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June E. Mirecki

Publications and source records attributed to June E. Mirecki.

4 recordsLinked to original sources

Leachate geochemistry at a municipal landfill, Memphis, Tennessee

A leachate plume emanating from the Shelby County Landfill located at Memphis, Tennessee is defined using selected major and trace inorganic constituents. High specific conductance values and elevated concentrations of ammonia, barium, boron, calcium, chloride, dissolved solids, potassium, sodium, and strontium were measured in water samples from wells screened in the alluvial and Memphis aquifers downgradient from or proximal to the landfill. Of these constituents, barium, boron, chloride, and strontium were used in the geochemical model code PHREEQE to estimate the percent leachate component in selected Memphis aquifer samples. Estimates of the leachate component in samples from affected Memphis aquifer wells range from 5 to 37 percent for barium and strontium, the most reliable tracers found during this study.

Groundwater

Hydrologic and geochemical evaluation of aquifer storage recovery in the Santee Limestone/Black Mingo Aquifer, Charleston, South Carolina, 1998-2002

The hydrologic and geochemical effects of aquifer storage recovery were evaluated to determine the potential for supplying the city of Charleston, South Carolina, with large quantities of potable water during emergencies, such as earthquakes, hurricanes, or hard freezes. An aquifer storage recovery system, including a production well and three observation wells, was installed at a site located on the Charleston peninsula. The focus of this study was the 23.2-meter thick Tertiary-age carbonate and sand aquifer of the Santee Limestone and the Black Mingo Group, the northernmost equivalent of the Floridan aquifer system. Four cycles of injection, storage, and recovery were conducted between October 1999 and February 2002. Each cycle consisted of injecting between 6.90 and 7.19 million liters of water for storage periods of 1, 3, or 6 months. The volume of recovered water that did not exceed the U.S. Environmental Protection Agency secondary standard for chloride (250 milligrams per liter) varied from 1.48 to 2.46 million liters, which is equivalent to 21 and 34 percent of the total volume injected for the individual tests. Aquifer storage recovery testing occurred within two productive zones of the brackish Santee Limestone/Black Mingo aquifer. The individual productive zones were determined to be approximately 2 to 4 meters thick, based on borehole geophysical logs, electromagnetic flow-meter testing, and specific-conductance profiles collected within the observation wells. A transmissivity and storage coefficient of 37 meters squared per day and 3 x 10-5, respectively, were determined for the Santee Limestone/Black Mingo aquifer. Water-quality and sediment samples collected during this investigation documented baseline aquifer and injected water quality, aquifer matrix composition, and changes in injected/aquifer water quality during injection, storage, and recovery. A total of 193 water-quality samples were collected and analyzed for physical properties, major and minor ions, and nutrients. The aquifer and treated surface water were sodiumchloride and calcium/sodium-bicarbonate water types, respectively. Forty-five samples were collected and analyzed for total trihalomethane. Total trihalomethane data collected during aquifer storage recovery cycle 4 indicated that this constituent would not restrict the use of recovered water for drinking-water purposes. Analysis of six sediment samples collected from a cored well located near the aquifer storage recovery site showed that quartz and calcite were the dominant minerals in the Santee Limestone/Black Mingo aquifer. Estimated cation exchange capacity ranged from 12 to 36 milliequivalents per 100 grams in the lower section of the aquifer. A reactive transport model was developed that included two 2-meter thick layers to describe each of the production zones. The four layers composing the production zones were assigned porosities ranging from 0.1 to 0.3 and hydraulic conductivities ranging from 1 to 8.4 meters per day. Specific storage of the aquifer and confining units was estimated to be 1.5 x 10-5 meter-1. Longitudinal dispersivity of all layers was specified to be 0.5 meter. Leakage through the confining unit was estimated to be minimal and, therefore, not used in the reactive transport modeling. Inverse geochemical modeling indicates that mixing, cation exchange, and calcite dissolution are the dominant reactions that occur during aquifer storage recovery testing in the Santee Limestone/Black Mingo aquifer. Potable water injected into the Santee Limestone/Black Mingo aquifer evolved chemically by mixing with brackish background water and reaction with calcite and cation exchangers in the sediment. Reactive-transport model simulations indicated that the calcite and exchange reactions could be treated as equilibrium processes.

South Carolina

Hydrogeology, ground-water quality, and source of ground water causing water-quality changes in the Davis well field at Memphis, Tennessee

An investigation was conducted by the U.S. Geological Survey from 1992 to 1994 to collect and interpret hydrogeologic and water-quality data to determine the source of ground water causing water-quality changes in water from wells screened in the Memphis aquifer in the Davis well field at Memphis, Tennessee. Water-quality changes in aquifers used for water supply are of concern because these changes can indicate a potential for contamination of the aquifers by downward leakage from near-surface sources. The water-quality changes at the Davis well field were detected by Memphis Light, Gas and Water Division, which has periodically sampled and analyzed water from many of the 14 production wells since the well field began operation in 1971. Memphis Light, Gas and Water Division analyzed the water samples primarily for hardness, alkalinity, chloride, ulfate, and iron. Results of the e analy es and results of more recent (1992) analyse of water samples by the U.S. Geological Survey indicate that the quality of water from eight of the production wells has changed since the well field began operation. For example, from 1972 to 1991, hardness of water from one well has increased from 90 to 292 milligrams per liter (224 percent). The confining unit, which separates the fluvial deposits aquifer from the Memphis aquifer in the area of the well field, is relatively thick and contains many clay layers. However, a test hole drilled for one of five shallow wells installed in the alluvial aquifer in the Mississippi Alluvial Plain just west of the well field indicated that the confining unit separating the alluvial aquifer from the Memphis aquifer locally is absent. Differences in hydrauLic head between the alluvial and fluvial deposits aquifers and the Memphis aquifer favor downward leakage of ground water. Thus, the absence of the confining unit beneath the Mississippi Alluvial Plain just west of the well field provides a direct pathway for water in the alluvial aquifer to enter the Memphis aquifer. Comparison of selected water-quality properties and major inorganic and trace element constituent concentrations in samples from the alluvial, fluvial deposits, and Memphis aquifers indicates that the source of ground water causing waterquality changes at the Davis well field is the alluvial aquifer west of the well field . The presence of tritium and chlorofluorocarbons in water from wells screened in the Memphis aquifer in the western part of the well field indicates that relatively young (post-1940) water from the alluvial aquifer has entered the Memphis aquifer. NETPATH geochemical model code was used to mix waters from the alluvial aquifer with water from the Memphis aquifer using chloride as a conservative tracer. The resulting models indicated that a mixture containing 3 percent alluvial aquifer water mixed with 97 percent unaffected Memphis aquifer water would produce the chloride concentration measured in water from the Memphis aquifer well most affected by water-quality changes. NETPATH also was used to calculate mixing percentages of alluvial and Memphis aquifer Abstract waters based on changes in the concentrations of selected dissolved major inorganic and trace element constituents that define the dominant reactions that occur during mixing. These models indicated that a mixture containing 18 percent alluvial aquifer water and 82 percent unaffected Memphis aquifer water would produce the major constituent and trace element concentrations measured in water from the Memphis aquifer well most affected by water-quality changes. However, these model simulations predicted higher dissolved methane concentrations than were measured in water samples from the Memphis aquifer wells.

Tennessee