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John Crusius

Publications and source records attributed to John Crusius.

At least 37 records · Page 2Linked to original sources
USGS2008

Submarine Hydrogeological Data from Cape Cod National Seashore

In order to test hypotheses about ground water flow under and into estuaries and the Atlantic Ocean, geophysical surveys, geophysical probing, submarine ground-water sampling, and sediment coring were conducted by U.S. Geological Survey (USGS) scientists at Cape Cod National Seashore (CCNS) in Massachusetts from 2004 through 2006. This USGS Open-File Report presents the data collected as a result of these field efforts.

Open-File Report↗
USGS2007

Persistent chlordane concentrations in long island sound sediment: Implications from chlordane, 210 Pb, and 137 Cs profiles

Concentrations of chlordane, a banned termiticide and pesticide, were examined in recently collected surficial sediment (10 sites) and sediment cores (4 sites) in Long Island Sound (LIS).The highest chlordane concentrations were observed in western LIS, near highly urbanized areas. Chlordane concentrations did not decrease significantly in the past decade when compared to the data collected in 1996, consistent with the observation of near-constant chlordane levels in blue mussel tissues collected during the same time period. Chlordane concentrations in many of the sites exceeded levels above which harmful effects on sediment-dwelling organisms are expected to frequently occur. Chlordane concentrations in two of the four sediment cores showed a peak below the sediment surface, suggesting reduced chlordane inputs in recent years. The lack of a chlordane concentration maximum below the sediment surface in the other two cores, coupled with the lack of a well-defined 137 Cs peak, indicated significant sediment mixing. Simulations of 137 Cs and 210 Pb profiles in sediment cores with a simple sediment-mixing model were used to constrain both the deposition rate and the bioturbation rate of the sediment. Simulations of the chlordane profiles indicated continued chlordane input to LIS long after chlordane was phased out in the U.S. Continued chlordane input and significant sediment mixing may have contributed to the persistent chlordane concentrations in surficial sediment, which poses long-term threats to benthic organisms in LIS.

New York↗
USGS2007

Ensuring confidence in radionuclide-based sediment chronologies and bioturbation rates

Sedimentary records of naturally occurring and fallout-derived radionuclides are widely used as tools for estimating both the ages of recent sediments and rates of sedimentation and bioturbation. Developing these records to the point of data interpretation requires careful sample collection, processing, analysis and data modeling. In this work, we document a number of potential pitfalls that can impact sediment core records and their interpretation. This paper is not intended as an exhaustive treatment of these potential problems. Rather, the emphasis is on potential problems that are not well documented in the literature, as follows: (1) the mere sampling of sediment cores at a resolution that is too coarse can result in an apparent diffusive mixing of the sedimentary record at rates comparable to diffusive bioturbation rates observed in many locations; (2) 210 Pb profiles in slowly accumulating sediments can easily be misinterpreted to be driven by sedimentation, when in fact bioturbation is the dominant control. Multiple isotopes of different half lives and/or origin may help to distinguish between these two possible interpretations; (3) apparent mixing can occur due simply to numerical artifacts inherent in the finite difference approximations of the advection diffusion equation used to model sedimentation and bioturbation. Model users need to be aware of this potential problem. Solutions to each of these potential pitfalls are offered to ensure the best possible sediment age estimates and/or sedimentation and bioturbation rates can be obtained.

Estuarine, Coastal and Shelf Science↗
USGS2007

Processes influencing the transport and fate of contaminated sediments in the coastal ocean– Boston Harbor and Massachusetts Bay

Most of the major urban centers of the United States including Boston, New York, Washington, Chicago, New Orleans, Miami, Los Angeles, San Francisco, and Seattle—are on a coast (fig. 1.1). All of these cities discharge treated sewage effluent into adjacent waters. In 2000, 74 percent of the U.S. population lived within 200 kilometers (km) of the coast. Between 1980 and 2002, the population density in coastal communities increased approximately 4.5 times faster than in noncoastal areas of the U.S. (Perkins, 2004). More people generate larger volumes of wastes, increase the demands on wastewater treatment, expand the area of impervious land surfaces, and use more vehicles that contribute contaminants to street runoff. According to the National Coastal Condition Report II (U.S. Environmental Protection Agency, 2005a), on the basis of coastal habitat, water and sediment quality, benthic index, and fish tissue, the overall national coastal condition is only poor to fair and the overall coastal condition in the highly populated Northeast is poor. Scientific information helps managers to prioritize and regulate coastal-ocean uses that include recreation, commercial fishing, transportation, waste disposal, and critical habitat for marine organisms. These uses are often in conflict with each other and with environmental concerns. Developing a strategy for managing competing uses while maintaining sustainability of coastal resources requires scientific understanding of how the coastal ocean system behaves and how it responds to anthropogenic influences. This report provides a summary of a multidisciplinary research program designed to improve our understanding of the transport and fate of contaminants in Massachusetts coastal waters. Massachusetts Bay and Boston Harbor have been a focus of U.S. Geological Survey (USGS) research because they provide a diverse geographic setting for developing a scientific understanding of the geology, geochemistry, and oceanography of coastal systems in general. Scientific data from this region can also be used to inform decisions about important economic, environmental, and political issues. From the economic viewpoint, the annual value of tourism and shipping in Massachusetts and Cape Cod Bays is about $1.5 billion and $1.9 billion, respectively. Commercial and recreational fishing generates about $240 million per year in the same region (U.S. Environmental Protection Agency, 2005b). The environmental issue is the 300-year history of waste discharge from the Boston metropolitan area into the harbor. This history is punctuated by cycles of environmental degradation, public outcry, and improvements in the sewage treatment system. With each improvement, however, the continuous growth of population in greater Boston (fig. 1.2) and the resulting increase in the volume of waste exceeded the capacity of the treatment system, thereby setting the stage for a new contamination crisis. By the 1980s, the levels of contaminants in sediments of Boston Harbor were among the highest in the nation (National Oceanic and Atmospheric Administration, 1987). Fish were diseased, shellfish beds were closed, and swimming beaches were unsafe after heavy rains; in general, water quality and aesthetics were below acceptable standards. Legal and political issues have always been part of Boston Harbor’s history. The environmental conditions in the 1980s were highlighted in a 1983 legal suit brought by the city of Quincy against the Metropolitan District Commission (MDC, the state agency responsible for sewage treatment) and heads of three state agencies for discharging untreated or poorly treated sewage into the harbor (Dolin, 2004). The suit never went to trial, but through the actions of a Massachusetts Superior Court, the issue of Boston Harbor contamination remained on the political and public agenda. The judge called the harbor “unsafe, unsanitary, indecent, in violation of the law (Clean Water Act), and a danger to the health and welfare of the people” (Forman, 1984). To force the state legislature to implement a plan to improve harbor conditions, the judge threatened to place the MDC in receivership and curtail new sewage hookups for industry. Under intense lobbying by business, the legislature created the Massachusetts Water Resources Authority (MWRA) in December 1984. The independent MWRA was established to manage Boston’s waste treatment system and was given the authority to float bonds to pay for major improvements in the treatment system. In 1985, a Federal court began hearings on a suit brought by the Conservation Law Foundation, the Environmental Protection Agency (USEPA), and towns of Quincy and Winthrop against the MDC and MWRA (as heir to responsibilities of the MDC) for years of violation of the Clean Water Act. The judge ruled against the defendants and required all the parties to submit a construction plan and schedule for a new sewage treatment system. From these submissions, he developed a schedule for treatment system upgrades that would give the “citizens of this commonwealth a public assurance that Boston Harbor will be cleaned up within a defined period of time” (Dolin, 2004). The MWRA’s Boston Harbor cleanup program (Levy and Connor, 1992) has transformed the Boston sewage system. Key improvements were to (1) reduce contaminants at the industrial source; (2) remediate leaks in the sewage-collection system; (3) eliminate sewage sludge discharge to the harbor; (4) upgrade sewage treatment from primary to secondary; (5) construct a new ocean outfall 15.2 km offshore in Massachusetts Bay for discharge of treated effluent (fig. 1.3); and (6) implement improvements in the combined-sewer-overflow system. As part of the harbor cleanup program, the MWRA developed a comprehensive monitoring program (summarized in MWRA, 2004) to assess changes in the harbor and bays that specifically related to the new sewage system. Additional information about conditions and processes in the coastal system on a regional scale and over a long time period was and continues to be important in predicting and interpreting local change. Implementation of the MWRA’s program and the mission of the USGS to understand the geology of the nation’s offshore waters provided an opportunity to conduct a cooperative multidisciplinary research program. This USGS program addresses basic scientific questions as well as concerns raised by management regarding the design, implementation, and assessment of the new sewage treatment system. Already active in Boston Harbor during the late 1970s, the USGS expanded research into Massachusetts Bay with a multidisciplinary program in 1989.

Massachusetts↗
USGS2006

Submarine ground-water discharge: nutrient loading and nitrogen transformations

Eutrophication of coastal waters due to nonpoint source land-derived nitrogen (N) loads is a worldwide phenomenon and perhaps the greatest agent of change altering coastal ecology (National Research Council, 2000; Howarth and others, 2000). Within the United States, a majority of estuaries have been determined to be moderately to severely impaired by eutrophication associated with increasing nutrient loads (Bricker and others, 1999). In coastal watersheds with soils of high hydraulic conductivity and permeable coastal sediments, ground water is a major route of transport of freshwater and its solutes from land to sea. Freshwater flowing downgradient from aquifers may either discharge from a seepage face near the intertidal zone, or flow directly into the sea as submarine ground-water discharge (SGD) (fig. 1). In the coastal aquifer, entrainment of saline pore water occurs prior to discharge, producing a gradient in ground-water salinity from land to sea, referred to as a subterranean estuary (Moore, 1999). In addition, processes including density-driven flow and tidal pumping create brackish and saline ground-water circulation. Hence, submarine ground-water discharge often consists of a substantial amount of recirculating seawater. Mixing of fresh and saline ground waters in the context of coastal sediments may alter the chemical composition of the discharging fluid. Depending on the biogeochemical setting, removal of fixed N due to processes leading to N 2 (dinitrogen gas) production in the nearshore aquifer and subterranean estuary may significantly attenuate land-derived N loads; or, processes such as ion exchange and tidal pumping in the subterranean estuary may substantially accelerate the transport of both land-derived and sediment re-mineralized N to estuarine water columns. As emphasized by Burnett and others (2001, 2002), a fundamental problem in evaluating the importance of ground-water discharge in marine geochemical budgets is the difficulty of collecting samples across the salinity gradients of coastal aquifers. In addition, locating and quantifying rates of submarine ground-water discharge remains a challenge due to the diffuse and spatially and temporally heterogeneous nature of discharge. As a result, with regard to the study of biogeochemical cycles and chemical loads to coastal waters, the seepage face and subterranean estuary are relatively new and under-studied zones in the aquatic cascade from watershed to sea. Processes occurring in those zones must be understood and considered for proper modeling and management of coastal water resources.

Fact Sheet↗
USGS2006

Continuous resistivity profiling data from the upper Neuse River Estuary, North Carolina, 2004-2005

The Neuse River Estuary in North Carolina has suffered impacts of eutrophication in recent years. As part of a larger project to better constrain nutrient budgets in the estuary, field investigations were performed to study occurrence and discharge of fresh and brackish ground water and nutrients beneath the estuary itself (fig. 1). A Continuous Resistivity Profiling (CRP) system (Manheim and others, 2004) was used to map the depth of the freshwater-saltwater interface (FSI) in sub-estuarine groundwater. This study area serves as a typological representation of a submarine groundwater environment characteristic of a shallow estuary in a wide coastal plain that has not experienced glaciation. Similar settings extend from New Jersey to Georgia, and along the Gulf of Mexico in the U.S. This report archives 29 lines of data collected during 2004 and 2005 surveys representing almost 210 km of survey lines. These data are further explained in the Data Processing section of the report and previews available of the processed data are available.

North Carolina↗
USGS2005

Submarine groundwater discharge to a small estuary estimated from radon and salinity measurements and a box model

Submarine groundwater discharge was quantified by a variety of methods for a 4-day period during the early summer of 2004, in Salt Pond, adjacent to Nauset Marsh, on Cape Cod, USA. Discharge estimates based on radon and salinity took advantage of the presence of the narrow channel connecting Salt Pond to Nauset Marsh, which allowed constructing whole-pond mass balances as water flowed in and out due to tidal fluctuations. The data suggest that less than one quarter of the discharge in the vicinity of Salt Pond happened within the pond itself, while three quarters or more of the discharge occurred immediately seaward of the pond, either in the channel or in adjacent regions of Nauset Marsh. Much of this discharge, which maintains high radon activities and low salinity, is carried into the pond during each incoming tide. A box model was used as an aid to understand both the rates and the locations of discharge in the vicinity of Salt Pond. The model achieves a reasonable fit to both the salinity and radon data assuming submarine groundwater discharge is fresh and that most of it occurs either in the channel or in adjacent regions of Nauset Marsh. Salinity and radon data, together with seepage meter results, do not rule out discharge of saline groundwater, but suggest either that the saline discharge is at most comparable in volume to the fresh discharge or that it is depleted in radon. The estimated rate of fresh groundwater discharge in the vicinity of Salt Pond is 3000-7000 m 3 d -1 . This groundwater flux estimated from the radon and salinity data is comparable to a value of 3200-4500 m 3 d -1 predicted by a recent hydrologic model (Masterson, 2004; Colman and Masterson, 2004), although the model predicts this rate of discharge to the pond whereas our data suggest most of the groundwater bypasses the pond prior to discharge. Additional work is needed to determine if the measured rate of discharge is representative of the long-term average, and to better constrain the rate of groundwater discharge seaward of Salt Pond.

Biogeosciences Discussions↗
USGS2004

Submarine ground-water discharge and its role in coastal processes and ecosystems

Submarine ground-water discharge (SGD) has recently been recognized as a phenomenon that can strongly influence coastal water and geochemical budgets and drive ecosystem change. For example, the discharge of nutrient-enriched ground water into coastal waters may contribute significantly to eutrophication and blooms of harmful algae. Similarly, the quantity of SGD can also directly affect the availability of fresh water to coastal communities, impact fragile coastal ecosystems such as estuaries and coral reefs, and influence geomorphology of shoreline features. Moore raised awareness of the global importance of SGD and much effort has been devoted to developing new tracer techniques and methods for the identification and quantification of SGD. Because the discharge of coastal ground water commonly occurs as diffuse seepage rather than focused discharge through identifiable springs, assessing SGD has remained difficult for both oceanographers and hydrologists. Through national and international research programs, Burnett, Moore, Charette, and others have developed a rigorous, systematic approach for quantifying SGD using a wide assortment of tracers and methods. Intercalibration experiments, such as those conducted in coastal waters off Australia, Brazil, and Long Island, NY, demonstrate that careful measurements can accurately quantify SGD, confirm some of the driving mechanisms (e.g. climatic and tidal forcing), and constrain the spatial and temporal scales at which these mechanisms operate. Now that approaches for rigorously quantifying SGD are becoming better established, scientists can now begin to investigate the wide variety of coastal processes affected by SGD.

Open-File Report↗
USGS2004

Bioturbation depths, rates and processes in Massachusetts Bay sediments inferred from modeling of 210Pb and 239 + 240Pu profiles

Profiles of 210 Pb and 239 + <240 Pu from sediment cores collected throughout Massachusetts Bay (water depths of 36-192 m) are interpreted with the aid of a numerical sediment-mixing model to infer bioturbation depths, rates and processes. The nuclide data suggest extensive bioturbation to depths of 25-35 cm. Roughly half the cores have 210 Pb and 239 + 240 Pu profiles that decrease monotonically from the surface and are consistent with biodiffusive mixing. Bioturbation rates are reasonably well constrained by these profiles and vary from ~0.7 to ~40 cm 2 yr -1 . As a result of this extensive reworking, however, sediment ages cannot be accurately determined from these radionuclides and only upper limits on sedimentation rates (of ~0.3 cm yr -1 ) can be inferred. The other half of the radionuclide profiles are characterized by subsurface maxima in each nuclide, which cannot be reproduced by biodiffusive mixing models. A numerical model is used to demonstrate that mixing caused by organisms that feed at the sediment surface and defecate below the surface can cause the subsurface maxima, as suggested by previous work. The deep penetration depths of excess 210 Pb and 239 + 240 Pu suggest either that the organisms release material over a range of >15 cm depth or that biodiffusive mixing mediated by other organisms is occurring at depth. Additional constraints from surficial sediment 234 Th data suggest that in this half of the cores, the vast majority of the present-day flux of recent, nuclide-bearing material to these core sites is transported over a timescale of a month or more to a depth of a few centimeters below the sediment surface. As a consequence of the complex mixing processes, surface sediments include material spanning a range of ages and will not accurately record recent changes in contaminant deposition.

Massachusetts↗
USGS2004

Export production in the subarctic North Pacific over the last 800 kyrs: No evidence for iron fertilization?

The subarctic North Pacific is a high nitrate-low chlorophyll (HNLC) region, where phytoplankton growth rates, especially those of diatoms, are enhanced when micronutrient Fe is added. Accordingly, it has been suggested that glacial Fe-laden dust might have increased primary production in this region. This paper reviews published palaeoceanographic records of export production over the last 800 kyrs from the open North Pacific (north of ∼35°N). We find different patterns of export production change over time in the various domains of the North Pacific (NW and NE subarctic gyres, the marginal seas and the transition zone). However, there is no compelling evidence for an overall increase in productivity during glacials in the subarctic region, challenging the paradigm that dust-born Fe fertilization of this region has contributed to the glacial draw down of atmospheric CO 2 . Potential reasons for the lack of increased glacial export production include the possibility that Fe-fertilization rapidly drives the ecosystem towards limitation by another nutrient. This effect would have been exacerbated by an even more stable mixed layer compared to today.

Journal of Oceanography↗
USGS2004

Influence of northwest Pacific productivity on North Pacific Intermediate Water oxygen concentrations during the Bølling-Ållerød interval (14.7-12.9 ka)

Elevated productivity in the northwest Pacific is suggested as a new possible control driving past intervals of low-O 2 intermediate water along the western continental margin of North America. According to this mechanism, O 2 consumption would occur near the site of formation of North Pacific Intermediate Water (NPIW), due to increased respiration of organic carbon in response to a high-productivity event. Evidence is provided for such a productivity increase during the Bølling-Ållerød interval (14.7–12.9 ka), a time when laminated sediments were deposited along the northern California margin. By this mechanism, low-O 2 events in intermediate waters off the western North American margin could occur without significant changes in the rate of NPIW ventilation.

Geology↗
USGS2003

Post-Depositional Behavior of Cu in a Metal-Mining Polishing Pond (East Lake, Canada)

The post-depositional behavior of Cu in a gold-mining polishing pond (East Lake, Canada) was assessed after mine closure by examination of porewater chemistry and mineralogy. The near-surface (upper 1.5 cm) sediments are enriched in Cu, with values ranging from 0.4 to 2 wt %. Mineralogical examination revealed that the bulk of the Cu inventory is present as authigenic copper sulfides. Optical microscopy, energy-dispersion spectra, and X-ray data indicate that the main Cu sulfide is covellite (CuS). The formation of authigenic Cu-S phases is supported by the porewater data, which demonstrate that the sediments are serving as a sink for dissolved Cu below sub-bottom depths of 1-2 cm. The zone of Cu removal is consistent with the occurrence of detectable sulfide and the consumption of sulfate. The sediments can be viewed as a passive bioreactor that permanently removes Cu as insoluble copper sulfides. This process is not unlike that which occurs in other forms of bioremediation, such as wetlands and permeable reactive barriers. Above the zone of Cu removal, dissolved Cu maxima in the interfacial porewaters range from 150 to 450 ??g L-1 and reflect the dissolution of a Cu-bearing phase in the surface sediments. The reactive phase is thought to be a component of treatment sludges delivered to the lake as part of cyanide treatment. Flux calculations indicate that the efflux of dissolved Cu from the sediments to the water column (14-51 ??g cm-2 yr-1) can account for the elevated levels of dissolved Cu in lake waters (???50 ??g L-1). Implications for lake recovery are discussed.

Environmental Science & Technology↗
USGS2003

Gas transfer velocities measured at low wind speed over a lake

The relationship between gas transfer velocity and wind speed was evaluated at low wind speeds by quantifying the rate of evasion of the deliberate tracer, SF 6 , from a small oligotrophic lake . Several possible relationships between gas transfer velocity and low wind speed were evaluated by using 1-min-averaged wind speeds as a measure of the instantaneous wind speed values. Gas transfer velocities in this data set can be estimated virtually equally well by assuming any of three widely used relationships between k 600 and winds referenced to 10-m height, U 10 : (1) a bilinear dependence with a break in the slope at ∼3.7 m s -1 , which resulted in the best fit; (2) a power dependence; and (3) a constant transfer velocity for U 10 < ∼3.7 m s -1 , with a linear dependence on wind speed at higher wind speeds. The lack of a unique relationship between transfer velocity and wind speed at low wind speeds suggests that other processes, such as convective cooling, contribute significantly to gas exchange when the wind speeds are low . All three proposed relationships clearly show a strong dependence on wind for winds >3.7 m s -1 which, coupled with the typical variability in instantaneous wind speeds observed in the field, leads to average transfer velocity estimates that are higher than those predicted for steady wind trends. The transfer velocities predicted by the bilinear steady wind relationship for U 10 < ∼3.7 m s -1 are virtually identical to the theoretical predictions for transfer across a smooth surface.

Limnology and Oceanography↗
USGS2003

Mobility of authigenic rhenium, silver, and selenium during postdepositional oxidation in marine sediments

Sedimentary records of redox-sensitive trace elements hold significant potential as indicators of paleoceanographic environmental conditions. Records of Re can reveal the intensity of past reducing conditions in sediments at the time of deposition, whereas records of Ag may record the magnitude of past diatom fluxes to the seafloor. Confidence in paleoenvironmental reconstruction from records of either metal, however, requires it to have experienced negligible redistribution since deposition. This study examines diagenetic rearrangements of Re and Ag that occur in response to exposure to bottom-water O 2 in environments of low sedimentation rate, including Madeira Abyssal Plain turbidites and eastern Mediterranean basin sapropels. Authigenic Re was remobilized quantitatively by oxidation but poorly retained by the underlying sediments. All records are consistent with previous work demonstrating that only a limited reimmobilization of Re occurs preferentially in C org -rich, reducing sediments. Silver was also mobilized quantitatively by oxidation, but it was subsequently immobilized more efficiently in all cases as sharp peaks immediately into anoxic conditions below active oxidation fronts, and these peaks remain immobile in anoxic conditions during long-term burial. Comparison of Ag, S, and Se records from various cores suggests that Ag is likely to have been immobilized as a selenide, a mechanism previously proposed for Hg in similar situations (Mercone et al., 1999) . Coexisting narrow peaks of Ag and Hg with Se offer a means of assessing whether oxidative burndown has ever occurred at the top of C org - and sulfide-rich sedimentary units. Although these results suggest that caution must be used when inferring paleoenvironmental information from records of Ag and Re in cores with low sediment accumulation rates (<5 cm ka −1 ), they should not affect the promise that authigenic Ag and Re records hold for paleoenvironmental reconstruction in sediments with higher accumulation rates and where anoxic conditions have been maintained continuously.

Geochimica et Cosmochimica Acta↗