Joshua J. Schwartz | USGS Science

USGS2022

Late Paleoproterozoic to early Mesoproterozoic deposition of quartz arenites across southern Laurentia

Supermature siliciclastic sequences were deposited between 1.64 Ga and 1.59 Ga over a broad swath of southern Laurentia in the Archean, Penokean, Yavapai, and Mazatzal Provinces. These siliciclastic sequences are notable for their extreme mineralogical and chemical maturity, being devoid of detrital feldspar and ferromagnesian minerals, containing the clay mineral kaolinite (or its metamorphic equivalent, pyrophyllite), and having a chemical index of alteration >95. Such maturity is the result of a perfect confluence of tectonic and climatic conditions, including a stable continental crust with low topographic relief (the Archean, Penokean, and Yavapai Provinces ca. 1.70 Ga), a warm humid climate, an elevated level of atmospheric CO 2 , and relatively acidic pore fluids in the critical zone. The weathered detritus was transported and deposited by southward-flowing streams across the Archean, Penokean, and Yavapai Provinces, ultimately to be deposited on 1.66 Ga volcanic and volcaniclastic rocks in the Mazatzal continental arc along the southern margin of Laurentia.

Laurentia↗

USGS2009

On the occurrence, trace element geochemistry, and crystallization history of zircon from in situ ocean lithosphere

We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro, and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs). The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a TiO2 ≈ 0.7, a SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La, Cl, S, Ca, and Fe, and low (Sm/La) N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects, in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance.

Contributions to Mineralogy and Petrology↗