Geology topics

K.E. Bencala

Publications and source records attributed to K.E. Bencala.

22 records · Page 2Linked to original sources

USGS1988

Iron photoreduction and oxidation in an acidic mountain stream

In a small mountain stream in Colorado that receives acidic mine drainage, photoreduction of ferric iron results in a well-defined increase in dissolved ferrous iron during the day. To quantify this process, an instream injection of a conservative tracer was used to measure discharge at the time that each sample was collected. Daytime production of ferrous iron by photoreduction was almost four times as great as nighttime oxidation of ferrous iron. The photoreduction process probably involves dissolved or colloidal ferric iron species and limited interaction with organic species because concentrations of organic carbon are low in this stream.

Science↗

USGS1988

Diel variations in iron chemistry in an acidic stream in the Colorado Rocky Mountains, USA

In the Snake River, an acidic mountain stream in the Colorado Rocky Mountains, the concentration of dissolved iron is apparently unrelated to seasonal changes in hydrologic regime, which strongly influence the concentrations of most other dissolved constituents. Hourly sampling indicated that short-term fluctuations in iron chemistry occur, whereas the concentrations of most other dissolved constituents, including other trace metals, remain stable. During the day, greater concentrations of dissolved total and ferrous iron generally occurred during periods of full sunlight. Photoreduction of hydrous iron oxides, which are abundant in the fine sediment and as coatings on the rocks, may be responsible for these observations. Iron chemistry also varied at night, decreasing in dissolved total and ferrous iron until about midnight and increasing until dawn. Oxidation of ferrous iron, and several microbial processes, may contribute to these nighttime changes. In an on-site batch experiment using rocks and streamwater, an increase in dissolved total and ferrous iron occurred on exposure to sunlight, and ferrous oxidation occurred on return to darkness. Short-term fluctuations in iron chemistry are consistent with the lack of correlation between iron and other constituents in the long-term data, and illustrate the potential importance of complex in-stream processes in such stream systems.

Colorado↗

USGS1987

Phytoplankton productivity in relation to light intensity: A simple equation

A simple exponential equation is used to describe photosynthetic rate as a function of light intensity for a variety of unicellular algae and higher plants where photosynthesis is proportional to (1-e −β1 ). The parameter β ( =I k −1 "> =I k −1 ) is derived by a simultaneous curve-fitting method, where I is incident quantum-flux density. The exponential equation is tested against a wide range of data and is found to adequately describe P vs. I curves. The errors associated with photosynthetic parameters are calculated. A simplified statistical model (Poisson) of photon capture provides a biophysical basis for the equation and for its ability to fit a range of light intensities. The exponential equation provides a non-subjective simultaneous curve fitting estimate for photosynthetic efficiency ( a ) which is less ambiguous than subjective methods: subjective methods assume that a linear region of the P vs. I curve is readily identifiable. Photosynthetic parameters β and a are used widely in aquatic studies to define photosynthesis at low quantum flux. These parameters are particularly important in estuarine environments where high suspended-material concentrations and high diffuse-light extinction coefficients are commonly encountered.

Estuarine, Coastal and Shelf Science↗

USGS1985

Data from a solute transport experiment in the Leviathan Mine drainage, Alpine County, California, October 1982

A twenty-four hour injection of chloride and sodium was made into Leviathan Creek, Alpine County, California to aid interpretation of the coupled interactions between physical transport processes and geochemical reactions. Leviathan Creek was chosen because it receives acid mine drainage from Leviathan Mine, an abandoned open-pit sulfur mine. Water samples were collected at 15 sites along a 4.39 kilometer reach and analyzed for chloride, sodium, sulfate and fluoride. Dissolved concentrations are presented in tabular format and time-series plots. Duplicate samples were analyzed by two laboratories: the Central Laboratory, Denver, Colorado and a research laboratory in Menlo Park, California. A tabular comparison of the analyses and plots of the differences between the two laboratories is presented. Hydrographs and instantaneous discharge measurements are included. (USGS)

Open-File Report↗