by variable amounts of upper Quaternary marine and fluvial sediments deposited as sea level fluctuated in the late Pleistocene. The large (130 km2) Goleta landslide complex lies along the shelf break in the southern part of the map area. This compound slump complex may have been initiated more than 200,000 years ago, but it also includes three recent failures that may have been generated between 8,000 to 10,000 years ago. A local, 5- to 10-m-high tsunami may have been generated from these failure events. The map area has had a long history of hydrocarbon development, which began in 1928 with discovery of the Ellwood oil field. Subsequent discoveries in the offshore include South Ellwood offshore oil field, Coal Oil Point oil field, and Naples oil and gas field. Development of South Ellwood offshore field began in 1966 from platform “Holly,” the last platform to be installed in California’s State Waters. The area also is known for “the world’s most spectacular marine hydrocarbon seeps,” and large tar seeps are exposed on beaches east of the mouth of Goleta Slough. Offshore seeps adjacent to South Ellwood oil field release about 40 tons per day of methane and about 19 tons per day of ethane, propane, butane, and higher hydrocarbons. Seafloor habitats in the broad Santa Barbara Channel region consist of significant amounts of soft sediment and isolated areas of rocky habitat that support kelp-forest communities nearshore and rocky-reef communities in deep water. The potential marine benthic habitat types mapped in the Offshore of Coal Oil Point map area are directly related to its Quaternary geologic history, geomorphology, and active sedimentary processes. These potential habitats, which lie primarily within the Shelf (continental shelf) but also partly within the Flank (basin flank or continental slope) megahabitats, range from soft, unconsolidated sediment to hard sedimentary bedrock. This heterogeneous seafloor provides promising habitat for rockfish, groundfish, crabs, shrimp, and other marine benthic organisms.

California

Thermogenic gases in near-surface sediments of Norton Sound, Alaska

A plume of hydrocarbon gases, assumed to be of thermogenic origin based on chemical compositions, has been noted by others in the water column of Norton Sound about 40 km south of Nome, Alaska. We used detailed geophysical transects, side-scan sonar, underwater television, and chromatographic analyses of gases in near-surface sediments to define a probable source area of hydrocarbon gases at the southern apex of the water plume epicenter. Geophysical, geotechnical, and geochemical evidence together indicate that hydrocarbon gases of subsurface, thermogenic origin apparently migrate into the near surface sediments along a fault zone. Subbottom reflector terminations on continuous seismic profiles outline a large zone of anomalous acoustic responses about 9 km in diameter and at 100-m depth that may be caused by a subsurface accumulation of gas. Gas migration from the accumulation to the surface sediment is indicated by smaller zones of reflector terminations observed in high-resolution profiles and by seafloor craters seen on underwater television at one station. The presence of gas-charged surface sediment also is suggested by low percent pore water saturation, greater penetration of the penetrometer, and more rapid penetration of the vibracorer in sediment at the station with near-surface acoustic anomalies and seafloor craters. Analyses of hydrocarbon gases in sediments from a 1.6-m vibracore taken at this station showed unusually high concentrations of hydrocarbon gases heavier than methane; the ethane, propane, n-butane, and isobutane were 76, 4, 6, and 52 times greater than in other near-surface sediments in this region, and also significant quantities of gasoline-range hydrocarbons were present. The gas composition and presence in near-surface sediments above a thick underlying section with acoustic anomalies points to the possibility of petroleum at depth in this region. Our work indicates that surface and near-surface studies of the continental shelf may contribute significantly to petroleum-resource evaluations in addition to defining areas of potential hazard from gas-charged sediment.

Alaska

The global occurrence of natural gas hydrate

Natural gas hydrate occurs worldwide in oceanic sediment of continental and insular slopes and rises of active and passive margins, in deep-water sediment of inland lakes and seas, and in polar sediment on both continents and continental shelves. In aquatic sediment, where water depths exceed about 300 m and bottom water temperatures approach 0° C, gas hydrate is found at the seafloor to sediment depths of about 1,100 m. In polar continental regions, gas hydrate can be present in sediment at depths between about 150 and 2000 m. Thus, natural gas hydrate is restricted to the shallow geosphere where its presence affects the physical and chemical properties of near-surface sediment. An updated global inventory reports on natural gas hydrate recovered from 19 places worldwide and includes 77 places where the presence of gas hydrate has been inferred from geophysical, geochemical, and geological evidence. The potential amount of methane in natural gas hydrate is enormous, with current estimates converging around about 10 teratonnes (10 19 g) of methane carbon.

Book chapter

The Beaufort Sea continental shelf as a seasonal source of atmospheric methane

Methane concentrations in the Beaufort Sea under the winter ice canopy offshore from northern Alaska are 3 to 28 times greater than they are in late summer when the ice is absent in a similar region offshore from northern Canada where methane is in approximate equilibrium with the atmosphere. These observations suggest that methane concentrates in the water under the sea‐ice cover during winter and ventilates rapidly in late summer as the ice melts and retreats. Conditions similar to those on the Beaufort Sea shelf likely exist on the much larger Siberian shelf, making the Arctic Ocean margin a possible seasonal, high‐latitude, marine source of about 0.1 Tg yr −1 atmospheric methane. The small addition of methane likely contributes to the late‐summer increase in atmospheric methane that is observed each year particularly in the northern hemisphere.

Alaska

Methane hydrates and global climate

Methane hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. The amount of methane sequestered in gas hydrates is probably enormous, but estimates of the amounts are speculative and range over three orders of magnitude (about 10 3 to 10 6 GT (gigatons = 10 15 g)). A question of current interest concerns the possible consequences of an addition of methane to the atmosphere from destabilized methane hydrates due to global warming. Models of greenhouse warming predict that climatic change will be greatest in the Arctic. Thus, if methane from destabilized gas hydrates contributes to greenhouse warming, this destabilization will most likely take place first in the Arctic, particularly in the shallow nearshore regions of the Arctic Ocean where offshore permafrost is found. The process of permafrost warming and release of methane from gas hydrates may already be in progress, but the amount being released now and to be released in the 21st century is probably small. The positive feedback of this atmospheric methane on global climates will likely be minimal.

Global Biogeochemical Cycles

Fifty years of IMOG (International Meetings on Organic Geochemistry)

IMOG2011 is the 25th of a series of international meetings on organic geochemistry that began in 1962. Thus, this 25th meeting marks the 50th anniversary year of IMOG, which has (a) had a rich history with meetings taking place in 11 different countries, (b) published Proceedings, titled “Advances in Organic Geochemistry,” from each meeting that now number 24 volumes totaling almost 18,000 pages, and (c) documented the content and development of the science of organic geochemistry. IMOG2011 adds a new milestone to the progress of organic geochemistry through time.

Organic Geochemistry

Future of gas hydrate research

Methane hydrates are ice‐like inclusion compounds, in which every volume of hydrate can contain as much as 180 volumes (STP) of gas.The amount of methane in natural gas hydrates is twice the total recoverable fossil fuel reserve. Because of their natural abundance in oceans and permafrost, hydrates have become an exciting national and international research issue. The movement of the gas and oil industry to ever deepening waters where hydrates occur, the compelling size and distribution of hydrate deposits, and strong international interest all support identification of crucial elements in a hydrate research program.

Eos, Earth and Space Science News

Gas hydrates—Geological perspective and global change

Natural gas hydrates occur worldwide in polar regions, normally associated with onshore and offshore permafrost, and in sediment of outer continental and insular margins. The total amount of methane in gas hydrates likely exceeds 10 19 g of methane carbon. Three aspects of gas hydrates are important: their fossil fuel resource potential, their role as a submarine geohazard, and their effects on global climate change. Because gas hydrates represent a large amount of methane within 2000 m of the Earth's surface, they are considered to be an unconventional, unproven source of fossil fuel. Because gas hydrates are metastable, changes of pressure and temperature affect their stability. Destabilized gas hydrates beneath the seafloor lead to geologic hazards such as submarine slumps and slides, examples of which are found worldwide. Destabilized gas hydrates may also affect climate through the release of methane, a “greenhouse” gas, which may enhance global warming and be a factor in global climate change.

Reviews of Geophysics

Natural offshore oil seepage and related tarball accumulation on the California coastline — Santa Barbara Channel and the southern Santa Maria Basin; source identification and inventory

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three “tribes” of 13 C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (Tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (Tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception, where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. It is very desirable to be able to clearly distinguish the naturally occurring seep oils from the anthropogenically derived platform oils. Within the “training set” of oils and tars (388 samples), the biomarker parameters are sometimes sufficient to allow unique discrimination of individual platform oils. More often however, platform samples and seep samples with sources geographically close to each other are too similar to each other, with respect to the biomarker parameters, to definitively differentiate them on that basis alone. In some cases other parameters can be helpful. These other parameters are related to the degree of biogeochemical degradation or weathering that the oils or tars have experienced. These components include the typical oil distribution of n-alkane hydrocarbons and isoprenoids pristane and phytane. All of the platform oils in our sample set contain these components. On the other hand, the seep oils or tars have been exposed to significant biodegradation while in the near subsurface. The majority, but not all of seep oils or tars have been biodegraded up to or beyond the loss of n-alkanes and isoprenoids. Seep oils found in the vicinity of Coal Oil Point or Arroyo Burro are apparently the least weathered and are particularly likely to retain significant n-alkanes and isoprenoids. Therefore the combination of chemometric fingerprinting and the presence or absence of n-alkanes and isoprenoids help to differentiate anthropogenic production oils versus natural seeps oils and tars. The differentiation is not always definitive because of the close chemical similarity of some samples and the variability in the biodegradation progression. This is the case near Coal Oil Point, and near Platform A (Dos Cuadros Field) where seep oils and Platform Holly and Platform A oils are genetically very similar and cannot be definitively distinguished after a period of a few days of weathering. In contrast, oils from the Point Conception platforms can be distinguished on the basis of chemometric fingerprinting alone. In the middle of this spectrum are oils from Platforms Harmony, Heritage, and Hondo, where it is expected that oil weathering would take on the order of two weeks to a month to produce tarballs similar to those seen near Point Conception. In this case there is a much greater degree of weathering needed to proceed from produced oil to the biodegraded tar characteristic of tarball stranded on the beach. Tar deposition on beaches was monitored as part of cooperative with the County of Santa Barbara Energy Division and the U.S. Geological Survey during 2001-2003. We found tar deposition varies on a seasonal basis. In general, tarballs accumulate at a faster rate or remain longer on all beaches during the summer and fall months. The reasons for this are unclear based on our limited observations, however we speculate that factors such as prevailing winds and currents combined with more quiescent wave conditions favors the accumulation and preservation of tarballs on the beach during the summer and fall months. In contrast, winter storms, with much greater wave action remove beach sand and other materials, and stormy seas tend to break up oil that might weather into tarballs. Natural seepage is affected by the spring/neap tidal cycle; however, the link to tar deposition is unclear. Longer periods of monitoring are needed to address the variability in the data and provide a more robust statistical analysis.

California

Attention turns to naturally occurring methane seepage

Methane is the most abundant organic compound in the Earth's atmosphere. As a powerful greenhouse gas, it has implications for global climate change. Sources of methane to the atmosphere are varied. Depending on the source, methane can contain either modern or ancient carbon. Methane exiting from swamps and wetlands contains modern carbon, whereas methane leaking from petroleum reservoirs contains ancient carbon. The total annual source of methane to the atmosphere has been constrained to about 540 teragrams (Tg) per year “ Cicerone and Oremland , 1988”. Notably absent from any identified sources is the contribution of geologically sourced methane from naturally occurring seepage.

Eos, Earth and Space Science News

Integrated strategy urged to address coastal contamination issues

Coastal bays and estuaries are well known for their intrinsic recreational and economic value, yet these ecosystems are also among our most troubled natural environments. Urban development, agriculture, and shipping are just a few examples of human activities that can cause a wide range of deleterious changes within the coastal environment. These alterations, however, occur simultaneously with cycles of natural variability such as climate change. To effectively manage coastal ecosystems, we need to be able to carefully distinguish between anthropogenic and natural causes of change.

Eos, Transactions, American Geophysical Union

National workshop on gas hydrates

The range of present knowledge on the subject of gas hydrates and related federal research programs was the topic of discussion at the National Workshop on Gas Hydrates, April 23–24. The intention of the meeting was to provide the impetus for an expanded and broader‐based national research program in both academia and government. Held at the U.S. Geological Survey National Center, Reston, Va., the workshop was organized by Michael D. Max, Naval Research Laboratory, Washington, D.C.; William P. Dillon, USGS, Woods Hole, Mass.; and Rodney D. Malone, U.S. Department of Energy, Morgantown Energy Technology Center, Morgantown, W.Va. The 33 attendees represented academia (33%), federal agencies (58%), and industry (9%).

Eos, Transactions, American Geophysical Union

Geochemistry of coastal tarballs in southern California—A tribute to I. R. Kaplan

In the southern offshore California borderland, natural oil seeps occur mainly in the Santa Barbara Channel and Santa Monica Bay. Coastal tar residues (tarballs) from beaches bordering these water bodies were analyzed for six geochemical parameters: stable carbon isotopic compositions (δ 13 C) and four biomarker ratios (C 28 IC 29 hopane, sterane/hopane, refractory index, bisnorhopane index), and the presence or absence of trisnorhopane. The objectives of this study were to group these residues and infer possible sources and transport directions. Three major groups were established. Two groups are likely from natural seeps near the Channel Islands, whereas the third group probably comes from seeps within Santa Monica Bay. Residues from all groups occur on the Channel Islands and on mainland beaches from as far south as San Diego to Point Reyes north of San Francisco.

California

Ubiquitous tar balls with a California-source signature on the shorelines of Prince William Sound, Alaska

Although the shorelines of Prince William Sound still bear traces of the 1989 Exxon Valdez oil spill, most of the flattened tar balls that can be found today on these shorelines are not residues of Exxon Valdez oil. Instead, the carbon-isotopic and hydrocarbonbiomarker signatures of 61 tar ball samples, collected from shorelines throughout the northern and western parts of the sound, are all remarkably similar and have characteristics consistent with those of oil products that originated from the Monterey Formation source rocks of California. The carbonisotopic compositions of the tar balls are all closely grouped (<513Cpdb = -23.7 ± 0.2%o), within the range found in crude oils from those rocks, but are distinct from isotopic compositions of 28 samples of residues from the Exxon ValdezoW spill (<513Cpdb = -29.4 ± 0.1%o). Likewise, values for selected biomarker ratios in the tar balls are all similar but distinct from values of residues from the 1989 oil spill. Carbon-isotopic and biomarker signatures generally relate the tar balls to oil products used in Alaska before ~1970 for construction and pavements. How these tar balls with such similar geochemical characteristics became so widely dispersed throughout the northern and western parts of the sound is not known with certainty, but the great 1964 Alaska earthquake was undoubtedly an important trigger, causing spills from ruptured storage facilities of California-sourced asphalt and fuel oil into Prince William Sound.

Alaska

Early developments in petroleum geochemistry

Petroleum geochemistry is the outgrowth of the application of the principles and methods of organic chemistry to petroleum refining and petroleum geology . This paper reviews 120 years of petroleum geochemistry, from about 1860 to 1980, and includes a discussion of the formal recognition of petroleum geochemistry as an earth-science discipline starting in 1959 when a general petroleum geochemistry symposium was first organized at Fordham University, New York. A chronology of significant events, including concepts, techniques, and textbook publications, is presented. Because petroleum geochemistry has been a tool for petroleum exploration from the beginning, the early developments of surface prospecting, source-rock identification, and oil/oil and oil/source correlation are discussed, along with the application of geochemistry to petroleum migration, accumulation, and alteration. In addition the paper deals with the biomarker revolution, which began in earnest about 1964, and with early models of geothermal history. Concepts in petroleum geochemistry have continually evolved, enhanced by the development of new analytical techniques, leading to new discoveries concerning the origin and occurrence of petroleum.

Organic Geochemistry