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Jiawen Hu

Publications and source records attributed to Jiawen Hu.

9 recordsLinked to original sources

Nitrogen in Chinese coals

Three hundred and six coal samples were taken from main coal mines of twenty-six provinces, autonomous regions, and municipalities in China, according to the resource distribution and coal-forming periods as well as the coal ranks and coal yields. Nitrogen was determined by using the Kjeldahl method at U. S. Geological Survey (USGS), which exhibit a normal frequency distribution. The nitrogen contents of over 90% Chinese coal vary from 0.52% to 1.41% and the average nitrogen content is recommended to be 0.98%. Nitrogen in coal exists primarily in organic form. There is a slight positive relationship between nitrogen content and coal ranking. ?? 2011 Science Press, Institute of Geochemistry, CAS and Springer Berlin Heidelberg.

Chinese Journal of Geochemistry

Structural stability of methane hydrate at high pressures

The structural stability of methane hydrate under pressure at room temperature was examined by both in-situ single-crystal and powder X-ray diffraction techniques on samples with structure types I, II, and H in diamond-anvil cells. The diffraction data for types II (sII) and H (sH) were refined to the known structures with space groups Fd 3 m and P 6 3 / mmc , respectively. Upon compression, sI methane hydrate transforms to the sII phase at 120 MPa, and then to the sH phase at 600 MPa. The sII methane hydrate was found to coexist locally with sI phase up to 500 MPa and with sH phase up to 600 MPa. The pure sH structure was found to be stable between 600 and 900 MPa. Methane hydrate decomposes at pressures above 3 GPa to form methane with the orientationally disordered Fm 3 m structure and ice VII ( Pn 3 m ). The results highlight the role of guest (CH 4 )-host (H 2 O) interactions in the stabilization of the hydrate structures under pressure.

Geoscience Frontiers

Atmospheric stability effects on wind fields and scalar mixing within and just above a subalpine forest in sloping terrain

Air temperature T a , specific humidity q , CO 2 mole fraction χ c , and three-dimensional winds were measured in mountainous terrain from five tall towers within a 1 km region encompassing a wide range of canopy densities. The measurements were sorted by a bulk Richardson number Ri b . For stable conditions, we found vertical scalar differences developed over a “transition” region between 0.05 < Ri b < 0.5. For strongly stable conditions ( Ri b > 1), the vertical scalar differences reached a maximum and remained fairly constant with increasing stability. The relationships q and χ c have with Ri b are explained by considering their sources and sinks. For winds, the strong momentum absorption in the upper canopy allows the canopy sublayer to be influenced by pressure gradient forces and terrain effects that lead to complex subcanopy flow patterns. At the dense-canopy sites, soil respiration coupled with wind-sheltering resulted in CO 2 near the ground being 5–7 μmol mol −1 larger than aloft, even with strong above-canopy winds (near-neutral conditions). We found Ri b -binning to be a useful tool for evaluating vertical scalar mixing; however, additional information (e.g., pressure gradients, detailed vegetation/topography, etc.) is needed to fully explain the subcanopy wind patterns. Implications of our results for CO 2 advection over heterogenous, complex terrain are discussed.

Boundary-Layer Meteorology

A multiscale and multidisciplinary investigation of ecosystem-atmosphere CO 2 exchange over the rocky mountains of colorado

A field study combined with modeling investigation demonstrated that the organization of CO2 transport by mountain terrain strongly affects the regional CO2 budget. Atmospheric dynamics can lead to complicated flows generated by inhomogeneous landscapes, topography or synoptic weather systems. The field campaign conducted of a ground deployment, the Carbon in the Mountain Experiment (CME04), and an aircraft deployment of the national Center for Atmospheric Research (NCAR) C-130, the Airborne Carbon in the Mountains Experiment (ACME04) over the period of spring to fall of 2004 to cover the seasonal variation of ecosystem-atmosphere carbon exchange. The role of the mountain circulation in CO2 transport can be played over seemingly flat terrain by mesoscale flows generated by various physical processes. The three dimensional observation strategy considered can also be applied over flat terrain.

Bulletin of the American Meteorological Society

Use of airborne and terrestrial lidar to detect ground displacement hazards to water systems

We investigate the use of multiepoch airborne and terrestrial lidar to detect and measure ground displacements of sufficient magnitude to damage buried pipelines and other water system facilities that might result, for example, from earthquake or rainfall-induced landslides. Lidar scans are performed at three sites with coincident measurements by total station surveying. Relative horizontal accuracy is evaluated by measurements of lateral dimensions of well defined objects such as buildings and tanks; we find misfits ranging from approximately 5 to 12 cm, which is consistent with previous work. The bias and dispersion of lidar elevation measurements, relative to total station surveying, is assessed at two sites: (1) a power plant site (PP2) with vegetated steeply sloping terrain; and (2) a relatively flat and unvegetated site before and after trenching operations were performed. At PP2, airborne lidar showed minimal elevation bias and a standard deviation of approximately 70 cm, whereas terrestrial lidar did not produce useful results due to beam divergence issues and inadequate sampling of the study region. At the trench site, airborne lidar showed minimal elevation bias and reduced standard deviation relative to PP2 (6-20 cm), whereas terrestrial lidar was nearly unbiased with very low dispersion (4-6 cm). Pre- and posttrench bias-adjusted normalized residuals showed minimal to negligible correlation, but elevation change was affected by relative bias between epochs. The mean of elevation change bias essentially matches the difference in means of pre- and posttrench elevation bias, whereas elevation change standard deviation is sensitive to the dispersion of individual epoch elevations and their correlation coefficient. The observed lidar bias and standard deviations enable reliable detection of damaging ground displacements for some pipelines types (e.g., welded steel) but not all (e.g., concrete with unwelded, mortared joints). ?? ASCE 2009.

Journal of Surveying Engineering

PVTx properties of the CO 2 -H 2 O and CO 2 -H 2 O-NaCl systems below 647 K: assessment of experimental data and thermodynamic models

Evaluation of CO 2 sequestration in formation brine or in seawater needs highly accurate experimental data or models of pressure&ndash;volume&ndash;temperature-composition ( PVTx ) properties for the CO 2 &ndash;H 2 O and CO 2 &ndash;H 2 O&ndash;NaCl systems. This paper presents a comprehensive review of the experimental PVTx properties and the thermodynamic models of these two systems. The following conclusions are drawn from the review: (1) About two-thirds of experimental data are consistent with each other, where the uncertainty in liquid volumes is within 0.5%, and that in gas volumes within 2%. However, this accuracy is not sufficient for assessing CO 2 sequestration. Among the data sets for liquids, only a few are available for accurate modeling of CO 2 sequestration. These data have an error of about 0.1% on average, roughly covering from 273 to 642 K and from 1 to 35 MPa; (2) There is a shortage of volumetric data of saturated vapor phase. (3) There are only a few data sets for the ternary liquids, and they are inconsistent with each other, where only a couple of data sets can be used to test a predictive density model for CO 2 sequestration; (4) Although there are a few models with accuracy close to that of experiments, none of them is accurate enough for CO 2 sequestration modeling, which normally needs an accuracy of density better than 0.1%. Some calculations are made available on www.geochem-model.org .

Chemical Geology

Concentration and distribution of sixty-one elements in coals from DPR Korea

Fifty coal samples (28 anthracite and 22 lignites) were collected from both main and small coal mines in DPR Korea prioritized by resource distribution and coal production. The concentrations of 61 elements in 50 coal samples were determined by several multielement and element-specific techniques, including inductively coupled plasma atomic emission spectrometry (ICP-AES), and inductively coupled plasma mass spectrometry (ICP-MS), ion chromatogram (IC), cold-vapor atomic absorption spectrometry (CV-AAS), and hydride generation atomic absorption spectrometry (HGAAS). The ranges, arithmetic means and geometric means of concentrations of these elements are presented. A comparison with crustal abundances (Clarke values) shows that some potentially hazardous elements in the coals of DPR Korea are highly enriched Li, B, S, Cl, Zn, As, Se, Cd, Sn, Sb, W, Te, Hg, Ag, Pb, and La, Ce, Dy, Tm, Ge, Mo, Cs, Tl, Bi, Th and U are moderately enriched. A comparison of ranges and means of elemental concentrations in DPR Korea, Chinese, and world coals shows the ranges of most elements in DPR Korea coals are very close to the ranges of world coals. Arithmetic means of most elements in DPR Korea coals are close to that of American coals. Most elements arithmetic means are higher in Jurassic and Paleogene coals than coals of other ages. In DPR Korea coals, only seven elements in early Permian coals are higher than other periods: Li, Zn, Se, Cd, Hg, Pb, and Bi. Only five elements B, As, Sr, Mo, W in Neogene coals have arithmetic means higher than others. SiO2 and Al2O 3 in ashes are more than 70% except six samples. The correlation between ash yields and major elements from high to low is in the order of Si>Al>Ti>K>Mg>Fe>Na>Ca>P>S. Most elements have high positive correlation with ash (r>0.5) and show high inorganic affinity. ?? 2005 Elsevier Ltd. All rights reserved.

Fuel

Relationship between occurrence mode of arsenic in coal and its washing rate

Based on the analysis of 15 raw coals and washed coals collected from Southwestern, the washing rate of arsenic, sulfur and ash from raw coals was studied. The average washing rate of arsenic in raw coal is 38%. Arsenic of raw coals is mainly associated with pyrite and sulfide. However, arsenic of some raw coals is mainly or wholly associated with organic matter and mineral enwrapped by organic matter. It is difficult to remove such part of arsenic and it will enrich in the washed coals. The results show that there is a little relationship between occurrence mode of arsenic associated with organic sulfur and rank of coal, but it is complicated with age of coal-bearing strata.

Ranliao Huaxue Xuebao/Journal of Fuel Chemistry an

Tectonics of the Qinling (Central China): Tectonostratigraphy, geochronology, and deformation history

The Qinling orogen preserves a record of late mid-Proterozoic to Cenozoic tectonism in central China. High-pressure metamorphism and ophiolite emplacement (Songshugou ophiolite) assembled the Yangtze craton, including the lower Qinling unit, into Rodinia during the ~1.0 Ga Grenvillian orogeny. The lower Qinling unit then rifted from the Yangtze craton at ~0.7 Ga. Subsequent intra-oceanic arc formation at ~470-490 Ma was followed by accretion of the lower Qinling unit first to the intra-oceanic arc and then to the Sino-Korea craton. Subduction then imprinted a ~400 Ma Andean-type magmatic arc onto all units north of the northern Liuling unit. Oblique subduction created Silurian-Devonian WNW-trending, sinistral transpressive wrench zones (e.g., Lo-Nan, Shang-Dan), and Late Permian-Early Triassic subduction reactivated them in dextral transpression (Lo-Nan, Shang-Xiang, Shang-Dan) and subducted the northern edge of the Yangtze craton. Exhumation of the cratonal edge formed the Wudang metamorphic core complex during dominantly pure shear crustal extension at ~230-235 Ma. Post-collisional south-directed shortening continued through the Early Jurassic. Cretaceous reactivation of the Qinling orogen started with NW-SE sinistral transtension, coeval with large-scale Early Cretaceous crustal extension and sinistral transtension in the northern Dabie Shan; it presumably resulted from the combined effects of the Siberia-Mongolia-Sino-Korean and Lhasa-West Burma-Qiangtang-Indochina collisions and Pacific subduction. Regional dextral wrenching was active within a NE-SW extensional regime between ~60 and 100 Ma. An Early Cretaceous Andean-type continental magmatic arc, with widespread Early Cretaceous magmatism and back-arc extension, was overprinted by shortening related to the collision of Yangtze-Indochina Block with the West Philippines Block. Strike-slip and normal faults associated with Eocene half-graben basins record Paleogene NNE-SSW contraction and WNW-ESE extension. The Neogene(?) is characterized by normal faults and NNE-trending sub-horizontal extension. Pleistocene(?)-Quaternary NW-SE extension and NE-SW contraction comprises sinistral strike-slip faults and is part of the NW-SE extension imposed across eastern Asia by the India-Asia collision.

Tectonophysics