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Johanna M. Blake

Publications and source records attributed to Johanna M. Blake.

9 recordsLinked to original sources

Hydrogeology and groundwater quality in the San Agustin Basin, New Mexico, 1975–2019

This report describes the findings of a U.S. Geological Survey study, completed in cooperation with the Bureau of Land Management, focused on better understanding the present-day (1975–2019) hydrogeology and groundwater quality of the San Agustin Basin in west-central New Mexico to support sustainable groundwater resource management. The basin hosts a relatively undeveloped basin-fill and alluvium aquifer system and is topographically divided into east and west subbasins by the McClure Hills. Groundwater chemistry and groundwater elevation data were compiled, collected, and interpreted in the context of groundwater flow and quality. The analyses presented in this report consider groundwater chemistry data collected within the last decade (2010–19) and groundwater elevation data collected from 1975 through 2019 to provide insight into present-day conditions. Groundwater elevations show that groundwater typically moves from the highlands to the lowlands, with a prominent east to west regional trend. Groundwater elevations were lowest in the southwestern portion of the west subbasin, where estimated flow directions suggest underflow through the local highlands into the northern East Fork Gila River watershed, which is further supported by historical groundwater elevation data from the northern East Fork Gila River watershed. Gradual groundwater elevation gradients (about 2 feet per mile) near the east and west subbasin divide suggest that groundwater slowly flows from the east subbasin to the west subbasin. Quantitative analyses of groundwater chemistry data show that groundwater in both subbasins has similar chemical characteristics. A systematic east to west groundwater evolution in water chemistry was not observed despite evidenced subbasin connectivity. The absence of this pattern suggests that groundwater mixing is regionally prevalent, sediment reactivity is low and variable, and (or) recharge conditions are comparable in both subbasins. Groundwater chemistry was generally independent of aquifer type, suggesting that the aquifers are hydrologically well connected. Corrected carbon-14 groundwater age estimates in the basin ranged from 232 to 13,916 years before present with a median of 5,409 years. A wide range of groundwater ages is therefore present in the basin, with waters commonly being thousands of years old, thereby supporting generally slow regional groundwater movement. A component of relatively young groundwater, for which estimated ages could not be accurately computed, is also present in the basin, and it may commonly mix with older waters. The spatial distribution of categorical and quantitative groundwater ages indicates that most recharge likely occurs in the highlands through mountain-block recharge and as focused recharge within arroyos, although evidence of modern (1953 and after) groundwater was minimal at sampled sites. Median annual gradients (groundwater elevation change over time) indicate that most groundwater elevations in the lowlands changed little (−0.2 to 0.2 foot per year) from 1975 through 2019. Groundwater elevations in the highlands varied more annually, which is likely due to recharge from precipitation events. These more variable groundwater elevations in the highlands compared with the lowlands, along with groundwater ages, provide further evidence that most groundwater recharge takes place in the highlands, with minimal recharge in the lowlands. Median groundwater elevation change for all sites was −0.05 foot per year. Temporal consistency of lowland groundwater elevations suggests that regional groundwater dynamics have been more or less stable through time under current climate and development conditions, although median annual gradients indicate that groundwater elevations may have slightly declined on average between 1975 and 2019.

New Mexico

Tracking the source of metals to the San Juan River

Introduction The San Juan River is a major water source for communities in the Four Corners Region of the United States (Colorado, Arizona, New Mexico, Utah) and is a vital source of water for the Navajo Nation. The Navajo Nation Environmental Protection Agency (NNEPA) periodically samples surface water on the Navajo Nation and has found that some elements exceed NNEPA surface water standards (the upper limits of an element for consumption or other use of water). Constituents of concern are substances that could be harmful if present in sufficient quantities, and it is important to keep track of the concentrations of these substances in the environment. In the San Juan River, constituents of concern include metals detected in river water, such as arsenic, lead, and aluminum. These metals can come from natural sources or can result from human activities (anthropogenic) and can affect the health of people, plants, and animals. The Animas River is one natural source of metals to the San Juan River because of the types of rock through which the Animas River flows and because of hard rock mining at the headwaters. Other potential sources of metals are oil and gas development, coal mining, coal-fired power plants, urban areas, illegal trash dumping, abandoned uranium mines and mills, overgrazed areas, natural geology, and leaching from subsurface agricultural return flows. Determining how much each of these sources contributes and the relative effect of each source on San Juan River water will help the Navajo Nation in their efforts to protect human health and the environment along the San Juan River. The U.S. Geological Survey (USGS) is working with the NNEPA to identify sources of metals and trace elements entering the San Juan River from tributaries in the reach flowing through the Navajo Nation and to quantify the contribution from each natural and human-caused source. The USGS and NNEPA worked with local community members to locate tributaries where sampling equipment was installed. The 3-year source-tracking project, starting in spring 2021, will identify where metals at concentrations above safe surface water standards might be entering the river by evaluating the chemical signatures of water in the major tributaries of the San Juan River. Results will provide valuable information to the Navajo Nation, public drinking-water managers, irrigation districts, other stakeholders, scientists, and the public.

Colorado, Arizona, New Mexico, Utah

Sediment record of mining legacy and water quality from a drinking-water reservoir, Aztec, New Mexico, USA

The record of mining legacy and water quality was investigated in sediments collected in 2018 from four trenches in the Aztec, New Mexico, drinking-water reservoir #1. Bulk chemical analysis of sediments with depth in the reservoir revealed variable trace-element (uranium, vanadium, arsenic, copper, sulfur, silver, lead, and zinc) concentrations, which appear to coincide with historical mining and milling operations. Cesium-137 age dating, which identified the location of the 1963 radioactive fallout maximum, combined with the known age of the bottom and top of the sediment trenches, was used to estimate a polynomial sedimentation rate (average rate = 1.7 cm/yr). The clay size fraction (< 0.004 mm) was the dominant grain-size fraction of the sediments. Abundant fine-grained phyllosilicate (clay) minerals, predominantly montmorillonite and kaolinite, may explain sorption properties of trace elements. Scanning electron microscopy evaluation of sediments from two trenches showed copper and zinc associated with sulfur, and arsenic associated with iron and aluminum oxides. Results from laboratory batch experiments indicated that uranium, vanadium, and arsenic were released when sediments were reacted with a 150 mg/L sodium bicarbonate solution whereas copper was released when sediments were reacted with 2 mMol/L acetic acid. Observed concentrations from the two leach tests were below regulatory thresholds for delivery of solids to a landfill and were below drinking-water standards. Diatom relative abundance indicates that the water quality in the reservoir was not impaired by high metal concentrations.

Colorado, New Mexico

Assessment of soil and water resources in the Organ Mountains-Desert Peaks National Monument, New Mexico

The Organ Mountains-Desert Peaks National Monument (Monument) in southern New Mexico was established in 2014. Given anticipated future demands in the Monument for recreation, livestock grazing, and maintenance of rights-of-way (for example, pipelines and powerlines), the Bureau of Land Management (BLM) needs a better understanding of the current soil and water resources and how infrastructure improvements could affect these resources and the watershed. Specifically, the BLM is concerned with infiltration and erosion and their relations to existing or planned infrastructure, such as roads, campgrounds, location of livestock grazing, and rights-of-way. Alternatives to the current land-use conditions, land-management practices, and infrastructure will be assessed by BLM to best protect Monument resources. The U.S. Geological Survey, in cooperation with the BLM, conducted a study to assess the soil and water resources within the Monument to provide an inventory and compilation of natural-resource information needed by resource managers for the BLM’s land-use planning process for this new national monument. The overall objectives of this study were to (1) compile and interpret existing soil- and water-resource data for the Monument and (2) provide a basic assessment of the surface hydrological effects of selected alternatives to current land use and infrastructure. Data were compiled by using geographic information system software and evaluated for hydrologic and landscape properties that influence infiltration, runoff, and erosion. The effects of changing vegetation were simulated by using different scenarios in the Rangeland Hydrology and Erosion Model. Results of this model indicate areas where soil loss or runoff may occur.

New Mexico

Identifying natural and anthropogenic variability of uranium at the well scale, Homestake Superfund site, near Milan, New Mexico, USA

The San Mateo Creek Basin in New Mexico, USA is located within the Grants Mineral Belt-an area with numerous uranium (U) ore deposits, mines, and milling operations. Six monitoring wells set in an alluvial aquifer near the Homestake Mining Co. Superfund site in the lower San Mateo Creek Basin were logged with a suite of borehole geophysical tools including spectral gamma-ray (SGR), vertically profiled with passive samplers for U and selenium (Se) concentrations, and purged sampled for same constituents. The integrated approach allowed for an assessment on the role of heterogeneity (both physical and chemical) in determining U concentrations in groundwater. Uranium, as measured with SGR logging, is ubiquitous in the alluvial aquifer and the underlying Chinle Group. Aqueous U concentrations appear to be inversely related to thorium (Th) concentrations, as measured by the SGR log, indicating the possibility that U is bound in or adsorbed to clays in the aquifer. The stratigraphy of the alluvium likely plays a role in elevated concentrations of aqueous U. Interbedded clay and sand layers allow for the mobilization of U in oxic sandy layers from U adsorbed in sediments in reduced clay layers. The stratigraphy also plays a role in the degree of mixing of groundwater in the formation and well. Mixing can obscure the ability to identify U sources. Mixing is exacerbated by the relatively long screens (> 20 ft long or > 6.1 m) of the monitoring wells.

New Mexico

Effect of calcium on the bioavailability of dissolved uranium(VI) in plant roots under circumneutral pH

We integrated field measurements, hydroponic experiments, microscopy, and spectroscopy to investigate the effect of Ca(II) on dissolved U(VI) uptake by plants in 1 mM HCO 3 – solutions at circumneutral pH. The accumulation of U in plants (3.1–21.3 mg kg –1 ) from the stream bank of the Rio Paguate, Jackpile Mine, New Mexico served as a motivation for this study. Brassica juncea was the model plant used for the laboratory experiments conducted over a range of U (30–700 μg L –1 ) and Ca (0–240 mg L –1 ) concentrations. The initial U uptake followed pseudo-second-order kinetics. The initial U uptake rate ( V 0 ) ranged from 4.4 to 62 μg g –1 h –1 in experiments with no added Ca and from 0.73 to 2.07 μg g –1 h –1 in experiments with 12 mg L –1 Ca. No measurable U uptake over time was detected for experiments with 240 mg L –1 Ca. Ternary Ca–U–CO 3 complexes may affect the decrease in U bioavailability observed in this study. Elemental X-ray mapping using scanning transmission electron microscopy–energy-dispersive spectrometry detected U–P-bearing precipitates within root cell walls in water free of Ca. These results suggest that root interactions with Ca and carbonate in solution affect the bioavailability of U in plants. This study contributes relevant information to applications related to U transport and remediation of contaminated sites.

Environmental Science & Technology

Determination of representative uranium and selenium concentrations from groundwater, 2016, Homestake Mining Company Superfund site, Milan, New Mexico

In 2016, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, collected data on isotopes, age dating, and geochemistry including aqueous uranium concentrations of samples from 20 locations in the vicinity of the Homestake Mining Company Superfund site near Milan, New Mexico. The 20 sampled locations include 19 groundwater wells and 1 treatment plant for water used for injection into aquifers. At 6 of the 19 wells, multiple samples were collected by several different sampling methods, including passive, micropurge, and volumetric methods. Aqueous uranium concentrations were adjusted on the basis of comparisons between three sampling methods (called sample adjustments). These adjustments were specific to passive sample results because they underestimated uranium concentrations compared with results from purge samples (micropurge and volumetric). Sample adjustments were also made on aqueous selenium concentrations from previously published data for passive sampler results following a similar procedure. Aqueous uranium concentrations in dissolved and total form were adjusted from the original analytical values (called laboratory analytical adjustments) on the basis of a rigorous comparison to several external tests, including reruns and analysis by a different laboratory after accuracy issues were identified in data from the original laboratory. The original laboratory analytical results were found to be two to five times greater than historical concentrations at the same locations, which prompted further evaluation, as described in this report.

New Mexico

Metal reactivity in laboratory burned wood from a watershed affected by wildfires

We investigated interfacial processes affecting metal mobility by wood ash under laboratory-controlled conditions using aqueous chemistry, microscopy, and spectroscopy. The Valles Caldera National Preserve in New Mexico experiences catastrophic wildfires of devastating effects. Wood samples of Ponderosa Pine, Colorado Blue Spruce, and Quaking Aspen collected from this site were exposed to temperatures of 60, 350, and 550 °C. The 350 °C Pine ash had the highest content of Cu (4997 ± 262 mg kg –1 ), Cr (543 ± 124 mg kg –1 ), and labile dissolved organic carbon (DOC, 11.3 ± 0.28 mg L –1 ). Sorption experiments were conducted by reacting 350 °C Pine, Spruce, and Aspen ashes separately with 10 μM Cu(II) and Cr(VI) solutions. Up to a 94% decrease in Cu(II) concentration was observed in solution while Cr(VI) concentration showed a limited decrease (up to 13%) after 180 min of reaction. X-ray photoelectron spectroscopy (XPS) analyses detected increased association of Cu(II) on the near surface region of the reacted 350 °C Pine ash from the sorption experiments compared to the unreacted ash. The results suggest that dissolution and sorption processes should be considered to better understand the potential effects of metals transported by wood ash on water quality that have important implications for postfire recovery and response strategies.

Environmental Science & Technology

Assessment of water resources and the potential effects from oil and gas development in the Bureau of Land Management Tri-County planning area, Sierra, Doña Ana, and Otero Counties, New Mexico

The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management, conducted a study to assess the water resources and potential effects on the water resources from oil and gas development in the Tri-County planning area, Sierra, Doña Ana, and Otero Counties, New Mexico. Publicly available data were used to assess these resources and effects and to identify data gaps in the Tri-County planning area. The Tri-County planning area includes approximately 9.3 million acres and is within the eastern extent of the Basin and Range Province, which consists of mountain ranges and low elevation basins. Three specific areas of interest within the Tri-County planning area are the Jornada del Muerto, Tularosa Basin, and Otero Mesa, which is adjacent to the Salt Basin. Surface-water resources are limited in the Tri-County planning area, with the Rio Grande as the main perennial river flowing from north to south through Sierra and Doña Ana Counties. The Tularosa Creek is an important surface-water resource in the Tularosa Basin. The Sacramento River, which flows southeast out of the Sacramento Mountains, is an important source of recharge to aquifers in the Salt Basin. Groundwater resources vary in aquifer type, depth to water, and water quality. For example, the Jornada del Muerto, Tularosa Basin, and Salt Basin each have shallow and deep aquifer systems, and water can range from freshwater, with less than 1,000 milligrams per liter (mg/L) of total dissolved solids, to brine, with greater than 35,000 mg/L of total dissolved solids. Water quality in the Tri-County planning area is affected by the dissolution of salt deposits and evaporation which are common in arid regions such as southern New Mexico. The potential for oil and gas development exists in several areas within the Tri-County area. As many as 81 new conventional wells and 25 coalbed natural gas wells could be developed by 2035. Conventional oil and gas well construction in the Tri-County planning area is expected to require 1.53 acre-feet (acre-ft) (500,000 gallons) of water per well, similar to requirements in the nearby Permian Basin of New Mexico, while construction of unconventional wells is expected to require 7.3 acre-ft of water per well. Produced waters in the Permian Basin have high total dissolved solids, in the brackish to brine range. Data gaps identified in this study include the limited detailed data on surface-water resources, the lack of groundwater data in areas of interest, and the lack of water chemistry data related to oil and gas development issues. Surface waters in the Tri-County planning area are sparse; some streams are perennial, and most are ephemeral. A more detailed study of the ephemeral channels and their interaction with groundwater could provide a better understanding of the importance of these surface-water resources. Groundwater data used in this study are from the USGS National Water Information System, which does not have continuous water-level depth data at many of the sites in the Tri-County planning area. On Otero Mesa, no recurrent groundwater-level data are available at any one site. The water-quality data compiled in this study provide a good overview of the general chemistry of groundwater in the Tri-County planning area. To fully understand the groundwater resources, it would be helpful to have more wells in specific areas of interest for groundwater-level and water-quality measurements.

New Mexico