Fluorometric determination of gold in rocks with rhodamine B
No abstract available.
Analytical Chemistry↗
Geology topics
John Marinenko
Publications and source records attributed to John Marinenko.
Spectrophotometric determination of vanadium in rutile and in mafic igneous rocks
Minor and major levels of vanadium in rutile are separated from titanium and iron by sample fusion with sodium carbonate followed by water leach and filtration. The filtrate is then acidified with hydrochloric acid. Silicates are decomposed with a mixture of hydrofluoric and hydrochloric acids, and iron is separated by extraction of its chloride with diethyl ether. Sample vanadium in hydrochloric acid is then quantitatively reduced to vanadium(IV) with sulfurous acid. The remaining sulfur dioxide is expelled by heating. Vanadium (IV) then is reacted with excess of iron(III) at reduced acidity (pH 5) in the presence of 1,10-phenanthroline to yield the orange-red iron(II) 1,10-phenanthroline complex. Iron(II) generated by vanadium(IV) is a measure of total vanadium in the sample. The proposed method is free from elemental interferences because the color development cannot take place without the two redox reactions described above, and these are, under the outlined experimental conditions, quantitative only for vanadium.
Journal of Research of the U.S. Geological Survey↗
Thermal conductimetric determination of submilligram amounts of total water in silicate and carbonate minerals
A simple and rapid method was developed for determining sub milligram amounts of total water in silicate and carbonate minerals. Powdered samples are fused by heating with sodium tungstate vanadium pentoxide flux in a Vycor combustion tube, and the evolved water vapor is absorbed on silica gel. After the water collection, the silica gel is heated at a controlled rate, and the released water vapor, carried by helium, is detected by thermal conductivity.
Journal of Research of the U.S. Geological Survey↗
Mineralogical studies of the nitrate deposits of Chile IV. Brüggenite, Ca(IO3)2-H2O, a new saline mineral
Br ü ggenite, Ca(I0 3 )2 - H2 0, is found in veins of high-purity soda niter in rhyolite tuff at Pampa Pique III, Oficina Lautaro, Chile, as long columnar anhedral crystals, as prismatic crystals, and as irregular anhedral crystals or encrusting masses. The mineral is colorless to bright yellow, and transparent to translucent, has vitreous luster and a hardness of about 3 1 / 2 , is brittle, and has conchoidal fracture. It is biaxial and has variable optic angle and refractive indices, which were determined by the spindle-stage method. Refractive indices are as follows: n α =1.772-1.779, n β =1.795-1.802, and n γ =1.817-1.824 (all ± 0.003); optic angle shows a range of 2 V Z = 86°-96°; Z = b and X ∧ c = -47°; dispersion (Z) is r < v , moderate. Brüggenite is monoclinic, space group P 2 1 / c , with a=8.509±0.001 A, b = 10.027±0.002 A, c = 7.512±0.001 A, β = 95°16.00'±0.55', volume 638.2 A 3 , Z = 4, G (calc) = 4.244, G (meas) =4.24±0.01. The X-ray diffraction powder pattern of brüggenite has the following strong lines ( hkl , d hkl 1 ): 031, 3.051 A (100); 220, 3.238 A (90); 200, 4.235 A (80); 002, 3.739 A (60); 012, 3.503 A (60); 231, 2.522 A (60). The composition was confirmed by chemical analyses.
Antofagasta Province↗
Establishment of gold-quartz standard GQS-1
A homogeneous gold-quartz standard, GQS-1, was prepared from a heterogeneous gold-bearing quartz by chemical treatment. The concentration of gold in GQS-1 was determined by both instrumental neutron activation analysis and radioisotope dilution analysis to be 2.61?0.10 parts per million. Analysis of 10 samples of the standard by both instrumental neutron activation analysis and radioisotope dilution analysis failed to reveal heterogeneity within the standard. The precision of the analytical methods, expressed as standard error, was approximately 0.1 part per million. The analytical data were also used to estimate the average size of gold particles. The chemical treatment apparently reduced the average diameter of the gold particles by at least an order of magnitude and increased the concentration of gold grains by a factor of at least 4,000.
Circular↗