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Karen R. Burow

Publications and source records attributed to Karen R. Burow.

29 records · Page 2Linked to original sources

Water-Quality Assessment of the San Joaquin-Tulare Basins: Entering a new decade

In 1991, the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey began to address the need for consistent and scientifically sound information for managing the Nation's water resources. The long-term goals of this program are to assess the status of the quality of freshwater streams and aquifers, to describe trends or changes in water quality over time, and to provide a sound understanding of the natural and human factors that affect the quality of these resources (Hirsch and others, 1988). Investigations are being conducted within major river basins and aquifer systems, or 'study units,' throughout the Nation to provide a framework for national and regional water-quality assessments. In 2001, the NAWQA Program began its second decade of intensive water-quality assessments. Forty-two of the original 59 study units (reduced by elimination or combination) are being revisited (Gilliom and others, 2001). The San Joaquin-Tulare Basins study unit (fig. 1), located in central California, was a part of the first decadal cycle of the Program investigations and remains in the second cycle.

California

Hydrogeologic characterization of the Modesto Area, San Joaquin Valley, California

Hydrogeologic characterization was done to develop an understanding of the hydrogeologic setting near Modesto by maximizing the use of existing data and building on previous work in the region. A substantial amount of new lithologic and hydrologic data are available that allow a more complete and updated characterization of the aquifer system. In this report, geologic units are described, a database of well characteristics and lithology is developed and used to update the regional stratigraphy, a water budget is estimated for water year 2000, a three-dimensional spatial correlation map of aquifer texture is created, and recommendations for future data collection are summarized. The general physiography of the study area is reflected in the soils. The oldest soils, which have low permeability, exist in terrace deposits, in the interfan areas between the Stanislaus, Tuolumne, and Merced Rivers, at the distal end of the fans, and along the San Joaquin River floodplain. The youngest soils have high permeability and generally have been forming on the recently deposited alluvium along the major stream channels. Geologic materials exposed or penetrated by wells in the Modesto area range from pre-Cretaceous rocks to recent alluvium; however, water-bearing materials are mostly Late Tertiary and Quaternary in age. A database containing information from more than 3,500 drillers'logs was constructed to organize information on well characteristics and subsurface lithology in the study area. The database was used in conjunction with a limited number of geophysical logs and county soil maps to define the stratigraphic framework of the study area. Sequences of red paleosols were identified in the database and used as stratigraphic boundaries. Associated with these paleosols are very coarse grained incised valley-fill deposits. Some geophysical well logs and other sparse well information suggest the presence of one of these incised valley-fill deposits along and adjacent to the Tuolumne River east of Modesto, a feature that may have important implications for ground-water flow and transport in the region. Although extensive work has been done by earlier investigators to define the structure of the Modesto area aquifer system, this report has resulted in some modification to the lateral extent of the Corcoran Clay and the regional dip of the Mehrten Formation. Well logs in the database indicating the presence of the Corcoran Clay were used to revise the eastern extent of the Corcoran Clay, which lies approximately parallel to the axis of valley. The Mehrten Formation is distinguished in the well-log database by its characteristic black sands consisting of predominantly andesitic fragments. Black sands in wells listed in the database indicate that the formation may lie as shallow as 120 meters (400 feet) below land surface under Modesto, approximately 90 meters (300 feet) shallower than previously thought. The alluvial aquifer system in the Modesto area comprises an unconfined to semiconfined aquifer above and east of the Corcoran Clay confining unit and a confined aquifer beneath the Corcoran Clay. The unconfined aquifer is composed of alluvial sediments of the Modesto, Riverbank, and upper Turlock Lake formations. The unconfined aquifer east of the Corcoran Clay becomes semiconfined with depth due to the numerous discontinuous clay lenses and extensive paleosols throughout the aquifer thickness. The confined aquifer is composed primarily of alluvial sediments of the Turlock Lake and upper Mehrten Formations, extending from beneath the Corcoran Clay to the base of fresh water. Ground water in the unconfined to semiconfined aquifer flows to the west and southwest. The primary source of present-day recharge is percolating excess irrigation water. The primary ground-water discharge is extensive ground-water pumping in the unconfined to semiconfined aquifer, imposing a significant component of vertical flow in the system. A water budget was calculated for water year 2000 using a land-use approach. During water year 2000, the total water supply in the Modesto area was more than 2.5 billion m3 (cubic meter) (2 million acre-ft [acre-foot]). Surface-water deliveries accounted for 60 percent of the total water supply, whereas ground-water pumpage accounted for 40 percent. Ninety-four percent of the water supply was used to meet irrigation demand and approximately 6 percent was used to meet urban demand. The total recharge in the model area was estimated at 1.4 billion m3 (1,100,000 acre-ft). The largest component of recharge is from excess irrigation water (58 percent); precipitation in excess of crop requirements accounted for 41 percent of the recharge. Geostatistical methods were used to develop a spatial correlation model of the percentage of coarse-grained texture in the Modesto area. The mean percentage coarse-grained texture calculated for each depth increment indicates a regional trend of decreasing coarse-grained texture with increasing depth, which is consistent with increasingly consolidated sediments with depth in the study area. The three-dimensional kriged estimates of percentage coarse-grained texture show significant heterogeneity in the texture of the sedimentary deposits. Assuming the hydraulic conductivity is correlated to the texture, the kriged result implies significant heterogeneity in the hydrogeologic framework.

California

Hydrogeologic data from a shallow flooding demonstration project, Twitchell Island, California, 1997-2001

Data were collected during a study to determine the effects of continuous shallow flooding on ground-water discharge to an agricultural drainage ditch on Twitchell Island, California. The conceptual model of the hydrogeologic setting was detailed with soil coring and borehole-geophysical logs. Twenty-two monitoring wells were installed to observe hydraulic head. Ten aquifer slug tests were done in peat and mineral sediments. Ground-water and surface-water temperature was monitored at 14 locations. Flow to and from the pond was monitored through direct measurement of flows and through the calculation of a water budget. These data were gathered to support the development of a two-dimensional ground-water flow model. The model will be used to estimate subsurface discharge to the drainage ditch as a result of the pond. The estimated discharge will be used to estimate the concentrations of DOC that can be expected in the ditch.

Open-File Report

Low-Level Volatile Organic Compounds in Active Public Supply Wells as Ground-Water Tracers in the Los Angeles Physiographic Basin, California, 2000

Data were collected to evaluate the use of low-level volatile organic compounds (VOC) to assess the vulnerability of public supply wells in the Los Angeles physiographic basin. Samples of untreated ground water from 178 active public supply wells in the Los Angeles physiographic basin show that VOCs were detected in 61 percent of the ground-water samples; most of these detections were low, with only 29 percent above 1 mg/L (microgram per liter). Thirty-nine of the 86 VOCs analyzed were detected in at least one sample, and 11 VOCs were detected in 7 percent or more of the samples. The six most frequently detected VOCs were trichloromethane (chloroform) (46 percent); trichloroethene (TCE) (28 percent); tetrachloro-ethene (PCE) (19 percent); methyl tert-butyl ether (MTBE) (14 percent); 1,1-dichloroethane (11 percent); and 1,1,1-trichloroethane (TCA) (11 percent). These VOCs were also the most frequently detected VOCs in ground water representative of a wide range of hydrologically conditions in urban areas nationwide. Only two VOCs (TCE and PCE) exceeded state and federal primary maximum contaminant levels (MCL) for drinking water in a total of seven samples. Because samples were collected prior to water treatment, sample concentrations do not represent the concentrations entering the drinking-water system.Ground water containing VOCs may be considered to be a tracer of postindustrial-aged water-water that was recharged after the onset of intense urban development. The overall distribution of VOC detections is related to the hydrological and the engineered recharge facilities in the Coastal Los Angeles Basin and the Coastal Santa Ana Basin that comprise the Los Angeles physiographic basin. Most of the ground-water recharge occurs at engineered recharge facilities in the generally coarse-grained northeastern parts of the study area (forebay areas). Ground-water recharge from the land surface is minimal in the southwestern part of the basins, distal from the recharge facilities, where clay layers impede the vertical migration of ground water (pressure areas).VOCs are not uniformly distributed over the study area. Most of the wells with multiple VOC detections, which also have the highest concentrations, are in the forebay areas and are clustered proximal to the recharge facilities. In addition, the number of VOC detections and VOC concentrations decrease beyond about 10-15 kilometers from the recharge facilities. The distribution of individual VOCs is also related to their history of use. MTBE traces ground water recharged during about the last decade and is detected almost exclusively in the forebay areas. Chloroform, which has been used since the 1920s, is more widely distributed and is detected at the greatest distances from the recharge facilities.Downward migration of VOCs from the land surface may be a viable process for VOCs to reach aquifers in parts of the forebay areas, but there is little indication that the same process is active in the pressure area. The lack of contrast in the number of VOC detections between wells of different depths over most of the study area suggests that the downward migration from the land surface is not a dominant pathway for VOCs to travel to the capture zones of public supply wells. Isolated occurrences of multiple VOC detections and high concentrations of VOCs in individual wells may indicate rapid vertical transport from a localized source. Stable isotope data indicate that ground water containing VOCs is a mixture of local precipitation and runoff with water that is isotopically lighter (more negative) than the local sources. The isotopically lighter water could either be Colorado River water or State Water Project water, both of which are imported to the basin and used as a source of recharge to the ground-water flow system. The stable isotope data support the interpretation that VOCs in ground water are associated with the engineered recharge facilities.Two of the most frequently detecte

Water-Resources Investigations Report

Water quality in the San Joaquin-Tulare basins, California, 1992-95

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the San Joaquin-Tulare Basins Study Unit and to relate these findings to water-quality issues of regional and national concern. The information is primarily intended for those who are involved in water-resource management. Yet, the information contained here may also interest those who simply wish to know more about the quality of water in the rivers and aquifers in the area where they live.

California

Environmental setting of the San Joaquin-Tulare basins, California

The National Water-Quality Assessment Program for the San Joaquin-Tulare Basins began in 1991 to study the effects of natural and anthropogenic influences on the quality of ground water, surface water, biology, and ecology. The San Joaquin-Tulare Basins study unit, which covers approximately 31,200 square miles in central California, is made up of the San Joaquin Valley, the eastern slope of the Coast Ranges to the west, and the western slope of the Sierra Nevada to the east. The sediments of the San Joaquin Valley can be divided into alluvial fans and basin deposits. The San Joaquin River receives water from tributaries draining the Sierra Nevada and Coast Ranges, and except for streams discharging directly to the Sacramento-San Joaquin Delta, is the only surface- water outlet from the study unit. The surface-water hydrology of the San Joaquin-Tulare Basins study unit has been significantly modified by development of water resources. Almost every major river entering the valley from the Sierra Nevada has one or more reservoirs. Almost every tributary and drainage into the San Joaquin River has been altered by a network of canals, drains, and wasteways. The Sierra Nevada is predominantly forested, and the Coast Ranges and the foothills of the Sierra Nevada are predominately rangeland. The San Joaquin Valley is dominated by agriculture, which utilized approximately 14.7 million acre-feet of water and 597 million pounds active ingredient of nitrogen and phosphorus fertilizers in 1990, and 88 million pounds active ingredient of pesticides in 1991. In addition, the livestock industry contributed 318 million pounds active ingredient of nitrogen and phosphorus from manure in 1987. This report provides the background information to assess the influence of these and other factors on water quality and to provide the foundation for the design and interpretation of all spatial data. These characterizations provide a basis for comparing the influences of human activities among basins and specific land use settings, as well as within and among study units at the national level.

California

Occurrence of nitrate and pesticides in ground water beneath three agricultural land-use settings in the eastern San Joaquin Valley, California, 1993-1995

The processes that affect nitrate and pesticide occurrence may be better understood by relating ground-water quality to natural and human factors in the context of distinct, regionally extensive, land- use settings. This study assesses nitrate and pesticide occurrence in ground water beneath three agricultural land-use settings in the eastern San Joaquin Valley, California. Water samples were collected from 60 domestic wells in vineyard, almond, and a crop grouping of corn, alfalfa, and vegetable land-use settings. Each well was sampled once during 1993?1995. This study is one element of the U.S. Geological Survey?s National Water-Quality Assessment Program, which is designed to assess the status of, and trends in, the quality of the nation?s ground- and surface-water resources and to link the status and trends with an understanding of the natural and human factors that affect the quality of water. The concentrations and occurrence of nitrate and pesticides in ground-water samples from domestic wells in the eastern alluvial fan physiographic region were related to differences in chemical applica- tions and to the physical and biogeochemical processes that charac- terize each of the three land-use settings. Ground water beneath the vineyard and almond land-use settings on the coarse-grained, upper and middle parts of the alluvial fans is more vulnerable to nonpoint- source agricultural contamination than is the ground water beneath the corn, alfalfa, and vegetable land-use setting on the lower part of the fans, near the basin physiographic region. Nitrate concentrations ranged from less than 0.05 to 55 milligrams per liter, as nitrogen. Nitrate concentrations were significantly higher in the almond land-use setting than in the vineyard land-use setting, whereas concentrations in the corn, alfalfa, and vegetable land-use setting were intermediate. Nitrate concentrations exceeded the maximum contaminant level in eight samples from the almond land- use setting (40 percent), in seven samples from the corn, alfalfa, and vegetable land-use setting (35 percent), and in three samples from the vineyard land-use setting (15 percent). The physical and chemical characteristics of the vineyard and the almond land-use settings are similar, characterized by coarse-grained sediments and high dissolved- oxygen concentrations, reflecting processes that promote rapid infiltration of water and solutes. The high nitrate concentrations in the almond land-use setting reflect the high amount of nitrogen appli- cations in this setting, whereas the low nitrate concentrations in the vineyard land-use setting reflect relatively low nitrogen applications. In the corn, alfalfa, and vegetable land-use setting, the relatively fine-grained sediments, and low dissolved-oxygen concentrations, reflect processes that result in slow infiltration rates and longer ground-water residence times. The intermediate nitrate concentrations in the corn, alfalfa, and vegetable land-use setting are a result of these physical and chemical characteristics, combined with generally high (but variable) nitrogen applications. Twenty-three different pesticides were detected in 41 of 60 ground- water samples (68 percent). Eighty percent of the ground-water samples from the vineyard land-use setting had at least one pesticide detection, followed by 70 percent in the almond land-use setting, and 55 percent in the corn, alfalfa, and vegetable land-use setting. All concentra- tions were less than state or federal maximum contaminant levels only 5 of the detected pesticides have established maximum contaminant levels) with the exception of 1,2-dibromo-3-chloropropane, which exceeded the maximum contaminant level of 0.2 micrograms per liter in 10 ground-water samples from vineyard land-use wells and in 5 ground- water samples from almond land-use wells. Simazine was detected most often, occurring in 50 percent of the ground-water samples from the vineyard land-use wells and in 30 percent

Water-Resources Investigations Report

Nitrate and pesticides in ground water in the eastern San Joaquin Valley, California : Occurrence and trends

The occurrence of nitrate and pesticides in ground water in California's eastern San Joaquin Valley may be greatly influenced by the long history of intensive farming and irrigation and the generally permeable sediments. This study, which is part of the U.S. Geological Survey National Water-Quality Assessment Program, was done to assess the quality of the ground water and to do a preliminary evaluation of the temporal trends in nitrate and pesticides in the alluvial fans of the eastern San Joaquin Valley. Ground-water samples were collected from 30 domestic wells in 1995 (each well was sampled once during 1995). The results of the analyses of these samples were related to various physical and chemical factors in an attempt to understand the processes that control the occurrence and the concentrations of nitrate and pesticides. A preliminary evaluation of the temporal trends in the occurrence and the concentration of nitrate and pesticides was done by comparing the results of the analyses of the 1995 ground-water samples with the results of the analyses of the samples collected in 1986-87 as part of the U.S. Geological Survey Regional Aquifer-System Analysis Program. Nitrate concentrations (dissolved nitrate plus nitrite, as nitrogen) in ground water sampled in 1995 ranged from less than 0.05 to 34 milligrams per liter, with a median concentration of 4.6 milligrams per liter. Nitrate concentrations exceeded the maximum contaminant level of 10 milligrams per liter (as nitrogen) in 5 of the 30 ground-water samples (17 percent), whereas 12 of the 30 samples (40 percent) had nitrate concentrations less than 3.0 milligrams per liter. The high nitrate concentrations were associated with recently recharged, well-oxygenated ground water that has been affected by agriculture (indicated by the positive correlations between nitrate, dissolved-oxygen, tritium, and specific conductance). Twelve pesticides were detected in 21 of the 30 ground-water samples (70 percent) in 1995, although only 5 pesticides were detected in more than 10 percent of the ground-water samples. All 12 pesticides were detected at concentrations below the maximum contaminant levels, except the banned soil fumigants 1,2-dibromo-3-chloropropane (3 detections) and 1,2-dibromoethane (1 detection). Atrazine and desethyl atrazine (a transformation product of atrazine) were the most frequently detected pesticides; they were detected in 11 ground-water samples. The frequent detections of atrazine and desethyl atrazine may be related either to past applications of atrazine or to recent application on rights-of-way. Simazine was detected in 10 ground-water samples and diuron was detected in 4 ground-water samples. The detections of simazine and diuron are generally consistent with their reported applications on the crops near the wells where they were detected. 1,2,3-trichloropropane, a manufacturing by-product of 1,2-dichloropropane and 1,3- dichloropropene formulations, was detected in 4 ground-water samples. The occurrence of 1,2,3-trichloropropane, 1,2-dibromo-3-chloropropane, and 1,2-dibromoethane is probably related to past use. Similar to nitrate concentrations, pesticide occurrence was positively correlated to dissolved-oxygen concentrations, indicating that areas with high dissolved-oxygen concentrations may be vulnerable to contamination by nitrate and pesticides. High dissolved-oxygen concentrations may be associated with water that has been rapidly recharged. A comparison of the concentrations and the occurrence of nitrate and pesticides between 1986-87 and 1995 indicates that nitrate concentrations may pose a greater threat to the quality of the ground-water resource in this region than pesticides, in the context of current drinking-water standards. Nitrate concentrations were significantly higher in the 1995 ground-water samples than in the 1986-87 samples collected from the same wells.

Calfornia

Hydrogeologic facies characterization of an alluvial fan near Fresno, California, using geophysical techniques

DBCP (1,2-dibromo-3-chloropropane) contamination in the sole source aquifer near Fresno, California, has significantly affected drinking-water supplies. Borehole and surface geophysical data were integrated with borehole textural data to characterize the Kings River alluvial fan sediments and to provide a framework for computer modeling of pesticide transport in ground water. Primary hydrogeologic facies units, such as gravel, coarse sand or gravel, fine sand, and silt and clay, were identified in cores collected from three borings located on a 4.6-kilometer transect of multilevel monitoring wells. Borehole geophysical logs collected from seven wells and surface geophysical surveys were used to extrapolate hydrogeologic facies to depths of about 82meters and to correlate the facies units with neighboring drilling sites. Thickness ranged from 0.3to 13 meters for sand and gravel units, and from 0.3 to 17 meters for silt and clay. The lateral extent of distinct silt and clay layers was mapped using shallow seismic reflection and ground-penetrating radar techniques. About 3.6 kilometers of seismic reflection data were collected; at least three distinct fine-grained layers were mapped. The depth of investigation of the seismic survey ranged from 34 to 107 meters below land surface, and vertical resolution was about 3.5 meters. The ground-penetrating radar survey covered 3.6kilometers and imaged a 1.5-meters thick, continuous fine-grained layer located at a depth of about 8 meters. Integrated results from the borehole sediment descriptions and geophysical surveys provided a detailed characterization over a larger areal extent than traditional hydrogeologic methods alone.

Open-File Report

Effects of two contrasting agricultural land uses on shallow groundwater quality in the San Joaquin Valley, California; design and preliminary interpretation

From 1992 through 1994, the San Joaquin-Tulare Basins Study team of the USGS National Water Quality Assessment program investigated the occurrence and distribution of water quality constituents in shallow groundwater underlying two areas of different agricultural land uses: almond orchards and vineyards. The study was restricted to the alluvial fans of the eastern San Joaquin Valley, the area of most groundwater use in the valley. A geographic information system (GIS) was used to delineate the distribution of the two target land uses, to evaluate ancillary data, and to select candidate wells that fit prescribed criteria. Twenty domestic water supply wells were sampled in each of the two areas. In addition, pairs of observation wells were installed and sampled at five of the sites in each area to evaluate whether the water quality in the domestic wells reflects that of the shallow groundwater underlying the target land use. A preliminary evaluation of the results shows that nitrate concentrations in the shallow groundwater are significantly higher in the almond orchard areas than in the vineyard area (p=0.005). In contrast, concentrations of 1,2-dibromo-3-chloropropane (DBCP) were higher in the vineyard area than in the almond orchard area (p=0.032). The most frequently detected pesticides in groundwater underlying both areas were simazine, atrazine, and desethylatrazine (an atrazine degradation product). These observations are explained, in part, by differences in chemical application and hydrogeologic factors.

California