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Geology topics

John P. Hoffmann

Publications and source records attributed to John P. Hoffmann.

16 recordsLinked to original sources

Gut contents from multiple morphs of lake trout (Salvelinus namaycush) at two offshore shoals in Lake Superior

Four lake trout, Salvelinus namaycush , Walbaum 1792 morphs occur in Lake Superior: lean, siscowet, humper, and redfin. Diets of lean and siscowet have been relatively well described. However, less is known about diets of humper and redfin, and overall few studies have been conducted at offshore shoals. We compared gut content data among mature (357–867 mm) sympatric lake trout morphs caught at two offshore shoals in Lake Superior, Stannard Rock and Superior Shoal, in 2013 and 2014 (total n = 416). All morphs were caught in shallow (<50 m), mid (50–100 m), and deep (>100 m) strata. Invertebrates made up a greater portion of the stomach contents than did fish for all morphs by both percent occurrence and proportional biomass, and Mysis was the primary invertebrate consumed by all morphs at both sites. Coregonus spp. and deepwater sculpin, Myoxocephalus thompsonii were the most commonly consumed fish. Humper had the highest average proportional biomass of deepwater sculpin and had no other identifiable species of fish in their guts. Biomass of fish in redfin guts was highest for Coregonus spp., followed by similar amounts of deepwater sculpin and burbot, Lota lota . Diet overlap among morphs was high, and differences in prey consumption between sites are likely related to prey availability. Additional study is needed to determine if differences in trophic ecology between humper and other morphs are sufficient to support concurrent stocking of multiple morphs, particularly in light of recent declines in native prey fishes, especially Coregonus spp., in the Laurentian Great Lakes.

Lake Superior

Dietary versus nondietary fatty acid profiles of lake trout ecotypes from Lake Superior and Great Bear Lake: Are fish really what they eat?

Fatty acids are well-established biomarkers used to characterize trophic ecology, food-web linkages, and the ecological niche of many different taxa. Most often, fatty acids that are examined include only those previously identified as “dietary” or “extended dietary” biomarkers. Fatty acids considered as nondietary biomarkers, however, represent numerous fatty acids that can be extracted. Some studies may include nondietary fatty acids (i.e., combined with dietary fatty acids), but do not specifically assess them, whereas in other studies, these data are discarded. In this study, we explored whether nondietary biomarker fatty acids can provide worthwhile information by assessing their ability to discriminate intraspecific diversity within and between lakes. Nondietary fatty acids used as biomarkers delineated variation among regions, among locations within a lake, and among ecotypes within a species. Physiological differences that arise from differences in energy processing can be adaptive and linked to habitat use by a species’ ecotype and likely explains why nondietary fatty acid biomarkers can be a relevant tool to delineate intraspecific diversity. Little is known about the nondietary-mediated differences in fatty acid composition, but our results showed that nondietary fatty acid biomarkers can be useful tool in identifying variation.

Lake Superior

The Puʻu ʻŌʻō eruption of Kīlauea Volcano, Hawai‘i—Episode 21 through early episode 48, June 1984–April 1987

The Pu‘u ‘Ō‘ō eruption from the middle East Rift Zone of Kīlauea Volcano began in January 1983 with intermittent activity along several fissures. By June 1983, the eruption had localized at the Pu‘u ‘Ō‘ō vent and the activity settled into an increasingly regular pattern of brief eruptive episodes characterized by high lava fountains. The first 18 months of the eruption (episodes 1–20) are chronicled in previous publications. In the two years following episode 20, Pu‘u ‘Ō‘ō produced another 27 high-fountaining episodes. Episodes 21–47 lasted an average of 12.9 hours and were separated by inter-episode periods averaging 26.5 days. The lava fountains, which reached as high as 510 meters (m), fed lava flows (mostly channelized ʻaʻā) that brought the total area covered by the eruption to 40 square kilometers (km 2 ) by the end of episode 47. Flow thickness measurements obtained for episodes 21–40 averaged 3.4 m; lava volumes for episodes 21–47 averaged 8.0×10 6 m 3 per episode (including the 16-day fissure outbreak of episode 35). The Pu‘u ‘Ō‘ō cone—a composite of pyroclastic material and lava flows—reached its maximum height of 255 m above the pre-eruption surface during episode 43 and maintained that height through episode 47. Short-lived eruptive fissures and vents at or near the base of the Pu‘u ‘Ō‘ō cone accompanied episodes 21, 25, 29, 35, 39, and 44. Episode 35 was unusual in that a fissure on the uprift flank of the cone erupted early in the episode, and then reactivated and extended 2.5 km uprift after the high fountaining was over and erupted for the next 16 days. The volcano was primed for the 48th episode of high fountaining on July 18, 1986, when the conduit beneath Pu‘u ‘Ō‘ō ruptured again and magma erupted through new fissures at the base of the cone on both its uprift and downrift sides. These fissures were active for only 21 hours, but a third fissure, which opened 3 km downrift from Pu‘u ‘Ō‘ō on July 20, persisted and evolved into a single vent, later named Kupaianaha. Kupaianaha erupted almost continuously for the next 5.5 years (the main part of episode 48). The onset of episode 48 marked the end of episodic high fountaining and the transition to nearly continuous effusion. A lava lake developed over the Kupaianaha vent, and overflows from the lake built a broad, low shield that reached a relatively stable height of 45 m by November 1986. After weeks of continuous eruption, the main lava channel leading from the lake gradually roofed over, forming a lava tube. By November 1986, the tube had extended from the lake to the ocean, 12 km southeast, closing the coastal highway. Tube-fed flows overran 28 houses in the coastal communities of Kapa‘ahu and Kalapana over the next month.

Hawai'i

Integrated geophysical surveys for mapping lati-andesite intrusive bodies, Chino Valley, Arizona

Three different geophysical methods (magnetic, transient electromagnetic (TEM) and gravity) were used near Chino Valley, Arizona, USA in order to map a suspected lati-andesite intrusive body (plug) previously located by interpretation of aeromagnetic data. The magnetic and TEM surveys provided the best indication of the location and depth of the plug. The north-south spatial extent of this plug was estimated to be approximately 600 meters. The depth to the top of the plug was found from the TEM survey to be approximately 350 meters near the center of the survey. The location of the plug defined by the ground magnetic data is consistent with that from the TEM data. Gravity data mostly image the basin-basement interface with a small contribution from the plug of about 0.5 mGal. Results from this investigation can be used to help define the irregular subsurface topography caused by several intrusive lati-andesite plugs that could influence groundwater flow in the area.

Arizona

Geophysical Methods for Investigating Ground-Water Recharge

While numerical modeling has revolutionized our understanding of basin-scale hydrologic processes, such models rely almost exclusively on traditional measurements?rainfall, streamflow, and water-table elevations?for calibration and testing. Model calibration provides initial estimates of ground-water recharge. Calibrated models are important yet crude tools for addressing questions about the spatial and temporal distribution of recharge. An inverse approach to recharge estimation is taken of necessity, due to inherent difficulties in making direct measurements of flow across the water table. Difficulties arise because recharging fluxes are typically small, even in humid regions, and because the location of the water table changes with time. Deep water tables in arid and semiarid regions make recharge monitoring especially difficult. Nevertheless, recharge monitoring must advance in order to improve assessments of ground-water recharge. Improved characterization of basin-scale recharge is critical for informed water-resources management. Difficulties in directly measuring recharge have prompted many efforts to develop indirect methods. The mass-balance approach of estimating recharge as the residual of generally much larger terms has persisted despite the use of increasing complex and finely gridded large-scale hydrologic models. Geophysical data pertaining to recharge rates, timing, and patterns have the potential to substantially improve modeling efforts by providing information on boundary conditions, by constraining model inputs, by testing simplifying assumptions, and by identifying the spatial and temporal resolutions needed to predict recharge to a specified tolerance in space and in time. Moreover, under certain conditions, geophysical measurements can yield direct estimates of recharge rates or changes in water storage, largely eliminating the need for indirect measures of recharge. This appendix presents an overview of physically based, geophysical methods that are currently available or under development for recharge monitoring. The material is written primarily for hydrogeologists. Uses of geophysical methods for improving recharge monitoring are explored through brief discussions and case studies. The intent is to indicate how geophysical methods can be used effectively in studying recharge processes and quantifying recharge. As such, the material constructs a framework for matching the strengths of individual geophysical methods with the manners in which they can be applied for hydrologic analyses. The appendix is organized in three sections. First, the key hydrologic parameters necessary to determine the rate, timing, and patterns of recharge are identified. Second, the basic operating principals of the relevant geophysical methods are discussed. Methods are grouped by the physical property that they measure directly. Each measured property is related to one or more of the key hydrologic properties for recharge monitoring. Third, the emerging conceptual framework for applying geophysics to recharge monitoring is presented. Examples of the application of selected geophysical methods to recharge monitoring are presented in nine case studies. These studies illustrate hydrogeophysical applications under a wide range of conditions and measurement scales, which vary from tenths of a meter to hundreds of meters. The case studies include practice-proven as well as emerging applications of geophysical methods to recharge monitoring.

Professional Paper

Estimated infiltration, percolation, and recharge rates at the Rillito Creek focused recharge investigation site, Pima County, Arizona

A large fraction of ground water stored in the alluvial aquifers in the Southwest is recharged by water that percolates through ephemeral stream-channel deposits. The amount of water currently recharging many of these aquifers is insufficient to meet current and future demands. Improving the understanding of streambed infiltration and the subsequent redistribution of water within the unsaturated zone is fundamental to quantifying and forming an accurate description of streambed recharge. In addition, improved estimates of recharge from ephemeral-stream channels will reduce uncertainties in water-budget components used in current ground-water models. This chapter presents a summary of findings related to a focused recharge investigation along Rillito Creek in Tucson, Arizona. A variety of approaches used to estimate infiltration, percolation, and recharge fluxes are presented that provide a wide range of temporal- and spatial-scale measurements of recharge beneath Rillito Creek. The approaches discussed include analyses of (1) cores and cuttings for hydraulic and textural properties, (2) environmental tracers from the water extracted from the cores and cuttings, (3) seepage measurements made during sustained streamflow, (4) heat as a tracer and numerical simulations of the movement of heat through the streambed sediments, (5) water-content variations, (6) water-level responses to streamflow in piezometers within the stream channel, and (7) gravity changes in response to recharge events. Hydraulic properties of the materials underlying Rillito Creek were used to estimate long-term potential recharge rates. Seepage measurements and analyses of temperature and water content were used to estimate infiltration rates, and environmental tracers were used to estimate percolation rates through the thick unsaturated zone. The presence or lack of tritium in the water was used to determine whether or not water in the unsaturated zone infiltrated within the past 40 years. Analysis of water-level and temporal-gravity data were used to estimate recharge volumes. Data presented in this chapter were collected from 1999 though 2002. Precipitation and streamflow during this period were less than the long-term average; however, two periods of significant streamflow resulted in recharge—one in the summer of 1999 and the other in the fall/winter of 2000. Flux estimates of infiltration and recharge vary from less than 0.1 to 1.0 cubic meter per second per kilometer of streamflow. Recharge-flux estimates are larger than infiltration estimates. Larger recharge fluxes than infiltration fluxes are explained by the scale of measurements. Methods used to estimate recharge rates incorporate the largest volumetric and temporal scales and are likely to have fluxes from other nearby sources, such as unmeasured tributaries, whereas the methods used to estimate infiltration incorporate the smallest scales, reflecting infiltration rates at individual measurement sites.

Arizona

Relative contributions of transient and steady state infiltration during ephemeral streamflow

Simulations of infiltration during three ephemeral streamflow events in a coarse‐grained alluvial channel overlying a less permeable basin‐fill layer were conducted to determine the relative contribution of transient infiltration at the onset of streamflow to cumulative infiltration for the event. Water content, temperature, and piezometric measurements from 2.5‐m vertical profiles within the alluvial sediments were used to constrain a variably saturated water flow and heat transport model. Simulated and measured transient infiltration rates at the onset of streamflow were about two to three orders of magnitude greater than steady state infiltration rates. The duration of simulated transient infiltration ranged from 1.8 to 20 hours, compared with steady state flow periods of 231 to 307 hours. Cumulative infiltration during the transient period represented 10 to 26% of the total cumulative infiltration, with an average contribution of approximately 18%. Cumulative infiltration error for the simulated streamflow events ranged from 9 to 25%. Cumulative infiltration error for typical streamflow events of about 8 hours in duration in is about 90%. This analysis indicates that when estimating total cumulative infiltration in coarse‐grained ephemeral stream channels, consideration of the transient infiltration at the onset of streamflow will improve predictions of the total volume of infiltration that may become groundwater recharge.

Water Resources Research

Hydrogeology of the upper and middle Verde River watersheds, central Arizona

The upper and middle Verde River watersheds in central Arizona are primarily in Yavapai County, which in 1999 was determined to be the fastest growing rural county in the United States; by 2050 the population is projected to more than double its current size (132,000 in 2000). This study combines climatic, surface-water, ground-water, water-chemistry, and geologic data to describe the hydrogeologic systems within the upper and middle Verde River watersheds and to provide a conceptual understanding of the ground-water flow system. The study area includes the Big Chino and Little Chino subbasins in the upper Verde River watershed and the Verde Valley subbasin in the middle Verde Rive watershed...more...A geochemical mixing model was used to quantify fractions of ground-water sources to the Verde River from various parts of the study area. Most of the water in the uppermost 0.2 mile of the Verde River is from the Little Chino subbasin, and the remainder is from the Big Chino subbasin. Discharge from a system of springs increases base flow to about 17 cubic feet per second within the next 2 miles of the river. Ground water that discharges at these springs is derived from the western part of the Coconino Plateau, from the Big Chino subbasin, and from the Little Chino subbasin. More...

Scientific Investigations Report

Simulated water-level responses, ground-water fluxes, and storage changes for recharge scenarios along Rillito Creek, Tucson, Arizona

A local ground-water flow model is used to simulate four recharge scenarios along Rillito Creek in northern Tucson to evaluate mitigating effects on ground-water deficits and water-level declines in Tucson's Central Well Field. The local model, which derives boundary conditions from a basin-scale model, spans the 12-mile reach of Rillito Creek and extends 9 miles south into the Central Well Field. Recharge scenarios along Rillito Creek range from 5,000 to 60,000 acre-feet per year and are simulated to begin in 2005 and extend through 2225 to estimate long-term changes in ground-water level, ground-water storage, ground-water flux, and evapotranspiration. The base case for comparison of simulated water levels and flows, referred to as scenario A, uses a long-term recharge rate of 5,000 acre-feet per year to 2225. Scenario B, which increases the recharge along Rillito Creek by 9,500 acre-feet per year, has simulated water-level rises beneath Rillito Creek that range from about 53 feet to 86 feet. Water-level rises within the Central Well Field range from about 60 feet to 80 feet. More than half of these rises occur by 2050, and more than 95 percent occur by 2188. Scenario C, which increases the recharge along Rillito Creek by 16,700 acre-feet per year relative to scenario A, has simulated water-level rises beneath Rillito Creek that range from about 71 feet to 102 feet. Water-level rises within the Central Well Field range from about 80 feet to 95 feet. More than half of the rises occur by 2036, and more than 95 percent occur by 2100. Scenario D, which initially increases the recharge rate by about 55,000 acre-feet per year relative to scenario A, resulted in simulated water levels that rise to land surface along Rillito Creek. This rise in water level resulted in rejected recharge. As the water table continued to rise, the area of stream-channel surface intersected by the water table increased causing continual decline in the recharge rate until a long-term recharge rate of about 34,000 acre-feet per year was sustained. The long-term recharge rate for scenario D is about 29,000 acre-feet per year greater than the long-term recharge rate for scenario A. Simulated long-term water-level rises beneath Rillito Creek range from about 97 feet to 131 feet, resulting in water levels near or at the land surface. Shallow depths to water associated with this scenario have implications for contamination owing to the presence of landfills within or adjacent to Rillito Creek. Water-level rises for cells within the Central Well Field range from about 96 feet to 109 feet. More than half of the water-level rises occur by 2018 and more than 95 percent occur by 2041. Almost all the increased water added to the ground-water system in the recharge scenarios can be accounted for by a combination of increased storage near Rillito Creek, ground-water flux to the south, ground-water flux to the northwest, and increased discharge as evapotranspiration along Rillito Creek. The percentage of newly added water accounted for by storage changes is large relative to the percentage accounted for by changes in flux and evapotranspiration at the onset of each scenario; however, the changes in storage become smaller throughout the simulation, and the long-term component accounted for by storage is minimal. Long-term ground-water fluxes to the south increase by about 3,300, 4,840, and 7,500 acre-feet per year for scenarios B, C, and D, respectively. The percentage of increased recharge that flows south toward the Central Well Field, therefore, is 35, 29, and 26 percent for scenarios B, C, and D, respectively. Long-term ground-water fluxes to the northwest increase by about 3,100, 3,900, and 6,980 acre-feet per year for scenarios B, C, and D, respectively. The long-term percentage of increased recharge flowing northwestward is about 31, 25, and 21 percent for scenarios B, C, and D, respectively. Shallow ground-water evapotranspiration along Rillito Creek incr

Scientific Investigations Report

Investigation of the geology and hydrology of the upper and middle Verde River watershed of central Arizona: A project of the Arizona Rural Watershed Initiative

The upper and middle Verde River watershed in west-central Arizona is an area rich in natural beauty and cultural history and is an increasingly popular destination for tourists, recreationists, and permanent residents seeking its temperate climate. The diverse terrain of the region includes broad desert valleys, upland plains, forested mountain ranges, narrow canyons, and riparian areas along perennial stream reaches. The area is predominantly in Yavapai County, which in 1999 was the fastest-growing rural county in the United States (Woods and Poole Economics, Inc., 1999); by 2050, the population is projected to more than double. Such growth will increase demands on water resources. The domestic, industrial, and recreational interests of the population will need to be balanced against protection of riparian, woodland, and other natural areas and their associated wildlife and aquatic habitats. Sound management decisions will be required that are based on an understanding of the interactions between local and regional aquifers, surface-water bodies, and recharge and discharge areas. This understanding must include the influence of climate, geology, topography, and cultural development on those components of the hydrologic system. In 1999, the U.S. Geological Survey (USGS), in cooperation with the Arizona Department of Water Resources (ADWR), initiated a regional investigation of the hydrogeology of the upper and middle Verde River watershed. The project is part of the Rural Watershed Initiative (RWI), a program established by the State of Arizona and managed by the ADWR that addresses water supply issues in rural areas while encouraging participation from stakeholder groups in affected communities. The USGS is performing similar RWI investigations on the Colorado Plateau to the north and in the Mogollon Highlands to the east of the Verde River study area (Parker and Flynn, 2000). The objectives of the RWI investigations are to develop: (1) a single database containing all hydrogeologic data available for the combined areas, (2) an understanding of the geologic units and structures in each area with a focus on how geology influences the storage and movement of ground water, (3) a conceptual model that describes where and how much water enters, flows through, and exits the hydrogeologic system, and (4) a numerical ground-water flow model that can be used to improve understanding of the hydrogeologic system and to test the effects of various scenarios of water-resources development. In 2001, Yavapai County became an additional cooperator in the upper and middle Verde River RWI investigation.

Arizona

Characteristics of shallow deposits beneath Rillito Creek, Pima County, Arizona

Characteristics of the stream-channel and basin-fill deposits beneath a 12-mile reach of Rillito Creek, Pima County, Arizona, were obtained to describe the geohydrologic system. The findings presented here are part of a larger project to improve the understanding of recharge processes beneath ephemeral streams. The stream-channel deposits, which range in thickness from 15 to 40 feet, generally are sandy gravels or gravelly sands. On average, the stream-channel deposits are 44 percent gravel, 51 percent sand, 2 percent silt, and 3 percent clay. The underlying basin-fill deposits also are sandy gravels or gravelly sands but have, on average, a larger component of silt and clay than the stream-channel deposits?about 9 percent silt and 6 percent clay. Porosity values for the stream-channel and basin-fill deposits are similar: about 31 and 34 percent on average, respectively. Volumetric moisture content and percent saturation, however, generally were lower in the stream-channel deposits than in the basin-fill deposits. Moisture content in the stream-channel deposits ranged from 2 to 40 percent and averaged about 18 percent, whereas moisture content in the basin-fill deposits ranged from 7 to 47 percent and averaged about 24 percent. Saturation in the stream-channel deposits ranged from 9 to 100 percent and averaged about 58 percent; saturation in the basin-fill deposits ranged from 30 to 100 percent and averaged about 69 percent. Porosity and moisture content correlate with silt and clay content. Cumulative thickness of water in the 100- to 125-foot thick unsaturated zone obtained by integrating the moisture content over depth, ranged from 17.2 to 40.4 feet. Matric potential for saturation levels at the time of sample collection generally was less than -1 bar for deposits that were less than 35 percent saturated. Matric potential generally was greater than -0.1 bar for deposits that were more than 65 percent saturated. Moisture-retention curves are a function of the physical properties, such as porosity and grain size, of the sediments. The shapes and van Genuchten fitting parameters of moisture-retention curves for the stream-channel deposits are different from those of the basin-fill deposits. For instance, the fitting parameter, a, for stream-channel deposits ranged from 4.56 to 1,220 bar-1 and averaged 220 bar-1, whereas a for basin-fill deposits ranged from 4.22 to 67.9 bar-1 and averaged 22.8 bar-1. The residual water content for the basin-fill deposits is greater than that for the stream-channel deposits. Relative hydraulic conductivity of the stream-channel deposits is less than relative hydraulic conductivity of the basin-fill deposits at the same matric potential. Unsaturated hydraulic conductivity for moisture conditions that existed at the time of sample collection typically was more than two orders of magnitude less than saturated hydraulic conductivity. Saturated vertical hydraulic conductivity of the stream-channel deposits is about an order of magnitude greater than that of the basin-fill deposits. The equivalent hydraulic conductivity of stream-channel deposits ranges from 2 to 7.3 feet per day, and averages about 4 feet per day, whereas the equivalent hydraulic conductivity of the basin-fill deposits ranges from 0.06 to 1.5 feet per day and averages 0.61 foot per day. The equivalent vertical hydraulic conductivity of the entire unsaturated zone cored is 0.75 foot per day. Assuming no vertical to horizontal anisotropy, the equivalent horizontal hydraulic conductivity generally is about two to three times that of the equivalent vertical hydraulic conductivity. The difference between average equivalent vertical and horizontal hydraulic conductivity values results from the differences in methods used to calculate the respective values. Electrical methods were useful in discriminating between stream-channel deposits and basin-fill deposits. In general, electrical conductivity of the stream-channel deposits was less than 30 millimhos per meter and averaged 27 millimhos per meter. The conductivity of the basin-fill deposits was greater than that of the stream-channel deposits and averaged 44 millimhos per meter. The greater conductivity probably is related to factors such as greater moisture content and fraction of fine sediments in the basin-fill deposits. Apparent resistivity measured with two-dimensional resistivity soundings generally decreased with depth. The resistivity values from the near-surface measurements represent dry stream-channel deposits and averaged 303 ohm meters. The resistivity values for basin-fill deposits generally were less than 140 ohm meters and less than 100 ohm meters when saturated. Seismic-velocity values for the recent alluvium (stream-channel and terrace deposits) ranged from 1,150 to 2,200 feet per second, whereas values for basin-fill deposits ranged from 2,000 to 11,650 feet per second. The average seismic velocity for the stream-channel deposits (1,300 feet per second) was less than that for the terrace deposits (1,600 feet per second). Saturated basin-fill deposits had an average velocity of 7,800 feet per second, whereas unsaturated basin-fill deposits had an average velocity of 2,750 feet per second.

Arizona

Maps showing the development of the Pu‘u ‘Ö‘ö-Küpaianaha flow field, June 1984-February 1987, Kïlauea Volcano, Hawaii

The Pu'u 'O'o - Kupaianaha eruption on the middle east rift zone of Kilauea began in January 1983 with intermittent activity along several fissures. By June 1983, the eruption had localized at the Pu'u 'O'o vent, and the activity settled into an increasingly regular pattern of brief eruptive episodes characterized by high lava fountains. The first 18 months of this eruption are chronicled in Wolfe and others (1988), which includes maps of the flows erupted in episodes 1-20. The maps presented here extend this series through the beginning of episode 48.

Hawaii

Hydrogeology, water quality, and stormwater-sediment chemistry of the Grande Wash area, Fort McDowell Indian Reservation, Maricopa County, Arizona

Grande Wash is a tributary of the Verde River and drains an area of 13 square miles within the McDowell Mountains and the Town of Fountain Hills in Central Arizona. The wash enters the Fort McDowell Indian Reservation at the eastern boundary of Fountain Hills and is incised in coarse-grained alluvium that is contiguous with the alluvial aquifer along the Verde River. The aquifer is used by the Fort McDowell Indian Community and the City of Phoenix for municipal water supplies. Episodic flows in Grande Wash, in response to storms, carry potentially hazardous runoff from Fountain Hills onto the reservation. Additional potential hazards to ground water include contamination from a wastewater-treatment plant located less than 1 mile upstream from the reservation boundary, and from a landfill and a cement-processing plant immediately adjacent to the main channel of the wash. Coarse-grained deposits in Grande Wash also include recent stream-channel deposits, soil backfill, landfill material, and the upper coarse-grained layer of basin-fill sediments. Surface-geophysical surveys and drilling indicated that the coarse-grained deposits are less than 60-feet thick along the wash and in adjacent areas within the reservation, and are underlain by a thick clay and silt unit, the base of which is below the bottom of the deepest monitor well (317 feet below land surface). The coarse-grained deposits form the alluvial aquifer beneath Grande Wash. Ground water in the alluvial aquifer beneath the wash is shallow and mounded above a less permeable clay and silt unit. Depth to water in the aquifer ranges from 1 to 22 feet below land surface. Saturation of the coarse-grained deposits does not extend laterally for more than about 1,000 feet from the main channel of Grande Wash; the extent varies in response to recharge amounts. Flux of ground water through the alluvial aquifer beneath the wash is toward the Verde River and is estimated to be about 8,000 cubic feet per day (about 0.2 acre-feet per day). The flow rate is four orders of magnitude less than the flow rate in the Verde River. Vertical flux of ground water through the underlying clay and silt unit is estimated to be 7,000 cubic feet per day (0.17 acre-feet per day). The volume of ground water in storage in the alluvial aquifer beneath Grande Wash is estimated to be about 5.6 million cubic feet (129 acre-feet). Concentrations of dissolved inorganic constituents in ground water and surface water are high relative to concentrations found in the regional aquifer in surrounding areas and are indicative of salts that can be expected to be mobilized by runoff in the drainage area. Concentrations of nitrate, chloride, and sulfate are near U.S. Environmental Protection Agency Primary or Secondary Drinking-Water Regulations. Concentrations of arsenic, antimony, and strontium are below drinking-water standards but can be attributed to geologic deposits in and near the study area. Low concentrations of anthropogenic compounds, including chloroform and dichlorobromomethane, were detected. These compounds are disinfection by-products of chlorinated water. Eight pesticide compounds were detected in the surface water, and two pesticide compounds were detected in the ground water. Pesticide concentrations were below U.S. Environmental Protection Agency Maximum Contaminant Levels. Several other organic anthropogenic compounds that probably originated from commercial activities in the area were detected but at concentrations below laboratory calibration standards. Concentrations of trace metals in the stormwater sediment collected from the sediment retention basin in the lowest part of the wash were low and several were below the laboratory’s detection limits. Concentrations of most organic compounds in the stormwater sediment were below detection limits. Organic compounds present at concentrations above detection limits were p-cresol and two phthalate esters—bis (2-ethylhexyl) phthalate and dibutyl phthalate. P-cresol is used in pesticides or in disinfectants and deodorizers, and phthalate esters are commonly used in plastics, hydraulic fluid, and electric capacitors.

Arizona

Geology, Ground-Water Occurrence, and Estimated Well Yields from the Mariana Limestone, Kagman Area, Saipan, Commonwealth of the Northern Mariana Islands

A study of the geology, ground-water occurrence, and estimated well yields from the Mariana Limestone was done to investigate ground-water availability in the Kagman area, Saipan. The Mariana and Tagpochau Limestone formations form the major aquifer in the Kagman drainage basin. The Mariana Limestone, which is the major water-bearing unit in the Kagman area, ranges in thickness from 300 to 500 feet and contains intermittent, thin clay stringers. The calcareous rocks of the Tagpochau Limestone range in thickness from 500 to 1,000 feet and are more sandy than those of the Mariana Limestone. Ground water is unconfined in the Mariana Limestone and ranges from unconfined to confined in the Tagpochau Limestone. The fresh ground-water lens (that part of the lens with less than 2-percent of the chloride-ion concentration in seawater) in the Mariana Limestone is relatively thin, ranging from about 15 to 21 feet. Altitude of the water table ranges from about 1.5 to 2.5 feet above mean sea level. Freshwater in the Mariana Limestone is underlain by seawater and is separated by a transition zone about 8 to 25 feet thick. Hydraulic conductivity and transmissivity of the Mariana Limestone were calculated from data collected at six test wells. Using the Newman method, estimated hydraulic conductivity and transmissivity range from 290 to 2,500 feet per day and 7,600 to 62,000 feet squared per day, respectively. The higher values probably are indicative of average conditions in the Mariana Limestone. The estimated storage coefficient of the Mariana Limestone is about 0.1. The availability of water from the Mariana Limestone is restricted by the thinness of the freshwater lens. Results of the study indicate that fresh ground water can be obtained from the Mariana Limestone when wells are designed for minimum drawdown, effectively skimming freshwater from the top of the lens. Wells that are shallow, widely spaced, and pumped at low uniform rates can prevent saltwater intrusion. Calculated long-term yields of wells are about 30 gallons per minute or less for potable water.

Water-Resources Investigations Report

Geochemical analyses of ground-water ages, recharge rates, and hydraulic conductivity of the N aquifer, Black Mesa area, Arizona

The Navajo Nation and Hopi Tribe of the Black Mesa area, Arizona, depend on ground water from the N aquifer to meet most tribal and industrial needs. Increasing use of this aquifer is creating concerns about possible adverse effects of increased ground-water withdrawals on the water resources of the region. A thorough understanding of the N aquifer is necessary to assess the aquifer's response to ground-water withdrawals. This study used geochemical techniques as an independent means of improving the conceptual model of ground-water flow in the N aquifer and to estimate recharge rates and hydraulic conductivity. Ground water flows in a south-southeastward direction from the recharge area around Shonto into the confined part of the N aquifer underneath Black Mesa. Ground-water flow paths diverge in the confined part of the aquifer to the northeast and south. The N aquifer thins to extinction south of Black Mesa. This discontinuity could force ground water to diverge along paths of least resistance. Ground water discharges from the confined part of the aquifer into Laguna Creek and Moenkopi Wash and from springs southwest of Kykotsmovi and southeast of Rough Rock after a residence time of about 35,000 years or more. Recent recharge along the periphery of Black Mesa mixes with older ground water that discharges from the confined part of the aquifer and flows away from Black Mesa. Dissolved-ion concentrations, ratios of dissolved ions, dissolved-gas concentrations, tritium, carbon-13, and chlorine-36 data indicate that water in the overlying D aquifer could be leaking into the confined part of the N aquifer in the southeastern part of Black Mesa. The boundary between the leaky and nonleaky zones is defined roughly by a line from Rough Rock to Second Mesa and separates ground waters that have significantly different chemistries. The Dakota Sandstone and Entrada Formation of the D aquifer could be the sources of leakage. Adjusted radiocarbon ground-water ages and data on isotopes of oxygen and hydrogen indicate that more than 90 percent of the water in the confined part of the N aquifer is older than 10,000 years and was recharged during glacial periods. Estimates of recharge rates made on the basis of ground-water ages, aquifer thicknesses, and assumed porosities indicate that the annual average recharge rate in the northwestern part of the study area during the glacial periods was about four times the average annual rate of the past 10,000 years, and that recharge rates for the past 10,000 years are less than modern recharge rates assumed in a previous study. Estimates of horizontal hydraulic conductivity were 0.95 and 1.16 feet per day for the northeast and southwest flow paths, respectively. These values are within the range of hydraulic conductivities calculated from aquifer tests, which ranged from 0.05 to 2.1 feet per day and averaged 0.65 foot per day.

Arizona