Geology topics

Kathleen A. McCarthy

Publications and source records attributed to Kathleen A. McCarthy.

13 recordsLinked to original sources

USGS2018

Agriculture — A river runs through it — The connections between agriculture and water quality

Sustaining the quality of the Nation’s water resources and the health of our diverse ecosystems depends on the availability of sound water-resources data and information to develop effective, science-based policies. Effective management of water resources also brings more certainty and efficiency to important economic sectors. Taken together, these actions lead to immediate and longterm economic, social, and environmental benefits that make a difference to the lives of the almost 400 million people projected to live in the United States by 2050. In 1991, Congress established the U.S. Geological Survey National Water-Quality Assessment (NAWQA) to address where, when, why, and how the Nation’s water quality has changed, or is likely to change in the future, in response to human activities and natural factors. Since then, NAWQA has been a leading source of scientific data and knowledge used by national, regional, state, and local agencies to develop science-based policies and management strategies to improve and protect water resources used for drinking water, recreation, irrigation, energy development, and ecosystem needs. Plans for the third decade of NAWQA (2013–23) address priority water-quality issues and science needs identified by NAWQA stakeholders, such as the Advisory Committee on Water Information and the National Research Council, and are designed to meet increasing challenges related to population growth, increasing needs for clean water, and changing land-use and weather patterns. This report is one of a series of publications, The Quality of Our Nation’s Waters , which describes major findings of the NAWQA Project on water-quality issues of regional and national concern and provides science-based information for assessing and managing the quality of our groundwater resources. Other reports in this series focus on occurrence and distribution of nutrients, pesticides, and volatile organic compounds in streams and groundwater, the effects of contaminants and stream-flow alteration on the condition of aquatic communities in streams, and on the quality of groundwater from private domestic and public supply wells. Each reports builds toward a more comprehensive understanding of the quality of regional and national water resources. All NAWQA reports are available online ( https://water.usgs.gov/nawqa/bib/ ). We hope this publication will provide you with insights and information to meet your water-resource needs and will foster increased citizen awareness and involvement in the protection and restoration of our Nation’s waters. The information in this report is intended primarily for those interested or involved in resource management and protection, conservation, regulation, and policymaking at the regional and national levels.

Circular↗

USGS2016

Contrasting nitrogen fate in watersheds using agricultural and water quality information

Surplus nitrogen (N) estimates, principal component analysis (PCA), and end-member mixing analysis (EMMA) were used in a multisite comparison contrasting the fate of N in diverse agricultural watersheds. We applied PCA-EMMA in 10 watersheds located in Indiana, Iowa, Maryland, Nebraska, Mississippi, and Washington ranging in size from 5 to 1254 km 2 with four nested watersheds. Watershed Surplus N was determined by subtracting estimates of crop uptake and volatilization from estimates of N input from atmospheric deposition, plant fixation, fertilizer, and manure for the period from 1987 to 2004. Watershed average Surplus N ranged from 11 to 52 kg N ha −1 and from 9 to 32% of N input. Solute concentrations in streams, overland runoff, tile drainage, groundwater (GW), streambeds, and the unsaturated zone were used in the PCA-EMMA procedure to identify independent components contributing to observed stream concentration variability and the end-members contributing to streamflow and NO 3 load. End-members included dilute runoff, agricultural runoff, benthic-processing, tile drainage, and oxic and anoxic GW. Surplus N was larger in watersheds with more permeable soils (Washington, Nebraska, and Maryland) that allowed greater infiltration, and oxic GW was the primary source of NO 3 load. Subsurface transport of NO 3 in these watersheds resulted in some removal of Surplus N by denitrification. In less permeable watersheds (Iowa, Indiana, and Mississippi), NO 3 was rapidly transported to the stream by tile drainage and runoff with little removal. Evidence of streambed removal of NO 3 by benthic diatoms was observed in the larger watersheds.

Indiana, Iowa, Maryland, Nebraska, Mississippi, Wa↗

USGS2014

Time-integrated passive sampling as a complement to conventional point-in-time sampling for investigating drinking-water quality, McKenzie River Basin, Oregon, 2007 and 2010-11

The Eugene Water & Electric Board (EWEB) supplies drinking water to approximately 200,000 people in Eugene, Oregon. The sole source of this water is the McKenzie River, which has consistently excellent water quality relative to established drinking-water standards. To ensure that this quality is maintained as land use in the source basin changes and water demands increase, EWEB has developed a proactive management strategy that includes a combination of conventional point-in-time discrete water sampling and time‑integrated passive sampling with a combination of chemical analyses and bioassays to explore water quality and identify where vulnerabilities may lie. In this report, we present the results from six passive‑sampling deployments at six sites in the basin, including the intake and outflow from the EWEB drinking‑water treatment plant (DWTP). This is the first known use of passive samplers to investigate both the source and finished water of a municipal DWTP. Results indicate that low concentrations of several polycyclic aromatic hydrocarbons and organohalogen compounds are consistently present in source waters, and that many of these compounds are also present in finished drinking water. The nature and patterns of compounds detected suggest that land-surface runoff and atmospheric deposition act as ongoing sources of polycyclic aromatic hydrocarbons, some currently used pesticides, and several legacy organochlorine pesticides. Comparison of results from point-in-time and time-integrated sampling indicate that these two methods are complementary and, when used together, provide a clearer understanding of contaminant sources than either method alone.

Oregon↗

USGS2012

Water-quality data from semipermeable-membrane devices and polar organic chemical integrative samplers deployed in the McKenzie River basin, Oregon

Two types of passive samplers—the semipermeable membrane device (SPMD) and the polar organic chemical integrative sampler (POCIS)—are being used to collect data from the McKenzie River, Oregon. The McKenzie River is the source of drinking water for the City of Eugene, Oregon, and passive-sampler data are part of an ongoing monitoring effort designed to help understand and protect the drinking water source. Data from the passive samplers are reported here. This data report is dynamic and will be appended with additional data as they become available.

Oregon↗

USGS2012

Environmental settings of the South Fork Iowa River basin, Iowa, and the Bogue Phalia basin, Mississippi, 2006-10

Studies of the transport and fate of agricultural chemicals in different environmental settings were conducted by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program's Agricultural Chemicals Team (ACT) at seven sites across the Nation, including the South Fork Iowa River basin in central Iowa and the Bogue Phalia basin in northwestern Mississippi. The South Fork Iowa River basin is representative of midwestern agriculture, where corn and soybeans are the predominant crops and a large percentage of the cultivated land is underlain by artificial drainage. The Bogue Phalia basin is representative of corn, soybean, cotton, and rice cropping in the humid, subtropical southeastern United States. Details of the environmental settings of these basins and the data-collection activities conducted by the USGS ACT over the 2006-10 study period are described in this report.

Iowa;Mississippi↗

USGS2011

Discrete and continuous water-quality data and hydrologic parameters from seven agricultural watersheds in the United States, 2002-09

Field and analytical methods; discrete organic and non-organic water-quality data and associated quality-control data; and continuous hydrologic and water-quality parameters are reported for sites in California, Indiana, Iowa, Maryland, Mississippi, Nebraska, and Washington. The sites were sampled as part of the U.S. Geological Survey National Water-Quality Assessment Program?s Agricultural Chemicals Team study to better understand how environmental processes and agricultural practices interact to determine the transport and fate of agricultural chemicals in the environment.

Data Series↗

USGS2010

Transport of volatile organic compounds across the capillary fringe

Physical experiments were conducted to investigate the transport of a dissolved volatile organic compound (trichloroethylene, TCE) from shallow groundwater to the unsaturated zone under a variety of conditions including changes in the soil moisture profile and water table position. Experimental data indicated that at moderate groundwater velocities (0.1 m/d), vertical mechanical dispersion was negligible and molecular diffusion was the dominant vertical transport mechanism. Under these conditions, TCE concentrations decreased nearly 3 orders of magnitude across the capillary fringe and soil gas concentrations remained low relative to those of underlying groundwater. Data collected during a water table drop showed a short-term increase in concentrations throughout most of the unsaturated zone, but these concentrations quickly declined and approached initial values after the water table was returned to its original level. In the deep part of the unsaturated zone, the water table drop resulted in a long-term decrease in concentrations, illustrating the effects of hysteresis in the soil moisture profile. A two-dimensional random walk advection-diffusion model was developed to simulate the experimental conditions, and numerical simulations agreed well with experimental data. A simpler, one-dimensional finite-difference diffusion-dispersion model was also developed. One-dimensional simulations based on molecular diffusion also agreed well with experimental data. Simulations which incorporated mechanical dispersion tended to overestimate flux across the capillary fringe. Good agreement between the one- and two-dimensional models suggested that a simple, one-dimensional approximation of vertical transport across the capillary fringe can be useful when conditions are appropriate.

Water Resources Research↗

USGS2009

Evaluation of passive samplers for long-term monitoring of organic compounds in the untreated drinking water supply for the city of Eugene, Oregon, September–October 2007

Two types of passive samplers, polar organic chemical integrative samplers (POCIS) and semipermeable membrane devices (SPMDs), were deployed at three sites in the McKenzie River basin during September-October 2007. The McKenzie River is the source of drinking water for the city of Eugene, Oregon, and the work presented here was designed to evaluate the use of POCIS and SMPDs as part of a long-term monitoring plan for the river. Various compounds were detected in extracts from the POCIS and SPMDs, indicating that some compounds of concern are present in the McKenzie River basin, including the intake for the drinking water plant. However, most concentrations were near the quantitation limits of the analytical methods used - generally at subnanogram per liter concentrations - and would not have been detectable with conventional water sampling and analysis methods. These results indicate that both POCIS and SPMDs are well suited to monitor organic compounds in the McKenzie River basin.

Oregon↗

USGS1999

Investigation of the distribution of organochlorine and polycyclic aromatic hydrocarbon compounds in the Lower Columbia River using semipermeable-membrane devices

Organochlorine and polycyclic aromatic hydrocarbon compounds are of concern in the Columbia River Basin because of their adverse effects on fish and wildlife. Because these compounds can have important biological consequences at concentrations well below the detection limits associated with conventional water-sampling techniques, we used semipermeable membrane devices (SPMDs) to sample water, and achieved sub-parts-per-quintillion detection limits. We deployed SPMDs during 1997 low-flow conditions and 1998 high-flow conditions at nine main-stem sites and seven tributary sites, spanning approximately 700 miles of the Columbia River. We also collected streambed sediment from three sites. SPMD extracts and sediments were analyzed for polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, polychlorinated biphenyls, organochlorine pesticides and related transformation products, and polycyclic aromatic hydrocarbons. Our data indicate that (1) in the absence of additional sources, mechanisms such as volatilization, dilution, and settling of suspended particles can act to significantly reduce concentrations of contaminants along the river's flow path, (2) elevated concentrations of contaminants in the Portland-Vancouver area are primarily from local rather than upstream sources, (3) elevated concentrations of many compounds tend to be diluted during periods of high discharge, (4) much higher discharge in the main stem considerably dilutes elevated concentrations entering from tributaries, (5) the distribution of hydrophobic organic compounds in streambed sediment is not necessarily indicative of their distribution in the dissolved-phase, and (6) SPMDs can reveal patterns of contaminant occurrence at environmentally relevant concentrations that are undetectable by conventional water-sampling techniques.

Oregon↗

USGS1998

Natural attenuation of chlorinated-hydrocarbon contamination at Fort Wainwright, Alaska: A hydrogeochemical and microbiological investigation workplan

Natural attenuation processes include biological degradation, by which microorganisms break down contaminants into simpler product compounds; adsorption of contaminants to soil particles, which decreases the mass of contaminants dissolved in ground water; and dispersion, which decreases dissolved contaminant concentrations through dilution. The primary objectives of this study are to (1) assess the degree to which such natural processes are attenuating chlorinated-hydrocarbon contamination in ground water, and (2) evaluate the effects of ground-water/surface-water interactions on natural-attenuation processes in the area of the former East and West Quartermasters Fueling Systems for Fort Wainwright, Alaska. The study will include investigations of the hydrologic, geochemical, and microbiological processes occurring at this site that influence the transport and fate of chlorinated hydrocarbons in ground water. To accomplish these objectives, a data-collection program has been initiated that includes measurements of water-table elevations and the stage of the Chena River; measurements of vertical temperature profiles within the subsurface; characterization of moisture distribution and movement in the unsaturated zone; collection of ground-water samples for determination of both organic and inorganic chemical constituents; and collection of ground-water samples for enumeration of microorganisms and determination of their potential to mineralize contaminants. We will use results from the data-collection program described above to refine our conceptual model of hydrology and contaminant attenuation at this site. Measurements of water-table elevations and river stage will help us to understand the magnitude and direction of ground-water flow and how changes in the stage of the Chena River affect ground-water flow. Because ambient ground water and surface water typically have different temperature characteristics, temperature monitoring will likely provide further insight into ground-water/surface-water interactions in the subsurface. Characterization of the unsaturated zone will improve our understanding of interactions among ground water, the unsaturated zone, and the atmosphere. The interactions likely of importance to this study include the migration of water, dissolved contaminants, nutrients, and gases (oxygen, carbon dioxide, and methane) between the saturated and unsaturated zones. We will use the results of ground-water chemical analyses to determine the spatial and temporal distribution of (1) chlorinated-hydrocarbon contaminants and their degradation products, (2) oxidation-reduction indicators, (3) nutrients, and (4) major ground-water ions. These water-quality data will provide insight into ground-water flow directions, interactions between ground water and surface water, attenuation of contaminant concentrations caused by dispersion, and intrinsic microbiological processes. Microbiological analyses will indicate whether microorganisms at the site are capable of degrading the contaminants of interest, and will allow us to estimate their potential to attenuate existing contamination. Physical and chemical data interpreted as part of the analysis of ground water and surface water mixing will improve our understanding of the relationship between water quality and contaminant source mixing.

Alaska↗

USGS1997

Assessment of the water resources of the Grand Ronde area, Oregon

Stream hydrographs show that throughout the Grand Ronde area most precipitation follows surface or shallow subsurface pathways to streams, resulting in rapid runoff and little natural water storage within the basin. Limited storage and low aquifer permeability restrict base flow to streams, and streamflows therefore decline rapidly once precipitation ceases. Shallow ground water and springs occur throughout the area, but because of the low permeability of aquifer materials, nearly all wells and springs have low yields. Water quality in streams, wells, and springs is generally good, but saline ground water has been reported on a number of drillers' logs for the study area and in several previous investigations of nearby areas. Further development of water resources in the Grand Ronde area is likely to be constrained by existing downstream water rights, the low permeability of geologic materials throughout the area, and possibly the intrusion of saline water. However, construction of facilities to store available water and thus compensate for low yields could provide a reliable, sustainable water supply for the Grand Ronde area.

Oregon↗

USGS1994

Assessment of the hydrologic interaction between Imikpuk Lake and the adjacent airstrip site near Barrow, Alaska, 1993

Imikpuk Lake serves as the drinking water source for the Ukpeagvik Inupiat Corporation-National Arctic Research Laboratory (UIC-NARL), formerly known as the Naval Arctic Research Laboratory, near Barrow, Alaska. During the 1970's and 1980's, accidental releases of more than 1,300 cubic meters of various types of fuel occurred at the airstrip site adjacent to the lake. To aid an assessment of the potential risk 10 the quality of water in the lake posed by fuel remaining in the subsurface, the hydrologic interaction between the lake and ground water at the airstrip site was examined. The study area lies within the region of continuous permafrost where hydrologic processes are largely controlled by the short annual thaw season and the presence of near-surface permafrost. Runoff occurs for only a short period each year, typically from early or mid-June to late September, and a shallow ground- water system develops during approximately the same period as a result of shallow thawing of the subsurface. During the spring and summer of 1993, snowpack and surface-water data were collected throughout the Imikpuk Lake basin, and subsurface- flow-system data were collected at the airstrip site. The total annual inflow to the lake was estimated 10 be approximately 300,000 cubic meters per year, based on four methods of estimation. The ground-water flow system at the airstrip site is complex, primarily because of variations in local land-surface topography. Subsurface frost-elevation data indicate that a permafrost ridge exists beneath one of the elevated building pads at the site. Similar ridges beneath elevated roadways at the site may act as impediments to ground-water flow, reducing the flux of subsurface water to Imikpuk Lake. However, on the basis of the assumption that such impediments do not reduce flux substantially, the ground-water flux from the airstrip site was estimated to be approximately 173 cubic meters per year--less than 0.1 percent of the estimated annual inflow to Imikpuk Lake.