USGS Science⌕ Search

Geology topics

John R. Jones

Publications and source records attributed to John R. Jones.

11 recordsLinked to original sources

Role of edaphic, hydrologic, and land cover variables in determining dissolved organic carbon in Missouri (USA) reservoirs and streams

In Missouri, distinct geophysical gradients influence statewide patterns in water quality. Here, we quantify the spatiotemporal variability of dissolved organic carbon (DOC) in reservoirs and streams and the edaphic, hydrologic, and land cover variables that account for cross-system variation. Datasets included statewide inventories collected over decades and studies with greater temporal resolution ( n = >6350 DOC measurements). Among reservoirs, the smallest DOC concentration was measured in a spring-fed system within a forested watershed, and the largest was where agricultural biosolids were applied to the land (range 1.0–15.9 mg/L, overall mean 5.8 mg/L). Reservoir values increased from the southern forested Highlands (mean 4.7 mg/L) to the northern agricultural Plains (mean 7.0 mg/L). Stream DOC was similar to reservoir values (overall mean in streams 6.3 mg/L; Highlands mean 4.0 mg/L; Plains mean 6.6 mg/L), despite differences in study design and collection period. Reservoir DOC increased in spring, indicative of allochthonous loading, with small autochthonous additions during a broad summer peak. Temporal variability in DOC was low relative to macronutrients and chlorophyll in both reservoirs and streams, indicating DOC may be a sensitive and readily detected indicator of temporal change in these systems. In regression analyses, watershed features accounted for more than 60% of overall cross-system variability in DOC in both reservoirs and streams. Driver-response relations, however, differed between regions. This analysis extends our understanding of environmental influences on surface water chemistry in Missouri and indicates DOC is nearly as predictable as macronutrients using landscape-level features.

Missouri↗

Nonlinear multidecadal trends in organic matter dynamics in Midwest reservoirs are a function of variable hydroclimate

Dissolved organic matter (DOM) and particulate organic matter (POM) can influence biogeochemical processes in aquatic systems. An understanding, however, of the source, composition, and processes driving inland reservoir organic matter (OM) cycling at a regional scale over the long term is currently unexplored. Here, we quantify decadal patterns (> 20 yr) of DOM quantity and composition and POM in 40 reservoirs in the midcontinent United States. We built 184 Random Forest models to identify how the relative influence of watershed characteristics and limnological parameters on OM dynamics may vary over time and in synchrony with hydroclimatic anomalies. The reservoir OM quantity and composition varied nonmonotonically through time and in contrast to lake browning observed in the northern hemisphere. Reservoir DOM composition switched from humic and aromatic during wet summers to aliphatic, potentially autochthonous DOM during particularly prolonged dry summers in the mid-2000s. The shift in reservoir DOM quantity and composition could be attributed to the change in time-varying control of watershed and limnological factors mediated by the hydroclimatic conditions. Watershed control (e.g., percent crops) was predominant during wet summers, while the effect of reservoir morphology (e.g., maximum depth) and water quality parameters (e.g., Secchi depth, chlorophyll a ) were evident during dry summers. Thus, future predictions of drier conditions may promote “greening” with negative implications for reservoir water quality and treated drinking water. Considering the nonlinear nature of reservoir OM dynamics and its controls will help to better mitigate water quality issues in these constructed systems increasingly impacted by global changes.

Missouri↗

LAGOS-NE: a multi-scaled geospatial and temporal database of lake ecological context and water quality for thousands of US lakes

Understanding the factors that affect water quality and the ecological services provided by freshwater ecosystems is an urgent global environmental issue. Predicting how water quality will respond to global changes not only requires water quality data, but also information about the ecological context of individual water bodies across broad spatial extents. Because lake water quality is usually sampled in limited geographic regions, often for limited time periods, assessing the environmental controls of water quality requires compilation of many data sets across broad regions and across time into an integrated database. LAGOS-NE accomplishes this goal for lakes in the northeastern-most 17 US states. LAGOS-NE contains data for 51 101 lakes and reservoirs larger than 4 ha in 17 lake-rich US states. The database includes 3 data modules for: lake location and physical characteristics for all lakes; ecological context (i.e., the land use, geologic, climatic, and hydrologic setting of lakes) for all lakes; and in situ measurements of lake water quality for a subset of the lakes from the past 3 decades for approximately 2600–12 000 lakes depending on the variable. The database contains approximately 150 000 measures of total phosphorus, 200 000 measures of chlorophyll, and 900 000 measures of Secchi depth. The water quality data were compiled from 87 lake water quality data sets from federal, state, tribal, and non-profit agencies, university researchers, and citizen scientists. This database is one of the largest and most comprehensive databases of its type because it includes both in situ measurements and ecological context data. Because ecological context can be used to study a variety of other questions about lakes, streams, and wetlands, this database can also be used as the foundation for other studies of freshwaters at broad spatial and ecological scales.

Connecticut, Iowa, Illinois, Indiana, Massachusett↗

Unexpected stasis in a changing world: Lake nutrient and chlorophyll trends since 1990

The United States (U.S.) has faced major environmental changes in recent decades, including agricultural intensification and urban expansion, as well as changes in atmospheric deposition and climate—all of which may influence eutrophication of freshwaters. However, it is unclear whether or how water quality in lakes across diverse ecological settings has responded to environmental change. We quantified water quality trends in 2913 lakes using nutrient and chlorophyll (Chl) observations from the Lake Multi-Scaled Geospatial and Temporal Database of the Northeast U.S. (LAGOS-NE), a collection of preexisting lake data mostly from state agencies. LAGOS-NE was used to quantify whether lake water quality has changed from 1990 to 2013, and whether lake-specific or regional geophysical factors were related to the observed changes. We modeled change through time using hierarchical linear models for total nitrogen (TN), total phosphorus (TP), stoichiometry (TN:TP), and Chl. Both the slopes (percent change per year) and intercepts (value in 1990) were allowed to vary by lake and region. Across all lakes, TN declined at a rate of 1.1% year −1 , while TP, TN:TP, and Chl did not change. A minority (7%–16%) of individual lakes had changing nutrients, stoichiometry, or Chl. Of those lakes that changed, we found differences in the geospatial variables that were most related to the observed change in the response variables. For example, TN and TN:TP trends were related to region-level drivers associated with atmospheric deposition of N; TP trends were related to both lake and region-level drivers associated with climate and land use; and Chl trends were found in regions with high air temperature at the beginning of the study period. We conclude that despite large environmental change and management efforts over recent decades, water quality of lakes in the Midwest and Northeast U.S. has not overwhelmingly degraded or improved.

Global Change Biology↗

Lake nutrient stoichiometry is less predictable than nutrient concentrations at regional and sub-continental scales

Production in many ecosystems is co-limited by multiple elements. While a known suite of drivers associated with nutrient sources, nutrient transport, and internal processing controls concentrations of phosphorus (P) and nitrogen (N) in lakes, much less is known about whether the drivers of single nutrient concentrations can also explain spatial or temporal variation in lake N:P stoichiometry. Predicting stoichiometry might be more complex than predicting concentrations of individual elements because some drivers have similar relationships with N and P, leading to a weak relationship with their ratio. Further, the dominant controls on elemental concentrations likely vary across regions, resulting in context dependent relationships between drivers, lake nutrients and their ratios. Here, we examine whether known drivers of N and P concentrations can explain variation in N:P stoichiometry, and whether explaining variation in stoichiometry differs across regions. We examined drivers of N:P in ~2,700 lakes at a sub-continental scale and two large regions nested within the sub-continental study area that have contrasting ecological context, including differences in the dominant type of land cover (agriculture vs. forest). At the sub-continental scale, lake nutrient concentrations were correlated with nutrient loading and lake internal processing, but stoichiometry was only weakly correlated to drivers of lake nutrients. At the regional scale, drivers that explained variation in nutrients and stoichiometry differed between regions. In the Midwestern U.S. region, dominated by agricultural land use, lake depth and the percentage of row crop agriculture were strong predictors of stoichiometry because only phosphorus was related to lake depth and only nitrogen was related to the percentage of row crop agriculture. In contrast, all drivers were related to N and P in similar ways in the Northeastern U.S. region, leading to weak relationships between drivers and stoichiometry. Our results suggest ecological context mediates controls on lake nutrients and stoichiometry. Predicting stoichiometry was generally more difficult than predicting nutrient concentrations, but human activity may decouple N and P, leading to better prediction of N:P stoichiometry in regions with high anthropogenic activity.

Ecological Applications↗

Seasonal patterns in carbon dioxide in 15 mid-continent (USA) reservoirs

Evidence suggests that lakes are important sites for atmospheric CO 2 exchange and so play a substantial role in the global carbon budget. Previous research has 2 weaknesses: (1) most data have been collected only during the open-water or summer seasons, and (2) data are concentrated principally on natural lakes in northern latitudes. Here, we report on the full annual cycle of atmospheric CO 2 exchanges of 15 oligotrophic to eutrophic reservoirs in the Glacial Till Plains of the United States. With one exception, these reservoirs showed an overall loss of CO 2 during the year, with most values within the lower range reported for temperate lakes. There was a strong cross-system seasonal pattern: an average of 70% of total annual CO 2 efflux occurred by the end of spring mixis; some 20% of annual flux was reabsorbed during summer stratification; and the remaining 50% of efflux was lost during autumnal mixing. Net annual flux was negatively correlated with depth and positively correlated with both water residence time and DOC, with the smallest annual CO 2 efflux measured in shallow fertile impoundments. Strong correlations yield relationships allowing regional up-scaling of CO 2 evasion. Understanding lacustrine CO 2 uptake and evasion requires seasonal analyses across the full range of lake trophic states and morphometric attributes.

Missouri↗

Temperature and oxygen in Missouri reservoirs

Vertical profiles of water temperature (n = 7193) and dissolved oxygen (n = 6516) were collected from 235 Missouri reservoirs during 1989–2007; most data were collected during May–August and provide a regional summary of summer conditions. Collectively, surface water temperature ranged from a mean of ~22 C in May to 28 C in July, and individual summer maxima typically were 28–32 C. Most (~95%) reservoirs stably stratify by mid-May, but few are deep enough to have hypolimnia with near-uniform temperatures. Among stratified reservoirs, maximum effective length and maximum depth accounted for 75% of the variation in mixed depth and thermocline depth. Ephemeral, near-surface thermoclines occurred in 39% of summer profiles and were most frequent in small, turbid reservoirs. Isotherms below the mixed layer deepen during stratification, and the water column is >20 C by August in all but the deepest reservoirs. Most reservoirs showed incipient dissolved oxygen (DO) depletion by mid-May, and by August, 80% of profiles had DO minima of <1 mg/L. Surface area and chlorophyll (Chl) explained 37% of variation in the earliest date of anoxia, and Chl explained >50% of variation in DO below the mixed layer during summer. Warm summer temperatures and widespread low DO often limit available fish habitat in Missouri reservoirs and compress warm-water fish communities into subsurface layers that exceed their thermal preferences. This study provides a regional baseline of reservoir temperature and oxygen conditions useful for future evaluations of eutrophication and the effects of a warming climate.

Missouri↗

A field assessment of long-term laboratory sediment toxicity tests with the amphipod Hyalella azteca

Response of the amphipod Hyalella azteca exposed to contaminated sediments for 10 to 42 d in laboratory toxicity tests was compared to responses observed in controlled three-month invertebrate colonization exposures conducted in a pond. Sediments evaluated included a sediment spiked with dichlorodiphenyldichloroethane (DDD) or dilutions of a field sediment collected from the Grand Calumet River (GCR) in Indiana (USA) (contaminated with organic compounds and metals). Consistent effects were observed at the highest exposure concentrations (400 ??g DDD/goc [DDD concentrations normalized to grams of organic carbon (goc) in sedimentl or 4% GCR sediment) on survival, length, and reproduction of amphipods in the laboratory and on abundance of invertebrates colonizing sediments in the field. Effect concentrations for DDD observed for 10-d length and 42-d reproduction of amphipods (e.g., chronic value [ChV] of 66 ??g DDD/goc and 25% inhibition concentration [IC25] of 68 ??g DDD/goc for reproduction) were similar to the lowest effect concentrations for DDD measured on invertebrates colonizing sediment the field. Effect concentrations for GCR sediment on 28-d survival and length and 42-d reproduction and length of amphipods (i.e., ChVs of 0.20-0.66% GCR sediment) provided more conservative effect concentrations compared to 10-d survival or length of amphipods in the laboratory or the response of invertebrates colonizing sediment in the field (e.g., ChVs of 2.2% GCR sediment). Results of this study indicate that use of chronic laboratory toxicity tests with H. azteca and benthic colonization studies should be used to provide conservative estimates of impacts on benthic communities exposed to contaminated sediments. Bioaccumulation of DDD by oligochaetes colonizing the DDD-spiked sediment was similar to results of laboratory sediment tests previously conducted with the oligochaete Lumbriculus variegates, confirming that laboratory exposures can be used to estimate bioaccumulation by oligochaetes exposed in the field. ?? 2005 SETAC.

Environmental Toxicology and Chemistry↗

Use of a subsurface plankton layer to benefit a cage-culture fishery in Lake Phewa, Nepal

The Nepalese government and some 225 families in the private sector are engaged in an expanding aquaculture program in lakes Phewa, Begnas and Rupa in the Pokhara Valley, Nepal (Swar & Pradhan 1992). Bighead carp ( Aristichthys nobilis ) and silver carp ( Hypopthalmichthys molitrix ) are propagated in hatchery ponds and are raised to market size in mesh enclosures (having sides, tops and bottoms) suspended to a depth of 2 m. Some 300 cages are presently in use, with annual production varying from 3.4 kg/m 3 Lake Phewa to about 5 kg/m 3 in lakes Begnas and Rupa (Swar & Pradhan 1992). These cage-reared fish are an important source of animal protein and revenue (Swar 1981). Tourism in the region provides growers a continuous market for their fish.

Lake Begnas, Lake Phewa, Lake Rupa↗

Toxicity of crude oil to the mayfly, Hexagenia bilineata (Ephemeroptera: Ephemeridae)

Effects of crude oil on survival and behavior of the mayfly Hexagenia bilineata were evaluated in laboratory studies. Mayfly nymphs were exposed to the water soluble and oil residue fractions of crude oil. Mayfly survival was not reduced by a 96-h exposure to either the water soluble fraction or the oil residue mixed with sediment. However, significant mortality did result from a 21-day exposure to oil residue mixed with sediment at concentrations as low as 500 μg g −1 . Survival was also reduced after a 21-day exposure to oil-contaminated sediments (1905 μg g −1 ) collected 6 weeks after a crude oil spill in the Chariton River, Missouri. In a behavioral test measuring habitat exclusion, organisms did not avoid contact with sediment containing oil residue (50–800 μg g −1 ). Collectively, results from these studies indicate that exposure to oil residue in sediment will reduce survival of H. bilineata in the laboratory and may reduce survival in the environment for 6 weeks or more after an oil spill,

Environmental Pollution↗

Evaluation of the river die-away biodegradation test

The reliability of the river die-away (RDA) test for establishing the biodegradability of chemicals was assessed. Reproducibility of biodegradation in the RDA test was analyzed under conditions in which the test is commonly done. Biodegradation results were not reproducible for di-2-ethylexyl phthalate (DEHP) and phthalic acid in replicated RDA tests using Missouri River water. Chemical and biological changes during the RDA tests probably reflected relative laboratory conditions. Initial suspended solids and subsequent DEHP biodegradation were directly related. Interpretation of RDA test results is enhanced by replicating experiments and comparing biodegradation of the test compound with a compound whose degradation properties are known. However, biodegradation measured with the RDA test is too variable and too dependent on laboratory treatment of samples to apply results directly to the aquatic environment.

Journal of the Water Pollution Control Federation↗