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Jennifer G. Savoie

Publications and source records attributed to Jennifer G. Savoie.

18 recordsLinked to original sources
USGS2022

Concentrations of per- and polyfluoroalkyl substances (PFAS) in selected rivers and streams in Massachusetts, 2020

Water samples collected from 27 rivers and streams in Massachusetts were analyzed to characterize the presence and concentrations of per- and polyfluoroalkyl substances (collectively known as PFAS) in surface waters across the Commonwealth. Sampling sites were selected in urban rivers where PFAS were expected to be present, such as those that receive treated municipal wastewater, and in rural rivers that were not known to be affected by municipal wastewater. The samples were collected three times in 2020 from 64 sites, and were analyzed for 24 PFAS, 18 of which are included in the U.S. Environmental Protection Agency’s Method 537.1. Samples were collected when the instantaneous flow of the rivers and streams were at base-flow condition to minimize PFAS input or dilution from stormwater runoff and overland flow. The analyses detected PFAS in samples from all 27 rivers and streams. The number of PFAS detected in each sample ranged from 2 to 16. Concentrations of individual PFAS ranged from no detectable concentrations (less than 1.74 nanograms per liter) to 109 nanograms per liter. Samples from sites associated with wastewater treatment facilities in urban areas had a larger number and variety of PFAS present, and at higher concentrations, than in samples from the more rural rivers. This report includes a summary of the chemical data and physical properties of both environmental and quality-control samples, and a description of procedures for the collection and processing of the samples.

Massachusetts↗
USGS2022

Surface-water-quality data to support implementation of revised freshwater aluminum water-quality criteria in Massachusetts, 2018–19

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed a study to inform the development of the department’s guidelines for the collection and use of water-chemistry data to support calculation of site-dependent aluminum criteria values. The U.S. Geological Survey collected and analyzed discrete water-quality samples at four wastewater-treatment facilities and seven water-treatment facilities in eastern and central Massachusetts from April 2018 through May 2019. For each of the 11 facilities considered, water-quality samples were collected from treatment-plant effluent and receiving-water bodies. Samples were collected for laboratory analysis of major ions (calcium and magnesium ions are used to calculate total hardness), dissolved organic carbon (DOC), total organic carbon (TOC), and total recoverable aluminum. Field parameters for pH, temperature, and specific conductance were measured in situ concurrently with sample collection. Water-quality conditions differed among monitoring stations. The highest pH values were observed for stations on the Assabet River that receive effluent discharges from wastewater-treatment facilities (the Westborough, Marlborough, Hudson, and Maynard wastewater-treatment facilities). High DOC concentrations (greater than 10 mg/L) were measured in water bodies associated with large areas of riparian wetlands—Lily Pond (Cohasset) and Third Herring Brook (Hanover), and low DOC concentrations (less than 2.5 mg/L) were measured at three water bodies in central Massachusetts—Hocomonco Pond (Westborough), Wyman Pond (Fitchburg), and Monoosnoc Brook (Leominster). Wyman Pond (Fitchburg), Monoosnoc Brook (Leominster), and Lily Pond (Cohasset) also had low pH values and low total hardness concentrations. The monthly discrete pH, DOC, and total hardness data for selected stations on receiving-water bodies were used in the U.S. Environmental Protection Agency Aluminum Criteria Calculator Version 2.0 to estimate site-dependent total recoverable aluminum concentrations that—if not exceeded—would be expected to protect fish, invertebrates, and other aquatic life from adverse effects associated with acute and chronic aluminum exposures. The U.S. Environmental Protection Agency Calculator output provides values for the acute criterion, defined as the criterion maximum concentration (CMC), an estimate of the highest aluminum concentration in surface water to which an aquatic community can be exposed briefly without resulting in an unacceptable effect. This output also provides values for the chronic criterion, defined as the criterion continuous concentration (CCC), an estimate of the highest concentration of aluminum in surface water to which an aquatic community can be exposed indefinitely without resulting in an unacceptable effect. To determine aluminum criteria values typically evaluated for use as protective water-quality criteria, the monthly instantaneous CMC and CCC values were used to calculate the minimum, 5th percentile, and 10th percentile CMC and CCC values for selected monitoring stations. The monthly instantaneous aluminum CMC and CCC values generated using the EPA Calculator varied among stations. Aluminum CMC and CCC values were highest for four ambient (upstream) stations on the Assabet River associated with wastewater-treatment facilities (Westborough, Marlboro, Hudson, and Maynard). Aluminum CMC and CCC values were lower for stations associated with water-treatment facilities, and lowest for selected ambient stations on Lily Pond, Monoosnoc Brook, and Wyman Pond associated with water-treatment facilities in Cohasset, Leominster, and Fitchburg, respectively. For many stations, the highest CMC and CCC instantaneous aluminum criteria values generated using the U.S. Environmental Protection Agency Calculator were for months during the growing season for algae and aquatic macrophytes (April or May through September or October) and the lowest values were for months during the nongrowing season (October or November through March or April), indicating the importance of collecting water-quality data during the nongrowing season. Aluminum CMC and CCC values generated by the U.S. Environmental Protection Agency Calculator are sensitive to variations in the input parameters (pH, DOC, and total hardness). Aluminum solubility is particularly affected by pH. To characterize diel and seasonal variations in pH, multiparameter water-quality monitors recording continuous (15-minute interval) water temperature and pH were installed in the receiving-water body for one station near each facility upstream from the effluent discharge (in rivers) or at a station outside the immediate effect of effluent discharge (in ponds). Continuous water temperature and pH data were collected from April or May 2018 through November or December 2018. Continuous pH data indicated that the pond stations and Assabet River stations had large diel variations in pH during the growing season. Continuous pH data were used together with discrete DOC and total hardness data to evaluate the potential effect of diel variations in pH on calculated site-dependent aluminum criteria values. For the 11 stations, diel variations in pH were determined to correspond to differences in the 10th percentile of CMC values by a median of 160 μg/L, ranging from 0 to 610 μg/L, and differences in the 10th percentile of CCC values by a median of 40 μg/L, ranging from 15 to 210 μg/L. The low monthly instantaneous CMC and CCC values that have the greatest effect on the minimum, 5th percentile, and 10th percentile aluminum values tend to result during the nongrowing season (October or November through March or April) when the range of diel variations in pH is small, thus minimizing the effect of diel variations in pH on the lowest CMC and CCC values. Historical water-quality data on organic carbon in Massachusetts streams were investigated using data retrieved from the USGS National Water Information System database. An assessment of the availability of historical pH, DOC, and hardness data indicated that more data were available for TOC than for DOC. A linear regression equation was developed for the relation between DOC and TOC concentrations to inform the potential use of available data to evaluate water-quality conditions at additional sites across Massachusetts where only pH, hardness, and TOC data are available. DOC and TOC concentrations were well correlated in the 223 samples in which both constituents were analyzed, and the equation had a coefficient of determination ( R 2 ) equal to 0.93.

Massachusetts↗
USGS2017

Analysis of trends of water quality and streamflow in the Blackstone, Branch, Pawtuxet, and Pawcatuck Rivers, Massachusetts and Rhode Island, 1979 to 2015

Trends in long-term water-quality and streamflow data from six water-quality-monitoring stations within three major river basins in Massachusetts and Rhode Island that flow into Narragansett Bay and Little Narragansett Bay were evaluated for water years 1979–2015. In this study, conducted by the U.S. Geological Survey in cooperation with the Rhode Island Department of Environmental Management, the Rhode Island Water Resources Board, and the U.S. Environmental Protection Agency, water-quality and streamflow data were evaluated with a Weighted Regressions on Time, Discharge, and Season smoothing method, which removes the effects of year-to-year variation in water-quality conditions due to variations in streamflow (discharge). Trends in annual mean, annual median, annual maximum, and annual 7-day minimum flows at four continuous streamgages were evaluated by using a time-series smoothing method for water years 1979–2015. Water quality at all monitoring stations changed over the study period. Decreasing trends in flow-normalized nutrient concentrations and loads were observed during the period at most monitoring stations for total nitrogen, nitrite plus nitrate, and total phosphorus. Average flow-normalized loads for water years 1979–2015 decreased in the Blackstone River by up to 46 percent in total nitrogen, 17 percent in nitrite plus nitrate, and 69 percent in total phosphorus. The other rivers also had decreasing flow-normalized trends in nutrient concentrations and loads, except for the Pawtuxet River, which had an increasing trend in nitrite plus nitrate. Increasing trends in flow-normalized chloride concentrations and loads were observed during the study period at all of the rivers, with increases of more than 200 percent in the Blackstone River. Small increasing trends in annual mean daily streamflow were observed in 3 of the 4 rivers, with increases of 1.2 to 11 percent; however, the trends were not significant. All 4 rivers had decreases in streamflow for the annual 7-day minimums, but only 3 of the 4 rivers had decreases that were significant (34 to 54 percent). The Branch River had decreasing annual mean daily streamflow (7.5 percent) and the largest decrease in the annual 7-day minimum streamflow. The Blackstone and Pawtuxet Rivers had the largest increases in annual maximum daily flows but had decreases in the annual 7-day minimum flows.

Massachusetts, Rhode Island↗
USGS2016

Changes in phosphorus concentrations and loads in the Assabet River, Massachusetts, October 2008 through April 2014

Treated effluent discharged from municipal wastewater-treatment plants to the Assabet River in central Massachusetts includes phosphorus, which leads to increased growth of nuisance aquatic plants that decrease the river’s water quality and aesthetics in impounded reaches during the growing season. To improve the river’s water quality and aesthetics, the U.S. Environmental Protection Agency approved a total maximum daily load for phosphorus in 2004 that directed the wastewater-treatment plants to reduce the amount of total phosphorus discharged to the river by 2012. The permitted total phosphorus monthly average of 0.75 milligrams per liter during the aquatic plant growing season (April 1 through October 31) was reduced by the total maximum daily load to a target of 0.1 milligrams per liter by 2012, and the nongrowing-season limit was unchanged at 1.0 milligrams per liter. From October 2008 through April 2014, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, measured streamflow and collected weekly flow-proportional, composite samples of water from the Assabet River for analysis of concentrations of total phosphorus and orthophosphate. Streamflow and concentration data were used to estimate total phosphorus and orthophosphate loads in the river. The purpose of this monitoring effort was to evaluate phosphorus concentrations and loads in the river before, during, and after the wastewater-treatment-plant upgrades and to assess the effects of seasonal differences in permitted discharges. The locations of water-quality-monitoring stations, with respect to the Hudson and Ben Smith impoundments, enabled examination of effects of phosphorus entering and leaving the impoundments. Annual median concentrations of total phosphorus in wastewater-treatment plants were reduced by more than 80 percent with the plant upgrades. Measured instream annual median concentrations of total phosphorus in the Assabet River decreased by about 38 to 50 percent at three of the four monitoring stations following the wastewater-treatment-plant upgrades. At the station farthest upstream, the median total phosphorus concentration remained unchanged throughout the study; this may be attributed to the site location and potential resuspension of particulate organic matter during periods of increased streamflow. Annual median loads from the wastewater-treatment plants were reduced by up to 91 percent following the upgrades, instream annual median total phosphorus loads at the three downstream stations decreased by 71 to 76 percent, and instream orthophosphate loads at the three downstream stations decreased by 79 to 87 percent. Seasonal fluctuations (growing versus nongrowing) of total phosphorus and orthophosphate were observed instream before the upgrades. However, after the upgrades, fluctuations in phosphorus released from the treatment plants were slight and seasonal changes were typically not observed instream. Annual loads entering and leaving the two impoundments were inconclusive in determining whether the impoundments were sources or sinks of total phosphorus during the study. Total phosphorus loads entering the Hudson impoundment were consistently greater than those leaving; however, there was uncertainty about the loads at the monitoring station upstream from this impoundment. At the Ben Smith impoundment, total phosphorus and orthophosphate loads downstream were slightly greater than those upstream from the impoundment, but the differences may reflect additions from tributaries and overland runoff. Estimated instream total phosphorus concentrations and loads indicated that the decreases in total phosphorus in wastewater-treatment-plant discharges were accompanied by reductions measured in the Assabet River. A statistical analysis which incorporates the effect of varying flow conditions demonstrated significant reductions in total phosphorus concentrations after the wastewater-treatment-plant upgrades at three of the four instream monitoring stations. No significant change was observed at the most upstream location, the Assabet River at Port Street at Hudson, Massachusetts (station number 01096835), which may have been affected by flow-related resuspension of particulate phosphorus.

Massachusetts↗
USGS2013

Monitoring to assess progress toward meeting the total maximum daily load for phosphorus in the Assabet River, Massachusetts: phosphorus loads, 2008 through 2010

Wastewater discharges to the Assabet River contribute substantial amounts of phosphorus, which support accumulations of nuisance aquatic plants that are most evident in the river’s impounded reaches during the growing season. To restore the Assabet River’s water quality and aesthetics, the U.S. Environmental Protection Agency required the major wastewater-treatment plants in the drainage basin to reduce the amount of phosphorus discharged to the river by 2012. From October 2008 to December 2010, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection and in support of the requirements of the Total Maximum Daily Load for Phosphorus, collected weekly flow-proportional, composite samples for analysis of concentrations of total phosphorus and orthophosphorus upstream and downstream from each of the Assabet River’s two largest impoundments: Hudson and Ben Smith. The purpose of this monitoring effort was to evaluate conditions in the river before enhanced treatment-plant technologies had effected reductions in phosphorus loads, thereby defining baseline conditions for comparison with conditions following the mandated load reductions. The locations of sampling sites with respect to the impoundments enabled examination of the impoundments’ effects on phosphorus sequestration and on the transformation of phosphorus between particulate and dissolved forms. The study evaluated the differences between loads upstream and downstream from the impoundments throughout the sampling period and compared differences during two seasonal periods of relevance to aquatic plants: April 1 through October 31, the growing season, and November 1 through March 31, the nongrowing season, when existing permit limits allowed average monthly wastewater-treatment-plant-effluent concentrations of 0.75 milligram per liter (growing season) or 1.0 milligram per liter (nongrowing season) for total phosphorus. At the four sampling sites during the growing season, median weekly total phosphorus loads ranged from 110 to 190 kilograms (kg) and median weekly orthophosphorus loads ranged from 17 to 41 kg. During the nongrowing season, median weekly total phosphorus loads ranged from 240 to 280 kg and median weekly orthophosphorus loads ranged from 56 to 66 kg. During periods of low and moderate streamflow, estimated loads of total phosphorus upstream from the Hudson impoundment generally exceeded those downstream during the same sampling periods throughout the study; orthophosphorus loads downstream from the impoundment were typically larger than those upstream. When storm runoff substantially increased the streamflow, loads of total phosphorus and orthophosphorus both tended to be larger downstream than upstream. At the Ben Smith impoundment, both total phosphorus and orthophosphorus loads were generally larger downstream than upstream during low and moderate streamflow, but the differences were not as pronounced as they were at the Hudson impoundment. High flows were also associated with substantially larger total phosphorus and orthophosphorus loads downstream than those entering the impoundment from upstream. In comparing periods of growing- and nongrowing-season loads, the same patterns of loads entering and leaving were observed at both impoundments. That is, at the Hudson impoundment, total phosphorus loads entering the impoundment were greater than those leaving it, and orthophosphorus loads leaving the impoundment were greater than those entering it. At the Ben Smith impoundment, both total phosphorus and orthophosphorus loads leaving the impoundment were greater than those entering it. However, the loads were greater during the nongrowing seasons than during the growing seasons, and the net differences between upstream and downstream loads were about the same. The results indicate that some of the particulate fraction of the total phosphorus loads is sequestered in the Hudson impoundment, where particulate phosphorus probably undergoes some physical and biogeochemical transformations to the dissolved form orthophosphorus. The orthophosphorus may be taken up by aquatic plants or transported out of the impoundments. The results for the Ben Smith impoundment are less clear and suggest net export of total phosphorus and orthophosphorus. Differences between results from the two impoundments may be attributable in part to differences in their sizes, morphology, unmonitored tributaries, riparian land use, and processes within the impoundments that have not been quantified for this study.

Massachusetts↗
USGS2012

Groundwater-quality data for a treated-wastewater plume near the Massachusetts Military Reservation, Ashumet Valley, Cape Cod, Massachusetts, 2006-08

A plume of contaminated groundwater extends from former disposal beds at the Massachusetts Military Reservation's wastewater-treatment plant toward Ashumet Pond, coastal ponds, and Vineyard Sound, Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to the rapid-infiltration beds for nearly 60 years before the disposal site was moved to a different location in December 1995. Water-quality samples were collected from monitoring wells, multilevel samplers, and profile borings to characterize the nature and extent of the contaminated groundwater and to observe the water-quality changes after the wastewater disposal ceased. Data are presented here for water samples collected in 2007 from 394 wells (at 121 well-cluster locations) and 780 multilevel-sampler ports (at 42 locations) and in 2006-08 at 306 depth intervals in profile borings (at 20 locations) in and near the treated-wastewater plume. Analyses of these water samples for field parameters (specific conductance, pH, dissolved oxygen and phosphate concentrations, and alkalinity); absorbance of ultraviolet/visible light; and concentrations of nitrous oxide, dissolved organic carbon, methylene blue active substances, selected anions and nutrients, including nitrate and ammonium, and selected inorganic solutes, including cations, anions, and minor elements, are presented in tabular format. The natural restoration of the sand and gravel aquifer after removal of the treated-wastewater source, along with interpretations of the water quality in the treated-wastewater plume, have been documented in several published reports that are listed in the references.

Massachusetts↗
USGS2012

Comparison of no-purge and pumped sampling methods for monitoring concentrations of ordnance-related compounds in groundwater, Camp Edwards, Massachusetts Military Reservation, Cape Cod, Massachusetts, 2009-2010

Field tests were conducted near the Impact Area at Camp Edwards on the Massachusetts Military Reservation, Cape Cod, Massachusetts, to determine the utility of no-purge groundwater sampling for monitoring concentrations of ordnance-related explosive compounds and perchlorate in the sand and gravel aquifer. The no-purge methods included (1) a diffusion sampler constructed of rigid porous polyethylene, (2) a diffusion sampler constructed of regenerated-cellulose membrane, and (3) a tubular grab sampler (bailer) constructed of polyethylene film. In samples from 36 monitoring wells, concentrations of perchlorate (ClO 4 - ), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), the major contaminants of concern in the Impact Area, in the no-purge samples were compared to concentrations of these compounds in samples collected by low-flow pumped sampling with dedicated bladder pumps. The monitoring wells are constructed of 2- and 2.5-inch-diameter polyvinyl chloride pipe and have approximately 5- to 10-foot-long slotted screens. The no-purge samplers were left in place for 13-64 days to ensure that ambient groundwater flow had flushed the well screen and concentrations in the screen represented water in the adjacent formation. The sampling methods were compared first in six monitoring wells. Concentrations of ClO 4 - , RDX, and HMX in water samples collected by the three no-purge sampling methods and low-flow pumped sampling were in close agreement for all six monitoring wells. There is no evidence of a systematic bias in the concentration differences among the methods on the basis of type of sampling device, type of contaminant, or order in which the no-purge samplers were tested. A subsequent examination of vertical variations in concentrations of ClO 4 - in the 10-foot-long screens of six wells by using rigid porous polyethylene diffusion samplers indicated that concentrations in a given well varied by less than 15 percent and the small variations were unlikely to affect the utility of the various sampling methods. The grab sampler was selected for additional tests in 29 of the 36 monitoring wells used during the study. Concentrations of ClO 4 - , RDX, HMX, and other minor explosive compounds in water samples collected by using a 1-liter grab sampler and low-flow pumped sampling were in close agreement in field tests in the 29 wells. A statistical analysis based on the sign test indicated that there was no bias in the concentration differences between the methods. There also was no evidence for a systematic bias in concentration differences between the methods related to location of the monitoring wells laterally or vertically in the groundwater-flow system. Field tests in five wells also demonstrated that sample collection by using a 2-liter grab sampler and sequential bailing with the 1-liter grab sampler were options for obtaining sufficient sample volume for replicate and spiked quality assurance and control samples. The evidence from the field tests supports the conclusion that diffusion sampling with the rigid porous polyethylene and regenerated-cellulose membranes and grab sampling with the polyethylene-film samplers provide comparable data on the concentrations of ordnance-related compounds in groundwater at the MMR to that obtained by low-flow pumped sampling. These sampling methods are useful methods for monitoring these compounds at the MMR and in similar hydrogeologic environments.

Massachusetts↗
USGS2006

Ground-water-quality data for a treated-wastewater plume undergoing natural restoration, Ashumet Valley, Cape Cod, Massachusetts

A plume of contaminated ground water extends from former disposal beds at the Massachusetts Military Reservation wastewater-treatment plant toward Ashumet Pond, and farther southward toward coastal ponds and Vineyard Sound, Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to the rapid-infiltration beds for nearly 60 years before the disposal site was moved to a different location in December 1995. Water-quality samples were collected periodically from monitoring wells and multilevel samplers during and after the disposal period to characterize the nature and extent of the contaminated ground water and to observe the water-quality changes after the wastewater disposal ceased. Data are presented here for water samples collected from 1994 through 2004 from 16 wells (at 2 locations) and 14 multilevel samplers (at 9 locations) along a longitudinal transect that extends through one of the disposal beds. Data collected from the treated-wastewater plume are presented in tabular format. These data include field parameters; concentrations of cations, anions, nitrate, ammonium, and organic and inorganic carbon species; and ultraviolet/visible absorbance. The natural restoration of the sand and gravel aquifer after removal of the nearly 60-year-long treated-wastewater source, along with interpretations of the water quality in the treated-wastewater plume on Cape Cod, have been documented in several published reports that are listed in the references.

Massachusetts↗
USGS2004

Changes in ground-water quality near two granular-iron permeable reactive barriers in a sand and gravel aquifer, Cape Cod, Massachusetts, 1997-2000

Two experimental permeable reactive barriers (PRBs) of granular zero-valent iron were emplaced in the path of a tetrachloroethene plume (the Chemical Spill-10 plume) at the Massachusetts Military Reservation, Cape Cod, Massachusetts, in June 1998. The goal of the field experiment was to achieve emplacement of a granular-iron PRB deeper than attempted before. The PRBs were expected to create a reducing environment and degrade the tetrachloroethene by reductive dechlorination. The goal of the work presented in this report was to observe temporary and sustained changes to the ground-water chemistry downgradient from the PRBs. A hydraulic-fracturing method involving injection of the granular iron with a guar-biopolymer and enzyme slurry was used to install the parallel 30- to 33-foot-wide wall-shaped barriers at a depth of 82 to 113 feet below land surface. An acetic acid and enzyme mixture was subsequently injected in wells near the barriers to degrade the guar biopolymer. Prior to the emplacement, tetrachloroethene concentrations in the Chemical Spill-10 plume at the study area were as high as 250 micrograms per liter. Other water properties in the plume generally were similar to the properties of uncontaminated ground water in the area, which typically has dissolved oxygen concentrations of 250 to 375 micromoles per liter, pH of 5.5 to 6.0, and specific conductance of 60 to 90 microsiemens per centimeter. Water-quality samples were collected periodically from monitoring wells near the PRBs to determine how the emplacement of the granular-iron walls altered the ground-water quality. In addition, an automated well-sampling device measured temperature, specific conductance, pH, and dissolved oxygen every 1–4 days for 16 months in a well downgradient from the two parallel PRBs. Temporary increases (lasting about 5 to 6 months) in specific conductance were observed downgradient from the PRBs as a result of the sodium chloride, potassium carbonate, and other salts included in the slurry and the acetic acid and enzyme mixture that was subsequently injected to degrade the guar biopolymer. Temporary increases in the concentrations of major cations (sodium, potassium, magnesium, and calcium) were observed downgradient from the PRBs, as were temporary but substantial increases in the dissolved and total organic carbon concentrations. Methane was detected, sulfate concentrations decreased temporarily, and concentrations of dissolved inorganic carbon increased in samples from wells downgradient from the PRBs. A sustained (longer than 12 months) reducing environment, in which dissolved oxygen concentrations decreased to zero, the pH increased to about 6.8, and dissolved iron concentrations increased substantially, developed as a result of the oxidation (corrosion) of the granular iron; this zone persisted at least 65 feet downgradient from the PRBs. The pH and dissolved iron concentrations increased with distance from the granular-iron walls. Concentrations of arsenic, cobalt, manganese, and phosphorus increased, and nitrate concentrations were reduced to below the detection limit downgradient from the walls. A sustained decrease of tetrachloroethene concentrations was not observed; however, reductive dechlorination products were observed at wells downgradient from the PRBs during several rounds of sampling. The emplacement of zero-valent iron in the aquifer to remove tetrachloroethene from the ground water caused changes in the water chemistry that persisted farther downgradient from the PRBs than has been observed at other sites because of the low chemical reactivity of the quartz-dominated aquifer sediments and the low ambient dissolved chemical concentrations in the ground water. The small transverse dispersion in the aquifer and the probable long-term persistence of the iron indicate that the chemically altered zone probably will extend a substantial distance downgradient from the PRBs for a substantial period of time (years); further investigation would be needed to determine this distance.

Massachusetts↗
USGS1999

Potential for advection of volatile organic compounds in ground water to the Cochato River, Baird & McGuire Superfund Site, Holbrook, Massachusetts, March and April 1998

In March and April 1998, a network of water-to-vapor diffusion samplers was installed along the Cochato River at the Baird & McGuire Superfund Site in Holbrook, Massachusetts, where a plume of volatile organic compounds (VOCs) is present in ground water. The purpose of installing the sampler network was to determine if VOCs were present in river-bottom sediments while a ground-water extraction system was operating and after the system had been shut down for two weeks. Water-to-water diffusion samplers placed at selected locations provided supplemental information about concentrations of VOCs in pore water in the river-bottom sediments. Water levels in piezometers and river stage were measured concurrently to determine if ground water was discharging to the river. Benzene, toluene, ethylbenzene and xylenes (BTEX compounds) were detected in water-tovapor and water-to-water diffusion samplers located in the area where the plume is known to pass beneath the river for both pumping and nonpumping conditions. Concentrations of total BTEX compounds in water-to-vapor diffusion samplers ranged from non-detect upriver and downriver from the plume area to greater than 200 parts per million by volume in the plume area. Concentrations of total BTEX compounds were not significantly different for pumping than for non-pumping conditions. Concentrations of total BTEX compounds in water-to-water diffusion samplers ranged from non-detect to 680 micrograms per liter. The limited number of water-to-water diffusion samplers did not indicate that concentrations were higher for pumping or non-pumping conditions. Trichloroethylene and tetrachloroethylene also were detected in water-to-vapor diffusion samplers downriver from the area where the BTEX compounds were detected. Water levels in four piezometers were consistently higher than the river stage, indicating an upward hydraulic gradient and ground-water discharge to the river. The concentrations of VOCs in riverbottom sediments and the upward hydraulic gradients observed indicate that contaminants from the Baird & McGuire ground-water plume were discharging to the Cochato River during the study period for both pumping and non-pumping conditions.

Massachusetts↗
USGS1997

Hydrogeologic framework of western Cape Cod, Massachusetts

The aquifer of western Cape Cod consists of several hydrogeologic units composed of sand, gravel, silt, and clay (fig. 1) that were deposited during the late Wisconsinan glaciation of New England. The aquifer is a shallow, unconfined hydrologic system in which ground-water flows radially outward from the apex of the ground-water mound near the center of the peninsula toward the coast (fig.2). The aquifer is the sole source of water supply for the towns of Bourne, Sandwich, Falmouth, and Mashpee, and the Massachusetts Military Reservation (MMR). Previous geologic studies summarized the characteristics and relative ages of the glacial moraines and meltwater deposits and the relation of these sediments to the extent of the ice-sheet lobes during the last glaciation of southern New England (Oldale and Barlow, 1986; Hartshorn and others, 1991). Hydrogeologic studies in western Cape Cod characterized the shallow regional ground-water-flow system (LeBlanc and others, 1986) and analyzed simulated responses of the aquifer to changes in hydrologic stresses (Guswa and LeBlanc, 1985; Barlow and Hess, 1993; Masterson and Barlow, 1994; and Masterson and others, 1996). Recent concerns about widespread ground-water contamination, especially from sources on the MMR, have resulted in extensive investigations to characterize the local hydrogeology of the aquifer near the MMR (ABB Environmental Services, 1992). Masterson and others (1996) illustrated the strong influence of geology on ground-water flow and the importance of characterizing the hydrogeology to predict the migration of the contaminant plumes beneath the MMR. This report, a product of a cooperative study between the National Guard Bureau and the U.S. Geological Survey (USGS), characterizes the regional hydrogeology of the western Cape Cod aquifer on the basis of surficial glacial geology previously described by Mather and others (1940) and Oldale and Barlow (1986), and presents a new analysis of the subsurface hydrogeology. The characterization of the regional hydrogeologic framework includes a detailed analysis of the glacial sediments, including deltaic and lacustrine deposits and their sedimentary facies; a structure-contour analysis of the transition between the shallow sand and gravel deposits and the underlying fine sand, silt, and clay deposits; and a summary of the relation between lithologic characteristics (grain size and stratigraphy) and empirically determined hydraulic-conductivity values.

Massachusetts↗
USGS1997

Use of particle tracking to improve numerical model calibration and to analyze ground-water flow and contaminant migration, Massachusetts Military Reservation, western Cape Cod, Massachusetts

A steady-state, three-dimensional flow model coupled with a particle-tracking algorithm was developed to assess the complex interaction of hydrogeologic conditions affecting ground-water flow and contaminant transport--including aquifer heterogeneities, hydrologic boundaries such as ponds and streams, ground-water withdrawals, and aquifer recharge to characterize the migration of contaminants emanating from beneath the Massachusetts Military Reservation, Cape Cod, Massachusetts. The known extent of contaminant plumes were used to assess the effects of changes in model input parameters on model-calculated water-table and pond altitudes, streamflow, and water-particle pathlines. Although changes in selected simulated hydrogeologic conditions resulted in minor changes in model-calculated water-table altitudes, pond altitudes, and streamflow, these changes had significant effects on the projection of model-calculated water-particle pathlines.

Water Supply Paper↗
USGS1996

Geochemical and hydrologic controls on phosphorus transport in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts

Currently (1993), about 170 kg/yr of phosphorus discharges into Ashumet Pond on Cape Cod from a plume of sewage-contaminated ground water. Phosphorus in the plume is mobile in two distinct geochemical environments--an anoxic zone containing dissolved iron and a suboxic zone containing dissolved oxygen. Phosphorus mobility in the suboxic zone is due to saturation of available sorption sites. Phosphorus loading to Ashumet Pond may increase significantly after sewage disposal is stopped due to phosphorus desorption from sediment surfaces.

Massachusetts↗
USGS1995

Geochemical and hydrologic controls on phosphorus transport in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts

The disposal of secondarily treated sewage onto rapid infiltration sand beds at the Massachusetts Military Reservation, Cape Cod, Massachusetts, has created a sewage plume in the underlying sand and gravel aquifer; the part of the\x11sewage plume that contains dissolved phosphorus extends about 2,500 feet downgradient of the sewage-disposal beds. A part of the plume that\x11contains nearly 2 milligrams per liter of phosphorus currently (1993) discharges into Ashumet Pond along about 700 feet of shoreline. The sewage plume discharges from about 59 to about 76 kilograms of phosphorus per year into the pond. Hydraulic-head measurements indicate that the north end of Ashumet Pond is a ground-water sink and an increased component of ground-water discharge and phosphorus flux into\x11the pond occurs at higher water levels. Phosphorus was mobile in ground water in two distinct geochemical environments-an anoxic zone that contains no dissolved oxygen and as much as 25\x11milligrams per liter of dissolved iron, and a more areally extensive suboxic zone that contains little or no iron, low but detectable dissolved oxygen, and as much as 12 milligrams per liter of dissolved manganese. Dissolved phosphorus is mobile in the suboxic geochemical environment because continued phosphorus loading has filled available sorption sites in the aquifer. Continued disposal of sewage since 1936 has created a large reservoir of sorbed phosphorus that is much greater than the mass of dissolved phosphorus in the ground water; the average ratio of sorbed to dissolved phosphorus in the anoxic and suboxic parts of the sewage plume were 31:1 and 155:1, respectively. Column experiments indicate that phosphorus in the anoxic core of the plume containing dissolved iron may be immobilized within 17 years by sorption and coprecipitation with new iron oxyhydroxides following the cessation of sewage disposal and the introduction of uncontaminated oxygenated ground water into the aquifer in December 1995. Residual oxygen demand associated with sorbed organic compounds and ammonia could retard the movement of oxygenated water into the aquifer. Sorbed phosphorus in the suboxic zone of the aquifer will continue to desorb into the ground water and will remain mobile in the ground water for perhaps hundreds of years. Also, the introduction of uncontaminated water into the aquifer may cause dissolved-phosphorus concentrations in the suboxic zone of the aquifer to increase sharply and remain higher than precessation levels for many years due to the desorption of loosely bound phosphorus. Data from three sampling sites, located along the eastern and western boundaries of the sewage plume and downgradient of abandoned sewage-disposal beds, indicate that ground-water mixing and phosphorus desorption may already be occurring in the aquifer in response to the introduction of uncontaminated recharge water into previously contaminated parts of the aquifer.

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